Combating pests with novel oxime-carbamates
    1.
    发明授权
    Combating pests with novel oxime-carbamates 失效
    用新型肟 - 氨基甲酸酯防治害虫

    公开(公告)号:US4470984A

    公开(公告)日:1984-09-11

    申请号:US343132

    申请日:1982-01-27

    CPC分类号: A01N47/24

    摘要: An N-sulphenylated oxime-carbamate of the formula ##STR1## in which R.sup.1 is optionally substituted alkyl, cycloalkyl, aryl or aralkyl,R.sup.2 is alkyl, alkenyl or alkynyl, orR.sup.1 and R.sup.2 together are an alkylene bridge having 1-6 C atoms, one of R.sup.3 and R.sup.4 is the radical ##STR2## and the other is alkyl, alkenyl, alkynyl, halogenoalkyl, halogenoalkenyl or alkoxyalkyl,R.sup.5 is alkyl,R.sup.6 is alkyl, halogenoalkyl, optionally substituted phenyl, alkoxycarbonyl or dialkylamino, NR.sup.8 --SO.sub.2 R.sup.7, or a radical identical to the radical to which the grouping --S--R.sup.6 is bonded,R.sup.7 is alkyl, dialkylamino or optionally substituted phenyl,R.sup.8 is alkyl, andX is O or S,which possesses pesticidal activity.

    摘要翻译: 其中R 1为任选取代的烷基,环烷基,芳基或芳烷基,R 2为烷基,烯基或炔基,或者R 1和R 2一起为具有1-6个C原子的亚烷基桥基的N-磺基肟 - 氨基甲酸酯 R3和R4之一是基团,另一个是烷基,烯基,炔基,卤代烷基,卤代烯基或烷氧基烷基,R 5是烷基,R 6是烷基,卤代烷基,任意取代的苯基,烷氧基羰基或二烷基氨基,NR 8 -SO 2 R 7 或与基团-S-R6键合的基团相同的基团,R 7为烷基,二烷基氨基或任选取代的苯基,R 8为烷基,X为O或S,具有杀虫活性。

    Combating pests with novel phenoxypyridylmethyl esters
    4.
    发明授权
    Combating pests with novel phenoxypyridylmethyl esters 失效
    用新的苯氧基吡啶甲基酯来防治害虫

    公开(公告)号:US4491585A

    公开(公告)日:1985-01-01

    申请号:US355044

    申请日:1982-03-05

    摘要: New phenoxypyridylmethyl esters of the general formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given in the description andR represents the radical ##STR2## wherein R.sup.4 and R.sup.5 have the meaning given in the description, and represents the radical ##STR3## wherein R.sup.6 and R.sup.7 have the meaning given in the description, are obtained by a process in which carboxylic acids of the general formulaR--COOH (II)wherein R has the meaning given previously, or reactive derivatives of these acids, are reacted with phenoxypyridyl alcohols of the general formula ##STR4## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given above, or with reactive derivatives of these alcohols, if appropriate in the presence of acid acceptors, if appropriate in the presence of catalysts and if appropriate in the presence of diluents. The new phenoxypyridylmethyl esters of the formula (I) are distinguished by a high pesticidal, particularly insecticidal and acardicidal activity.

    摘要翻译: 新颖的通式(I)的苯氧基吡啶甲基酯其中R1,R2和R3具有说明书中给出的含义,R代表基团,其中R4和R5具有说明书中给出的含义,并且表示基团 其中R6和R7具有说明书中给出的含义,通过其中R具有以前给出的含义或这些酸的反应性衍生物的通式为R-COOH(II)的羧酸为 与式(III)的苯氧基吡啶醇反应,其中R 1,R 2和R 3具有上述含义,或与这些醇的活性衍生物反应,如果合适,在酸受体存在下,如果合适的话,在催化剂存在下 并在适当的情况下在稀释剂存在下进行。 式(I)的新的苯氧基吡啶基甲基酯的特征在于高杀虫性,特别是杀虫和杀虫活性。

    Combating pests with novel pyrazol-4-yl N-alkylcarbamates
    6.
    发明授权
    Combating pests with novel pyrazol-4-yl N-alkylcarbamates 失效
    用新的吡唑-4-基N-烷基氨基甲酸酯抗虫

    公开(公告)号:US4423058A

    公开(公告)日:1983-12-27

    申请号:US360138

    申请日:1982-03-22

    IPC分类号: A01N47/18 C07D231/18

    CPC分类号: C07D231/18 A01N47/18

    摘要: New pyrazol-4-yl N-alkylcarbamates of the general formula ##STR1## in which R.sup.1 represents an optionally substituted alkyl group having more than one carbon atom or an alkenyl, alkinyl or cycloalkyl group, andR.sup.2 represents an optionally substituted alkyl,alkenyl, alkinyl, cycloalkyl, aralkyl or aryl group, can be obtained if a 4-hydroxypyrazole of the general formula ##STR2## is reacted with an isocyanate of the general formulaR.sup.1 --N.dbd.C.dbd.O (III)or with a carbamoyl halide of the general formulaR.sup.1 --NH--CO--Hal (IV).The new compounds are distinguished by a high degree of activity as pest-combating agents, in particular by their insecticidal and nematicidal activity.

    摘要翻译: 新的吡唑-4-基N-烷基氨基甲酸酯,其中R 1表示任选取代的具有多于一个碳原子的烷基或烯基,炔基或环烷基,R 2表示任选取代的烷基 如果通式为(II)的4-羟基吡唑与通式为R 1 -N = C = O(III)的异氰酸酯反应,则可以得到,烯基,炔基,环烷基,芳烷基或芳基, 与通式为R 1 -NH-CO-Hal(IV)的氨基甲酰卤反应。 新化合物的特征在于作为防虫剂的高度活性,特别是其杀虫和杀线虫活性。

    N-Methyl-N-(sulphonic acid amide-n'-sulphenyl)-carbamic acid esters
    9.
    发明授权
    N-Methyl-N-(sulphonic acid amide-n'-sulphenyl)-carbamic acid esters 失效
    N-甲基-N-(磺酰胺 - 正 - 硫苯基) - 氨基甲酸酯

    公开(公告)号:US4212887A

    公开(公告)日:1980-07-15

    申请号:US948190

    申请日:1978-10-02

    摘要: N-Methyl-N-(sulphonic acid amide-N'-sulphenyl)-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1 to 4 carbon atoms in each alkyl radical, phenyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trihalogenomethyl substituent,R.sup.2 is alkyl with 2 to 8 carbon atoms, cycloalkyl, phenyl or cycloalkyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trifluoromethyl substituent, andR.sup.3 is phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl; phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl substituted at least once by trihalogenomethyl, halogen, nitro, cyano, cycloalkyl, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto, alkynylmercapto or dialkylamino, each with up to 4 carbon atoms per aliphatic moiety, or an oxime radical of the formula ##STR2## R.sup.4 and R.sup.5 each independently is cyano or alkyl, alkoxy, alkylthio, alkoxycarbonyl, dialkylcarbamoyl or dialkoxyphosphoryl with up to 4 carbon atoms per alkyl moiety, orR.sup.4 and R.sup.5, conjointly with the adjacent carbon atom, form an optionally methyl- or phenyl-substituted dithiolane, dithiane, oxathiolane or oxathiane ring.

    摘要翻译: 具有式(I)的N-甲基-N-(磺酰胺-N'-硫苯基) - 氨基甲酸酯,其中R 1是每个烷基中具有1至4个碳原子的二烷基氨基,苯基或苯基 至少一个卤素,具有1至4个碳原子的烷基,硝基或三卤代甲基取代基,R 2是具有2至8个碳原子的烷基,环烷基,苯基或环烷基或带有至少一个卤素的苯基,具有1至4个碳原子的烷基,硝基或 三氟甲基取代基,R 3为苯基,萘基,苯并二恶烷基,二氢苯并呋喃基或茚满基; 苯基,萘基,苯并二氧杂环戊烷基,二氢苯并呋喃基或茚满烷基,其被三卤代甲基,卤素,硝基,氰基,环烷基,甲酰氨基,二烷基或二氧戊环,或烷基,烯基,炔基,烷氧基,链烯氧基,炔氧基,烷基巯基,烯基巯基,炔基巯基或 每个脂族部分具有至多4个碳原子的二烷基氨基,或下式的肟基团R 4和R 5各自独立地为氰基或烷基,烷氧基,烷硫基,烷氧基羰基,二烷基氨基甲酰基或每烷基具有至多4个碳原子的二烷氧基磷酰基 部分,或R 4和R 5与相邻的碳原子一起形成任选的甲基 - 或苯基取代的二硫戊环,二噻烷,氧硫杂环戊烷或氧硫杂环。