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    MULTISTAGE CUMENE OXIDATION
    7.
    发明申请
    MULTISTAGE CUMENE OXIDATION 有权
    多元素氧化

    公开(公告)号：US20110263905A1

    公开(公告)日：2011-10-27

    申请号：US13139932

    申请日：2009-12-17

    申请人： Veli-Matti Purola

    发明人： Veli-Matti Purola

    IPC分类号： C07C407/00 ,  B01D19/00

    CPC分类号： C07C409/10 ,  C07C407/00

    摘要： The present invention concerns a process for oxidizing cumene to cumene hydroperoxide using an oxygen containing gas, preferably air, which process comprises—conducting a cumene feed and an oxygen containing gas feed to at least the first oxidation reactor in a series of 3-8 reactors, thereby forming an oxidation mixture, and conducting the formed oxidation mixture from one reactor to the next, preferably after an oxidation reaction has taken place, wherein—the reactors comprise at least one lower pressure oxidizer (1) as the first reactor in the series and at least one higher pressure oxidizer (2) as the last reactor in the series; —any lower pressure oxidizer is operated at a pressure of at least atmospheric pressure and any higher pressure oxidizer is operated at a pressure of at least 0.5 bar higher than said at least one lower pressure oxidizer.

    摘要翻译： 本发明涉及使用含氧气体，优选空气将异丙基苯氧化为异丙基氢过氧化物的方法，该方法包括 - 在一系列3-8反应器中将至少第一氧化反应器进行枯烯进料和含氧气体进料 ，从而形成氧化混合物，并且将形成的氧化混合物从一个反应器导入下一个反应器，优选在发生氧化反应之后，其中反应器包括至少一个作为该系列中的第一反应器的低压氧化剂（1） 和作为该系列中最后一个反应器的至少一个较高压力的氧化剂（2）; - 任何低压氧化剂在至少大气压的压力下操作，并且任何更高压力的氧化剂在比所述至少一种低压氧化剂高至少0.5巴的压力下操作。

    Process for the hydrogenation of olefins
    8.
    发明授权
    Process for the hydrogenation of olefins 有权
    烯烃氢化方法

    公开(公告)号：US07473811B2

    公开(公告)日：2009-01-06

    申请号：US10986368

    申请日：2004-11-12

    申请人： Isto Eilos ,  Antti Pyhälahti ,  Matti Nurminen ,  Veli-Matti Purola

    发明人： Isto Eilos ,  Antti Pyhälahti ,  Matti Nurminen ,  Veli-Matti Purola

    IPC分类号： C07C5/03

    CPC分类号： C10G65/04 ,  B01J8/0453 ,  B01J8/16 ,  B01J2208/00256 ,  C07C5/03 ,  C07C2521/04 ,  C07C2523/755 ,  C10G45/00 ,  C10G49/002 ,  C07C11/02

    摘要： The present invention relates to a process for the hydrogenation of olefins. The process comprises hydrogenation of a feed stock comprising more than 90 wt-% of olefins, carried out in a hydrogenation reactor comprising at least two reaction stages, wherein the feed stock is hydrogenated in the first reaction stage equipped with a cooling circuit and comprising a first and an optional second catalyst bed, and the effluent from the first reaction stage is hydrogenated in the final reaction stage comprising one or more catalyst beds and optionally equipped with a cooling circuit, the process is operated in trickling or pulse flow mode in a three phase reactor with a fixed catalyst bed and at least one catalyst of same or different type is used in each stage, the catalyst having different particle size and/or optionally different shape in at least two stages.

    摘要翻译： 本发明涉及烯烃氢化方法。 该方法包括在包括至少两个反应阶段的氢化反应器中进行的包含大于90重量％的烯烃的原料的氢化，其中原料在装备有冷却回路的第一反应阶段中被氢化并且包含 第一和任选的第二催化剂床，并且来自第一反应阶段的流出物在包括一个或多个催化剂床并且任选地具有冷却回路的最终反应阶段中被氢化，该过程以三滴流动或脉冲流动模式操作 在每个阶段使用具有固定催化剂床和至少一种相同或不同类型的催化剂的三相反应器，所述催化剂在至少两个阶段具有不同的粒度和/或任选不同的形状。

    Fuel components and their selective manufacturing methods
    9.
    发明申请
    Fuel components and their selective manufacturing methods 有权
    燃料组分及其选择性制造方法

    公开(公告)号：US20050228205A1

    公开(公告)日：2005-10-13

    申请号：US10975476

    申请日：2004-10-29

    申请人： Veli-Matti Purola ,  Sami Toppinen ,  Antti Pyhalahti ,  Marina Lindblad ,  Johan Gronqvist ,  Pirjo Siira

    发明人： Veli-Matti Purola ,  Sami Toppinen ,  Antti Pyhalahti ,  Marina Lindblad ,  Johan Gronqvist ,  Pirjo Siira

    IPC分类号： C07C2/28 ,  C07C2/00

    CPC分类号： C07C2/28 ,  C07C2531/10 ,  Y02P20/127

    摘要： A method for dimerizing isobutene, wherein, in dimerizing conditions, the isobutene is brought into contact with a porous cation exchange resin comprising a styrene polymer, which is cross-linked with divinyl benzene, and any sulphonic acid groups adhering to the polymer. The harmful deactivation of this catalyst, which is caused by the accumulation of the oligomers and polymers of isobutene and other C4-olefins in the cation exchange resin catalyst, is essentially decreased by selecting the cation exchange resin from a group including cation exchange resins, the acid,capacity of which is 4.7 equivalents/kg at a minimum, and the portion of divinyl benzene units of which is 5% by weight at a minimum and smaller than 20% by weight.

    摘要翻译： 二异丁烯的二聚方法，其中在二聚条件下，使异丁烯与包含与二乙烯基苯交联的苯乙烯聚合物的多孔阳离子交换树脂和粘附到聚合物上的任何磺酸基团接触。 由阳离子交换树脂催化剂中异丁烯和其它C 4 - 烯烃的低聚物和聚合物的积聚引起的该催化剂的有害失活通过从阳离子交换树脂催化剂中选择阳离子交换树脂 包括阳离子交换树脂的组，其酸的量最小为4.7当量/ kg，二乙烯基苯单元的部分最小为5重量％且小于20重量％。

    Process for the hydrogenation of olefins
    10.
    发明申请
    Process for the hydrogenation of olefins 有权
    烯烃氢化方法

    公开(公告)号：US20050177014A1

    公开(公告)日：2005-08-11

    申请号：US10986368

    申请日：2004-11-12

    申请人： Isto Eilos ,  Antti Pyhalahti ,  Matti Nurminen ,  Veli-Matti Purola

    发明人： Isto Eilos ,  Antti Pyhalahti ,  Matti Nurminen ,  Veli-Matti Purola

    IPC分类号： B01J8/04 ,  B01J8/16 ,  B01J10/00 ,  C07C5/00 ,  C07C5/03 ,  C10G45/00 ,  C10G49/00 ,  C10G65/04

    CPC分类号： C10G65/04 ,  B01J8/0453 ,  B01J8/16 ,  B01J2208/00256 ,  C07C5/03 ,  C07C2521/04 ,  C07C2523/755 ,  C10G45/00 ,  C10G49/002 ,  C07C11/02

    摘要： The present invention relates to a process for the hydrogenation of olefins. The process comprises hydrogenation of a feed stock comprising more than 90 wt-% of olefins, carried out in a hydrogenation reactor comprising at least two reaction stages, wherein the feed stock is hydrogenated in the first reaction stage equipped with a cooling circuit and comprising a first and an optional second catalyst bed, and the effluent from the first reaction stage is hydrogenated in the final reaction stage comprising one or more catalyst beds and optionally equipped with a cooling circuit, the process is operated in trickling or pulse flow mode in a three phase reactor with a fixed catalyst bed and at least one catalyst of same or different type is used in each stage, the catalyst having different particle size and/or optionally different shape in at least two stages.

    摘要翻译： 本发明涉及烯烃氢化方法。 该方法包括在包括至少两个反应阶段的氢化反应器中进行的包含大于90重量％的烯烃的原料的氢化，其中原料在装备有冷却回路的第一反应阶段中被氢化并且包含 第一和任选的第二催化剂床，并且来自第一反应阶段的流出物在包括一个或多个催化剂床并且任选地具有冷却回路的最终反应阶段中被氢化，该过程以三滴流动或脉冲流动模式操作 在每个阶段使用具有固定催化剂床和至少一种相同或不同类型的催化剂的三相反应器，所述催化剂在至少两个阶段具有不同的粒度和/或任选不同的形状。