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    Process for the manufacture of alkoxysilanes and alkoxy orthosilicates
    1.
    发明授权
    Process for the manufacture of alkoxysilanes and alkoxy orthosilicates 失效
    制备烷氧基硅烷和原硅酸烷氧基酯的方法

    公开(公告)号：US06580000B1

    公开(公告)日：2003-06-17

    申请号：US10163839

    申请日：2002-06-06

    申请人： Amos R. Anderson ,  Jeffrey G. Meyer

    发明人： Amos R. Anderson ,  Jeffrey G. Meyer

    IPC分类号： C07F718

    CPC分类号： C07F7/025 ,  C07F7/045

    摘要： Process for the production of alkoxysilanes of the formula HSi(OR)3, where R is an alkyl group containing 1 to 6 carbon atoms, and/or alkyl orthosilicates of the formula Si(OR)4, where R is an alkyl group containing 1 to 6 carbon atoms. In a preferred embodiment, the process comprises reacting silicon metal with an alcohol in a suitable solvent in the presence of a cupric bis(diorganophosphate) catalyst. A polymeric form of ethyl orthosilicate, a by-product of the reaction, is the preferred solvent. The production of triethoxysilane and tetraethyl orthosilicate is preferred, with triethoxysilane being particularly preferred.

    摘要翻译： 制备式HSi（OR）3的烷氧基硅烷的方法，其中R是含有1至6个碳原子的烷基，和/或式Si（OR）4的原硅酸烷基酯，其中R是含1个 至6个碳原子。 在优选的实施方案中，该方法包括在二（二有机磷酸盐）二氧化二铜催化剂存在下，使合适的溶剂中的硅金属与醇反应。 作为反应的副产物的原硅酸乙酯的聚合物形式是优选的溶剂。 优选三乙氧基硅烷和原硅酸四乙酯的生产，特别优选三乙氧基硅烷。

    Chrome catalyst
    3.
    发明授权
    Chrome catalyst 失效
    铬催化剂

    公开(公告)号：US4008359A

    公开(公告)日：1977-02-15

    申请号：US542164

    申请日：1975-01-20

    申请人： Jeffrey G. Meyer ,  Glennis L. Phipps

    发明人： Jeffrey G. Meyer ,  Glennis L. Phipps

    IPC分类号： C08F4/62 ,  C08F10/00 ,  C08F10/02 ,  C08F4/78 ,  C08F10/06

    CPC分类号： C08F10/00 ,  C08F10/02

    摘要： This invention comprises the novel composition formed by mixing (A) a chromium tris-diorgano-orthophosphate of the general formula Cr[OP(O) (OR).sub.2 ].sub.3 wherein R can be an alkyl, alkoxyalkyl or cycloalkyl group of one to about eight carbon atoms and the chlorinated and brominated derivatives thereof, (B) an alkyl aluminum compound of the general formula R'.sub.2 R"Al in which each R' and R" can be an alkyl group of 1 to 6 carbon atoms and each R" can also be a hydrogen atom, and (C) a halogenated olefin of four to about eight carbon atoms containing at least four halogen atoms at least two of which are attached to doubly bonded carbon atoms.This invention also comprises the use of this novel combination as a catalyst for the polymerization of ethylene alone or with propylene and other olefins. This invention also comprises the polymer products prepared by said method.

    摘要翻译： 本发明包括通过混合（A）通式Cr [OP（O）（OR）2] 3的三 - 二有机 - 正磷酸铬，其中R可以是一个至约二个烷基的烷基，烷氧基烷基或环烷基 八个碳原子及其氯化和溴化衍生物，（B）通式R'2R''Al的烷基铝化合物，其中每个R'和R“可以是1至6个碳原子的烷基， R“也可以是氢原子，和（C）含有至少四个卤素原子的四至八个碳原子的卤代烯烃，其中至少两个连接到双键碳原子上。

    Process for the manufacture of alkoxysilanes and alkoxy orthosilicates
    4.
    发明授权
    Process for the manufacture of alkoxysilanes and alkoxy orthosilicates 失效
    制备烷氧基硅烷和原硅酸烷氧基酯的方法

    公开(公告)号：US06680399B2

    公开(公告)日：2004-01-20

    申请号：US10328436

    申请日：2002-12-23

    申请人： Amos R. Anderson ,  Jeffrey G. Meyer

    发明人： Amos R. Anderson ,  Jeffrey G. Meyer

    IPC分类号： C07F718

    CPC分类号： C07F7/025 ,  C07F7/045

    摘要： Process for the production of alkoxysilanes of the formula HSi(OR)3, where R is an alkyl group containing 1 to 6 carbon atoms, and/or alkyl orthosilicates of the formula Si(OR)4, where R is an alkyl group containing 1 to 6 carbon atoms. In a preferred embodiment, the process comprises reacting silicon metal with an alcohol in a suitable solvent in the presence of a cupric bis(diorganophosphate) catalyst. A polymeric form of ethyl orthosilicate, a by-product of the reaction, is the preferred solvent. The production of triethoxysilane and tetraethyl orthosilicate is preferred, with triethoxysilane being particularly preferred.

    摘要翻译： 制备式HSi（OR）3的烷氧基硅烷的方法，其中R是含有1至6个碳原子的烷基，和/或式Si（OR）4的原硅酸烷基酯，其中R是含1个 至6个碳原子。 在优选的实施方案中，该方法包括在二（二有机磷酸盐）二氧化二铜催化剂存在下，使合适的溶剂中的硅金属与醇反应。 作为反应的副产物的原硅酸乙酯的聚合物形式是优选的溶剂。 优选三乙氧基硅烷和原硅酸四乙酯的生产，特别优选三乙氧基硅烷。

    Nickel bis-diorgano-orthophosphates their preparation and use
    6.
    发明授权
    Nickel bis-diorgano-orthophosphates their preparation and use 失效
    尼克尔双相异构磷酸酯它们的制备和使用

    公开(公告)号：US4117022A

    公开(公告)日：1978-09-26

    申请号：US839117

    申请日：1977-10-03

    申请人： Jeffrey G. Meyer

    发明人： Jeffrey G. Meyer

    IPC分类号： B01J31/14 ,  B01J31/18 ,  C07C2/30 ,  C08F4/70 ,  C08F10/00 ,  C07C3/21

    CPC分类号： B01J31/185 ,  B01J31/143 ,  C07C2/30 ,  C08F10/00 ,  C08F4/7098 ,  B01J2231/122 ,  B01J2231/20 ,  B01J2531/847 ,  C07C2531/02 ,  C07C2531/14

    摘要： This invention comprises novel organic-solvent-soluble nickel bis-diorgano-orthophosphates and their preparation by the reaction of certain simple salts or esters of divalent nickel with certain non-aromatic triorgano orthophosphates free of aliphatic unsaturation and separation of the novel compounds. The simple salts or esters include preferably the halides, nitrates and acetates of divalent nickel.This invention further comprises the use of these novel compounds, preferably in solution, as catalysts. When used in conjunction with alkyl aluminum halides, controlled oligomerization of ethylene, propylene and other olefins is achieved with the formation of polymers with low degrees of polymerization, e.g. 2 to 10, preferably no more than about 6 mers. When certain vanadium catalysts are added to these combined catalysts, high polymers of such monomers are achieved with significant residual aliphatic unsaturation.