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    Process for preparing superparamagnetic transition metal nanoparticles
    3.
    发明申请
    Process for preparing superparamagnetic transition metal nanoparticles 审中-公开
    制备超顺磁性过渡金属纳米粒子的方法

    公开(公告)号：US20070085053A1

    公开(公告)日：2007-04-19

    申请号：US11250336

    申请日：2005-10-14

    申请人： John Gergely ,  Edwin Marston ,  Shekhar Subramoney ,  Lu Zhang

    发明人： John Gergely ,  Edwin Marston ,  Shekhar Subramoney ,  Lu Zhang

    IPC分类号： C01G49/08

    CPC分类号： B22F9/14 ,  B22F2998/00 ,  B82Y25/00 ,  H01F1/0054 ,  B22F1/0018 ,  B22F1/02 ,  B22F2201/30 ,  B22F2202/13 ,  B22F2201/013 ,  B22F2201/10

    摘要： A process for preparing superparamagnetic transition metal nanoparticles by introducing into a gas stream a hydrocarbon and a transition metal carboxyl wherein the transition metal carbonyl is introduced downstream from the hydrocarbon; wherein at the point of introduction of the hydrocarbon the gas stream is in the form of a plasma, and wherein at the point of introduction of the transition metal carbonyl the gas stream is at a temperature of at least 1000° C.; followed by quenching to form carbon-coated transition metal nanoparticles; and wherein the gas stream consists essentially of at least one inert gas and hydrogen.

    摘要翻译： 一种制备超顺磁性过渡金属纳米颗粒的方法，该方法是将烃和过渡金属羧基引入气流中，其中过渡金属羰基被引入烃的下游; 其中在烃的引入点，气流为等离子体的形式，并且其中在引入过渡金属羰基的点处，气流的温度为至少1000℃。 然后淬火以形成碳涂覆的过渡金属纳米颗粒; 并且其中气流基本上由至少一种惰性气体和氢气组成。

    Process for the preparation of 1,1,1,2,2-pentafluoroethane
    4.
    发明授权
    Process for the preparation of 1,1,1,2,2-pentafluoroethane 失效
    制备1,1,1,2,2-五氟乙烷的方法

    公开(公告)号：US07074973B2

    公开(公告)日：2006-07-11

    申请号：US10523227

    申请日：2003-08-21

    申请人： Mario J. Nappa ,  Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Shekhar Subramoney ,  Munirpallam A. Subramanian ,  Allen C. Sievert

    发明人： Mario J. Nappa ,  Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Shekhar Subramoney ,  Munirpallam A. Subramanian ,  Allen C. Sievert

    IPC分类号： C07C17/00

    CPC分类号： C07C17/206 ,  B01J23/864 ,  B01J35/002 ,  B01J37/0236 ,  B01J37/03 ,  B01J37/26 ,  C07C17/21 ,  Y02P20/582 ,  C07C19/08

    摘要： A process for the preparation of pentafluoroethane is disclosed which involves contacting a mixture comprising hydrogen fluoride and at least one starting material selected from haloethanes of the formula CX3CHX2 and haloethanes of the formula CX2═CX2, where each X is independently selected from the group consisting of F and Cl (provided that no more than four of X are F), with a fluorination catalyst in a reaction zone to produce a product mixture comprising HF, HCl, pentafluoroethane, underfluorinated halogenated hydrocarbon intermediates and less than 0.2 mole percent chloropentafluoroethane based on the total moles of halogenated hydrocarbons in the product mixture. The process is characterized by the fluorination catalyst comprising (i) a crystalline cobalt-substituted alpha-chromium oxide where from about 0.05 atom % to about 6 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by trivalent cobalt (Co+3) and/or (ii) a fluorinated crystalline oxide of (i).

    摘要翻译： 公开了一种制备五氟乙烷的方法，其涉及将包含氟化氢和至少一种选自式CX 3 CHX 2 2的卤代乙烷的起始物质和 式CX 2 -CX 2 X，其中每个X独立地选自F和Cl（条件是不超过四个X为F），与 反应区中的氟化催化剂，以产生基于产物混合物中卤代烃总摩尔数的HF，HCl，五氟乙烷，过氟化卤代烃中间体和小于0.2摩尔％氯五氟乙烷的产物混合物。 该方法的特征在于氟化催化剂，其包含（i）结晶钴取代的α-氧化铬，其中α-氧化铬晶格中约0.05原子％至约6原子％的铬原子被三价钴（Co （ⅰ））和/或（ⅱ）氟化结晶氧化物。

    Process for the preparation of 1,3,3,3-tetrafluoropropene and/or 2,3,3,3-tetrafluoropropene
    5.
    发明授权
    Process for the preparation of 1,3,3,3-tetrafluoropropene and/or 2,3,3,3-tetrafluoropropene 失效
    制备1,3,3,3-四氟丙烯和/或2,3,3,3-四氟丙烯的方法

    公开(公告)号：US07678949B2

    公开(公告)日：2010-03-16

    申请号：US11988983

    申请日：2006-08-04

    申请人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

    发明人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

    IPC分类号： C07C17/00

    CPC分类号： C07C21/18 ,  B01J23/868 ,  B01J37/26 ,  C07C17/21 ,  C07C17/23 ,  C07C17/25 ,  C07C19/10

    摘要： A process for the manufacture of CF3CH═CHF and/or CF3CF═CH2 is disclosed. The process involves (a) reacting HF and chlorine and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or Cl) to produce a product including both CF3CCI2CCIF2 and CF3CCIFCCI2F; (b) reacting CF3CCI2CCIF2 and CF3CCIFCCI2F produced in (a) with hydrogen to produce a product including both CF3CH2CHF2 and CF3CHFCH2F; (c) dehydrofluorinating CF3CH2CHF2 and CF3CHFCH2F produced in (b) to produce a product including both CF3CH═CHF and CF3CF═CH2; and (d) recovering CF3CH═CHF and/or CF3CF═CH2 from the product produced in (c). In (a), both CF3CCI2CCIF2 and CF3CCIFCCI2F are produced in the presence of a chlorofluorination catalyst consisting of (i) compositions comprising a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by copper, and (ii) compositions of (i) which have been treated with a fluorinating agent.

    摘要翻译： 公开了制造CF 3 CH = CHF和/或CF 3 CF = CH 2的方法。 该方法包括（a）使HF和氯与至少一种式CX3CCI = CCIX的卤代丙烯（其中每个X独立地为F或Cl）反应以产生包含CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F的产物; （b）使（a）中制备的CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F与氢反应以产生包含CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的产物; （c）在（b）中制备的CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F脱氟化氟化产生包括CF 3 CH = CHF和CF 3 CF = CH 2的产物; 和（d）从（c）中制备的产物中回收CF 3 CH = CHF和/或CF 3CF≡CH2。 在（a）中，CF3CCI2CCIF2和CF3CCIFCCI2F都是在氯氟化催化剂存在下制备的，所述氯氟化催化剂由（i）包含结晶α-氧化铬的组合物组成，其中至少0.05原子％的α-氧化铬晶格中的铬原子被替换 和（ii）已经用氟化剂处理的（i）的组合物。

    Process for the preparation of 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropane
    6.
    发明授权
    Process for the preparation of 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropane 失效
    制备1,1,1,3,3-五氟丙烷和1,1,1,2,3-五氟丙烷的方法

    公开(公告)号：US07659435B2

    公开(公告)日：2010-02-09

    申请号：US11988200

    申请日：2006-08-04

    申请人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

    发明人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

    IPC分类号： C07C17/00 ,  C07C17/10

    CPC分类号： B01J23/868 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/26 ,  C07C17/21 ,  C07C17/23 ,  C07C19/08 ,  C08J9/146 ,  C07C19/10

    摘要： A process is disclosed for the manufacture of CF3CH2CHF2 and CF3CHFCH2F. The process involves (a) reacting hydrogen fluoride, chlorine, and at least one halopropene of the formula CX3CCl═CClX (where each X is independently F or Cl) to produce a product including both CF3CCl2CClF2 and CF3CClFCCl2F; (b) reacting CF3CCl2CClF2 and CF3CClFCCl2F produced in (a) with hydrogen to produce a product including both CF3CH2CHF2, and CF3CHFCH2F; and (c) recovering CF3CH2CHF2 and CF3CHFCH2F from the product produced in (b). In (a), the CF3CCl2CF3 and CF3CClFCClF2 are produced in the presence of a chlorofluorination catalyst including (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and/or (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.

    摘要翻译： 公开了用于制造CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的方法。 该方法包括（a）使氟化氢，氯和至少一种式CX3CCl-CClX（其中每个X独立地为F或Cl）的卤代丙烯反应以产生包含CF 3 CCl 2 CClF 2和CF 3 CClFCCl 2 F的产物; （b）使（a）中制备的CF 3 CCl 2 CClF 2和CF 3 CClFCCl 2 F与氢反应，生成包含CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的产物; 和（c）从（b）中制备的产物中回收CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F。 在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFCClF 2在氯氟化催化剂的存在下制备，包括（i）结晶α-氧化铬，其中至少0.05原子％的α-氧化铬晶格中的铬原子被二价铜 ，和/或（ⅱ）已经用氟化剂处理的（ⅰ）的含铬组合物。

    Process For The Preparation Of 1,1,1,3,3- Pentafluoropropane And 1,1,1,2,3- Pentafluoropropane
    7.
    发明申请
    Process For The Preparation Of 1,1,1,3,3- Pentafluoropropane And 1,1,1,2,3- Pentafluoropropane 失效
    1,1,1,3,3-五氟丙烷和1,1,1,2,3-五氟丙烷的制备方法

    公开(公告)号：US20090124836A1

    公开(公告)日：2009-05-14

    申请号：US11988200

    申请日：2006-08-04

    申请人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

    发明人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

    IPC分类号： C07C17/20 ,  C07C19/08

    CPC分类号： B01J23/868 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/26 ,  C07C17/21 ,  C07C17/23 ,  C07C19/08 ,  C08J9/146 ,  C07C19/10

    摘要： A process is disclosed for the manufacture of CF3CH2CHF2 and CF3CHFCH2F. The process involves (a) reacting hydrogen fluoride, chlorine, and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or CI) to produce a product including both CF3CCI2CCIF2 and CF3CCIFCCI2F; (b) reacting CF3CCI2CCIF2 and CF3CCIFCCI2F produced in (a) with hydrogen to produce a product including both CF3CH2CHF2, and CF3CHFCH2F; and (c) recovering CF3CH2CHF2 and CF3CHFCH2F from the product produced in (b). In (a), the CF3CCI2CF3 and CF3CCIFCCIF2 are produced in the presence of a chlorofluorination catalyst including (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and/or (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.

    摘要翻译： 公开了用于制造CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的方法。 该方法包括（a）使氟化氢，氯和至少一种式CX3CCI-CCIX（其中每个X独立地为F或Cl）的卤代丙烯反应以产生包含CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F的产物; （b）使（a）中制备的CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F与氢反应以产生包含CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的产物; 和（c）从（b）中制备的产物中回收CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F。 在（a）中，CF 3 CCl 2 CF 3和CF 3 CClFCCIF 2在氯氟化催化剂存在下制备，包括（i）α-氧化铬晶格中至少0.05原子％的铬原子被二价铜取代的结晶α-氧化铬 ，和/或（ⅱ）已经用氟化剂处理的（ⅰ）的含铬组合物。

    Process for the preparation of 1,3,3,3-tetrafluoropropene and/or 2,3,3,3-tetrafluoropropene
    8.
    发明申请
    Process for the preparation of 1,3,3,3-tetrafluoropropene and/or 2,3,3,3-tetrafluoropropene 失效
    制备1,3,3,3-四氟丙烯和/或2,3,3,3-四氟丙烯的方法

    公开(公告)号：US20090118554A1

    公开(公告)日：2009-05-07

    申请号：US11988983

    申请日：2006-08-04

    申请人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

    发明人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

    IPC分类号： C07C17/21

    CPC分类号： C07C21/18 ,  B01J23/868 ,  B01J37/26 ,  C07C17/21 ,  C07C17/23 ,  C07C17/25 ,  C07C19/10

    摘要： A process for the manufacture of CF3CH═CHF and/or CF3CF═CH2 is disclosed. The process involves (a) reacting HF and chlorine and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or Cl) to produce a product including both CF3CCI2CCIF2 and CF3CCIFCCI2F; (b) reacting CF3CCI2CCIF2 and CF3CCIFCCI2F produced in (a) with hydrogen to produce a product including both CF3CH2CHF2 and CF3CHFCH2F; (c) dehydrofluorinating CF3CH2CHF2 and CF3CHFCH2F produced in (b) to produce a product including both CF3CH═CHF and CF3CF═CH2; and (d) recovering CF3CH═CHF and/or CF3CF═CH2 from the product produced in (c). In (a), both CF3CCI2CCIF2 and CF3CCIFCCI2F are produced in the presence of a chlorofluorination catalyst consisting of (i) compositions comprising a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by copper, and (ii) compositions of (i) which have been treated with a fluorinating agent.

    摘要翻译： 公开了制备CF 3 CH-CHF和/或CF 3 CF-CH 2的方法。 该方法包括（a）使HF和氯以及至少一种式CX3CCI-CCIX（其中每个X独立地为F或Cl）的卤代丙烯反应，以产生包含CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F的产物; （b）使（a）中制备的CF 3 CCl 2 CCIF 2和CF 3 CClFCCI 2 F与氢反应以产生包含CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F的产物; （c）在（b）中制备的CF 3 CH 2 CHF 2和CF 3 CHFCH 2 F脱氟化氢，制得包含CF 3 CH-CHF和CF 3 CF-CH 2的产物; 和（d）从（c）中制备的产物中回收CF 3 CH-CHF和/或CF 3 CF-CH 2。 在（a）中，CF3CCI2CCIF2和CF3CCIFCCI2F都是在氯氟化催化剂存在下制备的，所述氯氟化催化剂由（i）包含α-氧化铬晶格中的至少0.05原子％的铬原子的结晶α-氧化铬的组合物组成 和（ii）已经用氟化剂处理的（i）的组合物。

    Process for the Preparation of 1,3,3,3-Tetrafluoropropene and/or 1,1,3,3,3-Pentafluoropropene
    10.
    发明申请
    Process for the Preparation of 1,3,3,3-Tetrafluoropropene and/or 1,1,3,3,3-Pentafluoropropene 失效
    制备1,3,3,3-四氟丙烯和/或1,1,3,3,3-五氟丙烯的方法

    公开(公告)号：US20090043138A1

    公开(公告)日：2009-02-12

    申请号：US11988259

    申请日：2006-08-04

    申请人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

    发明人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Capron Sievert ,  Shekhar Subramoney

    IPC分类号： C07C17/23

    CPC分类号： B01J23/868 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/26 ,  C07C17/206 ,  C07C17/21 ,  C07C17/23 ,  C07C17/25 ,  C07C17/354 ,  C07C19/08 ,  C07C21/18 ,  C07C19/10

    摘要： A process for the manufacture of CF3CH═CHF and/or CF3CH═CF2 is disclosed. The process involves involves (a) reacting HF and at least one halopropene of the formula CX3CCI═CCIX (where each X is independently F or CI) to produce a product including both CF3CCI═CF2 and CF3CHCICF3; (b) reacting CF3CCI═CF2 and/or CF3CHCICF3 produced in (a) with hydrogen to produce a product including CF3CH2CHF2 and/or CF3CH2CF3; (c) dehydrofluorinating CF3CH2CHF2 and/or CF3CH2CF3 produced in (b) to produce a product comprising CF3CH═CHF and/or CF3CH═CF2; and (d) recovering CF3CH═CHF and/or CF3CH═CF2 from the product produced in (c). In (a), the CF3CCI═CF2 and CF3CHCICF3 are produced in the presence of a fluorination catalyst comprising at least one chromium-containing component selected from (i) a crystalline alpha-chromium oxide where at least 0.05 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper, and (ii) a chromium-containing composition of (i) which has been treated with a fluorinating agent.

    摘要翻译： 公开了制造CF 3 CH-CHF和/或CF 3 CH-CF 2的方法。 该方法涉及（a）使HF和至少一种式CX3CCI-CCIX的卤代丙烯（其中每个X独立地为F或Cl）反应以产生包含CF 3 CCl-CF 2和CF 3 CHCICF 3的产物; （b）使（a）中制备的CF 3 CCl-CF 2和/或CF 3 CHCICF 3与氢反应以产生包含CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3的产物; （c）在（b）中制备的CF 3 CH 2 CHF 2和/或CF 3 CH 2 CF 3脱氟化氢以产生包含CF 3 CH-CHF和/或CF 3 CH-CF 2的产物; 和（d）从（c）中制备的产物中回收CF 3 CH-CHF和/或CF 3 CH-CF 2。 在（a）中，CF 3 CCl-CF 2和CF 3 CHCICF 3在含有至少一种含铬组分的氟​​化催化剂的存在下制备，所述含铬组分选自（i）结晶α-氧化铬，其中至少0.05原子％ 所述α-氧化铬晶格被二价铜取代，和（ii）已经用氟化剂处理的（i）的含铬组合物。