-
1.发明授权Varnishes for glasscloth laminates, methods of their production and laminates made therefrom 失效玻璃纤维层压板的清漆，其制造方法和由其制成的层压板
公开(公告)号：US4408003A
公开(公告)日：1983-10-04
申请号：US311647
申请日：1981-10-15
申请人： Joseph G. Robinson , Sally A. Brain
发明人： Joseph G. Robinson , Sally A. Brain
CPC分类号： C08J5/24 , B32B27/04 , C08L61/34 , H05K1/0326 , C08J2361/34 , Y10T442/2992
摘要： The present invention relates to varnishes for use in the preparation of glasscloth laminates, methods of their production and laminates made therefrom.The varnish is made by dissolving 100 parts of a TFP resin having a number average molecular weight of about 1000 and an oxygen content of about 8% in 60 to 65 parts of butan-2-one or isopropanol. 8 to 12 parts of hexamine are dissolved in a minimum quantity of a solvent comprising water and IMS in a ratio of about 3:5. The two solutions are thoroughly mixed and filtered to produce the varnish.The varnish is used to prepare glasscloth laminates for use as printed circuit boards.
摘要翻译： 本发明涉及用于制备玻璃纤维层压板的清漆，其生产方法和由其制成的层压材料。 该清漆是通过将100份数均分子量为约1000，氧含量为约8％的TFP树脂溶解在60至65份丁-2-酮或异丙醇中制成的。 将8至12份六胺溶解在包含水和IMS的最小量的溶剂中，其比例约为3:5。 将两种溶液充分混合并过滤以产生清漆。 清漆用于制备用作印刷电路板的玻璃纤维层压板。
-
2.发明授权Resin derived from acenaphthene, process for its production and intermediates in its production 失效衍生自苊的树脂，其生产过程及其生产中的中间体
公开(公告)号：US4334055A
公开(公告)日：1982-06-08
申请号：US292037
申请日：1981-08-11
申请人： Joseph G. Robinson , Sally A. Brain
发明人： Joseph G. Robinson , Sally A. Brain
CPC分类号： C08G73/1067 , C07C65/34 , C08G10/02 , C08G10/04 , C08G73/20
摘要： The invention relates to a novel resin derived from acenaphthene and to process for its production.The resin comprises oligomers of naphthalic acid groups bridged by substantially only keto groups, the oligomers being joined together with a di- or tetra-functional primary aromatic amine and having been derived from a resin produced by acid-catalyzed condensation of acenaphthene and a formaldehyde donor.It is envisaged that the resin will be of use in the preparation of drogue parachutes and in other circumstances where a thermally stable resin is required.
摘要翻译： 本发明涉及一种衍生自苊的新型树脂及其生产方法。 该树脂包括仅由基团桥接的萘二甲酸基团的低聚物，该低聚物与二官能或四官能伯芳胺连接在一起，并且衍生自由苊和甲醛供体的酸催化缩合产生的树脂 。 预计该树脂将用于制备锥形降落伞，并且在需要热稳定性树脂的其它情况下。
-
3.发明授权Method of producing a resin for producing heat stable products, the resin and the products 失效生产热稳定产品的树脂，树脂和产品的方法
公开(公告)号：US4276408A
公开(公告)日：1981-06-30
申请号：US120395
申请日：1980-02-11
申请人： Joseph G. Robinson , Sally A. Brain
发明人： Joseph G. Robinson , Sally A. Brain
CPC分类号： C08J5/24 , C08G10/02 , C08G14/04 , C08L61/34 , H01B3/06 , H01B3/084 , H01B3/36 , C08J2361/34
摘要： This invention relates to a method of producing a phenolated resin which can be used to form heat stable (up to 250.degree.) products.Previously used resins are either very expensive or do not provide the requisite high temperature properties. An aim of the invention is to provide a cheap equivalent to commercially available high temperature resins.An aromatic hydrocarbon (e.g. toluene) formaldehyde condensation resin is prepared. The low molecular weight contaminants are removed by a distillation process. The residue contains less than 1% low molecular weight material, and is phenolated to give the final resin. The resin may be cured to give a heat stable product.The phenolated resin may be used to form glasscloth and asbestos laminates or as a lamp capping cement.
摘要翻译： 本发明涉及可用于形成热稳定（高达250°）产品的苯酚树脂的制备方法。 以前使用的树脂非常昂贵或不提供必要的高温性能。 本发明的目的是提供与市售的高温树脂相当的便宜的等价物。 制备芳族烃（如甲苯）甲醛缩合树脂。 通过蒸馏过程除去低分子量污染物。 残余物含有低于1％的低分子量材料，并被酚化以得到最终的树脂。 树脂可以固化以产生热稳定的产物。 苯酚树脂可用于形成玻璃纤维和石棉层压材料或作为灯头水泥。
-
公开(公告)号：US4350623A
公开(公告)日：1982-09-21
申请号：US236064
申请日：1981-02-19
申请人： Joseph G. Robinson , Sally A. Brain
发明人： Joseph G. Robinson , Sally A. Brain
CPC分类号： C08J5/24 , B32B27/04 , C03C25/34 , C08G14/04 , C08L61/34 , H05K1/0326 , C08J2361/34 , Y10T428/24926
摘要： The varnish comprises a phenolated naphthalene formaldehyde resin having a molecular weight from 350 to 500 and a combined phenol content from 37 to 54%, a curing agent for the resin, and a lower secondary alcohol as the solvent, the varnish containing about 50% w/w of the resin. The varnish can be used to form glasscloth laminates for the production of printed circuit boards, copper clad laminates and blading for turbines.
摘要翻译： 清漆包括分子量为350-500，苯酚含量为37-54％的苯酚萘甲醛树脂，树脂固化剂和低级二醇作为溶剂，该清漆含有约50％w / w的树脂。 清漆可用于形成玻璃纤维层压板，用于生产印刷电路板，铜包层压板和涡轮叶片。
-
公开(公告)号：US4577009A
公开(公告)日：1986-03-18
申请号：US651713
申请日：1984-09-18
CPC分类号： C08G73/101 , C08G18/6438 , C08G59/4042
摘要： Novel polyimide products of the general formula ##STR1## where n is from 2 to 20 and each R is hydrogen or a group effective to block further reaction with a diamine. These products are incapable of further polymerization with diamines, but are useful starting materials for reaction with other polyfunctional reagents such as diepoxides to form interesting new resins.
摘要翻译： 新型的具有通式“IMAGE”的聚酰亚胺产物，其中n为2至20，且每个R为氢或有效阻断与二胺进一步反应的基团。 这些产品不能用二胺进一步聚合，而且是与其它多官能试剂如二环氧化物反应的有用的起始原料，以形成有趣的新树脂。
-
6.发明授权Conversion of methanol to toluene using amorphous silica-alumina catalysts 失效使用无定形二氧化硅 - 氧化铝催化剂将甲醇转化为甲苯
公开(公告)号：US4511749A
公开(公告)日：1985-04-16
申请号：US554244
申请日：1983-11-22
CPC分类号： C07C1/20 , B01J21/12 , B01J37/0209 , C07C2521/12 , Y02P20/52
摘要： Amorphous silica-alumina catalysts, having a layer of an aluminum compound chemically bonded onto the surface of a silica xerogel and having protons as the electrical charge balancing species, have been found to give surprising selectivity in the conversion of water/methanol mixtures to toluene.
摘要翻译： 已经发现具有化学键合到二氧化硅干凝胶表面上并具有质子作为电荷平衡物质的铝化合物层的无定形二氧化硅 - 氧化铝催化剂在将水/甲醇混合物转化成甲苯时具有惊人的选择性。
-
公开(公告)号：US4379896A
公开(公告)日：1983-04-12
申请号：US333886
申请日：1981-12-23
CPC分类号： C08G73/14 , C07C51/31 , C07C65/34 , C08G10/02 , Y10T428/31721
摘要： This invention relates to thermally stable resins and provides such a resin made from cheaply available coal-derived materials, whereas presently available resins are made from increasingly expensive oil-derived materials.The resin comprises the condensation product of a reaction between an aromatic diamine and a phenanthrene-formaldehyde reaction product, which product has been oxidized to produce keto groups bridging the phenanthrene moieties and carboxy groups. The condensation product is a poly-(amine-imide).The invention also includes a method of making the resin and varnishes containing the resin.The resin will find use for instance as a high temperature insulator or in glass or asbestos laminates in compressor blades.
-
8.发明授权Method of producing an improved poly-(amide-imide) resin by reacting a phenanthrene with formaldehyde followed by oxidizing to produce a polycarboxylated product followed by reaction with an aromatic diamine 失效通过使菲与甲醛反应生成改进的聚（酰胺 - 酰亚胺）树脂的方法，然后氧化以产生多羧基化产物，然后与芳族二胺反应
公开(公告)号：US4352922A
公开(公告)日：1982-10-05
申请号：US240025
申请日：1981-03-03
摘要： According to the present invention, there is provided an improved method of producing a poly-(amide-imide) resin comprising the steps of:(1) reacting a phenanthrene with formaldehyde or a formaldehyde donor in the presence of an acid catalyst to give a phenanthreneformaldehyde reaction product having substantially only methylene bridges;(2) removing from the reaction product unreacted phenanthrene;(3) treating the reaction product with formaldehyde or a formaldehyde donor in the presence of an acid catalyst to give a high molecular weight product having substantially only methylene bridges;(4) oxidizing the high molecular weight product to break the 9, 10 bond in the phenanthrene moieties to produce a polycarboxylated reaction product;(5) reacting the polycarboxylated reaction product with an aromatic diamine to produce a poly-(amide-imide) resin.The resin would find use as a lamp capping cement, as a high temperature insulator, in copper clad high temperature printed circuits, in electrical heater panels, in transformers and in glass or asbestos laminates for use as compressor blades.
摘要翻译： 根据本发明，提供一种生产聚（酰胺 - 酰亚胺）树脂的改进方法，包括以下步骤：（1）在酸催化剂存在下，使菲与甲醛或甲醛供体反应，得到 菲甲醛反应产物基本上只有亚甲基桥; （2）从反应产物中除去未反应的菲; （3）在酸催化剂存在下用甲醛或甲醛供体处理反应产物，得到基本上只有亚甲基桥的高分子量产物; （4）氧化高分子量产物以破坏菲部分中的9,10键以产生多羧化反应产物; （5）使多羧化反应产物与芳族二胺反应，生成聚（酰胺 - 酰亚胺）树脂。 该树脂可用作铜包覆水泥，高温绝缘子，铜包覆高温印刷电路，电加热器板，变压器和用作压缩机叶片的玻璃或石棉层压板中。
-
公开(公告)号：US4394499A
公开(公告)日：1983-07-19
申请号：US290089
申请日：1981-08-04
CPC分类号： C08G73/0672 , Y10T428/31721
摘要： This invention relates to an improved polyimide resin and to a method of its production.The improved polyimide resin is made from phenanthrene which is converted via a 9, 10-diol to oligomers of diphenic anhydride units linked by keto bridges. The oligomers are reacted with from 0.1 to 0.6 of an equivalent quantity of an aromatic primary diamine. The remaining anhydride groups are reacted with a monofunctional amine to give a polyimide of low cross-link density.The resin will find use for instance in forming glasscloth laminates.
摘要翻译： 本发明涉及一种改进的聚酰亚胺树脂及其制备方法。 改进的聚酰亚胺树脂由菲衍生而成，其通过9,10-二醇转化成通过酮桥连接的二烯酸酐单元的低聚物。 低聚物与0.1至0.6当量的芳族伯胺反应。 剩余的酸酐基团与单官能胺反应，得到交联密度低的聚酰亚胺。 树脂将用于例如形成玻璃纤维层压板。
-
公开(公告)号：US4346212A
公开(公告)日：1982-08-24
申请号：US174152
申请日：1980-07-31
CPC分类号： C08G73/14 , C07C51/31 , C07C65/34 , C08G10/02 , Y10T428/31721
摘要： This invention relates to thermally stable resins and provides such a resin made from cheaply available coal-derived materials, whereas presently available resins are made from increasingly expensive oil-derived materials.The resin comprises the condensation product of a reaction between an aromatic diamine and a phenanthrene-formaldehyde reaction product, which product has been oxidized to produce keto groups bridging the phenanthrene moieties and carboxy groups. The condensation product is a poly-(amide-imide).The invention also includes a method of making the resin and varnishes containing the resin.The resin will find use for instance as a high temperature insulator or in glass or asbestos laminates in compressor blades.
摘要翻译： 本发明涉及热稳定树脂，并且提供由廉价的煤源材料制成的这种树脂，而目前可用的树脂由越来越昂贵的石油衍生材料制成。 树脂包括芳族二胺和菲 - 甲醛反应产物之间的反应的缩合产物，该产物已被氧化以产生桥接菲部分和羧基的酮基。 缩合产物是聚（酰胺 - 酰亚胺）。 本发明还包括制备含树脂的树脂和清漆的方法。 该树脂将用作例如高温绝缘体或在压缩机叶片中的玻璃或石棉层压材料中。
-
-
-
-
-
-
-
-
-
搜索结果
17 条记录 (耗时 0.036 秒)
