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    Process for producing phenol and methyl ethyl ketone
    3.
    发明授权
    Process for producing phenol and methyl ethyl ketone 失效
    苯酚和甲基乙基酮的制备方法

    公开(公告)号：US07834218B2

    公开(公告)日：2010-11-16

    申请号：US12162970

    申请日：2007-02-08

    申请人： Jihad M. Dakka ,  Jon E. Stanat ,  Francisco M. Benitez ,  John S. Buchanan ,  Jane C. Cheng ,  Jeffrey T. Elks

    发明人： Jihad M. Dakka ,  Jon E. Stanat ,  Francisco M. Benitez ,  John S. Buchanan ,  Jane C. Cheng ,  Jeffrey T. Elks

    IPC分类号： C07C45/53 ,  C07C37/08

    CPC分类号： C07C409/08 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C49/10 ,  C07C39/04

    摘要： A process for producing phenol and methyl ethyl ketone comprises contacting benzene and a C4 alkylating agent under alkylation conditions and in the presence of an alkylation catalyst comprising at least one molecular sieve of the MCM-22 family to produce an alkylation effluent comprising secbutylbenzene; wherein the contacting is conducted in a plurality of reaction zones and the C4 alkylating agent secbutylbenzene fraction is recovered from the alkylation effluent and comprises at least 95 wt % sec-butylbenzene, less than 100 wt ppm of C8+ olefins, and less than 0.5 wt % of isobutylbenzene and tert-butylbenzene. The sec-butylbenzene fraction is then oxidized to produce sec-butylbenzene hydroperoxide and the hydroperoxide is cleaved to produce phenol and methyl ethyl ketene.

    摘要翻译： 一种生产苯酚和甲基乙基酮的方法包括在烷基化条件下和在包含至少一种MCM-22族分子筛的烷基化催化剂的存在下使苯和C4烷基化剂接触以产生包含二丁基苯的烷基化流出物; 其中所述接触在多个反应区中进行，并且所述C4烷基化剂仲丁苯部分从烷基化流出物中回收，并且包含至少95重量％的仲丁基苯，小于100重量ppm的C 8+烯烃和小于0.5重量％ 的异丁基苯和叔丁基苯。 然后将仲丁基馏分氧化以产生仲丁基苯氢过氧化物，并将氢过氧化物裂解以产生苯酚和甲基乙基乙烯酮。

    PROCESS FOR PRODUCING PHENOL AND METHYL ETHYL KETONE
    4.
    发明申请
    PROCESS FOR PRODUCING PHENOL AND METHYL ETHYL KETONE 失效
    生产苯酚和甲基乙酮的方法

    公开(公告)号：US20090187047A1

    公开(公告)日：2009-07-23

    申请号：US12162970

    申请日：2007-02-08

    申请人： Jihad M. Dakka ,  Jon E. Stanat ,  Francisco M. Benitez ,  John S. Buchanan ,  Jane C. Cheng ,  Jeffrey T. Elks

    发明人： Jihad M. Dakka ,  Jon E. Stanat ,  Francisco M. Benitez ,  John S. Buchanan ,  Jane C. Cheng ,  Jeffrey T. Elks

    IPC分类号： C07C45/53 ,  C07C37/08

    CPC分类号： C07C409/08 ,  C07C37/08 ,  C07C45/53 ,  C07C407/00 ,  C07C49/10 ,  C07C39/04

    摘要： A process for producing phenol and methyl ethyl ketone comprises contacting benzene and a C4 alkylating agent under alkylation conditions and in the presence of an alkylation catalyst comprising at least one molecular sieve of the MCM-22 family to produce an alkylation effluent comprising secbutylbenzene; wherein the contacting is conducted in a plurality of reaction zones and the C4 alkylating agent secbutylbenzene fraction is recovered from the alkylation effluent and comprises at least 95 wt % sec-butylbenzene, less than 100 wt ppm of C8+ olefins, and less than 0.5 wt % of isobutylbenzene and tert-butylbenzene. The sec-butylbenzene fraction is then oxidized to produce sec-butylbenzene hydroperoxide and the hydroperoxide is cleaved to produce phenol and methyl ethyl ketone.

    摘要翻译： 一种生产苯酚和甲基乙基酮的方法包括在烷基化条件下和在包含至少一种MCM-22族分子筛的烷基化催化剂的存在下使苯和C4烷基化剂接触以产生包含二丁基苯的烷基化流出物; 其中所述接触在多个反应区中进行，并且所述C4烷基化剂仲丁苯部分从所述烷基化流出物中回收，并且包含至少95重量％的仲丁基苯，小于100重量ppm的C 8+烯烃和小于0.5重量％ 的异丁基苯和叔丁基苯。 然后将仲丁基馏分氧化以产生仲丁基苯氢过氧化物，并将氢过氧化物裂解以产生苯酚和甲基乙基酮。

    Oxidation of hydrocarbons
    5.
    发明授权
    Oxidation of hydrocarbons 有权
    碳氢化合物的氧化

    公开(公告)号：US08658836B2

    公开(公告)日：2014-02-25

    申请号：US12678419

    申请日：2008-10-08

    申请人： Francisco M. Benitez ,  Jihad M. Dakka ,  Edmund J. Mozeleski ,  Stephen Zushma ,  John Scott Buchanan ,  Jon E. Stanat

    发明人： Francisco M. Benitez ,  Jihad M. Dakka ,  Edmund J. Mozeleski ,  Stephen Zushma ,  John Scott Buchanan ,  Jon E. Stanat

    IPC分类号： C07C409/00

    CPC分类号： C07C409/08 ,  C07B41/00 ,  C07C37/07 ,  C07C37/08 ,  C07C37/20 ,  C07C45/33 ,  C07C45/53 ,  C07C51/313 ,  C07C407/00 ,  C07C409/04 ,  C07C409/10 ,  C07C409/14 ,  C07C2601/14 ,  C07C49/403 ,  C07C55/14 ,  C07C39/04 ,  C07C39/16

    摘要： In a process for oxidizing a hydrocarbon to the corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, a reaction medium comprising a hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N, and CR3; each of X and Z is independently selected from C, S, CH2, N, P and an element of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; l is 0, 1, or 2; m is 1 to 3; and R3 can be any of the entities listed for R1. The contacting is conducted under conditions such as to maintain the concentration of both water and organic acids in the reaction medium below 50 ppm.

    摘要翻译： 在将烃类氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，将包含烃的反应介质与含氧气体在含有通式 （I）：其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代烃基，或从SO 3 H，NH 2，OH和NO 2基团，或从原子H，F，Cl，Br和 我提供R1和R2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; l为0,1或2; m为1〜3; 而R3可以是为R1列出的任何实体。 在使反应介质中的水和有机酸的浓度保持在50ppm以下的条件下进行接触。