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公开(公告)号：US4973718A
公开(公告)日：1990-11-27
申请号：US247300
申请日：1988-09-21
IPC分类号： C07B61/00 , B01J31/22 , C07D301/12 , C07D303/04
CPC分类号： C07D301/12 , C07D303/04
摘要： A method for the catalytic epoxidation of olefins with hydrogen peroxide in the presence of rhenium-oxo-complexes or of a binuclear compound of the type .mu.-oxobis [porphyrinato-oxo-rhenium(V)] with octaethyl porphyrin or 5,10,15,20-tetraphenyl porphyrin or 5,10,15,20-tetra(4-pyridyl)-porphyrin as ligands.
摘要翻译： 在铼 - 氧合配合物或双氧杂双环[卟啉 - 氧 - 铼（Ⅴ）]双环化合物存在下用过氧化氢催化环氧化烯烃的方法与八乙基卟啉或5,10,15 ，20-四苯基卟啉或5,10,15,20-四（4-吡啶基） - 卟啉作为配体。
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公开(公告)号：US4987226A
公开(公告)日：1991-01-22
申请号：US555672
申请日：1990-07-18
IPC分类号： C07D487/22
CPC分类号： C07D487/22
摘要： Rhenium-oxo complexes withoctaethyl porphyrin or5,10,15,20-tetraphenyl porphyrins or5,10,15,20-tetra(4-pyridyl)-porphyrins as ligandswhich optionally carry an anion on the central atom. Methods of preparing the complexes are also disclosed.
摘要翻译： 具有八乙基卟啉或5,10,15,20-四苯基卟啉或5,10,15,20-四（4-吡啶基） - 卟啉的铼 - 氧代配合物，其任选地在中心原子上带有阴离子。 还公开了制备络合物的方法。
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公开(公告)号：US4845252A
公开(公告)日：1989-07-04
申请号：US172245
申请日：1988-03-23
IPC分类号： B01J31/18 , B01J31/24 , B01J31/40 , C07B61/00 , C07D301/12 , C07D303/04
CPC分类号： C07D303/04 , B01J31/1815 , B01J31/4015 , C07D301/12 , B01J2231/72 , B01J2531/025 , B01J2531/66 , Y02P20/584
摘要： A method for the catalytic epoxidation of olefines with hydrogen peroxide in the presence of tungsten oxo complexes or of a binuclear compound of the type .mu.-oxobis [porphyrinato-oxo tungsten (V)] or cis-oxo peroxo tungsten (VI) prophyrin or cis-dioxo porphyrinatotungsten (VI) with octaethyl porphyrin or 5,10,15,20-tetraphenyl porphyrin or 5,10,15,20-tetra(4-pyridyl)-porphyrin as ligands.
摘要翻译： 在氧羰基络合物或双氧杂双环[卟啉 - 氧代钨（Ⅴ）]或顺式 - 氧代过氧钨（Ⅵ）卟啉或顺式的双核化合物存在下，用过氧化氢催化环氧化烯烃的方法 （VI）与八乙基卟啉或5,10,15,20-四苯基卟啉或5,10,15,20-四（4-吡啶基）卟啉作为配体。
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4.发明授权Catalyst for catalytic gas phase oxidation of olefins into unsaturated aldehydes and method for making the catalyst 失效用于催化气相氧化烯烃进入不饱和醛的催化剂和制备催化剂的方法
公开(公告)号：US5082819A
公开(公告)日：1992-01-21
申请号：US581702
申请日：1990-09-13
CPC分类号： B01J35/026 , B01J27/192 , C07C45/35
摘要： A catalyst is described for the production of unsaturated aldehydes by means of oxidation with a oxygen-containing gas where an active mass, containing at least the elements Mo, Bi, P and O, as well as Si-containing carrier material, is used in the form of a catalyst body with a certain ratio between the outer surface and the volume and with a defined extent in terms of space, porosity, density, specific surface, breaking strength, abrasion, and gas through-flow capability. Also described is a method of making the catalyst.
摘要翻译： 描述了一种用于通过用含氧气体氧化生产不饱和醛的催化剂，其中至少含有Mo，Bi，P和O元素以及含Si载体材料的活性物质用于 在外表面和体积之间具有一定比例的催化剂体的形式，在空间，孔隙率，密度，比表面积，断裂强度，磨损和气体穿透能力方面具有确定的程度。 还描述了制备催化剂的方法。
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公开(公告)号：US4705868A
公开(公告)日：1987-11-10
申请号：US890448
申请日：1986-07-30
申请人： Ulrich Deschler , Andreas Grund , Guenter Prescher
发明人： Ulrich Deschler , Andreas Grund , Guenter Prescher
IPC分类号： C07F7/04 , C07F7/18 , C07D303/02 , C07F7/02 , C07F7/08
CPC分类号： C07F7/1892 , C07F7/04
摘要： A process for the preparation of expoxidized organosilicon compounds by reacting the corresponding unsaturated organosilicon compounds with perpropionic acid in benzene solution. The said solution can also be employed in purified form with maximum contents of hydrogen peroxide, water, or mineral acid.
摘要翻译： 通过使相应的不饱和有机硅化合物与苯甲酸中的过丙酸反应来制备过氧化的有机硅化合物的方法。 所述溶液也可以以最大含量的过氧化氢，水或无机酸的纯化形式使用。
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6.发明授权Process for the production of acrolein by catalytic gas-phase oxidation of propene 失效通过催化气相氧化丙烯生产丙烯酸的方法
公开(公告)号：US5072052A
公开(公告)日：1991-12-10
申请号：US581696
申请日：1990-09-12
IPC分类号： B01J23/88 , B01J23/883 , B01J27/192 , B01J35/02 , B01J35/10 , C07B61/00 , C07C45/28 , C07C45/34 , C07C45/35 , C07C47/22
CPC分类号： B01J35/026 , B01J23/002 , B01J23/883 , B01J27/192 , C07C45/35 , B01J2523/00
摘要： The present invention relates to a process for the production of acrolein by catalytic gas-phase oxidation of propene with air in the presence of steam and an inert gas or waste gas from the reaction, the starting materials being passed in defined quantitative ratios at 300.degree. to 380.degree. C. under 1.4 to 2.2 bar pressure over a catalyst containing the combination of elements MoFeCoNiBiP(As)K(Rb,Cs)SmSiO in the form of a bed of individual elements, the catalyst elements fulfilling certain geometric conditions and a number of critical physico-chemical parameters and a specific load of 2 to 8 mol propene/dm.sup.3 catalyst bed/h being adjusted.
摘要翻译： 本发明涉及一种通过在蒸汽和惰性气体或来自反应的废气的存在下用空气催化气相氧化丙烯的方法，原料以规定的定量比在300℃下通过 在含有单体元素床形式的MoFeCoNiBiP（As）K（Rb，Cs）SmSiO的组合的催化剂下，在1.4至2.2巴的压力下，达到380℃，催化剂元素满足某些几何条件和数量 的关键物理化学参数和2至8摩尔丙烯/ dm 3催化剂床/ h的特定负荷进行调整。
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公开(公告)号：US4733008A
公开(公告)日：1988-03-22
申请号：US77844
申请日：1987-07-27
申请人： Juan Andrade , Klaus Koehler , Guenter Prescher
发明人： Juan Andrade , Klaus Koehler , Guenter Prescher
IPC分类号： C07B61/00 , B01J31/00 , C07C45/00 , C07C45/50 , C07C47/02 , C07C51/00 , C07C51/235 , C07C55/21 , C07C67/00
CPC分类号： C07C45/50 , C07C51/235
摘要： A process for the production of 1,12-dodecanoic diacid by hydroformylating an olefin in the presence of a rhodium catalyst and oxidation with oxygen of the aldehyde which is thus formed wherein 1,9-decadiene is hydroformylated in the presence of hydridotris-triphenylphosphine-rhodium-carbonyl combined with triphenylphospine and/or triphenylphosphite, and the 1,12-dodecanedialdehyde which was thus formed is oxidized with oxygen in the presence of inorganic or organic Co(II) salts.
摘要翻译： 通过在铑催化剂的存在下对烯烃进行加氢甲酰化并用如此形成的醛的氧气氧化制备1,12-十二烷二酸的方法，其中1,9-癸二烯在氢化三苯基膦 - 与三苯基膦和/或亚磷酸三苯酯结合的铑 - 羰基和由此形成的1,12-十二烷二醛在无机或有机Co（II）盐的存在下用氧气氧化。
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公开(公告)号：US4733007A
公开(公告)日：1988-03-22
申请号：US77843
申请日：1987-07-27
申请人： Juan Andrade , Klaus Koehler , Guenter Prescher
发明人： Juan Andrade , Klaus Koehler , Guenter Prescher
IPC分类号： C07B61/00 , B01J31/00 , C07C51/00 , C07C51/235 , C07C51/373 , C07C55/21 , C07C59/147 , C07C67/00
CPC分类号： C07C51/235
摘要： A process for the production of 1,12-dodecanoic diacid by hydroformylating an unsaturated carboxy compound in the presence of a rhodium catalyst and oxidation of the aldehyde with oxygen, wherein undecyl-10-ene-acid is hydroformylated in the presence of hydridotristriphenylphosphine-rhodium-carbonyl combined with triphenylphosphine and/or triphenylphosphite, and the 11-formyl undecanioc acid which is thus formed is oxidized with oxygen in the presence of inorganic and organic Co(II) salts.
摘要翻译： 在铑催化剂存在下加氢甲酰化不饱和羧基化合物并用氧气氧化醛的方法，其中十一烷基-10-烯酸在氢三溴三苯基膦 - 铑的存在下加氢甲酰化 - 羰基与三苯基膦和/或三苯基亚磷酸酯结合，并且由此形成的11-甲酰基十一烷酸在无机和有机Co（II）盐的存在下用氧气氧化。
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公开(公告)号：US4851556A
公开(公告)日：1989-07-25
申请号：US163239
申请日：1988-03-02
申请人： Rainer Siegmeier , Andreas Grund , Guenter Prescher , Udo Brandt
发明人： Rainer Siegmeier , Andreas Grund , Guenter Prescher , Udo Brandt
CPC分类号： C08C19/06
摘要： Epoxidized polybutadienes with an average molecular weight of 500 to 100,000 and a certain content of epoxide oxygen were prepared from the corresponding polybutadienes with use of perpropionic acid in a benzene solution. The solution can also be employed in unpurified form with maximum contents of 1.5 weight percent hydrogen peroxide 1.5 weight percent of water, and about 800 ppm of mineral acid.
摘要翻译： 在苯溶液中使用过丙酸从相应的聚丁二烯制备平均分子量为500至100,000的环氧化聚丁二烯和一定量的环氧化物氧。 溶液也可以非纯化形式使用，最大含量为1.5重量％过氧化氢1.5重量％的水和约800ppm的无机酸。
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公开(公告)号：US4734529A
公开(公告)日：1988-03-29
申请号：US944071
申请日：1986-12-22
申请人： Marion Berg , Andreas Grund , Guenter Prescher
发明人： Marion Berg , Andreas Grund , Guenter Prescher
CPC分类号： C07C45/58
摘要： The method for the isomerization of oxiranes of the general formula: ##STR1## wherein R.sub.1 and R.sub.3 are hydrogen; R.sub.2 is alkyl or alkylene groups of 3 to 26 carbon atoms or the phenyl group which may also be substituted, and R.sub.4 is hydrogen or alkyl from 1 to 26 carbon atoms and in which the carbon atoms of the epoxy ring can also form components of a cyclic system, wherein as a catalyst there is used alkali iodide and a polyethyleneglycol with an average mol mass of 400 to 10,000 with a boiling point, preferably above the boiling point of the carbonyl compounds that are formed.
摘要翻译： 环烷烃的异构化方法，其通式如下：其中R1和R3是氢; R 2为3〜26个碳原子的烷基或亚烷基或可被取代的苯基，R 4为氢或1〜26个碳原子的烷基，其中环氧环的碳原子也可以形成 其中作为催化剂使用碱金属碘化物和平均摩尔质量为400至10,000的聚乙二醇，其沸点，优选高于形成的羰基化合物的沸点。
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