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1.发明授权
公开(公告)号：US5689025A
公开(公告)日：1997-11-18
申请号：US382103
申请日：1995-02-01
CPC分类号： C07C6/123 , B01J29/40 , B01J37/086 , C07C2/66 , C07C2/864 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70
摘要： A process for ethylbenzene production that involves contacting a hydrocarbon feedstream including benzene and ethylene, under alkylation conditions, with a catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the molecular sieve to at least two selectivation sequences, each selectivation sequence comprising contacting the catalyst with a silicon compound followed by calcination. The modified catalyst used in the process may also be steamed. Optionally, the modified catalyst may be trim-selectivated.
摘要翻译： 一种乙苯生产方法，其涉及在烷基化条件下使含有苯和乙烯的烃进料流与通过用硅化合物进行原位选择性修饰的催化分子筛接触。 异位选择包括将分子筛暴露于至少两个选择性序列，每个选择活性序列包括使催化剂与硅化合物接触，随后煅烧。 在该方法中使用的改性催化剂也可以蒸。 任选地，修饰的催化剂可以是修剪选择的。
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2.发明授权Selective ethylbenzene disproportionation process (SEBDP) with ex situ selectivated zeolite catalysts 失效选择性乙苯歧化过程（SEBDP）与非原位选择性沸石催化剂
公开(公告)号：US5382737A
公开(公告)日：1995-01-17
申请号：US69257
申请日：1993-05-28
CPC分类号： B01J37/086 , B01J29/40 , C07C6/123 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2529/40
摘要： A process for shape selective hydrocarbon conversion that involves contacting a hydrocarbon feedsteam, including ethylbenzene, under conversion conditions with a catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the molecular sieve to at least two silicon impregnation sequences, each sequence comprising an impregnation with a silicon compound followed by calcination. The modified catalyst used in the process may also be steamed. Optionally, the modified catalyst may be trim-selectivated.
摘要翻译： 一种用于形状选择性烃转化的方法，其包括在转化条件下将烃类原料（包括乙苯）与通过用硅化合物进行非原位选择性修饰的催化分子筛接触。 异位选择包括将分子筛暴露于至少两个硅浸渍序列，每个序列包含用硅化合物浸渍，然后煅烧。 在该方法中使用的改性催化剂也可以蒸。 任选地，修饰的催化剂可以是修剪选择的。
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3.发明授权Selective toluene disproportionation process (STDP) with ex situ selectivated zeolite catalyst 失效选择性甲苯歧化过程（STDP）与非原位选择性沸石催化剂
公开(公告)号：US5367099A
公开(公告)日：1994-11-22
申请号：US69254
申请日：1993-05-28
CPC分类号： C07C6/123 , B01J29/40 , B01J37/086 , B01J2229/42 , C07C2529/40 , Y02P20/52
摘要： A process for shape selective hydrocarbon conversion that involves contacting a hydrocarbon feedsteam, including toluene, under conversion conditions with a catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the molecular sieve to at least two silicon impregnation sequences, each sequence comprising an impregnation with a silicon compound followed by calcination. The modified catalyst used in the process may also be steamed. Optionally, the modified catalyst may be trim-selectivated.
摘要翻译： 一种用于形状选择性烃转化的方法，其包括在转化条件下使包含甲苯的烃进料流与通过用硅化合物进行非原位选择性修饰的催化分子筛接触。 异位选择包括将分子筛暴露于至少两个硅浸渍序列，每个序列包含用硅化合物浸渍，随后煅烧。 在该方法中使用的改性催化剂也可以蒸。 任选地，修饰的催化剂可以是修剪选择的。
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公开(公告)号：US06576582B1
公开(公告)日：2003-06-10
申请号：US08558309
申请日：1995-11-15
IPC分类号： B01J2906
CPC分类号： C07C6/123 , B01J29/40 , B01J37/086 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2/66 , C07C2/864 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/00
摘要： There is provided a substantially binder-free catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the molecular sieve to at least two silicon impregnation sequences, each sequence comprising an impregnation with a silicon compound followed by calcination. The catalyst may be used in a hydrocarbon conversion process, such as toluene disproportionation.
摘要翻译： 提供了基本上不含粘合剂的催化分子筛，其通过用硅化合物进行异地选择而被改性。 异位选择包括将分子筛暴露于至少两个硅浸渍序列，每个序列包含用硅化合物浸渍，随后煅烧。 催化剂可用于烃转化过程中，例如甲苯歧化。
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5.发明授权Enhanced shape selective applications and methods to increase the activity thereof 失效增强的形状选择性应用和增加其活性的方法
公开(公告)号：US5633417A
公开(公告)日：1997-05-27
申请号：US453042
申请日：1995-05-30
CPC分类号： C07C6/123 , B01J29/40 , B01J37/086 , C07C2/66 , C07C2/864 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70
摘要： An ex situ selectivated catalytic molecular sieve for enhanced shape selective hydrocarbon conversions in which a catalytic molecular sieve is modified by being exposed to at least two selectivation sequences, each sequence including an impregnation of the molecular sieve with a selectivating agent and a subsequent calcination of the impregnated molecular sieve. The ex situ selectivation method is also described, including the use of low volatility organic carriers for the selectivating agent. Also, a method for moderate steaming of the ex situ selectivated molecular sieve. Also a method for in situ trim-selectivating the ex situ selectivated catalytic molecular sieve. Also described is the process for shape selective hydrocarbon conversion comprising contacting a hydrocarbon feedstream under conversion conditions with the modified catalytic molecular sieve.
摘要翻译： 用于增强形状选择性烃转化的异位选择性催化分子筛，其中通过暴露于至少两个选择性序列来修饰催化分子筛，每个序列包括用选择性试剂浸渍分子筛，随后煅烧 浸渍分子筛。 还描述了非原位选择方法，包括使用低挥发性有机载体用于选择性试剂。 另外，用于非原位选择性分子筛的中等蒸度的方法。 还有一种用于原位选择活化的催化分子筛的原位选择方法。 还描述了形状选择性烃转化的方法，包括在转化条件下使烃进料流与改性的催化分子筛接触。
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6.发明授权Multiple impregnation technique for the preparation of ex situ selectivated zeolite catalysts 失效用于制备异位选择性沸石催化剂的多重浸渍技术
公开(公告)号：US5403800A
公开(公告)日：1995-04-04
申请号：US69255
申请日：1993-05-28
CPC分类号： B01J29/40 , B01J37/086 , C07C6/123 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2529/40
摘要： A ex situ selectivated catalytic molecular sieve for enhanced shape selective hydrocarbon conversions in which a catalytic molecular sieve is modified by being exposed to at least two selectivation sequences, each sequence including an impregnation of the molecular sieve with a selectivating agent and a subsequent calcination of the impregnated molecular sieve. The ex situ selectivation method is also described, including the use of aqueous carriers for the selecting agent. Also a method for in situ trim-selectivating the modified catalytic molecular sieve. Also, a method for moderate steaming of the selectivated molecular sieve. Also a method for in situ trim-selectivating the modified catalytic molecular sieve. Also described is the process for shape selective hydrocarbon conversion comprising contacting a hydrocarbon feedstream under conversion conditions with the selectivated molecular sieve.
摘要翻译： 用于增强形状选择性烃转化的异位选择性催化分子筛，其中通过暴露于至少两个选择性序列来修饰催化分子筛，每个序列包括用选择性试剂浸渍分子筛，随后煅烧 浸渍分子筛。 还描述了非原位选择方法，包括使用含水载体用于选择剂。 也是用于原位修剪选择改性催化分子筛的方法。 另外，选择性分子筛中等蒸度的方法。 也是用于原位修剪选择改性催化分子筛的方法。 还描述了形状选择性烃转化的方法，包括在转化条件下使烃进料流与选择性分子筛接触。
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公开(公告)号：US5698756A
公开(公告)日：1997-12-16
申请号：US471626
申请日：1995-06-06
CPC分类号： C07C6/123 , B01J29/40 , B01J37/086 , C07C2/66 , C07C2/864 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52
摘要： There is provided a process for the alkylation of toluene with ethylene to selectively produce para-ethyltoluene over a catalyst which has been selectivated by multiple treatments with a siliceous material.
摘要翻译： 提供了用乙烯烷基化甲苯以选择性地在催化剂上生成对乙基甲苯的方法，该催化剂已经通过用硅质材料进行多次处理而选择。
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8.发明授权High conversion touluene disproportionation with ex situ selectivated zeolite catalysts 失效高转化率touluene歧化与原位选择沸石催化剂
公开(公告)号：US5659098A
公开(公告)日：1997-08-19
申请号：US558312
申请日：1995-11-15
CPC分类号： B01J29/40 , B01J37/086 , C07C2/66 , C07C2/864 , C07C6/123 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52
摘要： There is provided a process for shape selective toluene disproportionation that involves contacting a feedstream which includes toluene under conversion conditions, with ZSM-5 that has been selectivated at least once with an organosilicon selectivating agent. The conversion conditions of the hydrocarbon conversion process provide a toluene conversion of at least 40 wt. %.
摘要翻译： 提供了形成选择性甲苯歧化的方法，其涉及在转化条件下将包含甲苯的进料流与已经用有机硅选择性试剂选择至少一次的ZSM-5接触。 烃转化方法的转化条件提供至少40重量％的甲苯转化率。 ％。
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9.发明授权Selective ethylbenzene disproportionation processes (SEBDP) with ex situ selectivated zeolite catalyst 失效选择性乙苯歧化过程（SEBDP）与非原位选择性沸石催化剂
公开(公告)号：US5406015A
公开(公告)日：1995-04-11
申请号：US69260
申请日：1993-05-28
CPC分类号： C07C6/123 , B01J29/40 , B01J37/086 , B01J2229/12 , B01J2229/32 , B01J2229/36 , B01J2229/42 , C07C2529/40
摘要： A process for shape selective hydrocarbon conversion that involves contacting a hydrocarbon feedsteam, including ethylbenzene, under conversion conditions with a catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the molecular sieve to at least two silicon impregnation sequences, each sequence comprising an impregnation with a silicon compound followed by calcination. The modified catalyst used in the process may also be steamed. Optionally, the modified catalyst may be trim-selectivated.
摘要翻译： 一种用于形状选择性烃转化的方法，其包括在转化条件下将烃类原料（包括乙苯）与通过用硅化合物进行非原位选择性修饰的催化分子筛接触。 异位选择包括将分子筛暴露于至少两个硅浸渍序列，每个序列包含用硅化合物浸渍，随后煅烧。 在该方法中使用的改性催化剂也可以蒸。 任选地，修饰的催化剂可以是修剪选择的。
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公开(公告)号：US06777583B2
公开(公告)日：2004-08-17
申请号：US10227663
申请日：2002-08-26
IPC分类号： C07C552
CPC分类号： C07C6/123 , B01J29/40 , B01J37/086 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2/66 , C07C2/864 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/00
摘要： There is provided a substantially binder-free catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the molecular sieve to at least two silicon impregnation sequences, each sequence comprising an impregnation with a silicon compound followed by calcination. The catalyst may be used in a hydrocarbon conversion process, such as toluene disproportionation.
摘要翻译： 提供了基本上不含粘合剂的催化分子筛，其通过用硅化合物进行异地选择而被改性。 异位选择包括将分子筛暴露于至少两个硅浸渍序列，每个序列包含用硅化合物浸渍，随后煅烧。 催化剂可用于烃转化过程中，例如甲苯歧化。
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