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    Reforming using a bound zeolite catalyst
    8.
    发明授权
    Reforming using a bound zeolite catalyst 失效
    使用结合的沸石催化剂进行重整

    公开(公告)号：US4830732A

    公开(公告)日：1989-05-16

    申请号：US141657

    申请日：1988-01-07

    申请人： Donald H. Mohr ,  Charles R. Wilson ,  Albert S. Behan ,  Robert L. Chiang ,  Mark T. Staniulis

    发明人： Donald H. Mohr ,  Charles R. Wilson ,  Albert S. Behan ,  Robert L. Chiang ,  Mark T. Staniulis

    IPC分类号： B01J29/60 ,  B01J29/50 ,  B01J29/62 ,  C10G35/06 ,  C10G35/085 ,  C10G35/095

    CPC分类号： C10G35/095 ,  B01J29/62 ,  B01J2229/26 ,  B01J2229/42

    摘要： Reforming to produce aromatics from aliphatics, using a bound zeolite catalyst containing a Group VIII metal such as platinum, has been found to be extremely sensitive to water, even at water concentrations as low as 3 ppm in the feed, unless certain catalysts having a low water sensitivity index are used. The water sensitivity index (WSI) is described and methods for making catalysts with a low WSI are described. The sulfur content of the feed to the reforming/aromatics production process is preferably below 50 parts per billion. The catalyst used in the reforming process is preferably a high crush strength catalyst and is preferably prepared by steps including treating L zeolite with a binding enhancement agent prior to binding with a binder such as silica, silica/alumina or alumina.

    摘要翻译： 已经发现使用含有VIII族金属如铂的结合的沸石催化剂从脂肪族产生芳族化合物，即使在进料中的低至3ppm的水浓度下，对水也非常敏感，除非某些催化剂具有低的 使用水敏感指数。 描述了水敏感指数（WSI），并描述了制备低WSI催化剂的方法。 重整/芳烃生产过程的进料的硫含量优选低于50ppm。 在重整过程中使用的催化剂优选是高抗压强度催化剂，并且优选通过以下步骤制备，所述步骤包括在与粘合剂如二氧化硅，二氧化硅/氧化铝或氧化铝结合之前用结合增强剂处理L沸石。

    Process for upgrading fischer-tropsch syncrude using thermal cracking and oligomerization
    9.
    发明授权
    Process for upgrading fischer-tropsch syncrude using thermal cracking and oligomerization 失效
    使用热裂解和低聚提升费 - 托合成原料的方法

    公开(公告)号：US06703535B2

    公开(公告)日：2004-03-09

    申请号：US10125879

    申请日：2002-04-18

    申请人： David R. Johnson ,  Christopher A. Simmons ,  Donald H. Mohr ,  Stephen J. Miller ,  Stephen K. Lee ,  William L. Schinski ,  Michael S. Driver ,  William J. Cannella

    发明人： David R. Johnson ,  Christopher A. Simmons ,  Donald H. Mohr ,  Stephen J. Miller ,  Stephen K. Lee ,  William L. Schinski ,  Michael S. Driver ,  William J. Cannella

    IPC分类号： C07C204

    CPC分类号： C10G2/32 ,  Y10S208/95

    摘要： A process for upgrading a Fischer-Tropsch feedstock which comprises (a) recovering from a Fischer-Tropsch reactor a Fischer-Tropsch wax fraction and a Fischer-Tropsch condensate fraction, wherein the Fischer-Tropsch condensate fraction contains alcohols boiling below about 370° C.; (b) contacting the Fischer-Tropsch condensate fraction with a dehydration catalyst in a dehydration zone under dehydration conditions pre-selected to convert at least some of the alcohols present in said fraction into olefins and recovering a first intermediate effluent from said dehydration zone; (c) pyrolyzing the paraffins in the Fischer-Tropsch wax fraction in a thermal cracking zone under thermal cracking conditions pre-selected to crack the Fischer-Tropsch wax molecules to form olefins and collecting a second intermediate effluent from the thermal cracking zone; (d) passing the first and second intermediate effluents recovered from steps (b) and (c) to an oligomerization zone containing an oligomerization catalyst under oligomerization conditions to form an oligomerization mixture having a higher molecular weight than either of said first and second intermediate effluent; (e) hydrofinishing the oligomerization mixture in a hydrofinishing zone; and (f) recovering from the hydrofinishing zone a C10 plus hydrocarbon product, most preferably a lubricating base oil.

    摘要翻译： 一种用于升级费 - 托原料的方法，其包括（a）从费 - 托反应器中回收费 - 托蜡馏分和费 - 托冷凝馏分，其中所述费 - 托冷凝馏分含有沸点低于约370℃的醇 。 （b）在脱水条件下，将脱水催化剂与脱水催化剂接触，预先将所述馏分中存在的至少一些醇转化成烯烃并从所述脱水区回收第一中间体流出物; （c）在热裂解条件下，在热裂解条件下热分解费 - 托蜡馏分中的链烷烃，预热裂解条件以裂解费 - 托蜡分子以形成烯烃并从热裂解区收集第二中间体流出物; （d）在低聚条件下将从步骤（b）和（c）回收的第一和第二中间流出物通入含有低聚催化剂的低聚区以形成具有比所述第一和第二中间流出物 ; （e）在加氢精制区中加氢精制低聚混合物; 和（f）从加氢精制区回收C10加烃产物，最优选润滑基础油。

    Reforming using a bound zeolite catalyst
    10.
    发明授权
    Reforming using a bound zeolite catalyst 失效
    使用结合的沸石催化剂进行重整

    公开(公告)号：US5106803A

    公开(公告)日：1992-04-21

    申请号：US352399

    申请日：1989-05-15

    申请人： Donald H. Mohr ,  Charles P. Wilson ,  Albert S. Behan ,  Robert L. Chiang ,  Mark T. Staniulis

    发明人： Donald H. Mohr ,  Charles P. Wilson ,  Albert S. Behan ,  Robert L. Chiang ,  Mark T. Staniulis

    IPC分类号： B01J29/62 ,  B01J29/72 ,  C10G35/095

    CPC分类号： C10G35/095 ,  B01J29/62 ,  B01J2229/26 ,  B01J2229/42

    摘要： Reforming to produce aromatics from aliphatics, using a bond zeolite catalyst containing a Group VIII metal such as platinum, has been found to be extremely sensitive to water, even at water concentrations as low as 3 ppm in the feed, unless certain catalysts having a low water sensitivity index are used. The water sensitivity index (WSI) is described and methods for making catalysts with a low WSI are described. The sulfur content of the feed to the reforming/aromatics production process is preferably below 50 parts per billion. The catalysts used in the reforming process is preferably a high crush strength catalyst and is preferably prepared by steps including treating L zeolite with a binding enhancement agent prior to binding with a binder such as silica, silica/alumina or alumina.

    摘要翻译： 已经发现使用含有VIII族金属如铂的键沸石催化剂从脂肪族产生芳族化合物，甚至在进料中的低至3ppm的水浓度下，对水是非常敏感的，除非某些催化剂具有低 使用水敏感指数。 描述了水敏感指数（WSI），并描述了制备低WSI催化剂的方法。 重整/芳烃生产过程的进料的硫含量优选低于50ppm。 在重整过程中使用的催化剂优选是高抗压强度催化剂，并且优选通过以下步骤制备，包括在与粘合剂例如二氧化硅，二氧化硅/氧化铝或氧化铝结合之前用结合增强剂处理L沸石。