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公开(公告)号：US20120128611A1
公开(公告)日：2012-05-24
申请号：US13381965
申请日：2010-06-29
摘要： Disclosed is the use of a UV filter combination, comprising (a) a first UV filter selected from benzylidene malonates of formula (1), wherein R1 methyl; ethyl; propyl; or n-butyl; if R1 is methyl, then R is tert. butyl; formula (II); formula (III); a radical of formula (1a); or a radical of formula (1b); wherein R2 and R3, independently from each other are hydrogen; or methyl; R4 is methyl; ethyl; or n-propyl; R5 and R6 independently from each other are hydrogen; or C1-C3alkyl; if R1 is ethyl; propyl; or n-butyl, then R is isopropyl; and (b) a second UV filter selected from (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; (b2) Butyl Methoxydibenzoylmethane; (b3)Diethylhexyl Butamido Triazone; (b4) Ethylhexyl Triazone; (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate; (b6) Ethylhexyl Methoxycinnamate; (b7) Ethylhexyl Salicylate; (b8) Homosalate; (b9) Octocrylene; (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol; (b11) Phenylbenzimidazole Sulfonic Acid; (b12) Titanium Dioxide; (b13) micronized Tris-Biphenyl Triazine; and (b14) micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone; (b15) benzoicacid,4,4-[[3-[1,3,3,3-tetramethyl-1-[trimethylsilyl)oxy]-1-disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester wherein the UV filter combination comprises at least 2 UV filters of component (b1)-(b14); for the protection of human and animal hair and skin against UV radiation.
摘要翻译： 公开了使用UV过滤器组合，其包含（a）选自式（1）的亚苄基丙二酸酯的第一UV过滤器，其中R 1甲基; 乙基; 丙基; 或正丁基; 如果R1是甲基，那么R是叔丁基。 丁基; 式（II）; 式（III）; 式（1a）的基团; 或式（1b）的基团; 其中R2和R3彼此独立地是氢; 或甲基; R4是甲基; 乙基; 或正丙基; R5和R6彼此独立地是氢; 或C 1 -C 3烷基; 如果R1是乙基; 丙基; 或正丁基，那么R是异丙基; 和（b）选自（b1）双 - 乙基己氧基苯酚甲氧基苯基三嗪的第二UV过滤器; （b2）丁基甲氧基二苯甲酰甲烷; （b3）丁酰己二酸二乙基己酯; （b4）乙基己基三嗪酮; （b5）二乙基氨基羟基苯甲酰己基苯甲酸酯; （b6）甲氧基肉桂酸乙基己酯; （b7）水杨酸乙基己酯; （b8）均质酸; （b9） （b10）微米亚甲基双苯并三唑基四甲基丁基苯酚; （b11）苯基苯并咪唑磺酸; （b12）二氧化钛; （b13）微粉化的三联苯三嗪; 和（b14）微粉化（2- {4- [2-（4-二乙基氨基-2-羟基 - 苯甲酰基） - 苯甲酰基] - 哌嗪-1-羰基} - 苯基） - （4-二乙基氨基-2-羟基 - 苯基） 甲酮 （b15）苯甲酸，4,4 - [[3- [1,3,3,3-四甲基-1- [三甲基甲硅烷基]氧基] -1-二硅氧烷基]丙基]氨基] -1,3,5-三嗪-2 ，4-二基]二亚氨基]双 - 二丁酯，其中UV滤光器组合包含至少2个组分（b1） - （b14）的UV滤光剂; 用于保护人和动物的头发和皮肤免受紫外线辐射。
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公开(公告)号：US09764169B2
公开(公告)日：2017-09-19
申请号：US13381965
申请日：2010-06-29
申请人： Julie Grumelard , Thomas Ehlis , Markus Hansch , Myriam Sohn
发明人： Julie Grumelard , Thomas Ehlis , Markus Hansch , Myriam Sohn
摘要： Disclosed is the use of a UV filter combination, comprising (a) a first UV filter selected from benzylidene malonates of formula (1), wherein R1 methyl; ethyl; propyl; or n-butyl; if R1 is methyl, then R is tert. butyl; formula (II); formula (III); a radical of formula (1a); or a radical of formula (1b); wherein R2 and R3, independently from each other are hydrogen; or methyl; R4 is methyl; ethyl; or n-propyl; R5 and R6 independently from each other are hydrogen; or C1-C3alkyl; if R1 is ethyl; propyl; or n-butyl, then R is isopropyl; and (b) a second UV filter selected from (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; (b2) Butyl Methoxydibenzoylmethane; (b3)Diethylhexyl Butamido Triazone; (b4) Ethylhexyl Triazone; (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate; (b6) Ethylhexyl Methoxycinnamate; (b7) Ethylhexyl Salicylate; (b8) Homosalate; (b9) Octocrylene; (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol; (b11) Phenylbenzimidazole Sulfonic Acid; (b12) Titanium Dioxide; (b13) micronized Tris-Biphenyl Triazine; and (b14) micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone;(b15) benzoicacid,4,4-[[3-[1,3,3,3-tetramethyl-1-[trimethylsilyl)oxy]-1-disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester wherein the UV filter combination comprises at least 2 UV filters of component (b1)-(b14); for the protection of human and animal hair and skin against UV radiation.
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3.发明申请SUNSCREEN AND PERSONAL CARE COMPOSITIONS COMPRISING A RANDOM TERPOLYMER 审中-公开SUNSCREEN和个人护理组合物包含随机的TERPOLYMER公开(公告)号：US20100129303A1
公开(公告)日：2010-05-27
申请号：US12575631
申请日：2009-10-08
申请人： Olga V. Dueva-Koganov , Bingham S. Jaynes , Joseph A. Lupia , Arjan T. Termaten , Marcelles Van der Sluis , Marleen Suurmeijer , David Normington , Marcel Schnyder , Julie Grumelard , Myriam Sohn
发明人： Olga V. Dueva-Koganov , Bingham S. Jaynes , Joseph A. Lupia , Arjan T. Termaten , Marcelles Van der Sluis , Marleen Suurmeijer , David Normington , Marcel Schnyder , Julie Grumelard , Myriam Sohn
CPC分类号： A61Q17/04 , A61K8/29 , A61K8/494 , A61K8/496 , A61K8/4966 , A61K8/8152 , A61K8/817 , A61K8/8182
摘要： Topically applicable, water-resistant cosmetic or dermatological compositions well suited for the UV-photoprotection of human skin and/or hair comprising an effective UV-photoprotecting amount of: (a) at least one UV screening agent from various classes and particularly effect mixtures thereof; and, (b) at least one random terpolymer; and, optionally, (c) other cosmetically acceptable ingredients. The various classes of UV-protecting compounds or UV sunscreens of special interest are selected from the groups b1 sparingly soluble micronized organic UV absorber, b2 Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, b3 at least one oil soluble organic UV absorber, b4 at least one inorganic UV absorber and b5 at least one water soluble UV absorber further defined herein.The present invention also relates to personal care compositions comprising at least one random terpolymer and other cosmetically acceptable ingredients.
摘要翻译： 本发明适用于非常适合人皮肤和/或毛发的UV光保护的耐水化妆品或皮肤病学组合物，其包含有效的UV-光保护剂量：（a）至少一种来自各种类别的UV屏蔽剂，特别是其影响混合物 ; 和（b）至少一种无规三元共聚物; 和（c）其它美容上可接受的成分。 各种类型的UV保护化合物或特别感兴趣的UV防晒剂选自b1微溶微粉化有机UV吸收剂，b2双 - 乙基己氧基苯酚甲氧基苯基三嗪，b3至少一种油溶性有机UV吸收剂，b4至少一种无机紫外线 吸收剂和b5至少一种本文进一步限定的水溶性紫外线吸收剂。 本发明还涉及包含至少一种无规三元共聚物和其它美容上可接受的成分的个人护理组合物。
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4.发明申请USE OF AMINES AND AMIDES FOR THE STABILIZATION OF ORGANIC MICRONIZED UV ABSORBERS 审中-公开用于有机微波紫外线吸收剂稳定化的氨基和氨基公开(公告)号：US20100143274A1
公开(公告)日：2010-06-10
申请号：US12529573
申请日：2008-02-27
申请人： Cyrille Deshayes , Thomas Ehlis , Julie Grumelard
发明人： Cyrille Deshayes , Thomas Ehlis , Julie Grumelard
CPC分类号： A61K8/41 , A61K8/35 , A61K8/494 , A61K2800/52 , A61Q17/04
摘要： Disclosed is the use of amines and amides for the stabilization of a cosmetic composition comprising: (a) an organic micronized UV absorber selected from a benzophenone derivative and (b) a dibenzoylmethane derivative. The use of the amines and amides results in the stabilization of the end-product formulations.
摘要翻译： 公开了胺和酰胺用于稳定化妆品组合物的用途，包括：（a）选自二苯甲酮衍生物和（b）二苯甲酰甲烷衍生物的有机微粉化UV吸收剂。 使用胺和酰胺导致最终产品配方的稳定化。
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公开(公告)号：US08557820B2
公开(公告)日：2013-10-15
申请号：US12597930
申请日：2008-04-28
申请人： Martin Vogt , Stefan Müller , Julie Grumelard , Cyrille Deshayes , Holger Paul , Jürg Haase , Thomas Ehlis
发明人： Martin Vogt , Stefan Müller , Julie Grumelard , Cyrille Deshayes , Holger Paul , Jürg Haase , Thomas Ehlis
IPC分类号： A61K31/497 , A61K8/00 , C07D241/04 , C07D295/00 , A61Q17/04
CPC分类号： C07D295/192 , A61K8/04 , A61K8/494 , A61K31/495 , A61Q17/04 , A61Q19/00 , A61Q19/08 , A61K2300/00
摘要： Disclosed is the use of an aqueous dispersion comprising (a) a micronized sparingly soluble organic benzophenone derivative of formula (1), selected from the crystal modifications (B) and (C), wherein the crystal modification (B) is characterized by a peak in the X-ray diffraction pattern at a d-spacing of about 7.70; and wherein the crystal modification (C) is characterized by a peak in the X-ray diffraction pattern at a d-spacing of about 7.06; and (b) a dispersing agent selected from anionic, non-ionic and amphoteric surfactants; for protecting the human skin from browning and skin aging. The new crystal modification (C) represents a thermodynamically stable compound of formula (1) at 25° C. This modification is therefore suitable in dispersions comprising micro-fine particles.
摘要翻译： 公开了含有（a）选自晶体改性（B）和（C）的式（1）的微粉化的微溶有机二苯甲酮衍生物的水性分散体的用途，其中所述晶体改性（B）的特征在于峰 在X-射线衍射图中，d-间距约为7.70; 并且其中所述晶体改性（C）的特征在于在约7.06的d间距处的X射线衍射图中的峰; 和（b）选自阴离子，非离子和两性表面活性剂的分散剂; 用于保护人体皮肤免受褐变和皮肤老化。 新的结晶改性（C）在25℃下代表热力学稳定的式（1）化合物。因此，该修饰适用于包含微细颗粒的分散体。
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公开(公告)号：US20100303746A1
公开(公告)日：2010-12-02
申请号：US12744495
申请日：2008-11-20
申请人： Sebastien Mongiat , Julie Grumelard , Thomas Ehlis
发明人： Sebastien Mongiat , Julie Grumelard , Thomas Ehlis
CPC分类号： A61Q17/04 , A61K8/494 , A61K2800/412
摘要： A method of preparing a composition, comprising (a) a micronised insoluble organic UV absorber, which method comprises grinding the insoluble organic UV absorber, in coarse particle form, in a grinding apparatus, in the presence of a grinding aid selected from the groups (b1) carboxylic acids and their salts; (b2) fatty acid esters (b3) alkyl phosphates or phosphoric acid esters; (b4) ethoxylated carboxylic acids or polyethyleneglycol (PEG) esters; (b5) fatty alcohol polyethyleneglycol (PEG) ethers of fatty alcohols; (b6) polyethylene/polypropylene -glycol ethers of saturated or unsaturated C4-C28 fatty acids; (b7) ethoxylated alkylphenols or ethoxylated alkylphenyl ethers; (b8) esters of polyol and mono-, di- or tri-glycerides; (b9) esters of fatty acids and saccharose; (b10) sorbitan mono- and di-esters of saturated and/or unsaturated C6-C22 fatty acids and ethylene oxide groups; and (b11) surfactants which are mainly acting as detergent or cleansing agents.
摘要翻译： 一种制备组合物的方法，包括（a）微粉化的不溶性有机UV吸收剂，该方法包括在研磨装置中，在选自以下组的研磨助剂的存在下研磨粗颗粒形式的不溶性有机UV吸收剂（ b1）羧酸及其盐; （b2）脂肪酸酯（b3）磷酸烷基酯或磷酸酯; （b4）乙氧基化羧酸或聚乙二醇（PEG）酯; （b5）脂肪醇的脂肪醇聚乙二醇（PEG）醚; （b6）饱和或不饱和C4-C28脂肪酸的聚乙烯/聚丙二醇醚; （b7）乙氧基化烷基酚或乙氧基化烷基苯基醚; （b8）多元醇和甘油单酯，甘油二酯或甘油酯的酯; （b9）脂肪酸和蔗糖的酯; （b10）饱和和/或不饱和C6-C22脂肪酸和环氧乙烷基团的脱水山梨糖醇单酯和二酯; 和（b11）主要作为洗涤剂或清洁剂的表面活性剂。
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公开(公告)号：US20100144753A1
公开(公告)日：2010-06-10
申请号：US12597930
申请日：2008-04-28
申请人： Martin Vogt , Stefan Müller , Julie Grumelard , Cyrille Deshayes , Holger Paul , Jürg Haase , Thomas Ehlis
发明人： Martin Vogt , Stefan Müller , Julie Grumelard , Cyrille Deshayes , Holger Paul , Jürg Haase , Thomas Ehlis
IPC分类号： A61K31/4965
CPC分类号： C07D295/192 , A61K8/04 , A61K8/494 , A61K31/495 , A61Q17/04 , A61Q19/00 , A61Q19/08 , A61K2300/00
摘要： Disclosed is the use of an aqueous dispersion comprising (a) a micronized sparingly soluble organic benzophenone derivative of formula (1), selected from the crystal modifications (B) and (C), wherein the crystal modification (B) is characterized by a peak in the X-ray diffraction pattern at a d-spacing of about 7.70; and wherein the crystal modification (C) is characterized by a peak in the X-ray diffraction pattern at a d-spacing of about 7.06; and (b) a dispersing agent selected from anionic, non-ionic and amphoteric surfactants; for protecting the human skin from browning and skin aging. The new crystal modification (C) represents a thermodynamically stable compound of formula (1) at 25° C. This modification is therefore suitable in dispersions comprising micro-fine particles.
摘要翻译： 公开了含有（a）选自晶体改性（B）和（C）的式（1）的微粉化的微溶有机二苯甲酮衍生物的水性分散体的用途，其中所述晶体改性（B）的特征在于峰 在X-射线衍射图中，d-间距约为7.70; 并且其中所述晶体改性（C）的特征在于在约7.06的d间距处的X射线衍射图中的峰; 和（b）选自阴离子，非离子和两性表面活性剂的分散剂; 用于保护人体皮肤免受褐变和皮肤老化。 新的结晶改性（C）在25℃下代表热力学稳定的式（1）化合物。因此，该修饰适用于包含微细颗粒的分散体。
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公开(公告)号：US09283160B2
公开(公告)日：2016-03-15
申请号：US13144113
申请日：2010-01-28
申请人： Bernd Herzog , Julie Grumelard
发明人： Bernd Herzog , Julie Grumelard
CPC分类号： A61K8/494 , A61K8/36 , A61K8/37 , A61K8/40 , A61K8/41 , A61K8/411 , A61K8/496 , A61K8/4966 , A61K2800/52 , A61K2800/592 , A61Q17/04
摘要： Disclosed is the Use of UV absorbers selected from (a1) diphenylacrylates; and (a2) specific hydroxyphenyl triazines for stabilizing cosmetic compositions comprising an organic UV absorber selected from (b1) a specific benzophenone derivative, (b2) a specific benzotriazole derivative and (b3) a specific triazine derivative and UV filters selected from (c1) cinnamic acid derivatives; and (c2) dibenzoylmethane derivatives.
摘要翻译： 公开了使用选自（a1）二苯基丙烯酸酯的UV吸收剂; 和（a2）用于稳定化妆品组合物的特定羟基苯基三嗪，其包含选自（b1）特定二苯甲酮衍生物，（b2）特定苯并三唑衍生物和（b3）特定三嗪衍生物的有机UV吸收剂和选自（c1）肉桂酸 酸衍生物; 和（c2）二苯甲酰甲烷衍生物。
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9.发明申请USE OF NANODISPERSIONS TO PROTECT WATER-SOLUBLE INGREDIENTS IN COSMETIC END FORMULATIONS 审中-公开使用纳米尺寸来保护化妆品配方中的水溶性成分公开(公告)号：US20120093896A1
公开(公告)日：2012-04-19
申请号：US12669972
申请日：2008-07-22
IPC分类号： A61K8/04 , A61K8/66 , A61K8/02 , A61Q19/00 , A61Q5/00 , A61K8/67 , A61Q1/12 , B82Y40/00 , B82Y99/00
CPC分类号： A61K8/676 , A61K8/04 , A61K8/345 , A61K8/375 , A61K8/4993 , A61K8/553 , A61K8/68 , A61K8/86 , A61K8/894 , A61K8/898 , A61K8/90 , A61K2800/413 , A61K2800/52 , A61K2800/522 , A61Q19/00 , B82Y5/00
摘要： The invention describes the use of a nanodispersion, which comprises: a) a membrane-forming molecule, b) a co-emulsifier, c) a lipophilic component, and d) a water-soluble ingredient sensitive to oxidation in cosmetic end formulations, the nanodispersion being obtainable by (α) mixing the components (a), (b) and (c) until a homogeneous liquid is obtained (so-called nanodispersion pre-phase), and (β) adding the water or aqueous phase (discontinuous phase) which contains the water-soluble ingredient and optionally the non-aqueous polar organic solvent to the liquid obtained in step (α). Component (d) is preferably ascorbic acid or vitamin C.
摘要翻译： 本发明描述了纳米分散体的使用，其包括：a）成膜分子，b）共乳化剂，c）亲脂性组分，和d）在化妆品末端制剂中对氧化敏感的水溶性成分， 通过（α）混合组分（a），（b）和（c）直到获得均匀的液体（所谓的纳米分散前相）和（＆bgr）加入水或水相（不连续的）可获得的纳米分散体 相），其包含水溶性成分和任选的非水极性有机溶剂与步骤（α）中获得的液体。 组分（d）优选为抗坏血酸或维生素C.
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公开(公告)号：US20110305650A1
公开(公告)日：2011-12-15
申请号：US13144113
申请日：2010-01-28
申请人： Bernd Herzog , Julie Grumelard
发明人： Bernd Herzog , Julie Grumelard
CPC分类号： A61K8/494 , A61K8/36 , A61K8/37 , A61K8/40 , A61K8/41 , A61K8/411 , A61K8/496 , A61K8/4966 , A61K2800/52 , A61K2800/592 , A61Q17/04
摘要： Disclosed is the Use of UV absorbers selected from (a1) diphenylacrylates; and (a2) specific hydroxyphenyl triazines for stabilizing cosmetic compositions comprising an organic UV absorber selected from (b1) a specific benzophenone derivative, (b2) a specific benzotriazole derivative and (b3) a specific triazine derivative and UV filters selected from (c1) cinnamic acid derivatives; and (c2) dibenzoylmethane derivatives.
摘要翻译： 公开了使用选自（a1）二苯基丙烯酸酯的UV吸收剂; 和（a2）用于稳定化妆品组合物的特定羟基苯基三嗪，其包含选自（b1）特定二苯甲酮衍生物，（b2）特定苯并三唑衍生物和（b3）特定三嗪衍生物的有机UV吸收剂和选自（c1）肉桂酸 酸衍生物; 和（c2）二苯甲酰甲烷衍生物。
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