公开(公告)号：US5670791A

公开(公告)日：1997-09-23

申请号：US561962

申请日：1995-11-22

申请人： Jonathan J. M. Halls ,  Richard H. Friend

发明人： Jonathan J. M. Halls ,  Richard H. Friend

IPC分类号： C08G61/10 ,  C08G61/00 ,  C08G61/12 ,  H01L31/10 ,  H01L51/00 ,  H01L51/05 ,  H01L51/30 ,  H01L51/42 ,  H01L35/24

CPC分类号： H01L51/428 ,  H01L51/0035 ,  H01L51/0038 ,  H01L51/4253 ,  H01L51/0043 ,  H01L51/0052 ,  Y02E10/549

摘要： First and second electrodes (3 and 4) are provided on respective ones (2' and 2") of the first and second major surfaces of a photoresponsive zone (2). The photoresponsive zone (2) is in the form of a polymer blend having regions (2a) of a first semiconductive polymer and regions (2b) of a second semiconductive polymer phase-separated from the first semiconductive polymer. The second semiconductive polymer has an electron affinity greater than that of the first semiconductive polymer so that, in use of the device (1), a photocurrent between the first and second electrodes (3 and 4) resulting from light incident on the photoresponsive layer comprises electrons travelling predominantly through the second semiconductive polymer and holes travelling predominantly through the first semiconductive polymer.

摘要翻译： 第一和第二电极（3和4）设置在光响应区（2）的第一和第二主表面的相应的（2'和2“）上。 光响应区（2）为具有第一半导体聚合物区域（2a）和与第一半导体聚合物相分离的第二半导体聚合物区域（2b）的聚合物共混物的形式。 第二半导体聚合物的电子亲和力大于第一半导体聚合物的电子亲和力，使得在使用器件（1）时，入射到光响应层上的光产生的第一和第二电极（3和4）之间的光电流包括 主要通过第二半导体聚合物的电子和主要穿过第一半导体聚合物的孔。

公开(公告)号：US06608323B2

公开(公告)日：2003-08-19

申请号：US09915210

申请日：2001-07-24

申请人： Tobin J. Marks ,  Antonio Facchetti ,  Henning Sirringhaus ,  Richard H. Friend

发明人： Tobin J. Marks ,  Antonio Facchetti ,  Henning Sirringhaus ,  Richard H. Friend

IPC分类号： H01L3524

CPC分类号： C08G61/126 ,  H01L27/32 ,  H01L51/0008 ,  H01L51/0036 ,  H01L51/0068 ,  H01L51/0512 ,  H01L51/0545

摘要： The new fluorocarbon-functionalized polythiophenes, in particular, &agr;,&ohgr;-diperfluorohexylsexithiophene DFH-6T (1) can be straightforwardly prepared in high yield and purified by gradient sublimation. Introduction of perfluorocarbon chains on the thiophene core affords enhanced thermal stability and volatility, and increased electron affinity versus the fluorine-free analog 2. Evaporated films of 1, for example, behave as n-type semiconductors, and can be used to fabricate thin film transistors with FET mobilities on the order of ˜0.01 cm2/Vs—some of the highest reported to date for n-type organic semiconductors.

公开(公告)号：US20110140091A1

公开(公告)日：2011-06-16

申请号：US12999614

申请日：2009-06-18

申请人： Richard H. Friend ,  Dinesh Kabra ,  Bernard Wenger ,  Henry Snaith ,  Myoung Hoon Song

发明人： Richard H. Friend ,  Dinesh Kabra ,  Bernard Wenger ,  Henry Snaith ,  Myoung Hoon Song

IPC分类号： H01L51/54

CPC分类号： H01L51/5265 ,  H01L51/422 ,  H01L51/4226 ,  H01L51/4233 ,  H01L51/5048 ,  H01L51/5092 ,  H01L51/5234 ,  Y02E10/549

摘要： A light emissive or photovoltaic device comprising: a cathode structure for injecting electrons, the cathode structure having one or more constituent regions; an anode structure for injecting holes, the anode structure having one or more constituent regions; and an organic light emissive component located between the anode structure and the cathode structure; the refractive indices and the thicknesses of the or each constituent region of the cathode and anode structures and of the light emissive component being such that the emission or absorption spectrum of the device is substantially angularly dependent.

摘要翻译： 一种发光或光电器件，包括：用于注入电子的阴极结构，所述阴极结构具有一个或多个组成区域; 用于注入空穴的阳极结构，所述阳极结构具有一个或多个构成区域; 以及位于阳极结构和阴极结构之间的有机发光部件; 阴极和阳极结构以及光发射部件的折射率和厚度都是使得器件的发射或吸收光谱基本上是角度依赖的。

公开(公告)号：US5247190A

公开(公告)日：1993-09-21

申请号：US634117

申请日：1990-12-28

申请人： Richard H. Friend ,  Jeremy H. Burroughes ,  Donal D. Bradley

发明人： Richard H. Friend ,  Jeremy H. Burroughes ,  Donal D. Bradley

IPC分类号： H01L33/00 ,  C08G61/00 ,  C08G61/02 ,  C08L65/00 ,  C09K11/06 ,  H01L51/30 ,  H01L51/50 ,  H05B33/10 ,  H05B33/14 ,  H05B33/22 ,  H05B33/26

CPC分类号： H05B33/14 ,  C09K11/06 ,  H01L51/0036 ,  H01L51/0038 ,  H01L51/5012

摘要： An electroluminescent device comprises a semiconductor layer (4) in the form of a thin dense polymer film comprising at least one conjugated polymer, a first contact layer (5) in contact with a first surface of the semiconductor layer, and a second contact layer (3) in contact with a second surface of the semiconductor layer. The polymer firm (4) of the semiconductor layer has a sufficiently low concentration of extrinsic charge carriers that on applying an electric field between the first and second contact layers across the semiconductor layer so as to render the second contact layer positive relative to the first contact layer charge carriers are injected into the semiconductor layer and radiation is emitted from the semiconductor layer. The polymer film can be poly(p-phenyenevinylene) [PPV] of formula (I) wherein the phenylene ring may optionally carry one or more substituents each independently selected from alkyl (preferably methyl), alkoxy (preferably methoxy or ethoxy), halogen (preferably chlorine or bromine) or nitro.

摘要翻译： PCT No.PCT / GB90 / 00584 Sec。 371 1990年12月28日第 102（e）日期1990年12月28日PCT 1990年4月18日提交PCT公布。 公开号WO90 / 13148 日期：1990年11月1日。电致发光器件包括半致密聚合物薄膜形式的半导体层（4），该薄膜包含至少一种共轭聚合物，与半导体层的第一表面接触的第一接触层 以及与半导体层的第二表面接触的第二接触层（3）。 半导体层的聚合物固体（4）具有足够低的非本征电荷载流子浓度，其在半导体层之间施加第一和第二接触层之间的电场，以使第二接触层相对于第一接触点为正 层电荷载流子注入到半导体层中，并从半导体层发射辐射。 聚合物膜可以是式（I）的聚（对苯乙烯）[PPV]，其中亚苯基环可以任选地带有一个或多个取代基，各自独立地选自烷基（优选甲基），烷氧基（优选甲氧基或乙氧基），卤素 优选氯或溴）或硝基。

公开(公告)号：US06872970B2

公开(公告)日：2005-03-29

申请号：US10740199

申请日：2003-12-18

申请人： Jonathan J. Halls ,  Richard H. Friend

发明人： Jonathan J. Halls ,  Richard H. Friend

IPC分类号： H01L21/00 ,  H01L31/00 ,  H01L51/00 ,  H01L51/30 ,  H01L51/44

CPC分类号： H01L51/0026 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/4253 ,  Y02E10/549 ,  Y02P70/521

摘要： A method of preparing an efficient photoresponsive device includes the steps of providing a first electrode on a substrate, providing a layer of an organic material including a blend of at least two semiconductive polymers having different electrode affinities and/or different ionization potentials over the first electrode, providing a second electrode over the layer of organic material, at least one of the electrodes being a transparent or semi-transparent, to form a photoresponsive device, and thermally annealing the photoresponsive device.

摘要翻译： 一种制备有效的光响应装置的方法包括以下步骤：在基底上提供第一电极，提供一层有机材料，该层包括在第一电极上具有不同电极亲和力和/或不同电离电位的至少两种半导体聚合物的共混物 在所述有机材料层上提供第二电极，所述电极中的至少一个是透明或半透明的，以形成光响应装置，并对光响应装置进行热退火。

公开(公告)号：US06670213B2

公开(公告)日：2003-12-30

申请号：US09974018

申请日：2001-10-10

申请人： Jonathan J. Halls ,  Richard H. Friend

发明人： Jonathan J. Halls ,  Richard H. Friend

IPC分类号： H01L2100

CPC分类号： H01L51/0026 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/4253 ,  Y02E10/549 ,  Y02P70/521

摘要： A method of preparing an efficient photoresponsive device includes the steps of providing a first electrode on a substrate, providing a layer of an organic material including a blend of at least two semiconductive polymers having different electrode affinities and/or different ionization potentials over the first electrode, providing a second electrode over the layer of organic material, at least one of the electrodes being a transparent or semi-transparent, to form a photoresponsive device, and thermally annealing the photoresponsive device.

摘要翻译： 一种制备有效的光响应装置的方法包括以下步骤：在基底上提供第一电极，提供一层有机材料，该层包括在第一电极上具有不同电极亲和力和/或不同电离电位的至少两种半导体聚合物的共混物 在所述有机材料层上提供第二电极，所述电极中的至少一个是透明或半透明的，以形成光响应装置，并对光响应装置进行热退火。

公开(公告)号：US5401827A

公开(公告)日：1995-03-28

申请号：US748777

申请日：1991-08-22

申请人： Andrew Holmes ,  Donal D. Bradley ,  Richard H. Friend ,  Arno Kraft ,  Paul Burn ,  Adam Brown

发明人： Andrew Holmes ,  Donal D. Bradley ,  Richard H. Friend ,  Arno Kraft ,  Paul Burn ,  Adam Brown

IPC分类号： C08G61/02 ,  C07C43/205 ,  C07C43/225 ,  C08G61/00 ,  C08G61/10 ,  C08G61/12 ,  C09K11/06 ,  H01B1/12 ,  H01L33/00 ,  H01L51/00 ,  H01L51/30 ,  H01L51/50 ,  H01L51/56 ,  H05B33/10 ,  H05B33/12 ,  H05B33/14 ,  C08G75/04

CPC分类号： H05B33/14 ,  C07C43/2055 ,  C07C43/225 ,  C08G61/00 ,  C09K11/06 ,  H01B1/127 ,  H01B1/128 ,  H01L51/0036 ,  H01L51/0038 ,  H01L51/0043 ,  H01L51/5012 ,  H01L51/5036 ,  H01L51/56 ,  Y10T428/3158 ,  Y10T428/31587 ,  Y10T428/31645

摘要： A semiconductive conjugated copolymer comprises at least two chemically different monomer units which, when existing in their individual homopolymer forms, have different semiconductor bandgaps. The proportion of said at least two chemically different monomer units in the copolymer is selected to control the semiconductor bandgap of the copolymer so as to control the optical properties of the copolymer. The copolymer is formed in a manner enabling it to be laid down as a film without substantially affecting the luminescent characteristics of the copolymer and is stable at operational temperature.The semiconductor bandgap may be spatially modulated so as to increase the quantum efficiency of the copolymer when excited to luminesce, to select the wavelength of radiation omitted during luminescence or to select the refractive index of the copolymer.

摘要翻译： 半导体共轭共聚物包含至少两种化学上不同的单体单元，当其各自的均聚物形式存在时，其具有不同的半导体带隙。 选择共聚物中所述至少两种化学上不同的单体单元的比例以控制共聚物的半导体带隙，从而控制共聚物的光学性能。 共聚物的形成方式使得其能够以膜形式放置而基本上不影响共聚物的发光特性，并且在操作温度下是稳定的。 半导体带隙可以被空间调制，以便当激发发光时提高共聚物的量子效率，以选择在发光期间省略的辐射波长或选择共聚物的折射率。

公开(公告)号：US5328809A

公开(公告)日：1994-07-12

申请号：US748795

申请日：1991-08-22

申请人： Andrew Holmes ,  Donal D. Bradley ,  Richard H. Friend ,  Arno Kraft ,  Paul Burn ,  Adam Brown

发明人： Andrew Holmes ,  Donal D. Bradley ,  Richard H. Friend ,  Arno Kraft ,  Paul Burn ,  Adam Brown

IPC分类号： C08G61/02 ,  C07C43/205 ,  C07C43/225 ,  C08G61/00 ,  C08G61/10 ,  C08G61/12 ,  C09K11/06 ,  H01B1/12 ,  H01L33/00 ,  H01L51/00 ,  H01L51/30 ,  H01L51/50 ,  H01L51/56 ,  H05B33/10 ,  H05B33/12 ,  H05B33/14 ,  B05D1/32 ,  G03C5/00

CPC分类号： H05B33/14 ,  C07C43/2055 ,  C07C43/225 ,  C08G61/00 ,  C09K11/06 ,  H01B1/127 ,  H01B1/128 ,  H01L51/0036 ,  H01L51/0038 ,  H01L51/0043 ,  H01L51/5012 ,  H01L51/5036 ,  H01L51/56 ,  Y10T428/3158 ,  Y10T428/31587 ,  Y10T428/31645

摘要： A method is provided for forming in a semiconductive conjugated polymer at least first and second regions having different optical properties. The method comprises: forming a layer of a precursor polymer and permitting the first region to come into contact with a reactant, such as an acid, and heat while permitting the second region to come into contact with a lower concentration of the reactant. The reactant affects the conversion conditions of the precursor polymer in such a way as to control the optical properties of at least the first region so that the optical properties of the first region are different from those of the second region.The precursor polymer may comprise a poly(arylene-1,2-ethanediyl) polymer, at least some of the ethane groups of which include a modifier group whose susceptibility to elimination is increased in the presence of the reactant.

摘要翻译： 提供一种在半导体共轭聚合物中形成具有不同光学特性的至少第一和第二区域的方法。 该方法包括：形成前体聚合物层，并允许第一区域与反应物（例如酸）​​接触并加热，同时允许第二区域与较低浓度的反应物接触。 反应物以这样的方式影响前体聚合物的转化条件，以便控制至少第一区域的光学性质，使得第一区域的光学性质与第二区域的光学性质不同。 前体聚合物可以包含聚（亚芳基-1,2-乙二基）聚合物，其中至少一些乙烷基团包括其在反应物存在下易于消除的易感性的改性剂基团。

公开(公告)号：US20130069043A1

公开(公告)日：2013-03-21

申请号：US13521692

申请日：2011-01-12

申请人： Richard H. Friend ,  Henry Snaith ,  Dinesh Kabra ,  Myoung Hoon Song ,  Li Ping Lu

发明人： Richard H. Friend ,  Henry Snaith ,  Dinesh Kabra ,  Myoung Hoon Song ,  Li Ping Lu

IPC分类号： H01L51/52 ,  H01L51/56

CPC分类号： H01L51/5088 ,  H01L51/0037 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/5092 ,  H01L2251/558

摘要： An electro optic device comprising a first electrode and a second electrode and an emissive layer located between the first and second electrodes, the emissive layer comprising a polymeric semiconductor, or semiconducting and luminescent material having a thickness of 200 nm to 3000 nm.

摘要翻译： 一种电光器件，包括第一电极和第二电极以及位于第一和第二电极之间的发射层，发射层包含聚合物半导体或厚度为200nm至3000nm的半导体和发光材料。

公开(公告)号：US5523555A

公开(公告)日：1996-06-04

申请号：US305848

申请日：1994-09-14

申请人： Richard H. Friend ,  Andrew B. Holmes ,  Donal D. C. Bradley ,  Robert N. Marks

发明人： Richard H. Friend ,  Andrew B. Holmes ,  Donal D. C. Bradley ,  Robert N. Marks

IPC分类号： H01L31/0224 ,  H01L31/08 ,  H01L51/30 ,  H01J40/14

CPC分类号： H01L51/4206 ,  H01L31/022466 ,  H01L51/0038 ,  H01L2251/308 ,  H01L51/0036 ,  Y02E10/549

摘要： A photodetector device includes a semiconductive conjugated polymer, such as PPV, arranged between first and second electrode layers having different work functions, a bias circuitry connected to apply a bias voltage between the first and second electrode layers, and a sensing circuitry connected to detect a photocurrent flowing between the first and second electrode layers across the polymer layer as a result of radiation incident on the polymer layer while the bias voltage is applied. The bias voltage is selected in relation to the thickness of the polymer layer.

摘要翻译： 光检测器装置包括布置在具有不同功函数的第一和第二电极层之间的诸如PPV的半导体共轭聚合物，连接到在第一和第二电极层之间施加偏置电压的偏置电路，以及连接以检测 由于在施加偏置电压时入射到聚合物层上的辐射的结果，在第一和第二电极层之间横跨聚合物层流动的光电流。 相对于聚合物层的厚度选择偏置电压。