公开(公告)号：US4423167A

公开(公告)日：1983-12-27

申请号：US288238

申请日：1981-07-29

Applicant: Joseph T. Valko

Inventor： Joseph T. Valko

IPC: C09D5/02 ,  C08G63/12 ,  C09D5/00 ,  C09D5/44 ,  C09D7/00 ,  C09D7/12 ,  C09D163/00 ,  C09D167/00 ,  C09D201/06 ,  C08L63/02

CPC classification number: C09D167/00 ,  C08G63/12 ,  C09D163/00 ,  C09D201/06 ,  Y10S524/901

Abstract: Coating compositions comprising a polymeric polyol with a polyester crosslinking agent having at least two beta-alkoxyester groups per molecule are disclosed. The compositions, when applied to a substrate and cured in the presence of a transesterification catalyst, give solvent-resistant coatings.

Abstract translation: 公开了包含具有每分子具有至少两个β-烷氧基酯基团的聚酯交联剂的聚合多元醇的涂料组合物。 当组合物施用于基材并在酯交换催化剂存在下固化时，得到耐溶剂涂层。

公开(公告)号：US06217674B1

公开(公告)日：2001-04-17

申请号：US09309849

申请日：1999-05-11

Applicant: Ralph C. Gray ,  Brian T. Hauser ,  Joseph T. Valko

Inventor： Ralph C. Gray ,  Brian T. Hauser ,  Joseph T. Valko

IPC: C23C2248

CPC classification number: C23C22/34 ,  C23C22/83

Abstract: A composition for passivating a metal substrate is provided. The composition is prepared by mixing together: a) Group IIIB or IVB metal compound; and b) a reaction product of an epoxy group-containing polymer or oligomer, a hydroxy functional acid and a dialkanolamine. The compositions, which are substantially free of chrome, are used to treat metal substrates prior to the application of a protective or decorative coating.

Abstract translation: 提供了用于钝化金属基板的组合物。 组合物通过混合在一起制备：a）IIIB或IVB族金属化合物; 和b）含环氧基的聚合物或低聚物，羟基官能酸和二链烷醇胺的反应产物。 基本上不含铬的组合物在施用保护性或装饰性涂层之前用于处理金属基材。

公开(公告)号：US5074979A

公开(公告)日：1991-12-24

申请号：US540991

申请日：1990-06-20

Applicant: Joseph T. Valko ,  Richard F. Karabin

Inventor： Joseph T. Valko ,  Richard F. Karabin

IPC: C08G18/58 ,  C08G18/80 ,  C08G59/14 ,  C09D5/44 ,  C09D163/00 ,  C09D175/00 ,  C09D175/04

CPC classification number: C08G18/581 ,  C08G18/8048 ,  C08G18/8054 ,  C08G18/8064 ,  C09D5/4434

Abstract: A cationic resin containing blocked isocyanate groups which is suitable for use in electrodeposition is disclosed. The cationic resin is derived from an epoxy resin and contains in the resin molecule cationic salt groups, active hydrogen groups and blocked isocyanate groups. The blocked isocyanate groups are incorporated into the resin molecule by reacting the epoxy resin with a compound selected from the class consisting of mercapto compounds and acid group-containing compounds where the compounds also contain blocked isocyanate groups. The resin can be formulated into an electrocoating composition which is free of lead and yet provides outstanding corrosion resistance when electrodeposited over steel substrates. The outstanding corrosion resistance can be attained when the substrate has not been given a chrome rinse which is conventional in pretreating the steel substrate before electrodeposition.

公开(公告)号：US4511447A

公开(公告)日：1985-04-16

申请号：US636632

申请日：1984-08-01

Applicant: Joseph T. Valko

Inventor： Joseph T. Valko

IPC: C08G63/12 ,  C09D5/44 ,  C09D163/00 ,  C09D167/00 ,  C09D201/06 ,  C25D13/06 ,  C08L63/02

CPC classification number: C09D167/00 ,  C08G63/12 ,  C09D163/00 ,  C09D201/06 ,  C09D5/44

Abstract: Coating compositions comprising a polymeric polyol with a polyester crosslinking agent having at least two gamma and/or delta-hydroxyester groups per molecule are disclosed. The compositions, when applied to a substrate and cured in the presence of a transesterification catalyst, give solvent-resistant coatings.

Abstract translation: 公开了包含聚合物多元醇与每分子具有至少两个γ和/或δ-羟基酯基团的聚酯交联剂的涂料组合物。 当组合物施用于基材并在酯交换催化剂存在下固化时，得到耐溶剂涂层。

公开(公告)号：US4423169A

公开(公告)日：1983-12-27

申请号：US288240

申请日：1981-07-29

Applicant: Joseph T. Valko

Inventor： Joseph T. Valko

IPC: C08G63/12 ,  C09D163/00 ,  C09D167/00 ,  C09D201/06 ,  C08L63/02

CPC classification number: C09D167/00 ,  C08G63/12 ,  C09D163/00 ,  C09D201/06 ,  Y10S524/901

Abstract: Coating compositions comprising a polymeric polyol with a polyester crosslinking agent having at least two beta- and/or gamma-ester ester groups per molecule are disclosed. The compositions, when applied to a substrate and cured in the presence of a transesterification catalyst, give solvent-resistant coatings.

Abstract translation: 公开了包含聚合物多元醇的聚酯多元醇与每分子具有至少两个β-和/或γ-酯酯基的聚酯交联剂的涂料组合物。 当组合物施用于基材并在酯交换催化剂存在下固化时，得到耐溶剂涂层。

公开(公告)号：US4423168A

公开(公告)日：1983-12-27

申请号：US288241

申请日：1981-07-29

Applicant: Joseph T. Valko

Inventor： Joseph T. Valko

IPC: C08G63/12 ,  C09D163/00 ,  C09D167/00 ,  C09D201/06 ,  C08L63/02

CPC classification number: C09D167/00 ,  C08G63/12 ,  C09D163/00 ,  C09D201/06 ,  Y10S524/901

Abstract: Coating compositions comprising a polymeric polyol with a polyester crosslinking agent having at least two beta-amido ester groups per molecule are disclosed. The compositions, when applied to a substrate and cured in the presence of a transesterification catalyst, give solvent-resistant coatings.

Abstract translation: 公开了包含聚合物多元醇与每分子具有至少两个β-酰氨基酯基的聚酯交联剂的涂料组合物。 当组合物施用于基材并在酯交换催化剂存在下固化时，得到耐溶剂涂层。

公开(公告)号：US08070927B2

公开(公告)日：2011-12-06

申请号：US11839142

申请日：2007-08-15

Applicant: Joseph T. Valko ,  Craig A. Wilson ,  Robin M. Peffer

Inventor： Joseph T. Valko ,  Craig A. Wilson ,  Robin M. Peffer

IPC: C25D13/06 ,  C08L63/00

CPC classification number: C09D5/4419

Abstract: Stabilization of aqueous resinous dispersions containing a pigment of a divalent metal such as strontium chromate is disclosed. Stabilization is achieved by incorporating a chelating agent in the dispersion.

Abstract translation: 公开了含有二价金属颜料如铬酸锶的水性树脂分散液的稳定化。 通过在分散体中加入螯合剂来实现稳定化。

公开(公告)号：US5760107A

公开(公告)日：1998-06-02

申请号：US724343

申请日：1996-10-01

Applicant: Joseph T. Valko ,  Philippe Faucher ,  Richard F. Karabin ,  Thomas C. Moriarity ,  V. Eswarakrishnan ,  Ellor J. Van Buskirk ,  Gregory J. McCollum ,  Raphael O. Kollah

Inventor： Joseph T. Valko ,  Philippe Faucher ,  Richard F. Karabin ,  Thomas C. Moriarity ,  V. Eswarakrishnan ,  Ellor J. Van Buskirk ,  Gregory J. McCollum ,  Raphael O. Kollah

IPC: C09D163/00 ,  C08G18/08 ,  C08G18/32 ,  C08G18/42 ,  C08G18/58 ,  C08G18/64 ,  C08G18/80 ,  C09D5/08 ,  C09D5/44 ,  C09D175/04 ,  C09D175/12 ,  C08L63/00 ,  C08L63/02

CPC classification number: C08G18/3256 ,  C08G18/0814 ,  C08G18/0823 ,  C08G18/4294 ,  C08G18/581 ,  C08G18/584 ,  C08G18/6407 ,  C08G18/643 ,  C08G18/80 ,  C08G18/8009 ,  C08G18/8048 ,  C08G18/8064 ,  C09D5/4434 ,  C09D5/4453 ,  C09D5/4457

Abstract: An electrodepositable composition is provided comprising: (A) a non-gelled cationic resin which is derived from a polyepoxide and which contains in the resin molecule cationic salt groups and active hydrogen groups selected from aliphatic hydroxyl and primary and secondary amino; and present as a separate component (B) a fully capped polyisocyanate curing agent containing substantially no free isocyanate groups. The electrodepositable composition contains from about 0.02 to 1.0 milliequivalents phenolic hydroxyl groups per gram of resin solids, and from about 0.1 to 2.0 milliequivalents beta-hydroxy ester groups per gram of resin solids. The composition provides excellent corrosion resistance when electrodeposited over steel substrates, and does not require lead in the formulation nor the use of a conventional chrome rinse for the steel substrate pretreatment before electrodeposition.

Abstract translation: 提供了一种可电沉积的组合物，其包含：（A）衍生自聚环氧化物的非胶凝阳离子树脂，其在树脂分子中含有阳离子盐基团和选自脂族羟基和伯和仲氨基的活性氢基团; 并且作为单独的组分（B）存在基本上不含游离异氰酸酯基团的完全封端的多异氰酸酯固化剂。 可电沉积组合物每克树脂固体含有约0.02-1.0毫当量酚羟基，每克树脂固体含约0.1-2.0毫当量β-羟基酯基。 当电沉积在钢基材上时，该组合物提供优异的耐腐蚀性，并且在电沉积之前不需要配方中的铅，也不使用常规的铬漂洗用于钢基材预处理。

公开(公告)号：US5250164A

公开(公告)日：1993-10-05

申请号：US954591

申请日：1992-09-28

Applicant: Joseph T. Valko

Inventor： Joseph T. Valko

IPC: C08G18/08 ,  C08G18/58 ,  C08G18/64 ,  C08G18/80 ,  C08K5/00 ,  C08L63/00 ,  C09D5/44 ,  C25D13/04

CPC classification number: C09D5/4496 ,  C08G18/0814 ,  C08G18/584 ,  C08G18/643 ,  C08G18/8009 ,  C08K5/0025 ,  C08L63/00 ,  C09D5/4453

Abstract: A curable composition, comprising a beta-hydroxy urethane which is particularly useful as a crosslinking agent which affords relatively low temperature cure, is provided.

Abstract translation: 提供一种可固化组合物，其包含特别可用作提供相对低温固化的交联剂的β-羟基氨基甲酸酯。

公开(公告)号：US4931157A

公开(公告)日：1990-06-05

申请号：US157013

申请日：1988-02-18

Applicant: Joseph T. Valko ,  Joseph E. Plasynski ,  Robert D. Miller

Inventor： Joseph T. Valko ,  Joseph E. Plasynski ,  Robert D. Miller

IPC: C08G59/62 ,  C08G18/64 ,  C08G59/04 ,  C08G59/14 ,  C09D5/44

CPC classification number: C08G18/643 ,  C08G18/6415 ,  C08G59/04 ,  C09D5/4434 ,  Y10S524/901

Abstract: An ungelled reaction product of a polyepoxide and an active hydrogen-containing material containing at least two active hydrogens per molecule is disclosed. The active hydrogen-containing material being a hydroxyalkyl-substituted urethane in which the hydroxy group is in the beta position to the urethane group. The reaction product is useful as a precursor in making cationic resins for use in cationic electrodeposition.