公开(公告)号：US4495261A

公开(公告)日：1985-01-22

申请号：US453281

申请日：1982-12-27

申请人： Jiro Takahashi ,  Tawara Komamura ,  Kiyoshi Sawada ,  Ssamu Sasaki ,  Satoshi Goto ,  Akira Kinoshita

发明人： Jiro Takahashi ,  Tawara Komamura ,  Kiyoshi Sawada ,  Ssamu Sasaki ,  Satoshi Goto ,  Akira Kinoshita

IPC分类号： G03G5/06

CPC分类号： G03G5/0683

摘要： An electrophotograhic photoreceptor that has great ability to generate carriers and which has high sensitivity but low residual potential is disclosed. This photoreceptor is characterized by having formed on an electrically conductive support a light-sensitive layer containing a bisazo compound of the following formula: ##STR1## (wherein R.sub.1 is a cyano group, a chlorine atom or a bromine atom; X.sub.1 is a halogen atom, an alkyl group, an alkoxy group or a cyano group; X.sub.2 is a hydrogen atom, a halogen atom, an alkyl atom or an alkoxy group; A is ##STR2## wherein Y is a substituted or unsubstituted carbamoyl group or a substituted or unsubstituted sulfamoyl group; Z is an atomic group necessary for forming a substituted or unsubstituted aromatic hydrocarbon ring or a substituted or unsubstituted heteroaromatic ring; R.sub.2 is a hydrogen atom, a substituted or unsubstituted amino group, a substituted or unsubstituted carbamoyl group, a carboxy group or an ester group thereof; and A' is a substituted or unsubstituted aryl group).

摘要翻译： 公开了具有很高的灵敏度但低残留电位的产生载体的能力的电子照相感光体。 该感光体的特征在于在导电载体上形成含有下式的双偶氮化合物的光敏层：其中R1是氰基，氯原子或溴原子; X1是卤素原子 ，烷基，烷氧基或氰基; X 2为氢原子，卤素原子，烷基或烷氧基; A为取代或未取代的氨基甲酰基或取代或未取代的氨基甲酰基 氨磺酰基; Z是形成取代或未取代的芳族烃环或取代或未取代的杂芳环所需的原子团; R 2是氢原子，取代或未取代的氨基，取代或未取代的氨基甲酰基，羧基或 其酯基; A'为取代或未取代的芳基）。

公开(公告)号：US4537847A

公开(公告)日：1985-08-27

申请号：US640205

申请日：1984-08-10

申请人： Jiro Takahashi ,  Kiyoshi Sawada ,  Akira Kinoshita ,  Tawara Komamura ,  Satoshi Goto ,  Osamu Sasaki

发明人： Jiro Takahashi ,  Kiyoshi Sawada ,  Akira Kinoshita ,  Tawara Komamura ,  Satoshi Goto ,  Osamu Sasaki

IPC分类号： C09B35/02 ,  C09B56/04 ,  G03G5/06

CPC分类号： C09B35/02 ,  C09B56/04 ,  G03G5/0677 ,  G03G5/0683 ,  G03G5/0685

摘要： Photoreceptor for electrophotography comprising a conductive support and an overlaying photosensitive layer thereon, said photosensitive layer containing at least one azo compound of Formula I or II ##STR1## wherein Ar.sub.1, Ar.sub.2, Ar.sub.3 and Ar.sub.4 each is an aromatic hydrocarbon ring radical or an aromatic heterocyclic ring radical; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each is an electron attractive group or hydrogen provided that at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is an electron attractive group; and A is ##STR2## wherein X is a hydroxy group or a group represented by the formula: ##STR3## wherein R.sub.6 and R.sub.7 each is hydrogen or an alkyl group, and R.sub.8 is an alkyl or aryl group; Y is halogen, an alkyl or alkoxy group, a carboxy group, a sulfo group, a carbamoyl or sulfamoyl group; Z is an atomic group necessary for making an aromatic hydrocarbon ring or an aromatic heterocyclic ring; R.sub.5 is hydrogen, an amino or carbamoyl group, a carboxy group or an ester group thereof; Ar.sub.5 is an aryl group; n is an integer of 1, 2 or 3; and m is an integer of 0, 1 or 2.

摘要翻译： 用于电子照相的感光体包括导电支撑体和其上的覆盖感光层，所述感光层含有至少一种式I或II式II的偶氮化合物，其中Ar1，Ar2，Ar3和Ar4各自为芳族 烃环基或芳族杂环基; R 1，R 2，R 3和R 4各自是吸电子基团或氢，条件是R 1，R 2，R 3和R 4中的至少一个是吸电子基团; 其中X为羟基或由下式表示的基团：其中R 6和R 7各自为氢或烷基，R 8为烷基或芳基 组; Y是卤素，烷基或烷氧基，羧基，磺基，氨基甲酰基或氨磺酰基; Z是制备芳族烃环或芳族杂环所必需的原子团; R5是氢，氨基或氨基甲酰基，羧基或其酯基; Ar5是芳基; n为1,2或3的整数; m为0,1或2的整数。

公开(公告)号：US4426432A

公开(公告)日：1984-01-17

申请号：US372228

申请日：1982-04-26

申请人： Kiyoshi Sawada ,  Satoshi Goto ,  Osamu Sasaki ,  Jiro Takahashi ,  Tawara Komamura

发明人： Kiyoshi Sawada ,  Satoshi Goto ,  Osamu Sasaki ,  Jiro Takahashi ,  Tawara Komamura

IPC分类号： C07D209/54 ,  C07D209/88 ,  C07D213/76 ,  C07D221/14 ,  C07D231/46 ,  G03G5/06 ,  G03G5/09

CPC分类号： G03G5/0687 ,  G03G5/0688 ,  G03G5/09

摘要： There is disclosed an electrophotosensitive receptor which comprises a conductive support and an electrophotosensitive layer which comprises a carrier transporting material and a specified trisazo compound wherein the azo compound is applied as a coating solution containing a solvent or as a liquid dispersion mixture containing a dispersion medium. Alternatively, the electrophotosensitive receptor comprises a conductive support and an electrophotosensitive layer which comprises said azo compound wherein the azo compound is applied as a coating solution containing a solvent and a binder or as a liquid dispersion medium containing a dispersion medium and a binder.

摘要翻译： 公开了一种电光敏感受体，其包含导电性载体和光电敏感层，其包含载体输送材料和特定的三偶氮化合物，其中偶氮化合物作为包含溶剂的涂布溶液或作为含有分散介质的液体分散混合物施加。 或者，电光敏感受体包括导电性载体和包含所述偶氮化合物的光电敏感层，其中偶氮化合物作为包含溶剂和粘合剂的涂布溶液或作为含有分散介质和粘合剂的液体分散介质施加。

公开(公告)号：US4425422A

公开(公告)日：1984-01-10

申请号：US375547

申请日：1982-05-06

申请人： Tawara Komamura ,  Jiro Takahashi ,  Ryuichiro Kobayashi

发明人： Tawara Komamura ,  Jiro Takahashi ,  Ryuichiro Kobayashi

IPC分类号： G03C8/56 ,  C09B29/28 ,  C09B29/42 ,  C09B29/50 ,  G03C8/10 ,  G03C1/40 ,  G03C1/10 ,  G03C5/54 ,  G03C7/00

CPC分类号： C09B29/28 ,  C09B29/363 ,  C09B29/366 ,  G03C8/10

摘要： A method for the formation of a color photographic image comprising exposure and development of a photographic element, said photographic element comprising at least one silver halide emulsion layer, a compound capable of releasing a diffusible azo dye compound during development, and at least one mordant layer arranged on a support. The color image formation is effected by the reaction of multivalent metallic ions with an azo dye compound having the formula: ##STR1## wherein G.sup.1 is an alkoxy or a thioalkoxy metallic chelating group; G.sup.2 is a metallic chelating group in which an oxygen atom is involved in the chelate formation; and Z.sup.1 and Z.sup.2 each is a group of atoms necessary to form an aromatic carbocyclic ring or a heterocyclic ring. The azo dye compound and the metallic ions form a metal complex by coordination of the azo group and the G.sup.1 and G.sup.2 groups of the azo dye compound with the multivalent metallic ions.

摘要翻译： 一种用于形成彩色摄影图像的方法，包括曝光和显影照相元件，所述照相元件包括至少一种卤化银乳剂层，在显影期间能够释放可扩散偶氮染料化合物的化合物，以及至少一种媒染剂层 安排在支持上。 彩色图像形成通过多价金属离子与具有下式的偶氮染料化合物的反应来实现：其中G1是烷氧基或硫代烷氧基金属螯合基团; G2是金属螯合基团，其中氧原子参与螯合物形成; 并且Z 1和Z 2各自是形成芳族碳环或杂环所必需的一组原子。 偶氮染料化合物和金属离子通过偶氮基团和偶氮染料化合物的G1和G2基团与多价金属离子的配位形成金属络合物。

公开(公告)号：US4416979A

公开(公告)日：1983-11-22

申请号：US375545

申请日：1982-05-06

申请人： Jiro Takahashi ,  Tawara Komamura ,  Ryuichiro Kobayashi

发明人： Jiro Takahashi ,  Tawara Komamura ,  Ryuichiro Kobayashi

IPC分类号： C09B45/00 ,  C09B29/28 ,  G03C8/10 ,  G03C7/00 ,  G03C1/10 ,  G03C1/40 ,  G03C5/54

CPC分类号： C09B29/28 ,  G03C8/10

摘要： A photographic light-sensitive element for a color diffusion transfer process which has a silver halide emulsion layer and also employs a nondiffusible cyan dye releasing compound. The compound is capable of releasing a diffusible metallic complex which forms an azo dye under alkaline conditions as a function of the development of the silver halide in said silver halide emulsion layer.

摘要翻译： 一种用于彩色扩散转印方法的照相感光元件，其具有卤化银乳剂层，并且还采用不扩散的青色染料释放化合物。 该化合物能够释放在碱性条件下形成偶氮染料的可扩散金属络合物，作为所述卤化银乳剂层中卤化银的发展的函数。

公开(公告)号：US4368260A

公开(公告)日：1983-01-11

申请号：US333900

申请日：1981-12-23

申请人： Tawara Komamura ,  Jiro Takahashi ,  Ryuichiro Kobayashi

发明人： Tawara Komamura ,  Jiro Takahashi ,  Ryuichiro Kobayashi

IPC分类号： C09B29/42 ,  G03C8/10 ,  G03C1/40 ,  G03C1/10

CPC分类号： G03C8/10 ,  C09B29/3621

摘要： A photographic light-sensitive element which comprises on a support a light-sensitive silver halide emulsion layer and having associated therewith a non-diffusible compound capable of, under alkaline condition, releasing a diffusible azo dye, said compound having the formula (1), ##STR1## wherein X represents a group of atoms necessary to complete a naphthalene ring or a benzene ring, G.sup.1 represents a hydroxy group, a salt thereof or a hydrolyzable precursor thereof, G.sup.2 represents a carboxy group, a salt thereof or a hydrolyzable precursor thereof, a hydroxy group, a salt thereof or a hydrolyzable precursor thereof, R.sup.1 is a hydrogen atom, an alkyl group or an aryl group, R.sup.2 is a hydrogen atom, an alkyl group or an aryl group, R.sup.2 represents a hydrogen atom, a halogen atom, an alkyl group, a carboxy group, a carbamoyl group or an amino group, each of which group may be substituted, R.sup.3 represents a hydrogen atom, a carboxy group, a carbamoyl group, a cyano group or a trifluoromethyl group, J represents a divalent linking group, Y represents a ballasted carrier moiety capable of releasing said diffusible dye under alkaline condition as a function of development of silver halide, m represents an integer of 1 to 3 and n represents zero or an positive integer not larger than m.

摘要翻译： 一种照相感光元件，其在支撑体上包含感光卤化银乳剂层，并且与其相关联地具有能够在碱性条件下释放扩散性偶氮染料的不扩散化合物，所述具有式（1）的化合物， （1）其中X表示完成萘环或苯环所需的原子团，G1表示羟基，其盐或其可水解的前体，G2表示羧基，其盐或 可水解的前体，羟基，其盐或其可水解的前体，R1是氢原子，烷基或芳基，R2是氢原子，烷基或芳基，R2表示氢原子 ，卤素原子，烷基，羧基，氨基甲酰基或氨基，其各自可以被取代，R 3表示氢原子，羧基，氨基甲酰基，氰基或三氟甲基， J表示二价连接基团，Y表示能够在碱性条件下作为卤化银显影的函数释放所述可扩散染料的压载载体部分，m表示1〜3的整数，n表示0或1〜 大于m。

公开(公告)号：US5032499A

公开(公告)日：1991-07-16

申请号：US384911

申请日：1989-07-25

申请人： Junichi Kohno ,  Tawara Komamura ,  Ken Okauchi

发明人： Junichi Kohno ,  Tawara Komamura ,  Ken Okauchi

IPC分类号： G03C1/498

CPC分类号： G03C1/49845

摘要： There is disclosed a thermal developing light-sensitive material comprising a support and, provided thereon, photographic structural layers comprising at least one layer containing light-sensitive silver halide, said photographic structural layer comprising a compound represented by general formula (1);Formula (1)X.sub.1 --L.sub.1 --Awherein X.sub.1 represents a residual group of a photographic restrainer, L.sub.1 is a mere bonding hand or a divalent group and A is selected from the group consisting of a hydrogen atom, an amino group, a hydroxyl group, a carboxyl group or a salt thereof, a sulfo group or a salt thereof and a sulfin group or a salt thereof;and a compound represented by general formula (2);Formula (2)X.sub.2 --L.sub.2 --Bwherein X.sub.2 represents a residual group of a photographic restrainer, L.sub.2 is a divalent group and B is a ballast group.

摘要翻译： 公开了一种热显影感光材料，其包括载体，并且在其上提供包含至少一层含有感光卤化银的照相结构层，所述照相结构层包含由通式（1）表示的化合物; 式（1）X1-L1-A其中X1表示摄影抑制剂的残基，L1仅为键合手或二价基团，A选自氢原子，氨基，羟基 ，羧基或其盐，磺基或其盐和亚磺酰基或其盐; 和由通式（2）表示的化合物。 式（2）X2-L2-B其中X2表示摄影抑制剂的残基，L2表示二价基团，B表示镇流剂组。

公开(公告)号：US4847188A

公开(公告)日：1989-07-11

申请号：US150777

申请日：1988-02-01

申请人： Tawara Komamura ,  Hidenobu Ohya

发明人： Tawara Komamura ,  Hidenobu Ohya

IPC分类号： G03C8/40

CPC分类号： G03C8/4033

摘要： A thermally developable light-sensitive material having at least a light-sensitive silver halide, a reducing agent, a binder and a dye-providing material on a support is disclosed. The dye-providing material is a compound that releases or forms a diffusible dye as a function of development and which has a group capable of reacting with the nucleophilic agent.

公开(公告)号：US4840870A

公开(公告)日：1989-06-20

申请号：US170063

申请日：1988-03-14

申请人： Masaru Iwagaki ,  Toyoaki Masukawa ,  Tawara Komamura ,  Wataru Ishikawa ,  Kimie Hoshino

发明人： Masaru Iwagaki ,  Toyoaki Masukawa ,  Tawara Komamura ,  Wataru Ishikawa ,  Kimie Hoshino

IPC分类号： B41M5/382 ,  B41M5/50 ,  B41M5/52 ,  G03C7/00 ,  G03C8/40

CPC分类号： G03C7/00 ,  B41M5/52 ,  B41M2205/02 ,  B41M2205/06 ,  B41M5/5227 ,  B41M5/5254 ,  B41M5/5272 ,  Y10S428/913 ,  Y10S428/914 ,  Y10S430/132

摘要： In a heat-transfer image-receiving element adapted to have a superposed relation, at least during a heat-transfer processing, with a heat-transfer element containing a heat-transferable dye donator, wherein said heat-transfer image-receiving element comprises at least one of compounds having the following general Formula (I), (II) or (III) and at least one of compounds having the following general Formula (IV) ##STR1## wherein R.sub.1, R.sub.1 ', R.sub.3, R.sub.3 ' and R.sub.5 each is a hydrogen atom, alkyl, alkenyl, cycloalkyl, phenyl, naphthyl, heterocyclic, acyl, alkylsulfonyl, arylsulfonyl or aralkylsulfonyl group; R.sub.2, R.sub.4, R.sub.4 ', R.sub.6 and R.sub.7 each is a hydrogen atom, a halogen atom, or a monovalent organic group, l is an integer of from 1 to 4, q is an integer of from 1 to 6, m, n and p each is an integer of from 1 to 3, provided if the l, m, n, p and q each is an integer of not less than 2, the R.sub.2, R.sub.4, R.sub.4 ', R.sub.6 and R.sub.7 are allowed to be either the same as or different from one another; R.sub.8, R.sub.9 and R.sub.10 each is a hydrogen atom, a halogen atom, alkyl, alkenyl, cycloalkyl, phenyl, naphthyl, heterocyclic, acyl, amino, alkylsulfonyl, arylsulfonyl or aralkylsulfonyl group, and a, b and c each is an integer of from 1 to 4, R.sub.8, R.sub.9 and R.sub.10 are allowed to be either the same as or different from one another. The heat-transfer image receiving element renders a dye image formed in the color heat-diffusion transfer process stable particularly under a light irradiation condition and excellent in stability against discoloration by light and heat.

摘要翻译： 在适于具有叠加关系的热传递图像接收元件中，至少在传热处理期间，使用含有可热转印染料供体的传热元件，其中所述热传递图像接收元件包括 至少一种具有下列通式（I），（II）或（III）的化合物和至少一种具有以下通式（Ⅳ）的化合物：式（I） 式（III）其中R1，R1'，R3，R3'和R5各自为氢原子，烷基，烯基，环烷基，苯基，萘基，杂环，酰基，烷基磺酰基，芳基磺酰基或芳烷基磺酰基 ; R2，R4，R4'，R6和R7各自为氢原子，卤素原子或一价有机基团，l为1〜4的整数，q为1〜6的整数，m，n和 p各自为1〜3的整数，如果l，m，n，p和q各自为不小于2的整数，则R2，R4，R4'，R6和R7被允许为 相同或不同; R 8，R 9和R 10各自为氢原子，卤素原子，烷基，烯基，环烷基，苯基，萘基，杂环，酰基，氨基，烷基磺酰基，芳基磺酰基或芳烷基磺酰基，a，b和c各自为 1至4，R8，R9和R10被允许彼此相同或不同。 传热图像接收元件使得在彩色热扩散转印过程中形成的染料图像特别在光照条件下稳定，并且对于光和热的变色的稳定性优异。

公开(公告)号：US5814580A

公开(公告)日：1998-09-29

申请号：US608285

申请日：1996-02-28

申请人： Akira Onishi ,  Noriyasu Kita ,  Noritaka Nakayama ,  Tatsuo Tanaka ,  Tawara Komamura

发明人： Akira Onishi ,  Noriyasu Kita ,  Noritaka Nakayama ,  Tatsuo Tanaka ,  Tawara Komamura

IPC分类号： B41M5/382 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/392 ,  B41M5/42 ,  B41M5/50 ,  B41M5/52 ,  C07D401/04 ,  C07D401/14 ,  C07D403/04 ,  C07D409/04 ,  C07D487/04 ,  C09B55/00 ,  C09B57/00 ,  D06P5/13 ,  B41M5/035 ,  B41M5/38

CPC分类号： B41M5/5218 ,  B41M5/39 ,  B41M5/392 ,  B41M5/426 ,  C09B55/009 ,  B41M2205/40 ,  Y10S428/913 ,  Y10S428/914

摘要： A thermal transfer recording material is disclosed, comprising an azomethine dye represented by the following formula and a metal ion-containing compound. ##STR1##

摘要翻译： 公开了一种热转印记录材料，其包含由下式表示的偶氮甲碱染料和含金属离子的化合物。 公式