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    Processes for preparing certain hexaazaisowurtzitanes and their use in preparing hexanitrohexaazaisowurtzitane
    2.
    发明授权
    Processes for preparing certain hexaazaisowurtzitanes and their use in preparing hexanitrohexaazaisowurtzitane 有权
    制备某些六氮杂异纤锌矿型结构烷烃的方法及其在制备六硝基六氮杂异纤锌矿型结构烷烃

    公开(公告)号：US07875714B1

    公开(公告)日：2011-01-25

    申请号：US11789678

    申请日：2007-04-23

    申请人： Robert D. Chapman ,  Richard A. Hollins

    发明人： Robert D. Chapman ,  Richard A. Hollins

    IPC分类号： C07D255/00

    CPC分类号： C07D487/22

    摘要： The present invention describes a novel heavy-metal-free sequence leading to a superior, more economical, and scalable process for the high efficiency conversion of hexaallylhexaazaisowurtzitane (HAllylIW) to hexanitrohexaazaisowurtzitane (CL-20). The process of the present invention avoids both the preparation of benzyl chloride, which uses elemental chlorine, and catalytic hydrogenolysis steps that require palladium metal/compounds.It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.

    摘要翻译： 本发明描述了一种新的无重金属顺序，导致六烯丙基六氮杂异纤锌矿型结构烷烃（HAllylIW）高效转化为六硝基六氮杂异纤锌矿型结构烷烃（CL-20）的优越，更经济和可扩展的方法。 本发明的方法避免了使用元素氯的苄基氯的制备和需要钯金属/化合物的催化氢解步骤。 要强调的是，该摘要被提供以符合要求抽象的规则，允许搜索者或其他读者快速确定技术公开内容的主题。 提交它的理解是，它不会用于解释或限制权利要求的范围。

    Polarized films from pairwise-deposited semi-ionomeric syndioregic polymers
    4.
    发明授权
    Polarized films from pairwise-deposited semi-ionomeric syndioregic polymers 失效
    成对沉积的半离聚物共聚聚合物的极化膜

    公开(公告)号：US6114031A

    公开(公告)日：2000-09-05

    申请号：US246197

    申请日：1999-01-11

    申请人： Marion J. Roberts ,  John D. Stenger-Smith ,  Kenneth J. Wynne ,  Peter Zarras ,  Andrew P. Chafin ,  Richard A. Hollins ,  Geoffrey A. Lindsay

    发明人： Marion J. Roberts ,  John D. Stenger-Smith ,  Kenneth J. Wynne ,  Peter Zarras ,  Andrew P. Chafin ,  Richard A. Hollins ,  Geoffrey A. Lindsay

    IPC分类号： B05D1/20 ,  G02F1/361

    CPC分类号： B82Y30/00 ,  B05D1/202 ,  B82Y20/00 ,  B82Y40/00 ,  G02F1/3616 ,  G02F1/3618 ,  Y10T428/261

    摘要： This invention is comprised of new nonlinear optic polymers and a new Lanir-Blodgett (LB) film deposition scheme for which these polymers were designed. The invention is unique because it produces an electro-optic film which has never undergone electric-field poling nor high temperature treatment. It eliminates the dilution effect of the long hydrophobic alkyl groups, and creates stronger ionic bonds between the polymer chains. Finally, the invention reduces the time to make a film of a given thickness by at least half by virtue of depositing two polymer layers per stroke. The new polymers are comprised of asymmetric chromophores linked head-to-head by alternating two different kinds of bridging groups. One of the bridging groups contains one or more ionic groups, and the other bridging group contains one or more non-ionic, hydrophilic groups.

    摘要翻译： 本发明由新型非线性光学聚合物和这些聚合物设计的新型Langmuir-Blodgett（LB）薄膜沉积方案组成。 本发明是独特的，因为它产生从未经过电场极化或高温处理的电光膜。 它消除了长疏水烷基的稀释效应，并在聚合物链之间产生更强的离子键。 最后，本发明通过每冲程沉积两个聚合物层，减少了将给定厚度的膜制成至少一半的时间。 新的聚合物由不对称的发色团组成，通过交替两种不同种类的桥连基团与头对头连接。 桥连基团之一含有一个或多个离子基团，另一个桥连基团含有一个或多个非离子的亲水基团。

    Preparation of fine aluminum powders by solution methods
    5.
    发明授权
    Preparation of fine aluminum powders by solution methods 失效
    通过溶液法制备细铝粉

    公开(公告)号：US5885321A

    公开(公告)日：1999-03-23

    申请号：US684781

    申请日：1996-07-22

    申请人： Kelvin T. Higa ,  Curtis E. Johnson ,  Richard A. Hollins

    发明人： Kelvin T. Higa ,  Curtis E. Johnson ,  Richard A. Hollins

    IPC分类号： B22F9/24 ,  B22F9/30 ,  C22B21/00

    CPC分类号： C22B21/0053 ,  B22F9/24 ,  B22F9/30 ,  B22F2998/00

    摘要： Fine aluminum powders are prepared by decomposing alane-adducts in organic solvents under an inert atmosphere to provide highly uniform particles selectably sized from about 65 nm to about 500 nm and believed particularly effective as fuels and additives, in pyrotechnics, and in energetic materials including composites, super thermite, and other explosives. Effective adduct species are trialkyl amines and tetramethylethylenediamine, ethers and other aromatic amines being believed effective. Effective production is obtained at atmospheric pressure and at temperatures as low as 50.degree. C. with xylene solvent. Increased production rate is achieved at higher temperatures. Toluene, dioxane, and tetramethylethylenediamine were also effective solvents. Aliphatic solvents and other aromatic and polar solvents are believed effective. Titanium catalyst was provided as a halide, amide, and alkoxide; and it is believed that the corresponding compounds of zirconium, hafnium, vanadium, niobium, and tantalum are effective as catalysts. Particle size was controlled by varying catalyst concentration and by varying the concentration of an adducting species, as by adding an amine to the solution or using an amine as the solvent. It is believed that particle size is controllable by varying the catalyst, concentration of the reactants, polarity of the solvent, reaction temperature, and the stage and rate at which the solution is brought to this temperature. The product powder is passivated in the reaction vessel by exposing the solution to air before product separation or by controlling the admission of air to the separated, dried powder.

    摘要翻译： 通过在惰性气氛下在有机溶剂中分解丙烯加成物制备细铝粉，以提供高度均匀的颗粒，其尺寸可选择为约65nm至约500nm，并且被认为特别有效作为烟火中的燃料和添加剂，以及包括复合材料在内的高能材料 ，超级铁和其他炸药。 有效的加成物质是三烷基胺和四甲基乙二胺，醚和其他芳族胺被认为是有效的。 在大气压和低于50℃的温度下用二甲苯溶剂有效生产。 在较高的温度下实现生产率的提高。 甲苯，二恶烷和四甲基乙二胺也是有效的溶剂。 脂肪族溶剂和其他芳族和极性溶剂被认为是有效的。 提供钛催化剂作为卤化物，酰胺和醇盐; 相信锆，铪，钒，铌和钽的相应化合物作为催化剂是有效的。 通过改变催化剂浓度和通过改变加合物质的浓度来控制粒度，如通过向溶液中加入胺或使用胺作为溶剂。 据信通过改变催化剂，反应物的浓度，溶剂的极性，反应温度以及溶液达到该温度的阶段和速率来控制粒度。 通过在产品分离之前将溶液暴露于空气或通过控制空气进入分离的干燥粉末，将产物粉末在反应容器中钝化。

    Processes for preparing certain hexaazaisowurtzitanes and their use in preparing hexanitrohexaazaisowurtzitane
    6.
    发明授权
    Processes for preparing certain hexaazaisowurtzitanes and their use in preparing hexanitrohexaazaisowurtzitane 有权
    制备某些六氮杂异纤锌矿型结构烷烃的方法及其在制备六硝基六氮杂异纤锌矿型结构烷烃

    公开(公告)号：US08268991B1

    公开(公告)日：2012-09-18

    申请号：US12022930

    申请日：2008-01-30

    申请人： Robert D. Chapman ,  Richard A. Hollins

    发明人： Robert D. Chapman ,  Richard A. Hollins

    IPC分类号： C07D487/00

    CPC分类号： C07D487/22

    摘要： The present invention describes a novel heavy-metal-free sequence leading to a superior, more economical, and scalable process for the high efficiency conversion of hexaallylhexaazaisowurtzitane (HAllylIW) to hexa(1-propenyl)hexaazaisowurtzitane (HPIW) and hence via reaction with singlet oxygen and subsequent nitrolysis to hexanitrohexaazaisowurtzitane (CL-20).

    摘要翻译： 本发明描述了一种新的无重金属顺序，导致六烯丙基六氮杂异纤锌矿型结构烷烃（HAllylIW）与六（1-丙烯基）六氮杂异纤锌矿型结构烷烃（HPIW）的高效转化并因此通过与单线态反应的优异，更经济和可扩展的方法 氧和随后的硝基分解到六硝基六氮杂异纤锌矿型结构烷烃（CL-20）。

    Octafluoropentaerythrityltetramine (octafluoro-peta) and process for its preparation
    7.
    发明授权
    Octafluoropentaerythrityltetramine (octafluoro-peta) and process for its preparation 有权
    八氟五季戊四醇（八氟 - peta）及其制备方法

    公开(公告)号：US08008527B1

    公开(公告)日：2011-08-30

    申请号：US12496962

    申请日：2009-07-02

    申请人： Robert D. Chapman ,  Richard A. Hollins

    发明人： Robert D. Chapman ,  Richard A. Hollins

    IPC分类号： C07C291/00

    CPC分类号： C07C239/04

    摘要： A composition and method of manufacturing the same. Embodiments of an aspect of the invention relate to the formula C(CH2NF2)4 having the name octafluoropentaerythrityltetramine (octafluoro-PETA). In embodiments of another aspect generally relate to a method for manufacturing octafluoropentaerythrityltetramine (octafluoro-PETA) including, basifying pentaerythrityltetramine tetrahydrochloride in an aqueous solution with an aqueous alkali and treating with alkyl chloroformate for producing a tetraalkyl pentaerythrityltetra carbamate, extracting the compound into a nonaqueous solvent suitable for extraction from water and removing the solvent for providing a pure form of tetraethyl pentaerythrityltetracarbamate, bubbling elemental fluorine and/or mixtures of fluorine with an inert gas through tetraalkyl pentaerythrityltetracarbamate in a solvent suitable for direct fluorinations of protected amines until excess fluorine appears, and purifying the resultant octafluoropentaerythrityltetramine.

    摘要翻译： 一种组合物及其制造方法。 本发明的一个方面的实施方案涉及具有名称八氟五甲基四胺（octadecluoro-PETA）的式C（CH 2 NF 2）4。 在另一方面的实施方案中，一般涉及制备八氟季戊四醇四胺（八氟-PETA）的方法，其包括在含水碱的水溶液中碱化季戊四醇四胺盐酸盐，并用氯甲酸烷基酯处理以制备四烷基季戊四醇四氨基甲酸酯，将该化合物萃取到非水溶剂 适用于从水中萃取并除去溶剂以提供纯形式的四乙基季戊四醇四氨基甲酸盐，在适用于直接氟化被保护的胺直到氟出现的溶剂中，将元素氟和/或氟与惰性气体的混合物通过四烷基季戊四醇四氨基甲酸四烷基季铵式四氨基甲酸铵鼓泡， 纯化所得的八氟季戊四醇四胺。