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1.发明授权Bridged clays of improved thermal stability process for their preparation and utilization as catalysts 失效具有改进的热稳定性工艺的桥接粘土，用于其制备和利用作为催化剂
公开(公告)号：US4753909A
公开(公告)日：1988-06-28
申请号：US921002
申请日：1986-10-17
申请人： Jacques Bousquet , Francois Fajula , Francois Figueras , Claude Gueguen , Abbas Mattrod-Bashi , Didier Tichit
发明人： Jacques Bousquet , Francois Fajula , Francois Figueras , Claude Gueguen , Abbas Mattrod-Bashi , Didier Tichit
IPC分类号： B01J21/16 , B01J20/16 , B01J23/10 , B01J29/04 , C01B33/26 , C01B33/40 , C09K3/00 , C10G11/04 , B01J20/12
CPC分类号： B01J29/049
摘要： There are provided clays of laminated structure bridged by metallic oxides selected from oxides of aluminum and zirconium and containing from 10 to 50% and preferably from 20 to 40% of an oxide of the metal of the group of the lanthanides, preferably of cerium. The presence of cerium improves the thermal resistance during a dry calcination or even under humid air. The clays can be used as catalysts during the conversion of hydrocarbons.
摘要翻译： 提供了由选自铝和锆的氧化物的金属氧化物桥接并且含有10至50％，优选20至40％的镧系元素，优选铈的金属的氧化物的层压结构的粘土。 铈的存在提高了干燥煅烧期间的耐热性，甚至在潮湿的空气下。 在烃转化过程中，粘土可用作催化剂。
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公开(公告)号：US4847224A
公开(公告)日：1989-07-11
申请号：US64321
申请日：1987-06-19
IPC分类号： B01J29/70 , B01J29/06 , B01J29/18 , B01J29/50 , B01J29/80 , C01B39/00 , C01B39/04 , C01B39/06 , C01B39/26 , C01B39/30 , C10G11/05
CPC分类号： B01J29/80 , C10G11/05 , B01J2229/62 , B01J29/18 , B01J29/50 , B01J29/7011 , C10G2300/70 , Y10S423/25 , Y10S423/26
摘要： The present invention concerns binary zeolitic systems comprising two zeolites A and B having different crystalline structures while having common structural units. The crystals of the zeolite A form a central core surrounded by a crown of crystals of zeolite B, the zeolites A and B being disposed concentrically and following the same longitudinal axis. These systems are formed by the introduction of a nucleation gel containing seeds of the zeolite A in a growth gel where the crystallization parameters are favorable to the crystallization of the zeolite B. The binary zeolitic systems are useful as catalysts for transforming hydrocarbons and more especially as cracking catalysts.
摘要翻译： 本发明涉及包含具有不同结晶结构的两个沸石A和B的二元沸石体系，同时具有共同的结构单元。 沸石A的晶体形成由沸石B的晶体顶部包围的中心核心，沸石A和B同心地设置并且沿着相同的纵向轴线。 这些体系通过在生长凝胶中引入含有沸石A的种子的成核凝胶形成，其中结晶参数有利于沸石B的结晶。二元沸石体系可用作转化烃的催化剂，更特别地作为 裂解催化剂。
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公开(公告)号：US4611086A
公开(公告)日：1986-09-09
申请号：US606641
申请日：1984-05-03
IPC分类号： B01J29/00 , B01J29/70 , C07B61/00 , C07C27/00 , C07C29/04 , C07C31/02 , C07C67/00 , C07C31/12 , C07C31/125
CPC分类号： C07C29/04
摘要： A process for the preparation of aliphatic alcohols by hydration of olefins in the presence of a catalyst comprising a zeolitic crystalline silicoaluminate of the offretite type. The offretite used can be natural or sythetic. Particularly convenient among the olefins are olefins of low molecular weight having up to 5 carbon atoms. The alcohols obtained are used as solvents, as bases for lubricants and as adjuvants of essences.
摘要翻译： 在催化剂存在下通过烯烃的水合制备脂肪族醇的方法，所述催化剂包含无色型沸石结晶硅铝酸盐。 所使用的漂白剂可以是天然的或合成的。 在烯烃中特别方便的是具有至多5个碳原子的低分子量烯烃。 获得的醇用作溶剂，作为润滑剂的碱和作为香精佐剂。
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4.发明授权Omega type zeolite having high thermal stability, its process of preparation and its utilization 失效具有高热稳定性的Omega型沸石，其制备方法及其应用
公开(公告)号：US4891200A
公开(公告)日：1990-01-02
申请号：US865179
申请日：1986-05-19
申请人： Francois Fajula , Francois Figueras , Latifa Moudafi , Mercedes Vera Pacheco , Serge Nicolas , Pierre Dufresne , Claude Gueguen
发明人： Francois Fajula , Francois Figueras , Latifa Moudafi , Mercedes Vera Pacheco , Serge Nicolas , Pierre Dufresne , Claude Gueguen
IPC分类号： C07B61/00 , B01J20/16 , B01J20/30 , B01J29/00 , B01J29/70 , C01B39/04 , C01B39/34 , C01B39/46 , C01B39/48 , C07C1/00 , C07C5/27 , C07C15/08 , C07C27/00 , C07C29/04 , C07C31/02 , C07C31/125 , C07C67/00
CPC分类号： C07C5/2708 , B01J29/7011 , C01B39/34 , C07C29/04 , B01J2229/26 , B01J2229/42 , Y10S423/26
摘要： This invention concerns an omega type zeolite of high thermal stability, present in the form of hexagonal prismatic monocrystals having scored or plane faces of 0.1 .mu.m in edge and 0.5 to 5 .mu.m in length, this zeolite being obtained through crystallization from a mother solution containing a silica source, alumina, metallic oxide, an organic cation and water, in which the alumina source is a crystalline aluminosilicate of which at least one part is in suspension in the mother solution. In its acid form this zeolite can be used as catalyst for hydration of olefins and isomeric change of xylenes.
摘要翻译： 本发明涉及一种具有高热稳定性的ω型沸石，以六边形棱柱形单晶形式存在，其边缘为0.1μm，平均长度为0.5-5μm，该沸石是通过母溶液结晶获得的 含有二氧化硅源，氧化铝，金属氧化物，有机阳离子和水，其中氧化铝源是其中至少一部分在母溶液中悬浮的结晶硅铝酸盐。 在其酸性形式中，该沸石可用作烯烃水合和二甲苯异构体变化的催化剂。
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公开(公告)号：US4946580A
公开(公告)日：1990-08-07
申请号：US348285
申请日：1989-05-05
CPC分类号： C10G11/05 , B01J29/80 , B01J2229/62 , B01J29/18 , B01J29/50 , B01J29/7011 , C10G2300/70
摘要： The present invention concerns binary zeolitic systems comprising two zeolites A and B having different crystalline structures while having common structural units. The crystals of the zeolite A form a central core surrounded by a crown of crystals of zeolite B, the zeolites A and B being disposed concentrically and following the same longitudinal axis. These systems are formed by the introduction of a nucleation gel containing germs of the zeolite A in a growth gel where the crystallization parameters are favorable to the crystallization of the zeolite B. The binary zeolitic systems are useful as catalysts for transforming hydrocarbons and more especially as cracking catalysts.
摘要翻译： 本发明涉及包含具有不同结晶结构的两个沸石A和B的二元沸石体系，同时具有共同的结构单元。 沸石A的晶体形成由沸石B的晶体顶部包围的中心核心，沸石A和B同心地设置并且沿着相同的纵向轴线。 这些体系通过在生长凝胶中引入含有沸石A的细菌的成核凝胶形成，其中结晶参数有利于沸石B的结晶。二元沸石体系可用作转化烃的催化剂，更特别的是用作 裂解催化剂。
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公开(公告)号：US4834961A
公开(公告)日：1989-05-30
申请号：US906017
申请日：1986-09-11
IPC分类号： C10G35/095 , B01J20/18 , B01J29/50 , C01B39/04 , C01B39/30 , C10G3/00 , C10G45/12 , C10G45/54 , C10G45/64 , C10G47/16 , C10G49/08
CPC分类号： C01B39/305 , B01J29/50 , C01B39/30 , Y02P30/20 , Y10S423/38
摘要： A crystalline alumino-silicate having a powder X-ray diffraction diagram, a specific area, and a porous volume to nitrogen corresponding to offretite, and containing at least one metal selected from the groups I, II, VI, VII, VII, rare earth group, and/or at least an ammonium or quaternary ammonium group, presenting an aspect of the crystals as observed by electron microscopy in the form of hexagonal prisms with well defined edges of a length of 0.5 to 2.5 micrometers and a width of 0.1 to 1 micrometer.
摘要翻译： 一种结晶铝硅酸盐，其具有粉末X射线衍射图，比表面积和对应于白云母的氮的多孔体积，并且含有选自I，II，VI，VII，VII，稀土的至少一种金属 基团和/或至少一个铵或季铵基团，呈现出以六边形棱镜的形式通过电子显微镜观察到的晶体的一个方面，具有良好限定的长度为0.5至2.5微米的边缘和0.1至1的宽度 千分尺
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7.发明授权Zeolite from the class of mazzite, process for its synthesis, and its use as a catalyst 失效沸石来自于mazzite类，其合成方法及其用作催化剂
公开(公告)号：US5277791A
公开(公告)日：1994-01-11
申请号：US917162
申请日：1992-07-20
IPC分类号： B01J20/18 , B01J29/06 , B01J29/70 , C01B39/04 , C01B39/06 , C01B39/24 , C01B39/30 , C01B39/34 , C01B39/46 , C01B39/48 , C10G11/05 , C10G25/03 , C10G35/095 , C10G45/64 , C10G49/08 , C01B33/34
CPC分类号： C01B39/34 , B01J29/70 , B01J29/7011 , Y10S423/26
摘要： This invention relates to a new zeolite from the class of mazzite, containing a fraction of non-exchangeable potassium cations, and also to a process for its synthesis. The crystallinity and the adsorption capacity of the protonated form of this zeolite are maintained after a prolonged hydrothermal treatment.
摘要翻译： 本发明涉及一种由一类不可交换的钾阳离子组成的一类新型沸石，也涉及一种其合成方法。 在长时间的水热处理后，保持该沸石的质子化形式的结晶度和吸附能力。
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8.发明授权Process for isomerizing normal paraffins in the presence of at least one catalyst based on a particular omega zeolite 失效基于特殊的OMEGA ZEOLITE在至少一种催化剂存在下异构化的方法
公开(公告)号：US5157198A
公开(公告)日：1992-10-20
申请号：US785192
申请日：1991-11-01
申请人： Francis Raatz , Christine Travers , Christian Marcilly , Thierry Descourieres , Francois Fajula , Francois Figueras
发明人： Francis Raatz , Christine Travers , Christian Marcilly , Thierry Descourieres , Francois Fajula , Francois Figueras
CPC分类号： B01J29/7223 , C07C5/2791 , B01J2229/22 , B01J2229/36 , B01J2229/37 , B01J2229/42
摘要： The invention relates to a process for isomerizing normal paraffins, particularly C.sub.5 -C.sub.6, in the presence of at least one catalyst based on an omega zeolite having a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 ranging from 6.5 to 80, a content by weight of sodium lower than 0.2%, crystalline parameters "a" and "c" respectively smaller than or equal to 1.814 nm and 0.760 nm, a capacity of adsorption of nitrogen, measured at 77K under a partial pressure of 0.19, higher than about 8% by weight, the catalyst also comprising at least one metal from group VIII of the periodic table of elements, preferably platinum or/and palladium.
摘要翻译： 本发明涉及一种在至少一种催化剂存在下使正构烷烃特别是C5-C6异构化的方法，该催化剂基于SiO 2 / Al 2 O 3的摩尔比为6.5至80的ω-沸石，钠的重量比低于 0.2％，分别小于或等于1.814nm和0.760nm的结晶参数“a”和“c”，在77K下在0.19Kg，高于约8％重量下测量的氮吸附容量， 催化剂还包含元素周期表第Ⅷ族中的至少一种金属，优选铂或/和钯。
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9.发明授权Zeolite from the class of mazzite, process for its synthesis, an its use as a catalyst 失效来自MAZZITE类的沸石，其合成方法，用作催化剂
公开(公告)号：US5165906A
公开(公告)日：1992-11-24
申请号：US574275
申请日：1990-08-28
IPC分类号： B01J20/18 , B01J29/06 , B01J29/70 , C01B39/04 , C01B39/06 , C01B39/24 , C01B39/30 , C01B39/34 , C01B39/46 , C01B39/48 , C10G11/05 , C10G25/03 , C10G35/095 , C10G45/64 , C10G49/08
CPC分类号： C01B39/34 , B01J29/70 , B01J29/7011 , Y10S423/26
摘要： This invention relates to a new zeolite from the class of mazzite, containing a fraction of non-exchangeable potassium cations, and also to a process for its synthesis. The crystallinity and the adsorption capacity of the protonated form of this zeolite are maintained after a prolonged hydrothermal treatment.
摘要翻译： 本发明涉及一种由一类不可交换的钾阳离子组成的一类新型沸石，也涉及一种其合成方法。 在长时间的水热处理后，保持该沸石的质子化形式的结晶度和吸附能力。
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公开(公告)号：US08541542B2
公开(公告)日：2013-09-24
申请号：US12374807
申请日：2007-07-13
CPC分类号： C08F12/08 , C08F6/006 , C08F212/08 , Y10T428/31794 , Y10T428/31804 , C08L25/00 , C08F220/06
摘要： The present invention relates to a process for reducing residuals content in a vinyl aromatic polymer, said residuals comprising essentially unpolymerized vinyl aromatic monomer, wherein the vinyl aromatic polymer in the molten state is brought in contact with a solid in powder capable to catalyze the alkylation of said residual vinyl aromatic monomer on the vinyl aromatic polymer. Advantage of the present invention is a sharp reduction of the unpolymerized vinyl aromatic monomer in the vinyl aromatic polymer without generating a new residual and without inducing a colored vinyl aromatic polymer. The present invention also relates to said vinyl aromatic polymer having a low residuals content.
摘要翻译： 本发明涉及一种减少乙烯基芳族聚合物中残留物含量的方法，所述残余物包含基本上未聚合的乙烯基芳族单体，其中熔融状态的乙烯基芳族聚合物与能够催化烷基化的粉末中的固体接触 所述乙烯基芳族聚合物上的所述残余乙烯基芳族单体。 本发明的优点是在乙烯基芳族聚合物中未聚合的乙烯基芳族单体的急剧减少，而不会产生新的残留物并且不引起着色的乙烯基芳族聚合物。 本发明还涉及具有低残留含量的所述乙烯基芳族聚合物。
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