公开(公告)号：US06961508B2

公开(公告)日：2005-11-01

申请号：US10421946

申请日：2003-04-24

申请人： Jan van Eekelen ,  Sandra Nagelvoort ,  Duurt Alkema ,  Paul Buijsen ,  Huimin Cao ,  Robert W. Johnson ,  David M. Szum

发明人： Jan van Eekelen ,  Sandra Nagelvoort ,  Duurt Alkema ,  Paul Buijsen ,  Huimin Cao ,  Robert W. Johnson ,  David M. Szum

IPC分类号： G02B6/44 ,  C03C25/10 ,  C03C25/24 ,  C08F2/48 ,  C08G18/48 ,  C08G18/67 ,  C09D175/16 ,  C09J175/16 ,  G02B6/02 ,  G02B6/036 ,  G02B6/00 ,  G02B6/10

CPC分类号： C09J175/16 ,  C03C25/1065 ,  C08G18/4854 ,  C08G18/672 ,  C09D175/16 ,  G02B6/02395 ,  Y10S525/932 ,  C08G18/40 ,  C08G18/48

摘要： A coated optical fiber can have a primary coating and a secondary coating, where the primary coating can have good microbending resistance and is obtained by curing a composition having a high cure speed. In one example, a coated optical fiber can include as optical fiber, a primary coating and a secondary coating. The optical fiber can have an attenuation increase of less than 0.650 dB/km at 1550 nm, with the primary coating having a modulus retention ratio of at least 0.5, a glass transition temperature of −35° C., and where the primary coating is obtained by curing a primary coating composition having a cure dose to attain 95% of the maximum attainable modulus of less than 0.65 J/cm2.

摘要翻译： 涂覆光纤可以具有初级涂层和二次涂层，其中初级涂层可以具有良好的抗微弯曲性，并且通过固化具有高固化速度的组合物获得。 在一个示例中，涂覆的光纤可以包括作为光纤，初级涂层和二次涂层。 光纤可以在1550nm处具有小于0.650dB / km的衰减增加，其中初级涂层的模量保持率至少为0.5，玻璃化转变温度为-35℃，其中初级涂层为 其通过固化具有固化剂量的初级涂料组合物获得小于0.65J / cm 2的最大可获得模量的95％。

公开(公告)号：US07171103B2

公开(公告)日：2007-01-30

申请号：US11240397

申请日：2005-10-03

申请人： Jan van Eekelen ,  Sandra Nagelvoort ,  Duurt Alkema ,  Paul Buijsen ,  Huimin Cao ,  Robert W. Johnson ,  David M. Szum

发明人： Jan van Eekelen ,  Sandra Nagelvoort ,  Duurt Alkema ,  Paul Buijsen ,  Huimin Cao ,  Robert W. Johnson ,  David M. Szum

IPC分类号： G02B6/00 ,  G02B6/02 ,  G02B6/22

CPC分类号： C09J175/16 ,  C03C25/1065 ,  C08G18/4854 ,  C08G18/672 ,  C09D175/16 ,  G02B6/02395 ,  Y10S525/932 ,  C08G18/40 ,  C08G18/48

摘要： A coated optical fiber can have a primary coating and a secondary coating, where the primary coating can have good microbending resistance and is obtained by curing a composition having a high cure speed. In one example, a coated optical fiber can include as optical fiber, a primary coating and a secondary coating. The optical fiber can have an attenuation increase of less than 0.650 dB/km at 1550 nm, with the primary coating having a modulus retention ratio of at least 0.5, a glass transition temperature of −35° C., and where the primary coating is obtained by curing a primary coating composition having a cure dose to attain 95% of the maximum attainable modulus of less than 0.65 J/cm2.

摘要翻译： 涂覆光纤可以具有初级涂层和二次涂层，其中初级涂层可以具有良好的抗微弯曲性，并且通过固化具有高固化速度的组合物获得。 在一个示例中，涂覆的光纤可以包括作为光纤，初级涂层和二次涂层。 光纤可以在1550nm处具有小于0.650dB / km的衰减增加，其中初级涂层的模量保持率至少为0.5，玻璃化转变温度为-35℃，其中初级涂层为 其通过固化具有固化剂量的初级涂料组合物获得小于0.65J / cm 2的最大可获得模量的95％。

公开(公告)号：US6080483A

公开(公告)日：2000-06-27

申请号：US891450

申请日：1997-07-10

申请人： David M. Szum ,  Timothy E. Bishop ,  Steven R. Schmid

发明人： David M. Szum ,  Timothy E. Bishop ,  Steven R. Schmid

IPC分类号： G02B6/44 ,  C03C25/10 ,  C03C25/24 ,  C08F2/48 ,  C08G18/67 ,  C09D175/16 ,  G02B6/02 ,  C08F2/50 ,  C08L75/08 ,  C08L75/16

CPC分类号： C09D175/16 ,  C03C25/106 ,  C03C25/1065 ,  C08G18/672 ,  Y10T428/2938

摘要： Provided is a radiation-curable, glass optical fiber coating composition which when suitably cured exhibits resistance to attack from hydrocarbon gel cable filing material. The composition containsabout 10 to about 90% by weight of a first radiation-curable oligomer;from 0 to about 40% by weight of a reactive diluent;from 0 to about 40% by weight of a photoinitiator;from 0 to about 10% by weight of a pigment; andabout 10 to about 90% by weight of a second radiation-curable oligomer according to the following formula:R.sup.1 -L.sup.1 -C.sup.1 -L.sup.2 -R.sup.2 (1)where:R.sup.1 and R.sup.2, independently, each represent a radiation-curable functional group;L.sup.1 and L.sup.2, independently, each represent an alkyleneoxy chain having from about 2 to about 40 carbon atoms, wherein L.sup.1 and L.sup.2 are linked to C.sup.1 through an oxygen atomC.sup.1 comprises a hydrocarbon having from about 5 to about 40 carbon atoms and containing at least one cyclic group.

摘要翻译： 提供了一种可辐射固化的玻璃光纤涂层组合物，其在适当固化时表现出抗烃凝胶电缆填料的抗性。 该组合物含有约10至约90重量％的第一可辐射固化的低聚物; 0至约40重量％的反应性稀释剂; 0至约40重量％的光引发剂; 0至约10重量％的颜料; 和约10至约90重量％的根据下式的第二可辐射固化低聚物：R1-L1-C1-L2-R2（1）其中：R1和R2各自表示可辐射固化的官能团 ; L1和L2各自独立地表示具有约2至约40个碳原子的亚烷基氧基，其中L1和L2通过氧原子连接到C1包括具有约5至约40个碳原子的烃并且至少包含 一个循环组。

公开(公告)号：US5595820A

公开(公告)日：1997-01-21

申请号：US484650

申请日：1995-06-07

申请人： David M. Szum

发明人： David M. Szum

IPC分类号： G02B6/44 ,  C03C17/30 ,  C03C25/10 ,  C03C25/24 ,  C03C25/40 ,  C09D4/02 ,  C09D175/14 ,  C09D175/16 ,  C09D183/04 ,  D02G3/00 ,  B32B9/04

CPC分类号： C03C25/106 ,  C03C17/30 ,  C03C25/40 ,  Y10T428/2938 ,  Y10T428/31612 ,  Y10T428/31663

摘要： This invention provides an improved coating composition for glass substrates that comprises a poly(siloxane). The introduction of a poly(siloxane) in a coating composition for a glass substrate, and in particular an optical fiber, acts to delay the rate of deterioration of the glass or optical fiber due to moisture, and improves adhesion between the glass substrate and the coating composition. The introduction of a poly(siloxane) into a polymeric coating composition also improves the interlayer adhesion when more than one coating is applied to a glass substrate. This invention also provides an improved coated glass substrate having a decreased rate of deterioration due to moisture, improved adhesion between the glass substrate and the coating composition and between the various coatings, wherein the coating composition comprises a poly(siloxane).

摘要翻译： 本发明提供了一种改进的包含聚（硅氧烷）的玻璃基底涂料组合物。 在玻璃基板，特别是光纤的涂料组合物中引入聚（硅氧烷），其作用是延迟玻璃或光纤由于水分导致的劣化速率，并提高玻璃基板与玻璃基板之间的粘合性 涂料组合物。 当聚合物（硅氧烷）引入聚合物涂料组合物时，当将多于一种涂层施加到玻璃基底上时也可以改善层间粘合性。 本发明还提供了一种改进的涂层玻璃基材，其具有由于水分降低的劣化速率，玻璃基材和涂料组合物之间以及各种涂料之间的粘合性改善，其中涂料组合物包含聚（硅氧烷）。

公开(公告)号：US5384342A

公开(公告)日：1995-01-24

申请号：US113997

申请日：1993-08-30

申请人： David M. Szum

发明人： David M. Szum

IPC分类号： C03C17/32 ,  C03C25/10 ,  C03C25/38 ,  C03C25/40 ,  C07F7/18 ,  C07F7/28 ,  C08K5/5465 ,  C09D4/00 ,  C09D4/02 ,  C07F7/04 ,  C07F7/10 ,  B32B17/02 ,  C09J201/10

CPC分类号： C08K5/5465 ,  C03C17/32 ,  C03C25/106 ,  C03C25/38 ,  C03C25/40 ,  C07F7/182 ,  C07F7/1836 ,  C07F7/184 ,  C09D4/00 ,  Y10T428/2938 ,  Y10T428/31612 ,  Y10T428/31663

摘要： The present invention is directed to a compound of the Formula:R.sub.1 --R.sub.2 --R.sub.3 --R.sub.4 --A--(R.sub.5).sub.n (R.sub.6).sub.3-nwherein: A is Si or Ti; R.sub.1 is an alkenoxy, acryloxy or ethylenically unsaturated dicarboxylate group; R.sub.2 is a 2 to 18 carbon linear, branched or cyclo alkyl, alkenyl, alkynyl, acyl, aryl or poly(alkoxy) group; R.sub.3 contains a urethane, urea, or thiourethane linkage; R.sub.4 is a 2 to 18 carbon linear, branched, or cyclic alkyl, alkenyl, alkynyl, aryl or acyl non-hydrolyzable silyl linking group; R.sub.5 is a 2 to 18 carbon linear, branched, or cyclic alkyl, alkenyl, alkynyl, aryl or acyl group; R.sub.6 is any hydrolyzable silyl linking group (alkoxy, alkenoxy, or halogen); and n is 0 to 2.The present invention is further directed to an improved method of using of a compound of the above Formula as an adhesion promoter in a UV-curable composition for a surface with a free nucleophilic group. Preferably, that surface is glass.The present invention is yet further directed to an improved UV-curable coating composition, wherein the improvement comprises adding to said coating composition a compound of the above formula in an amount sufficient to promote adhesion of a coating to a surface with a free nucleophilic group.

摘要翻译： 本发明涉及式：R1-R2-R3-R4-A-（R5）n（R6）3-n的化合物，其中：A是Si或Ti; R1是烯氧基，丙烯酰氧基或烯属不饱和二羧酸酯基; R2是2至18个碳直链，支链或环烷基，烯基，炔基，酰基，芳基或聚（烷氧基）基团; R3含有氨基甲酸酯，尿素或硫代氨基甲酸酯键; R4是2至18个碳直链，支链或环状的烷基，烯基，炔基，芳基或酰基不可水解的甲硅烷基连接基团; R5是2至18个碳直链，支链或环状的烷基，烯基，炔基，芳基或酰基; R6是任何可水解的甲硅烷基连接基团（烷氧基，烯氧基或卤素）; n为0〜2。本发明还涉及使用上述式的化合物作为具有游离亲核基团的表面的UV固化性组合物中的粘合促进剂的改进方法。 优选地，该表面是玻璃。 本发明还涉及改进的可UV固化涂料组合物，其中改进包括向所述涂料组合物中加入足以促进涂料与游离亲核基团粘合到表面上的量的上式化合物。

公开(公告)号：US06680118B2

公开(公告)日：2004-01-20

申请号：US10084660

申请日：2002-02-28

申请人： David M. Szum ,  Kevin P. Murray ,  John M. Zimmerman

发明人： David M. Szum ,  Kevin P. Murray ,  John M. Zimmerman

IPC分类号： D02G300

CPC分类号： C09D175/16 ,  C08G18/5015 ,  C08G18/672 ,  C08G65/007 ,  C08G65/2609 ,  Y10T428/2913 ,  Y10T428/2933 ,  Y10T428/2971 ,  Y10T428/3154 ,  Y10T428/31551 ,  Y10T428/31573 ,  C08G18/50

摘要： A radiation-curable composition is disclosed. An fluorinated oligomer is combined with a diluent monomer and a photoinitiator to form the radiation-curable coating composition. The fluorinated oligomer is substantially free of isocyanate groups. The radiation-curable compositions provide a suitable coating for substrates, are resistant to penetration by water and liquid hydrocarbons, retain their physical properties over a wide temperature range and exhibit immeasurably low surface friction properties.

摘要翻译： 公开了可辐射固化的组合物。 将氟化低聚物与稀释剂单体和光引发剂组合以形成可辐射固化的涂料组合物。 氟化低聚物基本上不含异氰酸酯基团。 可辐射固化组合物为基材提供了合适的涂层，耐水和液态烃的渗透，在宽的温度范围内保持其物理性能，并表现出不可估量的低表面摩擦性能。

公开(公告)号：US06472450B2

公开(公告)日：2002-10-29

申请号：US09479873

申请日：2000-01-10

申请人： David M. Szum ,  Timothy E. Bishop ,  Steven R. Schmid

发明人： David M. Szum ,  Timothy E. Bishop ,  Steven R. Schmid

IPC分类号： G02B602

CPC分类号： C09D175/16 ,  C03C25/106 ,  C03C25/1065 ,  C08G18/672 ,  Y10T428/2938 ,  C08G18/48

摘要： Provided is a radiation-curable, glass optical fiber coating composition which when suitably cured exhibits resistance to attack from hydrocarbon gel cable filing material. The composition contains about 10 to about 90% by weight of a first radiation-curable oligomer; from 0 to about 40% by weight of a reactive diluent; from 0 to about 40% by weight of a photoinitiator; from 0 to about 10% by weight of a pigment; and about 10 to about 90% by weight of a second radiation-curable oligomer according to the following formula: R1-L1-C1-L2-R2  (1) where: R1 and R2, independently, each represent a radiation-curable functional group; L1 and L2, independently, each represent an an alkyleneoxy chain having from about 2 to about 40 carbon atoms, wherein L1 and L2 are linked to C1 through an oxygen atom C1 comprises a hydrocarbon having from about 5 to about 40 carbon atoms and containing at least one cyclic group.

摘要翻译： 提供了一种可辐射固化的玻璃光纤涂层组合物，其在适当固化时表现出抗烃凝胶电缆填料的抗性。 组合物含有10至约90重量％的第一可辐射固化低聚物; 0至约40重量％的反应性稀释剂; 0至约40重量％的光引发剂; 0至约10重量％ 颜料的重量; 和约10至约90重量％的根据下式的第二可辐射固化低聚物：其中：R 1和R 2各自独立地表示可辐射固化的官能团; L 1和L 2独立地表示亚烷氧基链 具有约2至约40个碳原子，其中L1和L2通过氧原子C1与C1连接，包括具有约5至约40个碳原子并含有至少一个环状基团的烃。

公开(公告)号：US06298189B1

公开(公告)日：2001-10-02

申请号：US09035771

申请日：1998-03-06

申请人： David M. Szum ,  Chander P. Chawla ,  James R. Petisce ,  John T. Vandeberg ,  George Pasternack ,  Timothy E. Bishop ,  Paul E. Snowwhite ,  Edward P. Zahora ,  Stephen C. Lapin

发明人： David M. Szum ,  Chander P. Chawla ,  James R. Petisce ,  John T. Vandeberg ,  George Pasternack ,  Timothy E. Bishop ,  Paul E. Snowwhite ,  Edward P. Zahora ,  Stephen C. Lapin

IPC分类号： G02B622

CPC分类号： C03C25/1065

摘要： Optical fiber coatings are disclosed having excellent ribbon stripping and adhesion behavior. The coatings are radiation-curable. The excellent stripping and adhesion behavior can be achieved by several means which include by use of additives, by use of radiation-curable oligomers having higher molecular weight, or by use of coatings having certain thermal properties. Combination of means can be employed. Stripping behavior can be measured by crack propagation and fiber friction measurements.

摘要翻译： 公开了具有优异的带剥离和粘合行为的光纤涂层。 涂层是可辐射固化的。 通过使用添加剂，通过使用具有较高分子量的可辐射固化的低聚物，或通过使用具有某些热性质的涂层，可以通过几种方式实现优异的剥离和粘合行为。 可以组合手段。 剥离行为可以通过裂纹扩展和纤维摩擦测量来测量。

公开(公告)号：US06187835B1

公开(公告)日：2001-02-13

申请号：US09099198

申请日：1998-06-18

申请人： David M. Szum ,  Chander P. Chawla ,  Timothy E. Bishop

发明人： David M. Szum ,  Chander P. Chawla ,  Timothy E. Bishop

IPC分类号： C08F248

CPC分类号： C03C25/1065 ,  C03C25/106 ,  C09D4/06 ,  Y10T428/2933 ,  Y10T428/2938 ,  Y10T428/31645 ,  C08F290/06

摘要： Radiation-curable inner and outer primary optical fiber coatings are disclosed having both fast cure speed and reduced rates of yellowing. The compositions comprise particular photoinitiators and UV absorbers which are used in amounts to provide the combination of properties. The UV absorber can have ethylenic unsaturation. Outer primary coatings can be formulated to screen inner primary coatings and have fast cure speed.

摘要翻译： 公开了可辐射固化的内部和外部初级光纤涂层，其具有快速固化速度和降低的黄化速率。 组合物包含特定的光引发剂和UV吸收剂，其量用于提供性质的组合。 紫外线吸收剂可具有烯属不饱和键。 外部初级涂层可以配制成筛分内部初级涂层并具有快速固化速度。

公开(公告)号：US5502145A

公开(公告)日：1996-03-26

申请号：US204993

申请日：1994-03-02

申请人： David M. Szum

发明人： David M. Szum

IPC分类号： G02B6/44 ,  C03C17/30 ,  C03C25/10 ,  C03C25/24 ,  C03C25/40 ,  C09D4/02 ,  C09D175/14 ,  C09D175/16 ,  C09D183/04 ,  C08G77/04 ,  C08L75/16 ,  C08L83/06

CPC分类号： C03C25/106 ,  C03C17/30 ,  C03C25/40 ,  Y10T428/2938 ,  Y10T428/31612 ,  Y10T428/31663

摘要： This invention provides an improved coating composition for glass substrates that comprises a poly(siloxane). The introduction of a poly(siloxane) in a coating composition for a glass substrate, and in particular an optical fiber, acts to delay the rate of deterioration of the glass or optical fiber due to moisture, and improves adhesion between the glass substrate and the coating composition. The introduction of a poly(siloxane) into a polymeric coating composition also improves the interlayer adhesion when more than one coating is applied to a glass substrate. This invention also provides an improved coated glass substrate having a decreased rate of deterioration due to moisture, improved adhesion between the glass substrate and the coating composition and between the various coatings, wherein the coating composition comprises a poly(siloxane).

摘要翻译： 本发明提供了一种改进的包含聚（硅氧烷）的玻璃基底涂料组合物。 在玻璃基板，特别是光纤的涂料组合物中引入聚（硅氧烷），其作用是延迟玻璃或光纤由于水分导致的劣化速率，并提高玻璃基板与玻璃基板之间的粘合性 涂料组合物。 当聚合物（硅氧烷）引入聚合物涂料组合物时，当将多于一种涂层施加到玻璃基底上时也可以改善层间粘合性。 本发明还提供了一种改进的涂层玻璃基材，其具有由于水分降低的劣化速率，玻璃基材和涂料组合物之间以及各种涂料之间的粘合性改善，其中涂料组合物包含聚（硅氧烷）。