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公开(公告)号：US09561476B2
公开(公告)日：2017-02-07
申请号：US13672975
申请日：2012-11-09
申请人： Jonathan A. Lane , Jamie R. Wilson , Gervase Maxwell Christie , Nathalie Petigny , Christos Sarantopoulos
发明人： Jonathan A. Lane , Jamie R. Wilson , Gervase Maxwell Christie , Nathalie Petigny , Christos Sarantopoulos
IPC分类号： H01M8/10 , C25B13/04 , C25C7/04 , B01D53/22 , H01M8/12 , B01D71/02 , B01D69/12 , C01B13/02 , B01J23/00 , B01J29/10 , B01J23/86 , B01J35/00 , B01J35/02 , B01J35/06 , B01J35/10 , B01J37/02 , H01M4/86 , H01M4/88 , H01M4/90
CPC分类号： B01D71/024 , B01D53/228 , B01D69/12 , B01D2325/021 , B01D2325/10 , B01J23/002 , B01J23/10 , B01J23/862 , B01J29/10 , B01J35/002 , B01J35/023 , B01J35/065 , B01J35/109 , B01J37/0201 , B01J37/0213 , B01J2523/00 , C01B13/0255 , C01B2210/0046 , H01M4/8621 , H01M4/885 , H01M4/9033 , H01M8/1246 , Y02E60/521 , Y02E60/525 , Y02P70/56 , B01J2523/24 , B01J2523/36 , B01J2523/3706 , B01J2523/3712 , B01J2523/375 , B01J2523/48 , B01J2523/55 , B01J2523/67 , B01J2523/842 , B01J2523/35 , B01J2523/72
摘要： A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a microstructure exhibiting substantially uniform pore size distribution as a result of using PMMA pore forming materials or a bi-modal particle size distribution of the porous support layer materials. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.
摘要翻译： 一种复合氧传输膜，其具有致密层，多孔载体层和位于致密层和多孔载体层之间的中间多孔层。 致密层和中间多孔层都由离子导电材料形成以导电氧离子和导电材料以导电。 由于使用PMMA孔隙形成材料或多孔载体层材料的双峰粒度分布，多孔载体层具有高渗透性，高孔隙率和显微组织显示出基本均匀的孔径分布。 被选择用于促进可燃物质的氧化的催化剂颗粒位于中间多孔层和邻近中间多孔层的多孔载体中。 可以通过将催化剂前体的溶液通过多孔载体向中间多孔层芯吸而形成催化剂颗粒。
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公开(公告)号：US20130072374A1
公开(公告)日：2013-03-21
申请号：US13671835
申请日：2012-11-08
IPC分类号： B01J31/06 , B01J27/138
CPC分类号： B01J31/06 , B01D53/228 , B01D69/12 , B01D71/024 , B01D2325/021 , B01D2325/10 , B01J23/002 , B01J23/10 , B01J27/138 , B01J35/002 , B01J35/0033 , B01J35/023 , B01J35/065 , B01J37/0201 , B01J2523/00 , C01B13/0255 , C01B2210/0046 , B01J2523/24 , B01J2523/3706 , B01J2523/55 , B01J2523/67 , B01J2523/842 , B01J2523/3712 , B01J2523/72
摘要： A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a microstructure exhibiting substantially uniform pore size distribution as a result of using PMMA pore forming materials or a bi-modal particle size distribution of the porous support layer materials. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.
摘要翻译： 一种复合氧传输膜，其具有致密层，多孔载体层和位于致密层和多孔载体层之间的中间多孔层。 致密层和中间多孔层都由离子导电材料形成以导电氧离子和导电材料以导电。 由于使用PMMA孔隙形成材料或多孔载体层材料的双峰粒度分布，多孔载体层具有高渗透性，高孔隙率和显微组织显示出基本均匀的孔径分布。 被选择用于促进可燃物质的氧化的催化剂颗粒位于中间多孔层和邻近中间多孔层的多孔载体中。 可以通过将催化剂前体的溶液通过多孔载体向中间多孔层芯吸而形成催化剂颗粒。
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公开(公告)号：US20130072375A1
公开(公告)日：2013-03-21
申请号：US13672975
申请日：2012-11-09
IPC分类号： B01D71/02
CPC分类号： B01D71/024 , B01D53/228 , B01D69/12 , B01D2325/021 , B01D2325/10 , B01J23/002 , B01J23/10 , B01J23/862 , B01J29/10 , B01J35/002 , B01J35/023 , B01J35/065 , B01J35/109 , B01J37/0201 , B01J37/0213 , B01J2523/00 , C01B13/0255 , C01B2210/0046 , H01M4/8621 , H01M4/885 , H01M4/9033 , H01M8/1246 , Y02E60/521 , Y02E60/525 , Y02P70/56 , B01J2523/24 , B01J2523/36 , B01J2523/3706 , B01J2523/3712 , B01J2523/375 , B01J2523/48 , B01J2523/55 , B01J2523/67 , B01J2523/842 , B01J2523/35 , B01J2523/72
摘要： A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a microstructure exhibiting substantially uniform pore size distribution as a result of using PMMA pore forming materials or a bi-modal particle size distribution of the porous support layer materials. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.
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公开(公告)号：US20140311346A1
公开(公告)日：2014-10-23
申请号：US14322981
申请日：2014-07-03
IPC分类号： B01D53/22
CPC分类号： B01D53/228 , B01D67/0041 , B01D69/02 , B01D69/12 , B01D71/024 , B01D71/028 , B01D2255/402 , B01D2255/407 , B01D2255/902 , B01D2256/12 , B01D2257/104 , B01D2258/06 , B01D2325/023 , C01B13/0255 , C04B35/01 , C04B35/016 , C04B35/2633 , C04B35/42 , C04B35/44 , C04B35/462 , C04B35/488 , C04B38/00 , C04B2111/00612 , C04B2111/00801 , C04B2111/0081 , C04B2235/3208 , C04B2235/3217 , C04B2235/3222 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3234 , C04B2235/3243 , C04B2235/3246 , C04B2235/3262 , C04B2235/3268 , C04B2235/3272 , C04B2235/3274 , C04B2235/3275 , C04B2235/5445 , C04B2235/768 , C04B2235/80 , Y10T428/1314 , Y10T428/24997 , Y10T428/24999 , C04B35/48 , C04B38/0074 , C04B35/443 , C04B35/04
摘要： A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln1-xAx)wCr1-yByO3-δ and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La0.8Ca0.2)0.95Cr0.5Mn0.5O3-δ for the porous fuel oxidation and optional porous surface exchange layers and (La0.8Sr0.2)0.95Cr0.5Fe0.5O3-δ for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.
摘要翻译： 一种制备复合氧离子膜和复合氧离子膜的方法，其中多孔燃料氧化层和致密分离层以及任选的多孔表面交换层由（Ln1-xAx）wCr1的混合物形成在多孔载体上 -yByO3-δ和掺杂的氧化锆。 在多孔燃料氧化层和任选的多孔表面交换层中，A为钙，密实分离层A不为钙，优选为锶。 优选的材料是（La0.8Ca0.2）0.95Cr0.5Mn0.5O3-δ用于多孔燃料氧化和任选的多孔表面交换层和（La0.8Sr0.2）0.95Cr0.5Fe0.5O3-δ用于致密分离层 。 使用这种材料允许膜在空气中烧结而不使用成孔剂来降低膜的制造成本。 如本文所述用于形成多孔层的材料的使用具有用于形成任何类型的多孔结构例如催化剂载体的应用。
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公开(公告)号：US09492784B2
公开(公告)日：2016-11-15
申请号：US14322981
申请日：2014-07-03
IPC分类号： B01D53/22 , B01D67/00 , B01D69/02 , B01D69/12 , B01D71/02 , C01B13/02 , C04B38/00 , C04B35/01 , C04B35/26 , C04B35/42 , C04B35/44 , C04B35/462 , C04B35/488 , C04B111/00
CPC分类号： B01D53/228 , B01D67/0041 , B01D69/02 , B01D69/12 , B01D71/024 , B01D71/028 , B01D2255/402 , B01D2255/407 , B01D2255/902 , B01D2256/12 , B01D2257/104 , B01D2258/06 , B01D2325/023 , C01B13/0255 , C04B35/01 , C04B35/016 , C04B35/2633 , C04B35/42 , C04B35/44 , C04B35/462 , C04B35/488 , C04B38/00 , C04B2111/00612 , C04B2111/00801 , C04B2111/0081 , C04B2235/3208 , C04B2235/3217 , C04B2235/3222 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3234 , C04B2235/3243 , C04B2235/3246 , C04B2235/3262 , C04B2235/3268 , C04B2235/3272 , C04B2235/3274 , C04B2235/3275 , C04B2235/5445 , C04B2235/768 , C04B2235/80 , Y10T428/1314 , Y10T428/24997 , Y10T428/24999 , C04B35/48 , C04B38/0074 , C04B35/443 , C04B35/04
摘要： A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln1-xAx)wCr1-yByO3-δ and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La0.8Ca0.2)0.95Cr0.5Mn0.5O3-δ for the porous fuel oxidation and optional porous surface exchange layers and (La0.8Sr0.2)0.95Cr0.5Fe0.5O3-δ for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.
摘要翻译： 一种制备复合氧离子膜和复合氧离子膜的方法，其中多孔燃料氧化层和致密分离层以及任选的多孔表面交换层由（Ln1-xAx）wCr1的混合物形成在多孔载体上 -yByO3-δ和掺杂的氧化锆。 在多孔燃料氧化层和任选的多孔表面交换层中，A为钙，密实分离层A不为钙，优选为锶。 优选的材料是（La0.8Ca0.2）0.95Cr0.5Mn0.5O3-δ用于多孔燃料氧化和任选的多孔表面交换层和（La0.8Sr0.2）0.95Cr0.5Fe0.5O3-δ用于致密分离层 。 使用这种材料允许膜在空气中烧结而不使用成孔剂来降低膜的制造成本。 如本文所述用于形成多孔层的材料的使用具有用于形成任何类型的多孔结构例如催化剂载体的应用。
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公开(公告)号：US09486735B2
公开(公告)日：2016-11-08
申请号：US14856038
申请日：2015-09-16
申请人： Zigui Lu , Pawel J. Plonczak , Jonathan A. Lane
发明人： Zigui Lu , Pawel J. Plonczak , Jonathan A. Lane
IPC分类号： B01D53/22 , B01D69/12 , B01D71/02 , B01D67/00 , B01J19/24 , B01D69/02 , C04B35/01 , C04B35/26 , C04B35/42 , C04B35/44 , C04B35/462 , C04B35/488 , C04B38/02 , C01B13/02 , C04B111/00
CPC分类号： B01D53/228 , B01D67/0041 , B01D69/02 , B01D69/12 , B01D71/024 , B01D71/028 , B01D2255/204 , B01D2255/2063 , B01D2255/20738 , B01D2255/20784 , B01D2255/40 , B01D2255/402 , B01D2255/407 , B01D2255/902 , B01D2256/12 , B01D2257/104 , B01D2258/06 , B01D2325/023 , B01J19/2475 , B01J2219/24 , C01B13/0255 , C04B35/01 , C04B35/016 , C04B35/2633 , C04B35/42 , C04B35/44 , C04B35/462 , C04B35/488 , C04B38/02 , C04B2111/00612 , C04B2111/00801 , C04B2111/0081 , C04B2235/3208 , C04B2235/3217 , C04B2235/3222 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3234 , C04B2235/3243 , C04B2235/3246 , C04B2235/3262 , C04B2235/3268 , C04B2235/3272 , C04B2235/3274 , C04B2235/3275 , C04B2235/5445 , C04B2235/768 , C04B2235/80 , Y10T428/1314 , Y10T428/24997 , Y10T428/24999 , C04B35/48 , C04B38/0074
摘要： A method is described of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln1-xAx)wCr1-yByO3-δ and a doped zirconia. Preferred materials are (La0.8Sr0.2)0.95Cr0.7Fe0.3O3-δ for the porous fuel oxidation layer, (La0.8Sr0.2)0.95Cr0.5Fe0.5O3-δ for the dense separation layer, and (La0.8Sr0.2)0.95Cr0.3Fe0.7O3-δ for the porous surface exchange layer. Firing the said fuel activation and separation layers in nitrogen atmosphere unexpectedly allows the separation layer to sinter into a fully densified mass.
摘要翻译： 描述了一种制备复合氧离子膜和复合氧离子膜的方法，其中多孔燃料氧化层和致密分离层以及任选的多孔表面交换层由（Ln1-xAx）的混合物形成在多孔载体上 ）wCr1-yByO3-δ和掺杂的氧化锆。 优选的材料是用于多孔燃料氧化层的（La0.8Sr0.2）0.95Cr0.7Fe0.3O3-δ（La0.8Sr0.2）用于致密分离层的0.95Cr0.5Fe0.5O3-δ，（La0。 8Sr0.2）0.95Cr0.3Fe0.7O3-δ用于多孔表面交换层。 在氮气氛中烧制所述燃料活化和分离层意外地允许分离层烧结成完全致密的物质。
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公开(公告)号：US10441922B2
公开(公告)日：2019-10-15
申请号：US14753815
申请日：2015-06-29
IPC分类号： B32B3/26 , B01D71/02 , B01D67/00 , B01D69/12 , B01J23/46 , B01J23/89 , B01J35/06 , B01D69/04 , B01D69/10 , B01D53/22
摘要： A dual function composite oxygen transport membrane having a layered structure of mixed conducting oxygen transport materials on a first side of a porous substrate and a reforming catalyst layer on an opposing second side of the porous substrate. The layered structure of the mixed conducting oxygen transport materials contains an intermediate porous layer of mixed conducting oxygen transport materials formed on the porous substrate with a dense impervious layer of mixed conducting oxygen transport materials over the intermediate porous layer, and an optional surface exchange layer of mixed conducting oxygen transport materials over the dense impervious layer. The layered structure and the reforming catalyst layer are formed in separate steps.
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公开(公告)号：US20180299035A1
公开(公告)日：2018-10-18
申请号：US16014642
申请日：2018-06-21
申请人： Zigui Lu , Sang Muk Kwark , Joseph M. Corpus , Jonathan A. Lane , David P. Potempa , Maulik R. Shelat
发明人： Zigui Lu , Sang Muk Kwark , Joseph M. Corpus , Jonathan A. Lane , David P. Potempa , Maulik R. Shelat
IPC分类号： F16L9/02 , C09D131/02 , C09D5/26 , C08J9/00 , C09D101/28
CPC分类号： F16L9/02 , C08J9/0066 , C08J2301/28 , C08J2331/02 , C08K3/08 , C08K3/22 , C08K2003/0812 , C08K2201/003 , C08K2201/014 , C09D1/00 , C09D5/00 , C09D5/26 , C09D101/284 , C09D131/02 , C23C24/082 , F28F13/187 , Y02P20/124
摘要： A porous metallic coating is provided. The coating is characterized by a combination of optimized properties that improve coating performance, as measured by heat transfer efficiency. The porous coating has optimal ranges for properties such as porosity, particle size and thickness, and has particular applicability in boiling heat transfer applications as part of an air separations unit. The porous coatings are derived from slurry-based formulations that include a mixture of metallic particles, a binder and a solvent.
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公开(公告)号：US20090152107A1
公开(公告)日：2009-06-18
申请号：US11957926
申请日：2007-12-17
IPC分类号： C25B11/00
CPC分类号： H01M8/0232 , B01D53/326 , B01D2256/12 , C01B13/0248 , C01B13/0255 , H01M8/0206 , H01M8/0215 , H01M8/0226 , H01M8/0236 , H01M8/0243 , H01M8/0247 , H01M2008/1293
摘要： A current collector structure that is used to distribute an electrical potential to an electrode layer of an electrochemical cell. The electrochemical cell has an electrolyte layer adjacent the electrode layer for transport of oxygen ions. The current collector structure has a porous, electrically conductive layer located on the electrode layer. Additionally, at least one elongated strip-like layer formed of an electrically conductive material is located on the porous, electrically conductive layer, opposite the electrode and oriented in a lengthwise direction of the electrode layer.
摘要翻译： 用于将电位分布到电化学电池的电极层的集电器结构。 电化学电池具有邻近电极层的电解质层，用于输送氧离子。 集电器结构具有位于电极层上的多孔导电层。 此外，由导电材料形成的至少一个细长条状层位于与电极相对的多孔导电层上，并在电极层的长度方向上定向。
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公开(公告)号：US09789445B2
公开(公告)日：2017-10-17
申请号：US14853157
申请日：2015-09-14
申请人： Jonathan A. Lane , Zigui Lu , Pawel J. Plonczak
发明人： Jonathan A. Lane , Zigui Lu , Pawel J. Plonczak
CPC分类号： B01D71/024 , B01D53/228 , B01D67/0046 , B01D69/02 , B01D69/10 , B01D69/12 , B01D2325/023 , B01D2325/04 , B01D2325/26 , C01B13/0255
摘要： A composite oxygen ion transport membrane having a dense layer, a porous support layer, an optional intermediate porous layer located between the porous support layer and the dense layer and an optional surface exchange layer, overlying the dense layer. The dense layer has electronic and ionic phases. The ionic phase is composed of scandia doped, yttrium or cerium stabilized zirconia. The electronic phase is composed of a metallic oxide containing lanthanum, strontium, chromium, iron and cobalt. The porous support layer is composed of zirconia partially stabilized with yttrium, scandium, aluminum or cerium or mixtures thereof. The intermediate porous layer, if used, contains the same ionic and electronic phases as the dense layer. The surface exchange layer is formed of an electronic phase of a metallic oxide of lanthanum and strontium that also contains chromium, iron and cobalt and an ionic phase of scandia doped zirconia stabilized with yttrium or cerium.
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