公开(公告)号：US08268991B1

公开(公告)日：2012-09-18

申请号：US12022930

申请日：2008-01-30

申请人： Robert D. Chapman ,  Richard A. Hollins

发明人： Robert D. Chapman ,  Richard A. Hollins

IPC分类号： C07D487/00

CPC分类号： C07D487/22

摘要： The present invention describes a novel heavy-metal-free sequence leading to a superior, more economical, and scalable process for the high efficiency conversion of hexaallylhexaazaisowurtzitane (HAllylIW) to hexa(1-propenyl)hexaazaisowurtzitane (HPIW) and hence via reaction with singlet oxygen and subsequent nitrolysis to hexanitrohexaazaisowurtzitane (CL-20).

摘要翻译： 本发明描述了一种新的无重金属顺序，导致六烯丙基六氮杂异纤锌矿型结构烷烃（HAllylIW）与六（1-丙烯基）六氮杂异纤锌矿型结构烷烃（HPIW）的高效转化并因此通过与单线态反应的优异，更经济和可扩展的方法 氧和随后的硝基分解到六硝基六氮杂异纤锌矿型结构烷烃（CL-20）。

公开(公告)号：US08008527B1

公开(公告)日：2011-08-30

申请号：US12496962

申请日：2009-07-02

申请人： Robert D. Chapman ,  Richard A. Hollins

发明人： Robert D. Chapman ,  Richard A. Hollins

IPC分类号： C07C291/00

CPC分类号： C07C239/04

摘要： A composition and method of manufacturing the same. Embodiments of an aspect of the invention relate to the formula C(CH2NF2)4 having the name octafluoropentaerythrityltetramine (octafluoro-PETA). In embodiments of another aspect generally relate to a method for manufacturing octafluoropentaerythrityltetramine (octafluoro-PETA) including, basifying pentaerythrityltetramine tetrahydrochloride in an aqueous solution with an aqueous alkali and treating with alkyl chloroformate for producing a tetraalkyl pentaerythrityltetra carbamate, extracting the compound into a nonaqueous solvent suitable for extraction from water and removing the solvent for providing a pure form of tetraethyl pentaerythrityltetracarbamate, bubbling elemental fluorine and/or mixtures of fluorine with an inert gas through tetraalkyl pentaerythrityltetracarbamate in a solvent suitable for direct fluorinations of protected amines until excess fluorine appears, and purifying the resultant octafluoropentaerythrityltetramine.

摘要翻译： 一种组合物及其制造方法。 本发明的一个方面的实施方案涉及具有名称八氟五甲基四胺（octadecluoro-PETA）的式C（CH 2 NF 2）4。 在另一方面的实施方案中，一般涉及制备八氟季戊四醇四胺（八氟-PETA）的方法，其包括在含水碱的水溶液中碱化季戊四醇四胺盐酸盐，并用氯甲酸烷基酯处理以制备四烷基季戊四醇四氨基甲酸酯，将该化合物萃取到非水溶剂 适用于从水中萃取并除去溶剂以提供纯形式的四乙基季戊四醇四氨基甲酸盐，在适用于直接氟化被保护的胺直到氟出现的溶剂中，将元素氟和/或氟与惰性气体的混合物通过四烷基季戊四醇四氨基甲酸四烷基季铵式四氨基甲酸铵鼓泡， 纯化所得的八氟季戊四醇四胺。

公开(公告)号：US5882785A

公开(公告)日：1999-03-16

申请号：US800943

申请日：1997-01-23

申请人： Richard A. Hollins ,  Geoffrey A. Lindsay ,  Marion J. Roberts ,  Peter Zarras ,  John D. Stenger-Smith ,  Kenneth J. Wynne ,  Andrew P. Chafin

发明人： Richard A. Hollins ,  Geoffrey A. Lindsay ,  Marion J. Roberts ,  Peter Zarras ,  John D. Stenger-Smith ,  Kenneth J. Wynne ,  Andrew P. Chafin

IPC分类号： B05D1/20 ,  G02F1/361 ,  C09K19/02 ,  C09K19/48

CPC分类号： B82Y30/00 ,  B05D1/202 ,  B82Y20/00 ,  B82Y40/00 ,  G02F1/3616 ,  G02F1/3618 ,  Y10T428/261 ,  Y10T428/31504 ,  Y10T428/31728

摘要： This invention is comprised of new nonlinear optic polymers and a new Lanir-Blodgett (LB) film deposition scheme for which these polymers were designed. The invention is unique because it produces an electro-optic film which has never undergone electric-field poling nor high temperature treatment. It eliminates the dilution effect of the long hydrophobic alkyl groups, and creates stronger ionic bonds between the polymer chains. Finally, the invention reduces the time to make a film of a given thickness by at least half by virtue of depositing two polymer layers per stroke. The new polymers are comprised of asymmetric chromophores linked head-to-head by alternating two different kinds of bridging groups. One of the bridging groups contains one or more ionic groups, and the other bridging group contains one or more non-ionic, hydrophilic groups.

摘要翻译： 本发明由新型非线性光学聚合物和这些聚合物设计的新型Langmuir-Blodgett（LB）薄膜沉积方案组成。 本发明是独特的，因为它产生从未经过电场极化或高温处理的电光膜。 它消除了长疏水烷基的稀释效应，并在聚合物链之间产生更强的离子键。 最后，本发明通过每冲程沉积两个聚合物层，减少了将给定厚度的膜制成至少一半的时间。 新的聚合物由不对称的发色团组成，通过交替两种不同种类的桥连基团与头对头连接。 桥连基团之一含有一个或多个离子基团，另一个桥连基团含有一个或多个非离子的亲水基团。

公开(公告)号：USH753H

公开(公告)日：1990-03-06

申请号：US297891

申请日：1989-01-17

申请人： John H. Hall ,  Ronald A. Henry ,  Richard A. Hollins

发明人： John H. Hall ,  Ronald A. Henry ,  Richard A. Hollins

IPC分类号： C07D413/04

CPC分类号： C07D413/04

摘要： The quaternary salts of rigidized 1,3-oxazole compounds of the formula: ##STR1## where R is either H or CH.sub.3 O. The compounds are produced in a modif Robinson-Gabriel synthesis of oxazoles. These dyes are used in solution with non-interfering polar solvents, such as ethanol and H.sub.2 O, to form lasing media useful in dye lasers.

公开(公告)号：US07875714B1

公开(公告)日：2011-01-25

申请号：US11789678

申请日：2007-04-23

申请人： Robert D. Chapman ,  Richard A. Hollins

发明人： Robert D. Chapman ,  Richard A. Hollins

IPC分类号： C07D255/00

CPC分类号： C07D487/22

摘要： The present invention describes a novel heavy-metal-free sequence leading to a superior, more economical, and scalable process for the high efficiency conversion of hexaallylhexaazaisowurtzitane (HAllylIW) to hexanitrohexaazaisowurtzitane (CL-20). The process of the present invention avoids both the preparation of benzyl chloride, which uses elemental chlorine, and catalytic hydrogenolysis steps that require palladium metal/compounds.It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.

摘要翻译： 本发明描述了一种新的无重金属顺序，导致六烯丙基六氮杂异纤锌矿型结构烷烃（HAllylIW）高效转化为六硝基六氮杂异纤锌矿型结构烷烃（CL-20）的优越，更经济和可扩展的方法。 本发明的方法避免了使用元素氯的苄基氯的制备和需要钯金属/化合物的催化氢解步骤。 要强调的是，该摘要被提供以符合要求抽象的规则，允许搜索者或其他读者快速确定技术公开内容的主题。 提交它的理解是，它不会用于解释或限制权利要求的范围。

公开(公告)号：US06861497B2

公开(公告)日：2005-03-01

申请号：US10282307

申请日：2002-10-28

申请人： Geoffrey A. Lindsay ,  Richard A. Hollins ,  Peter Zaras ,  Andrew J. Guenthner ,  Andrew P. Chafin ,  Mathew C. Davis ,  Stephen Fallis

发明人： Geoffrey A. Lindsay ,  Richard A. Hollins ,  Peter Zaras ,  Andrew J. Guenthner ,  Andrew P. Chafin ,  Mathew C. Davis ,  Stephen Fallis

IPC分类号： C08G73/06 ,  C08G73/10 ,  C08L79/08 ,  C09K11/06 ,  H01L51/00 ,  H01L51/30 ,  C08G69/28 ,  B32B27/00

CPC分类号： C08G73/06 ,  C08G73/1085 ,  C08L79/08 ,  C09K11/06 ,  H01L51/0035 ,  H01L51/0043 ,  Y10T428/31504 ,  Y10T428/31721

摘要： A polyimide is disclosed of the formula: CG1 and CG2 are independently electron-accepting and/or electron-donating groups; x is an integer from about 3 to about 3000; ODAH is any of a number of known dianhydride residues; ODAM is any of a number of known diamine residues; and m, n, o, and p cumulatively add to 1.0, with the sum of m and n ranging from about 0.05 to about 1.0, the sum of o and p ranging from about 0 to about 0.95, the sum of m and o being about 0.5 and the sum of n and p being about 0.5. In addition, a film structure comprising the polyimide and devices utilizing the film structure are disclosed.

摘要翻译： 公开了下式的聚酰亚胺：CG1和CG2独立地是电子接受和/或给电子基团; x为约3至约3000的整数; ODAH是许多已知的二酐残基中的任何一种; ODAM是许多已知二胺残基中的任何一种; 并且m，n，o和p累积加到1.0，m和n的总和范围为约0.05至约1.0，o和p的总和范围为约0至约0.95，m和o的和为 约0.5，n和p的和为约0.5。 此外，公开了包含聚酰亚胺的膜结构和利用膜结构的装置。

公开(公告)号：US08426583B1

公开(公告)日：2013-04-23

申请号：US12982357

申请日：2010-12-30

申请人： Robert D. Chapman ,  Richard A. Hollins

发明人： Robert D. Chapman ,  Richard A. Hollins

IPC分类号： C07D255/00 ,  C07D487/22

CPC分类号： C07D487/22

摘要： A heavy-metal-free sequence leading to a superior, more economical, and scalable process for the high efficiency conversion of hexaallylhexaazaisowurtzitane (HAllylIW) to hexanitohexaazaisowurtzitane (CL-20).

摘要翻译： 一种无重金属的顺序，导致六烯丙基六氮杂异纤锌矿型结构烷烃（HAllylIW）高效转化为己烷六氮杂异纤锌矿型结构烷烃（CL-20）的优越，更经济和可扩展的工艺。

公开(公告)号：US08426582B1

公开(公告)日：2013-04-23

申请号：US12975968

申请日：2010-12-22

申请人： Robert D. Chapman ,  Richard A. Hollins

发明人： Robert D. Chapman ,  Richard A. Hollins

IPC分类号： C07D255/00 ,  C06B25/34

CPC分类号： C07D487/22

摘要： A heavy-metal-free sequence leading to a superior, more economical, and scalable process for the high efficiency conversion of hexaallylhexaazaisowurtzitane (HAllylIW) to hexanitrohexaazaisowurtzitane (CL-20).

摘要翻译： 一种无重金属的顺序，导致六烯丙基六氮杂异纤锌矿型结构烷烃（HAllylIW）高效转化为六硝基六氮杂异纤锌矿型结构烷烃（CL-20）的优越，更经济和可扩展的工艺。

公开(公告)号：US07435310B2

公开(公告)日：2008-10-14

申请号：US11452564

申请日：2006-06-07

申请人： M. Joseph Roberts ,  Scott K. Johnson ,  Richard A. Hollins ,  Curtis E. Johnson ,  Thomas J. Groshens ,  David J. Irvin

发明人： M. Joseph Roberts ,  Scott K. Johnson ,  Richard A. Hollins ,  Curtis E. Johnson ,  Thomas J. Groshens ,  David J. Irvin

IPC分类号： B29C39/12

CPC分类号： H01L27/14601 ,  B82Y10/00 ,  H01L27/14665 ,  H01L51/0004 ,  H01L51/0036 ,  H01L51/0048 ,  H01L51/422 ,  H01L51/424 ,  H01L51/426 ,  H01L2251/105 ,  Y02E10/549 ,  Y10S977/773 ,  Y10S977/778 ,  Y10S977/842 ,  Y10T156/1023 ,  Y10T156/1039 ,  Y10T156/1041 ,  Y10T156/1044

摘要： A method of making films surface imprinted with nanometer-sized particles to produce micro- and/or nano-structured electron and hole collecting interfaces, include providing at least one transparent substrate, providing at least one photoabsorbing conjugated polymer, providing a sufficient amount of nanometer-sized particles to produce a charge separation interface, providing at least one transparent polymerizable layer, embedding the nanometer-sized particles in the conjugated polymer, applying the polymerizable layer and the conjugated polymer/nanometer-sized particle mixture on separate substrates where the nanometer-sized particles form a stamp surface, imprinting the stamp surface into the surface of the polymerizable film layer to produce micro- and/or nano-structured electron and hole collecting interfaces, polymerizing the polymerizable film layer to form a conformal gap, and filling the gap with at least one photoabsorbing material to promote the generation of photoexcited electrons and transport to the charge separation interface.

摘要翻译： 制备表面印有纳米尺寸颗粒以产生微观和/或纳米结构的电子和空穴收集界面的膜的方法包括提供至少一个透明基底，提供至少一种光吸收共轭聚合物，提供足够量的纳米 提供至少一个透明可聚合层，将纳米尺寸的颗粒嵌入到共轭聚合物中，将可聚合层和共轭聚合物/纳米尺寸的颗粒混合物施加在分开的基底上， 大小的颗粒形成印模表面，将印模表面印刷到可聚合膜层的表面中以产生微观和/或纳米结构的电子和空穴收集界面，聚合可聚合膜层以形成共形间隙，并填充间隙 具有至少一种光吸收材料以促进产生光激发的电子 电解质和运输到电荷分离界面。

公开(公告)号：US5149818A

公开(公告)日：1992-09-22

申请号：US593413

申请日：1990-10-01

申请人： Stephen L. Christian ,  Andrew P. Chafin ,  Arnold T. Nielsen ,  Ronald L. Atkins ,  William P. Norris ,  Richard A. Hollins

发明人： Stephen L. Christian ,  Andrew P. Chafin ,  Arnold T. Nielsen ,  Ronald L. Atkins ,  William P. Norris ,  Richard A. Hollins

IPC分类号： C07D498/04

CPC分类号： C07D498/04

摘要： Aminonitrobenzodifuroxan (CL-18) is prepared by directly converting pentanitroaniline to aminonitrobenzodifuroxan with heat in the presence of an excess of sodium azide. The pentanitroaniline is prepared in high yield from 3,5-dinitroaniline with a mixture of nitric acid and sulfuric acid in which the final sulfuric acid concentration is from 99.0 to 99.5%.

摘要翻译： 在过量的叠氮化钠存在下，通过加热将戊基苯胺直接转化为氨基硝基苯并二呋喃来制备氨基硝基苯并二呋喃（CL-18）。 以硝酸和硫酸的混合物从3,5-二硝基苯胺以高产率制备戊基苯胺，其中最终硫酸浓度为99.0-99.5％。