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    PROCESS FOR MAKING MIXED TRIGLYCERIDE PLASTICIZER FROM BENZOIC AND TOLUIC ACID
    1.
    发明申请
    PROCESS FOR MAKING MIXED TRIGLYCERIDE PLASTICIZER FROM BENZOIC AND TOLUIC ACID 审中-公开
    从苯甲酸和柠檬酸制备混合的TRIGLYCERIDE PLASTICZER的方法

    公开(公告)号：US20120022197A2

    公开(公告)日：2012-01-26

    申请号：US12878166

    申请日：2010-09-09

    申请人： Jihad Dakka ,  Edmund Mozeleski ,  Lisa Baugh ,  Allen Godwin ,  Manika Varma-Nair

    发明人： Jihad Dakka ,  Edmund Mozeleski ,  Lisa Baugh ,  Allen Godwin ,  Manika Varma-Nair

    IPC分类号： C08K5/101 ,  C09K3/00 ,  C07C69/76 ,  C08K5/12 ,  C08K5/11

    CPC分类号： C11C3/02 ,  C07C67/08 ,  C08K5/0016 ,  C07C69/78

    摘要： Provided are compositions, processes for making, and processes for using mixed triglycerides as plasticizers. Triglyceride plasticizers can be produced by recovery of linear or branched C4 to C13 aldehydes from a hydroformylation product, oxidation to linear or branched C4 to C13 acids with oxygen and/or air, recovery of the resulting acids, combining the linear or branched C4 to C13 acid with benzoic acid, toluic acid or a combination thereof to form a mixed acid blend, and esterification of the mixed acid blend with glycerol, wherein the total carbon number of the triester groups ranges from 20 to 25 and includes from 1 to 2 aryl groups for greater than or equal to 45 wt % of the plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or pour point, glass transition temperature, low volatility, increased compatibility, increased hydrolytic stability, and excellent low temperature properties in a range of polymeric resins.

    摘要翻译： 提供组合物，制备方法和使用混合甘油三酸酯作为增塑剂的方法。 甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C4至C13醛，通过用氧和/或空气氧化成直链或支链C 4至C 13酸，回收所得酸，将直链或支链C4与C13 酸与苯甲酸，甲苯甲酸或其组合形成混合酸混合物，并将混合酸共混物与甘油酯化，其中三酯基团的总碳数为20-25，包括1至2个芳基 大于或等于45重量％的增塑剂。 这种增塑剂可以是无邻苯二甲酸酯，并且提供突出的性能，包括合适的熔点或倾点，玻璃化转变温度，低挥发性，增加的相容性，增加的水解稳定性和在一系列聚合物树脂中的优异的低温性能。

    Chromium complexes and their use in olefin polymerization
    2.
    发明申请
    Chromium complexes and their use in olefin polymerization 失效
    铬络合物及其在烯烃聚合中的应用

    公开(公告)号：US20080071090A1

    公开(公告)日：2008-03-20

    申请号：US11904056

    申请日：2007-09-25

    申请人： Smita Kacker ,  Enock Berluche ,  Robert Stibrany ,  Joseph Sissano ,  Lisa Baugh

    发明人： Smita Kacker ,  Enock Berluche ,  Robert Stibrany ,  Joseph Sissano ,  Lisa Baugh

    IPC分类号： C07F11/00

    CPC分类号： C07F11/005 ,  B01J31/143 ,  B01J31/183 ,  C08F110/02 ,  C08F4/69034

    摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.

    摘要翻译： 具有式I的组合物，其中R 1和R 2独立地是氢，C 1至C 12直链 和支链烷基，C 3至C 12环烷基，芳基，C 1至C 12烷氧基，F， Cl，SO 3，C 1至C 12全氟烷基和N（​​CH 3 3）2 R 3，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 1〜 C 1 -C 4 - （CH 3） - ，其中C（R 4） - ， x（CH 2）2 - ， - （CH 2 CH 2）x NH 2（CH 2） ）其中R 4是烃基，卤代烃基，卤代烃基， 或1至12个碳原子的烷氧基，x是1至12的整数，Y是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。 当与活化助催化剂组合时，可用于聚合烯烃单体。

    Linear functional copolymers of ethylene with precise and minimum run length distributions and method of making thereof
    4.
    发明申请
    Linear functional copolymers of ethylene with precise and minimum run length distributions and method of making thereof 失效
    具有精确和最小游程长度分布的乙烯的线性官能团共聚物及其制备方法

    公开(公告)号：US20050137369A1

    公开(公告)日：2005-06-23

    申请号：US10962086

    申请日：2004-10-08

    申请人： Lisa Baugh ,  Stephen Lehman ,  Kenneth Wagener ,  Donald Schulz ,  Enock Berluche

    发明人： Lisa Baugh ,  Stephen Lehman ,  Kenneth Wagener ,  Donald Schulz ,  Enock Berluche

    IPC分类号： C08F210/02 ,  C08F210/16 ,  C08F4/80

    CPC分类号： C08F210/02 ,  C08F210/16 ,  C08F4/80 ,  C08F236/20 ,  C08F2500/02 ,  C08F2500/03 ,  C08F220/10 ,  C08F218/00 ,  C08F218/08 ,  C08F232/00

    摘要： The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B represents and unit D represents where R1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.

    摘要翻译： 本发明涉及具有重复单元A，B和D的线性官能聚合物。单元A表示-CH 2 - ，单元B表示，单元D表示其中R 1 表示极性官能团。 每个B单元，每个D单元和每个B和D单元分开至少四个A单元。 值y表示B个单位的总数，并且是大于或等于1的整数.D单位的总数由h表示，并且是大于或等于0的整数。x表示A的总数 单元，并且是足以使线性官能聚合物中B和D单元的摩尔分数由以下等式定义的值j表示的整数： < MATH OVERFLOW =“SCROLL”> j = y + h x + y + > <= 0.032

    Transition metal polymerization catalysts, their synthesis and use in olefin polymerization
    6.
    发明申请
    Transition metal polymerization catalysts, their synthesis and use in olefin polymerization 有权
    过渡金属聚合催化剂，它们在烯烃聚合中的合成和应用

    公开(公告)号：US20060173144A1

    公开(公告)日：2006-08-03

    申请号：US11333639

    申请日：2006-01-17

    申请人： Lisa Baugh ,  Enock Berluche ,  Paul Hinkle ,  Francis Rix

    发明人： Lisa Baugh ,  Enock Berluche ,  Paul Hinkle ,  Francis Rix

    IPC分类号： C08F4/80 ,  C07F13/00 ,  C07F11/00

    CPC分类号： C07F15/045 ,  C07F15/04 ,  C08F4/619 ,  C08F10/00 ,  C08F110/02 ,  C08F2500/20 ,  C08F4/7013

    摘要： A transition metal ligand complex has the following formula: wherein R1 and R2 (each occurrence) independently represent an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms; R3 and R4 (each occurrence) independently represent an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms; R5 represents an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms, provided that R4 and R5 may be joined to form a cyclic structure; R6 represents an alkyl or aryl group having up to 20 carbon atoms; and Mt represents a transition metal selected from Group 7, 8, 9, 10, 11, or 12 of the Periodic Table of the Elements.

    摘要翻译： 过渡金属配体络合物具有下式：其中R 1和R 2（每次出现）独立地表示具有至多20个碳原子的芳基，烷基或环烷基 ; R 3和R 4（每次出现）独立地表示具有至多20个碳原子的芳基，烷基或环烷基; R 5表示具有至多20个碳原子的芳基，烷基或环烷基，条件是R 4和R 5可以连接到 形成循环结构; R 6表示具有至多20个碳原子的烷基或芳基; 而Mt表示选自元素周期表第7,8,9,10,11或12族的过渡金属。

    Chromium complexes and their use in olefin polymerization
    8.
    发明申请
    Chromium complexes and their use in olefin polymerization 有权
    铬络合物及其在烯烃聚合中的应用

    公开(公告)号：US20050288464A1

    公开(公告)日：2005-12-29

    申请号：US11152802

    申请日：2005-06-14

    申请人： Smita Kacker ,  Enock Berluche ,  Robert Stibrany ,  Joseph Sissano ,  Lisa Baugh

    发明人： Smita Kacker ,  Enock Berluche ,  Robert Stibrany ,  Joseph Sissano ,  Lisa Baugh

    IPC分类号： C07F11/00 ,  C08F4/06 ,  C08F110/02

    CPC分类号： C07F11/005 ,  B01J31/143 ,  B01J31/183 ,  C08F110/02 ,  C08F4/69034

    摘要： A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.

    摘要翻译： 具有式I的组合物，其中R 1和R 2独立地是氢，C 1至C 12直链 和支链烷基，C 3至C 12环烷基，芳基，C 1至C 12烷氧基，F， Cl，SO 3，C 1至C 12全氟烷基和N（​​CH 3 3）2 R 3，R 3独立地选自氢，C 1至C 12直链和支链烷基，C 1〜 C 1 -C 4 - （CH 3） - ，其中C（R 4） - ， x（CH 2）2 - ， - （CH 2 CH 2）x NH 2（CH 2） ）其中R 4是烃基，卤代烃基，卤代烃基， 或1至12个碳原子的烷氧基，x是1至12的整数，Y是卤素，X是卤素，三氟甲磺酸酯，乙酸酯，三氟乙酸酯，氢化物或四氟硼酸根。 当与活化助催化剂组合时，可用于聚合烯烃单体。