ION EXCHANGE MEMBRANES CONTAINING INORGANIC PARTICLES
    3.
    发明申请
    ION EXCHANGE MEMBRANES CONTAINING INORGANIC PARTICLES 有权
    离子交换膜含有无机颗粒

    公开(公告)号:US20160067654A1

    公开(公告)日:2016-03-10

    申请号:US14783873

    申请日:2013-04-12

    IPC分类号: B01D69/12

    摘要: An ion exchange membrane and a method of making it. The membrane may be used, for example, in an electrodialysis module or electrochemical cell. The membrane comprises an ion exchange polymer and inorganic particles preferably linked to the ion exchange polymer. To make a membrane, inorganic particles are mixed into an ion exchange membrane pre-cursor. A polymerization initiator or catalyst is then added and the resulting mixture is placed in a form and cured. The inorganic particles may comprise, for example, an oxidized form of graphite such as graphite oxide. The ion exchange polymer may comprise an ionic monomer, containing a quaternary ammonium group for anion exchange or a sulfonate group for cation exchange, along with a crosslinking co-monomer containing polymerizable diacrylic functionalities. The membrane is self-supporting and can be made without a supporting fabric.

    摘要翻译: 一种离子交换膜及其制备方法。 膜可以用于例如电渗析模块或电化学电池中。 膜包含离子交换聚合物和优选连接到离子交换聚合物的无机颗粒。 为了制造膜,将无机颗粒混合到离子交换膜前体中。 然后加入聚合引发剂或催化剂,将所得混合物置于一种形式并固化。 无机颗粒可以包括例如氧化形式的石墨如氧化石墨。 离子交换聚合物可以包含含有用于阴离子交换的季铵基团或用于阳离子交换的磺酸盐基团的离子单体,以及含有可聚合二丙烯酸官能团的交联共聚单体。 膜是自支撑的,并且可以在没有支撑织物的情况下制造。

    METHOD OF POLYMERIZING AN IONIC CROSSLINKER
    4.
    发明申请

    公开(公告)号:US20200071462A1

    公开(公告)日:2020-03-05

    申请号:US16613360

    申请日:2017-05-15

    摘要: The present disclosure provides a polymerizing method where (i) an ionic crosslinker that includes a quaternary ammonium group and (ii) a non-ionic crosslinker, is polymerized in a reaction solution whose solvent is substantially a mixture of propylene glyocol (PG) and an aprotic amide-based solvent. The polymerization makes an anion-exchange polymer composition. The PG and the aprotic amide-based solvent are present in a weight ratio of from about 25:75 to about 70:30, and the reactants and solvents are present in amounts to generate the anion-exchange polymer composition with a theoretical water content from about 35% to about 60% (wt/wt).

    ION EXCHANGE POLYMERS AND A METHOD FOR MAKING ION EXCHANGE POLYMERS
    6.
    发明申请
    ION EXCHANGE POLYMERS AND A METHOD FOR MAKING ION EXCHANGE POLYMERS 审中-公开
    离子交换聚合物和制备离子交换聚合物的方法

    公开(公告)号:US20160228867A1

    公开(公告)日:2016-08-11

    申请号:US15022751

    申请日:2013-09-17

    IPC分类号: B01J41/12 B01D61/44 C08J5/22

    摘要: An ion exchange polymer is provided. The ion exchange polymer is a reaction product of a reaction between a crosslinker monomer and a cationic monomer. The crosslinker monomer is a reaction product of a reaction between a first crosslinking monomer and a second crosslinking monomer. Further, the cationic monomer comprises a quaternary ammonium group. A method for making an ion exchange polymer is also provided. The method comprises a step of preparing a curable solution and a step of curing the curable solution. The step of preparing the curable solution comprises mixing a pair of crosslinking monomers, a cationic monomer that comprises a quaternary ammonium group and an acid. A membrane is also provided. The membrane comprises the ion exchange polymer made by the method provided.

    摘要翻译: 提供离子交换聚合物。 离子交换聚合物是交联剂单体和阳离子单体之间的反应的反应产物。 交联剂单体是第一交联单体和第二交联单体之间的反应的反应产物。 此外,阳离子单体包含季铵基。 还提供了一种制备离子交换聚合物的方法。 该方法包括制备可固化溶液的步骤和固化可固化溶液的步骤。 制备可固化溶液的步骤包括混合一对交联单体,包含季铵基团的阳离子单体和酸。 还提供膜。 该膜包括通过所提供的方法制备的离子交换聚合物。