CATHODE MATERIALS FOR LITHIUM BATTERY HAVING HIGHER PERFORMANCE
    1.
    发明申请
    CATHODE MATERIALS FOR LITHIUM BATTERY HAVING HIGHER PERFORMANCE 有权
    具有更高性能的锂离子电池的阴极材料

    公开(公告)号:US20080026292A1

    公开(公告)日:2008-01-31

    申请号:US11688358

    申请日:2007-03-20

    IPC分类号: H01M4/52

    摘要: Provided is a cathode material for a lithium secondary battery, comprising a heat-treated mixture of an oxide powder (a) represented by Formula I and an oxide powder (b) represented by Formula II, wherein a mixing ratio of the oxide powder (a):oxide powder (b) is in a range of 30:70 to 90:10, the oxide powder (a) is monolithic particles having a D50 of more than 10 μm, and the oxide powder (b) is agglomerated particles having a D50 of less than 10 μm, and heat treatment is carried out at a temperature of 400° C. or higher. LiCoO2  (I) LizMO2  (II) wherein 0.95

    摘要翻译: 本发明提供一种锂二次电池用正极材料,其特征在于,包含由式I表示的氧化物粉末(a)和式II表示的氧化物粉末(b)的热处理混合物,其中,氧化物粉末(a ):氧化物粉末(b)的比例范围为30:70〜90:10,氧化物粉末(a)为D50大于10um的整体颗粒,氧化物粉末(b)为具有 D50小于10微米,并且在400℃或更高的温度下进行热处理。 <?in-line-formula description =“In-line Formulas”end =“lead”?> LiCoO 2(I)<?in-line-formula description =“In-line Formulas”end =“tail”?> <?in-line-formula description =“In-line Formulas”end =“lead”????????????(II) ?in-line-formula description =“In-line formula”end =“tail”?>其中0.95

    Ni-based lithium transition metal oxide
    4.
    发明申请
    Ni-based lithium transition metal oxide 有权
    Ni基锂过渡金属氧化物

    公开(公告)号:US20060233696A1

    公开(公告)日:2006-10-19

    申请号:US11104734

    申请日:2005-04-13

    IPC分类号: C01D1/02

    摘要: The present invention provides a powderous lithium transition metal oxide with the composition as represented by the below Formula and prepared by solid state reaction in air from a mixed transition metal precursor and Li2CO3, with being practically free of Li2CO3 impurity: LixMyO2 wherein M=M′l-kAk, where M′=Nil-a-b(Ni1/2Mn1/2)aCob on condition of 0.65≦a+b≦0.85 and 0.1≦b≦0.4; A is a dopant; and 0≦k≦0.05; and x+y=2 on condition of 0.95≦x≦1.05. The Ni-based lithium transition metal oxide according to the present invention has a well-layered structure, and also improved safety, cycling stability and stability against aging and low gas evolution during storage, when used as an active material for cathode of lithium secondary batteries, because it has a high sintering stability and is substantially free of soluble bases. Moreover, the lithium transition metal oxide of the present invention can be prepared by a low-cost process using a mixed transition metal precursor and Li2CO3 as raw stocks and under relatively unrestricted conditions.

    摘要翻译: 本发明提供一种粉末状锂过渡金属氧化物,其组成如下式所示,并通过空气中的混合过渡金属前体和Li 2 CO 3 3固相反应制备, 实际上不含有Li 2 CO 3杂质:<?in-line-formula description =“In-line Formulas”end =“lead”→> α-in-line-formula description =“In-line Formulas”end =“tail”?>其中 M = M'其中M'= Ni实验室(Ni 1/2 Mn x + y = 2。 根据本发明的Ni基锂过渡金属氧化物具有良好的结构,并且还提高了安全性,循环稳定性和 由于其具有高的烧结稳定性并且基本上不含可溶性碱,所以当用作锂二次电池阴极的活性材料时,储存期间的稳定性和储存期间的低气体逸出。 此外,本发明的锂过渡金属氧化物可以通过使用混合过渡金属前体和Li 3 CO 3 3作为原料的低成本方法制备, 相对无限制的条件。

    HIGH NICKEL CATHODE MATERIAL HAVING LOW SOLUBLE BASE CONTENT
    6.
    发明申请
    HIGH NICKEL CATHODE MATERIAL HAVING LOW SOLUBLE BASE CONTENT 有权
    具有低可溶性碱性内容物的高镍铬阴极材料

    公开(公告)号:US20140054495A1

    公开(公告)日:2014-02-27

    申请号:US13983596

    申请日:2012-01-31

    IPC分类号: H01M4/505 H01M4/525 C01D15/02

    摘要: The invention relates to cathode materials for Li-ion batteries in the quaternary phase diagram Li[Li1/3Mn2/3]O2—LiMn1/2Ni1/2O2—LiNiO2—LiCoO2, and having a high nickel content. Also a method to manufacture these materials is disclosed. The cathode material has a general formula Lia((Niz(Ni1/2Mn1/2)yCox)1-kAk)2-aO2, wherein x+y+z=1, 0.1≦x≦0.4, 0.36≦z≦0.50, A is a dopant, 0≦k≦0.1, and 0.95≦a≦1.05, and having a soluble base content (SBC) within 10% of the equilibrium soluble base content.

    摘要翻译: 本发明涉及Li [Li1 / 3Mn2 / 3] O2-LiMn1 / 2Ni1 / 2O2-LiNiO2-LiCoO2四元相图中锂离子电池的阴极材料,镍含量高。 还公开了制造这些材料的方法。 阴极材料具有通式Li((Niz(Ni1 / 2Mn1 / 2)yCox)1-kAk)2-aO2,其中x + y + z = 1,0.1 @ x @ 0.4,0.36 @ z @ 0.50,A 是掺杂剂,0 @ k @ 0.1和0.95 @ a @ 1.05,并且具有可溶性碱含量(SBC)在平衡可溶性碱含量的10%以内。

    Alumina dry-coated cathode material precursors
    7.
    发明授权
    Alumina dry-coated cathode material precursors 有权
    氧化铝干涂阴极材料前体

    公开(公告)号:US09543581B2

    公开(公告)日:2017-01-10

    申请号:US13817324

    申请日:2011-08-04

    摘要: A particulate precursor compound for manufacturing an aluminum doped lithium transition metal (M)-oxide powder usable as an active positive electrode material in lithium-ion batteries includes a transition metal (M)-hydroxide or (M)-oxyhydroxide core and a non-amorphous aluminum oxide coating layer covering the core. By providing an aluminum dry-coating process where the particulate precursor core compound is mixed with alumina powder in one or more procedures, higher doping levels of aluminum compared to the known prior art may be achieved. The crystal structure of the alumina is maintained during the coating procedures and the core of each mixed transition metal precursor particle is surrounded by a coating layer containing crystalline alumina nano particles. The aluminum concentration in the particulate precursor decreases as the size of the core increases.

    摘要翻译: 用于制造可用作锂离子电池中的活性正极材料的铝掺杂锂过渡金属(M) - 氧化物粉末的颗粒前体化合物包括过渡金属(M) - 羟基氧化物或(M) - 羟基氧化物核心和非 - 无定形氧化铝覆层覆盖核心。 通过提供铝干法涂覆方法,其中颗粒前体核心化合物与氧化铝粉末以一种或多种方法混合,可以实现与已知现有技术相比较较高掺杂水平的铝。 在涂布过程中保持氧化铝的晶体结构,并且每个混合的过渡金属前体颗粒的芯被包含结晶氧化铝纳米颗粒的涂层包围。 颗粒前体中的铝浓度随着核心尺寸的增加而减小。