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公开(公告)号：US08431642B2
公开(公告)日：2013-04-30
申请号：US12472022
申请日：2009-05-26
申请人： Jean M. Tancrede , Christopher L. Curry , David R. Johnsrud , George Rodriguez , Fran A. Shipley
发明人： Jean M. Tancrede , Christopher L. Curry , David R. Johnsrud , George Rodriguez , Fran A. Shipley
IPC分类号： D21H19/18
CPC分类号： C09J123/10 , C08L23/06 , C08L2666/06
摘要： Provided are adhesive compositions composed of a polyolefin composition comprising at least about 50 wt. % polypropylene and at least one wax. The polymer compositions have a Dot T-Peel of about 1 Newton or more, a branching index (g′) of 0.95 or less measured at the Mz of the polymer, a molecular weight of 100,000 or less, and the adhesive compositions has a fast set time. The packaging industry desires adhesive compositions having a fast set time, such as those setting in less than five seconds from a molten state at conventional packaging operating temperatures to a solid or quasi solid having favorable Dot T-Peel, set time, and or fiber tear adhesion properties. Polymer based adhesives performing within this window are a favorable alternative to conventional formulated adhesives. The provided adhesive compositions exhibit a favorable balance of properties such as high adhesive strength, wide temperature operating window, and fast set time.
摘要翻译： 提供了由聚烯烃组合物组成的粘合剂组合物，其包含至少约50wt。 ％聚丙烯和至少一种蜡。 聚合物组合物具有约1牛顿或更多的点T皮，在聚合物的Mz下测量的支化指数（g'）为0.95或更小，分子量为100,000或更小，并且粘合剂组合物具有快速 设置时间。 包装工业希望具有快速固化时间的粘合剂组合物，例如在常规包装操作温度下从熔融状态设定在不到5秒钟的固态或准固体，具有有利的点T-Peel，凝固时间和/或纤维撕裂 粘附性能。 在该窗口内执行的基于聚合物的粘合剂是常规配制粘合剂的有利替代。 所提供的粘合剂组合物表现出良好的性能平衡，例如高粘合强度，宽温度操作窗口和快速凝固时间。
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公开(公告)号：US20090306281A1
公开(公告)日：2009-12-10
申请号：US12472022
申请日：2009-05-26
申请人： Jean M. Tancrede , Christopher L. Curry , David R. Johnsrud , George Rodriguez , Fran A. Shipley
发明人： Jean M. Tancrede , Christopher L. Curry , David R. Johnsrud , George Rodriguez , Fran A. Shipley
CPC分类号： C09J123/10 , C08L23/06 , C08L2666/06
摘要： Provided are adhesive compositions composed of a polyolefin composition comprising at least about 50 wt. % polypropylene and at least one wax. The polymer compositions have a Dot T-Peel of about 1 Newton or more, a branching index (g′) of 0.95 or less measured at the Mz of the polymer, a molecular weight of 100,000 or less, and the adhesive compositions has a fast set time. The packaging industry desires adhesive compositions having a fast set time, such as those setting in less than five seconds from a molten state at conventional packaging operating temperatures to a solid or quasi solid having favorable Dot T-Peel, set time, and or fiber tear adhesion properties. Polymer based adhesives performing within this window are a favorable alternative to conventional formulated adhesives. The provided adhesive compositions exhibit a favorable balance of properties such as high adhesive strength, wide temperature operating window, and fast set time.
摘要翻译： 提供了由聚烯烃组合物组成的粘合剂组合物，其包含至少约50wt。 ％聚丙烯和至少一种蜡。 聚合物组合物具有约1牛顿或更多的点T皮，在聚合物的Mz下测量的支化指数（g'）为0.95或更小，分子量为100,000或更小，并且粘合剂组合物具有快速 设置时间。 包装工业希望具有快速固化时间的粘合剂组合物，例如在常规包装操作温度下从熔融状态设定在不到5秒钟的固态或准固体，具有有利的点T-Peel，凝固时间和/或纤维撕裂 粘附性能。 在该窗口内执行的基于聚合物的粘合剂是常规配制粘合剂的有利替代。 所提供的粘合剂组合物表现出良好的性能平衡，例如高粘合强度，宽温度操作窗口和快速凝固时间。
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公开(公告)号：US20100132886A1
公开(公告)日：2010-06-03
申请号：US12634222
申请日：2009-12-09
申请人： George Rodriguez , Fran A. Shipley , Peijun Jiang
发明人： George Rodriguez , Fran A. Shipley , Peijun Jiang
CPC分类号： C09J123/14 , C08L23/06 , C08L51/06 , C08L91/06 , C08L2205/02 , C08L2205/03 , C08L2666/02
摘要： An adhesive and method for hot melt adhesive application. The adhesive comprises polyolefin base polymer and from 1 to 15 wt % of a at least two wax components, based on the total weight of the polyolefin base polymer and the at least two wax components, wherein the at least two wax components comprise a first wax component having a relatively low weight average molecular weight at least 1000 g/mole less than a second wax component having a relatively high weight average molecular weight. The adhesive may have at least 50% fiber tear at 25° C., and a characteristic set time of less than 3 seconds. The adhesive may also include from 1 to 10 wt % of at least one functionalized polyolefin.
摘要翻译： 一种用于热熔胶应用的粘合剂和方法。 基于聚烯烃基础聚合物和至少两种蜡组分的总重量，粘合剂包含聚烯烃基聚合物和1至15重量％的至少两种蜡组分，其中至少两种蜡组分包含第一蜡 组分具有比具有相对高的重均分子量的第二蜡组分相对较低的重均分子量至少1000g / mol。 粘合剂在25℃下可能具有至少50％的纤维撕裂，并且特征设定时间小于3秒。 粘合剂还可以包含1至10重量％的至少一种官能化聚烯烃。
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公开(公告)号：US08242198B2
公开(公告)日：2012-08-14
申请号：US12616637
申请日：2009-11-11
申请人： Peijun Jiang , George Rodriguez , Fran A. Shipley , Aspy K. Mehta
发明人： Peijun Jiang , George Rodriguez , Fran A. Shipley , Aspy K. Mehta
IPC分类号： D21H19/18
CPC分类号： C09J5/06 , C08L23/02 , C08L23/06 , C08L51/003 , C08L51/06 , C08L91/06 , C08L2666/02 , C09J123/142
摘要： An adhesive and method for hot melt application. The adhesive comprises polyolefin base polymer, from 1 to 10 wt % of at least one functionalized polyolefin, and from 1 to 15 wt % of a wax, based on the total weight of the polyolefin base polymer, functionalized polyolefin and wax, wherein the wax has a weight average molecular weight at least 8% of the weight average molecular weight of the polyolefin base polymer, viscosity at 190° C. of 60 mPa·s or more, and a crystallization temperature greater than the polyolefin base polymer and greater than 100° C., and wherein the adhesive has at least 5% fiber tear at 2° C., at least 50% fiber tear at 25° C., and a characteristic set time of less than 3 seconds.
摘要翻译： 一种用于热熔胶应用的粘合剂和方法。 基于聚烯烃基础聚合物，官能化聚烯烃和蜡的总重量，粘合剂包括聚烯烃基聚合物，1至10重量％的至少一种官能化聚烯烃和1至15重量％的蜡，其中蜡 重均分子量为聚烯烃基聚合物的重均分子量的至少8％，190℃下的粘度为60mPa·s以上，结晶温度大于聚烯烃基聚合物，大于100 ℃，并且其中粘合剂在2℃下具有至少5％的纤维撕裂，在25℃下至少50％的纤维撕裂，以及小于3秒的特征设定时间。
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公开(公告)号：US20100305259A1
公开(公告)日：2010-12-02
申请号：US12761531
申请日：2010-04-16
CPC分类号： C09J123/10 , C08L23/0853 , C08L23/0869 , C08L51/06 , C08L91/06 , C08L2666/02 , C09J123/14
摘要： The packaging industry desires adhesive compositions having a fast set time, such as those setting in less than five seconds from a molten state at conventional packaging operating temperatures to a solid or quasi solid having favorable Dot T-Peel, set time, and/or fiber tear adhesion properties. Polymer based adhesives performing within this window are a favorable alternative to conventional formulated adhesives. The provided adhesive compositions exhibit a favorable balance of properties such as high adhesive strength, wide temperature operating window, and fast set time. Provided are adhesive compositions composed of a polyolefin composition comprising at least about 50 mol % polypropylene, at least one wax and at least one wax modifier.
摘要翻译： 包装工业期望具有快速固化时间的粘合剂组合物，例如在常规包装操作温度下从熔融状态设置到具有有利的点T-Peel，凝固时间和/或纤维的固体或准固体的不到5秒钟的粘合剂组合物 撕裂粘合性能。 在该窗口内执行的基于聚合物的粘合剂是常规配制粘合剂的有利替代。 所提供的粘合剂组合物表现出良好的性能平衡，例如高粘合强度，宽温度操作窗口和快速凝固时间。 提供由包含至少约50mol％聚丙烯，至少一种蜡和至少一种蜡改性剂的聚烯烃组合物组成的粘合剂组合物。
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公开(公告)号：US20100059178A1
公开(公告)日：2010-03-11
申请号：US12616637
申请日：2009-11-11
申请人： Peijun Jiang , George Rodriguez , Fran A. Shipley , Aspy K. Mehta
发明人： Peijun Jiang , George Rodriguez , Fran A. Shipley , Aspy K. Mehta
CPC分类号： C09J5/06 , C08L23/02 , C08L23/06 , C08L51/003 , C08L51/06 , C08L91/06 , C08L2666/02 , C09J123/142
摘要： An adhesive and method for hot melt application. The adhesive comprises polyolefin base polymer, from 1 to 10 wt % of at least one functionalized polyolefin, and from 1 to 15 wt % of a wax, based on the total weight of the polyolefin base polymer, functionalized polyolefin and wax, wherein the wax has a weight average molecular weight at least 8% of the weight average molecular weight of the polyolefin base polymer, viscosity at 190° C. of 60 mPa·s or more, and a crystallization temperature greater than the polyolefin base polymer and greater than 100° C., and wherein the adhesive has at least 5% fiber tear at 2° C., at least 50% fiber tear at 25° C., and a characteristic set time of less than 3 seconds.
摘要翻译： 一种用于热熔胶应用的粘合剂和方法。 基于聚烯烃基础聚合物，官能化聚烯烃和蜡的总重量，粘合剂包括聚烯烃基聚合物，1至10重量％的至少一种官能化聚烯烃和1至15重量％的蜡，其中蜡 重均分子量为聚烯烃基聚合物的重均分子量的至少8％，190℃下的粘度为60mPa·s以上，结晶温度大于聚烯烃基聚合物，大于100 ℃，并且其中粘合剂在2℃下具有至少5％的纤维撕裂，在25℃下至少50％的纤维撕裂，以及小于3秒的特征设定时间。
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公开(公告)号：US08431643B2
公开(公告)日：2013-04-30
申请号：US12761531
申请日：2010-04-16
IPC分类号： D21H19/18
CPC分类号： C09J123/10 , C08L23/0853 , C08L23/0869 , C08L51/06 , C08L91/06 , C08L2666/02 , C09J123/14
摘要： The packaging industry desires adhesive compositions having a fast set time, such as those setting in less than five seconds from a molten state at conventional packaging operating temperatures to a solid or quasi solid having favorable Dot T-Peel, set time, and/or fiber tear adhesion properties. Polymer based adhesives performing within this window are a favorable alternative to conventional formulated adhesives. The provided adhesive compositions exhibit a favorable balance of properties such as high adhesive strength, wide temperature operating window, and fast set time. Provided are adhesive compositions composed of a polyolefin composition comprising at least about 50 mol % polypropylene, at least one wax and at least one wax modifier.
摘要翻译： 包装工业期望具有快速固化时间的粘合剂组合物，例如在常规包装操作温度下从熔融状态设置到具有有利的点T-Peel，凝固时间和/或纤维的固体或准固体的不到5秒钟的粘合剂组合物 撕裂粘合性能。 在该窗口内执行的基于聚合物的粘合剂是常规配制粘合剂的有利替代。 所提供的粘合剂组合物表现出良好的性能平衡，例如高粘合强度，宽温度操作窗口和快速凝固时间。 提供由包含至少约50mol％聚丙烯，至少一种蜡和至少一种蜡改性剂的聚烯烃组合物组成的粘合剂组合物。
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公开(公告)号：US08283400B2
公开(公告)日：2012-10-09
申请号：US12634222
申请日：2009-12-09
申请人： George Rodriguez , Fran A. Shipley , Peijun Jiang
发明人： George Rodriguez , Fran A. Shipley , Peijun Jiang
IPC分类号： D21H19/18
CPC分类号： C09J123/14 , C08L23/06 , C08L51/06 , C08L91/06 , C08L2205/02 , C08L2205/03 , C08L2666/02
摘要： An adhesive and method for hot melt adhesive application. The adhesive comprises polyolefin base polymer and from 1 to 15 wt % of a at least two wax components, based on the total weight of the polyolefin base polymer and the at least two wax components, wherein the at least two wax components comprise a first wax component having a relatively low weight average molecular weight at least 1000 g/mole less than a second wax component having a relatively high weight average molecular weight. The adhesive may have at least 50% fiber tear at 25° C., and a characteristic set time of less than 3 seconds. The adhesive may also include from 1 to 10 wt % of at least one functionalized polyolefin.
摘要翻译： 一种用于热熔胶应用的粘合剂和方法。 基于聚烯烃基础聚合物和至少两种蜡组分的总重量，粘合剂包含聚烯烃基聚合物和1至15重量％的至少两种蜡组分，其中至少两种蜡组分包含第一蜡 组分具有比具有相对高的重均分子量的第二蜡组分相对较低的重均分子量至少1000g / mol。 粘合剂在25℃下可能具有至少50％的纤维撕裂，并且特征设定时间小于3秒。 粘合剂还可以包含1至10重量％的至少一种官能化聚烯烃。
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公开(公告)号：US06710008B2
公开(公告)日：2004-03-23
申请号：US10052058
申请日：2002-01-17
IPC分类号： B01J27182
CPC分类号： B01J37/0009 , B01J29/83 , B01J29/85 , B01J29/90 , B01J35/023 , B01J35/10 , B01J37/0045 , B01J37/10 , B01J2229/26 , B01J2229/42 , C07C1/20 , C07C2529/85 , C10G3/49 , C10G2400/20 , C10G2400/22 , Y02P20/584 , Y02P30/20
摘要： Disclosed is a method for making molecular sieve catalyst particles. Dried molecular sieve catalyst particles are used to make the catalyst. The dried molecular sieve catalyst particles are put into an aqueous solution and stirred to make a slurry. The slurry is dried to make the molecular sieve catalyst particles. Optionally, the dried molecular sieve catalyst particles made from the slurry are calcined.
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公开(公告)号：US07358412B2
公开(公告)日：2008-04-15
申请号：US10787920
申请日：2004-02-26
IPC分类号： C07C1/20
CPC分类号： B01J37/0009 , B01J29/83 , B01J29/85 , B01J29/90 , B01J35/023 , B01J35/10 , B01J37/0045 , B01J37/10 , B01J2229/26 , B01J2229/42 , C07C1/20 , C07C2529/85 , C10G3/49 , C10G2400/20 , C10G2400/22 , Y02P20/584 , Y02P30/20
摘要： Disclosed is a method for making molecular sieve catalyst particles. Dried molecular sieve catalyst particles are used to make the catalyst. The dried molecular sieve catalyst particles are put into an aqueous solution and stirred to make a slurry. The slurry is dried to make the molecular sieve catalyst particles. Optionally, the dried molecular sieve catalyst particles made from the slurry are calcined.
摘要翻译： 公开了一种制备分子筛催化剂颗粒的方法。 干燥的分子筛催化剂颗粒用于制备催化剂。 将干燥的分子筛催化剂颗粒放入水溶液中并搅拌以制备浆料。 将浆料干燥以制备分子筛催化剂颗粒。 任选地，将由浆料制成的干燥分子筛催化剂颗粒煅烧。
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