摘要:
Disclosed are primary materials, precursor materials and final materials as well as methods to prepare these materials. The final materials are mixed lithium transition metal oxides, useful as performance optimized cathode materials for rechargeable lithium batteries. The transition metal is a solid solution mixture of manganese, nickel and cobalt, M=(Mn1-uNiu)1-u-yCoy, with 0.2
摘要:
The invention relates to cathode materials for Li-ion batteries in the quaternary phase diagram Li[Li1/3Mn2/3]O2—LiMn1/2Ni1/2O2—LiNiO2—LiCoO2, and having a high nickel content. Also a method to manufacture these materials is disclosed. The cathode material has a general formula Lia ((Niz(Ni1/2Mn1/2)yCox)1−kAk)2−aO2, wherein x+y+z=1, 0.1≦x≦0.4, 0.36≦z≦0.50, A is a dopant, 0≦k≦0.1, and 0.95≦a≦1.05, and having a soluble base content (SBC) within 10% of the equilibrium soluble base content.
摘要:
The invention relates to cathode materials for Li-ion batteries in the quaternary phase diagram Li[Li1/3Mn2/3]O2—LiMn1/2Ni1/2O2—LiNiO2—LiCoO2, and having a high nickel content. Also a method to manufacture these materials is disclosed. The cathode material has a general formula Lia((Niz(Ni1/2Mn1/2)yCox)1-kAk)2-aO2, wherein x+y+z=1, 0.1≦x≦0.4, 0.36≦z≦0.50, A is a dopant, 0≦k≦0.1, and 0.95≦a≦1.05, and having a soluble base content (SBC) within 10% of the equilibrium soluble base content.
摘要翻译:本发明涉及Li [Li1 / 3Mn2 / 3] O2-LiMn1 / 2Ni1 / 2O2-LiNiO2-LiCoO2四元相图中锂离子电池的阴极材料,镍含量高。 还公开了制造这些材料的方法。 阴极材料具有通式Li((Niz(Ni1 / 2Mn1 / 2)yCox)1-kAk)2-aO2,其中x + y + z = 1,0.1 @ x @ 0.4,0.36 @ z @ 0.50,A 是掺杂剂,0 @ k @ 0.1和0.95 @ a @ 1.05,并且具有可溶性碱含量(SBC)在平衡可溶性碱含量的10%以内。
摘要:
A particulate precursor compound for manufacturing an aluminum doped lithium transition metal (M)-oxide powder usable as an active positive electrode material in lithium-ion batteries includes a transition metal (M)-hydroxide or (M)-oxyhydroxide core and a non-amorphous aluminum oxide coating layer covering the core. By providing an aluminum dry-coating process where the particulate precursor core compound is mixed with alumina powder in one or more procedures, higher doping levels of aluminum compared to the known prior art may be achieved. The crystal structure of the alumina is maintained during the coating procedures and the core of each mixed transition metal precursor particle is surrounded by a coating layer containing crystalline alumina nano particles. The aluminum concentration in the particulate precursor decreases as the size of the core increases.
摘要:
The present invention provides a powdery composite precursor, which comprises a core of a lithium transition metal oxide, and an aluminum hydroxide-based precipitate layer coated on the surface of the core, and a process to prepare the composite precursor. The preparation process comprises the formation of a water based slurry by dispersing lithium transition metal oxide powder in water, and a precipitation reaction of an aluminum salt solution with a base solution where the lithium transition metal particles act as seed particles, whereby a mechanically stable precipitate layer of homogeneous thickness can be achieved. The composite precursor can be converted into aluminum-containing, e.g., aluminum-doped, lithium transition metal oxide suitable for a cathode active material of lithium rechargeable battery by heat treatment.
摘要:
The invention relates to cathode materials for Li-ion batteries having a size dependent compositions. The lithium metal oxide powder has a general formula LiaNixCoyMnzM′mO2±eAf, with 0.9
摘要:
A lithium transition metal oxide powder for use in a rechargeable battery is disclosed, where the surface of the primary particles of said powder is coated with a first inner and a second outer layer, the second outer layer comprising a fluorine-containing polymer, and the first inner layer consisting of a reaction product of the fluorine-containing polymer and the primary particle surface. An example of this reaction product is LiF, where the lithium originates from the primary particles surface. Also as an example, the fluorine-containing polymer is either one of PVDF, PVDF-HFP or PTFE.
摘要:
A lithium transition metal oxide powder for use in a rechargeable battery is disclosed, where the surface of the primary particles of said powder is coated with a LiF layer, where this layer consists of a reaction product of a fluorine-containing polymer and the primary particle surface. The lithium of the LiF originates from the primary particles surface. Examples of the fluorine-containing polymer are either one of PVDF, PVDF-HFP or PTFE. Examples of the lithium transition metal oxide are either one of —LiCodMeO2, wherein M is either one of both of Mg and Ti, with e
摘要:
This invention describes a heterogeneous metal bearing material, comprising a host material composed of primary particles agglomerated into secondary particles, and a particulate dopant material, characterised in that the particulate dopant material is homogeneously distributed within the secondary particles of said host material. In particular, the dopant material is TiO2 and the host material is either one or a mixture of NixMnyCO2 hydroxide, oxyhydroxide, and oxide, with 0≦x, y, z≦1, and x+y+z=1.
摘要翻译:本发明描述了一种异质金属轴承材料,其包含由附聚到二次颗粒中的初级颗粒组成的主体材料和颗粒状掺杂剂材料,其特征在于所述颗粒状掺杂剂材料均匀分布在所述主体材料的二次颗粒内。 特别地,掺杂剂材料是TiO 2,并且主体材料是NixMnyCO 2氢氧化物,羟基氧化物和氧化物中的一种或其混合物,其中0≤n1; x,y,z和nlE; 1和x + y + z = 1。