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公开(公告)号：US06777583B2
公开(公告)日：2004-08-17
申请号：US10227663
申请日：2002-08-26
IPC分类号： C07C552
CPC分类号： C07C6/123 , B01J29/40 , B01J37/086 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2/66 , C07C2/864 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/00
摘要： There is provided a substantially binder-free catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the molecular sieve to at least two silicon impregnation sequences, each sequence comprising an impregnation with a silicon compound followed by calcination. The catalyst may be used in a hydrocarbon conversion process, such as toluene disproportionation.
摘要翻译： 提供了基本上不含粘合剂的催化分子筛，其通过用硅化合物进行异地选择而被改性。 异位选择包括将分子筛暴露于至少两个硅浸渍序列，每个序列包含用硅化合物浸渍，随后煅烧。 催化剂可用于烃转化过程中，例如甲苯歧化。
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公开(公告)号：US06576582B1
公开(公告)日：2003-06-10
申请号：US08558309
申请日：1995-11-15
IPC分类号： B01J2906
CPC分类号： C07C6/123 , B01J29/40 , B01J37/086 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C2/66 , C07C2/864 , C07C2529/06 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/00
摘要： There is provided a substantially binder-free catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the molecular sieve to at least two silicon impregnation sequences, each sequence comprising an impregnation with a silicon compound followed by calcination. The catalyst may be used in a hydrocarbon conversion process, such as toluene disproportionation.
摘要翻译： 提供了基本上不含粘合剂的催化分子筛，其通过用硅化合物进行异地选择而被改性。 异位选择包括将分子筛暴露于至少两个硅浸渍序列，每个序列包含用硅化合物浸渍，随后煅烧。 催化剂可用于烃转化过程中，例如甲苯歧化。
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公开(公告)号：US07361798B2
公开(公告)日：2008-04-22
申请号：US10946553
申请日：2004-09-21
CPC分类号： C07C6/126 , Y02P20/582 , C07C15/02
摘要： The invention relates to a process for producing a desired dialkylbenzene isomer having a formula R2C6H4, where R is an alkyl substituent, by contacting a polyalkylbenzene compound of formula RnC6H6-n, where n is an integer between 2 and 4, with a monoalkylbenzene compound of formula RC6H5 in the presence of a molecular sieve catalyst under reaction conditions sufficient to produce said dialkybenzene isomer. The preferred molecular sieve catalysts have pores or surface cavities greater than 5.6 Angstroms in diameter and/or an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07, and 3.42±0.07 Angstrom.
摘要翻译： 本发明涉及制备具有式R 2 C 6 H 4 H 4的所需二烷基苯异构体的方法，其中R是烷基取代基， 通过使式R n 6 C 6 H 6-n N的多烷基苯化合物（其中n是2和4之间的整数）与单烷基苯 在分子筛催化剂存在下，在足以产生所述二烷基苯异构体的反应条件下，式RC 6 H 5 H 5的化合物。 优选的分子筛催化剂具有直径大于5.6埃的孔或表面空腔和/或包括在12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃处的d间距最大值的X射线衍射图。
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公开(公告)号：US6049018A
公开(公告)日：2000-04-11
申请号：US234544
申请日：1999-01-21
申请人： David C. Calabro , Jane C. Cheng , Robert A. Crane, Jr. , Charles T. Kresge , Sandeep S. Dhingra , Michael A. Steckel , David L. Stern , Simon C. Weston
发明人： David C. Calabro , Jane C. Cheng , Robert A. Crane, Jr. , Charles T. Kresge , Sandeep S. Dhingra , Michael A. Steckel , David L. Stern , Simon C. Weston
IPC分类号： C07D487/04 , B01J29/04 , B01J29/70 , C01B39/08 , C01B39/46 , C01B39/48 , C07B61/00 , C07C2/54 , C07C2/66 , C07C4/18 , C07C5/22 , C07C5/27 , C07C6/12 , C07C15/073 , C07C15/085 , C07D209/56 , C07D487/00 , C01B39/50
CPC分类号： C07C6/126 , B01J29/04 , B01J29/70 , C01B39/085 , C01B39/48 , C07C2/66 , C07C4/18 , C07C5/2708 , C07C6/123 , C07C2529/70
摘要： This invention relates to a new synthetic porous crystalline material, designated MCM-68, a method and novel polycyclic organic cation for its preparation and its use in catalytic conversion of organic compounds. The new crystalline material exhibits a distinctive X-ray diffraction pattern and has a unique crystal structure which contains at least one channel system, in which each channel is defined by a 12-membered ring of tetrahedrally coordinated atoms, and at least two further, independent channel systems, in each of which each channel is defined by a 10-membered ring of tetrahedrally coordinated atoms, wherein the number of unique 10-membered ring channels is twice the number of 12-membered ring channels.
摘要翻译： 本发明涉及一种新的合成多孔结晶材料，称为MCM-68，其制备方法和新型多环有机阳离子及其在有机化合物催化转化中的应用。 新的结晶材料表现出独特的X射线衍射图案，并且具有独特的晶体结构，其包含至少一个通道系统，其中每个通道由四面体配位的原子的12元环定义，并且至少两个独立的 通道系统，其中每个通道由四面体配位原子的10元环定义，其中唯一的10-元环通道的数目是12元环通道数目的两倍。
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公开(公告)号：US09233887B2
公开(公告)日：2016-01-12
申请号：US13885611
申请日：2011-11-04
申请人： Jihad M. Dakka , Teng Xu , Edward A. Lemon , James R. Lattner , Jane C. Cheng
发明人： Jihad M. Dakka , Teng Xu , Edward A. Lemon , James R. Lattner , Jane C. Cheng
CPC分类号： C07C2/66 , C07C37/07 , C07C37/08 , C07C45/53 , C07C2529/08 , C07C2529/18 , C07C2529/70 , Y02P20/127 , C07C13/28
摘要： In a process for producing mono-cycloalkyl-substituted aromatic compound, benzene and cyclic monoolefin are contacted with a catalyst under alkylation conditions to produce an effluent containing mono-cycloalkyl-substituted aromatic compound. The catalyst comprises a molecular sieve.
摘要翻译： 在制备单环烷基取代的芳族化合物的方法中，苯和环状单烯烃在烷基化条件下与催化剂接触以产生含有单环烷基取代的芳族化合物的流出物。 催化剂包括分子筛。
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公开(公告)号：US08212096B2
公开(公告)日：2012-07-03
申请号：US12994278
申请日：2009-07-15
IPC分类号： C07C2/66
CPC分类号： B01J29/7038 , B01J29/7276 , B01J29/7476 , B01J29/7676 , C01B39/46 , C01B39/48 , C07C2/74 , C07C2601/14 , C07C13/28
摘要： This disclosure relates to a process for manufacturing a mono-cycloalkyl-substituted aromatic compound, said process comprising contacting a feedstock comprising an aromatic compound and hydrogen under hydroalkylation reaction conditions with a catalyst system comprising a molecular sieve, wherein said molecular sieve comprises a framework of tetrahedral atoms bridged by oxygen atoms, the tetrahedral atom framework being defined by a unit cell with atomic coordinates in nanometers shown in Table 2.
摘要翻译： 本公开涉及制备单环烷基取代的芳族化合物的方法，所述方法包括在加氢烷基化反应条件下将包含芳族化合物和氢的原料与包含分子筛的催化剂体系接触，其中所述分子筛包括 由氧原子桥接的四面体原子，四面体原子框架由具有如表2所示的纳米的原子坐标的单元电池定义。
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公开(公告)号：US08106243B2
公开(公告)日：2012-01-31
申请号：US12933709
申请日：2009-02-23
CPC分类号： C07C37/06 , C07C2/74 , C07C6/126 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are contacted with a catalyst under hydroalkylation conditions to produce an effluent containing cyclohexylbenzene. The catalyst comprises a composite of a molecular sieve, an inorganic oxide different from said molecular sieve and at least one hydrogenation metal, wherein at least 50 wt % of said hydrogenation metal is supported on the inorganic oxide and the inorganic oxide has an average particle size less than 40 μm (microns).
摘要翻译： 在生产环己基苯的方法中，苯和氢在加氢烷基化条件下与催化剂接触以产生含有环己基苯的流出物。 催化剂包括分子筛，不同于所述分子筛的无机氧化物和至少一种氢化金属的复合物，其中至少50重量％的所述氢化金属负载在无机氧化物上，无机氧化物具有平均粒度 小于40μm（微米）。
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公开(公告)号：US20110028762A1
公开(公告)日：2011-02-03
申请号：US12904215
申请日：2010-10-14
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid-to-metal molar ratio of from about 75 to about 750.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 催化剂体系具有约75-约750的酸 - 金属摩尔比。
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公开(公告)号：US07834218B2
公开(公告)日：2010-11-16
申请号：US12162970
申请日：2007-02-08
申请人： Jihad M. Dakka , Jon E. Stanat , Francisco M. Benitez , John S. Buchanan , Jane C. Cheng , Jeffrey T. Elks
发明人： Jihad M. Dakka , Jon E. Stanat , Francisco M. Benitez , John S. Buchanan , Jane C. Cheng , Jeffrey T. Elks
CPC分类号： C07C409/08 , C07C37/08 , C07C45/53 , C07C407/00 , C07C49/10 , C07C39/04
摘要： A process for producing phenol and methyl ethyl ketone comprises contacting benzene and a C4 alkylating agent under alkylation conditions and in the presence of an alkylation catalyst comprising at least one molecular sieve of the MCM-22 family to produce an alkylation effluent comprising secbutylbenzene; wherein the contacting is conducted in a plurality of reaction zones and the C4 alkylating agent secbutylbenzene fraction is recovered from the alkylation effluent and comprises at least 95 wt % sec-butylbenzene, less than 100 wt ppm of C8+ olefins, and less than 0.5 wt % of isobutylbenzene and tert-butylbenzene. The sec-butylbenzene fraction is then oxidized to produce sec-butylbenzene hydroperoxide and the hydroperoxide is cleaved to produce phenol and methyl ethyl ketene.
摘要翻译： 一种生产苯酚和甲基乙基酮的方法包括在烷基化条件下和在包含至少一种MCM-22族分子筛的烷基化催化剂的存在下使苯和C4烷基化剂接触以产生包含二丁基苯的烷基化流出物; 其中所述接触在多个反应区中进行，并且所述C4烷基化剂仲丁苯部分从烷基化流出物中回收，并且包含至少95重量％的仲丁基苯，小于100重量ppm的C 8+烯烃和小于0.5重量％ 的异丁基苯和叔丁基苯。 然后将仲丁基馏分氧化以产生仲丁基苯氢过氧化物，并将氢过氧化物裂解以产生苯酚和甲基乙基乙烯酮。
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公开(公告)号：US20100179351A1
公开(公告)日：2010-07-15
申请号：US12663303
申请日：2008-08-12
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid-to-metal molar ratio of from about 75 to about 750.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 催化剂体系具有约75-约750的酸 - 金属摩尔比。
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