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    Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups and their use as surface active substances
    1.
    发明授权
    Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups and their use as surface active substances 失效
    具有长链烃和聚氧化烯基团的聚丙烯酸酯及其作为表面活性物质的用途

    公开(公告)号：US5338485A

    公开(公告)日：1994-08-16

    申请号：US843912

    申请日：1992-02-27

    申请人： Jurgen Fock ,  Eberhard Esselborn ,  Dietmar Schaefer

    发明人： Jurgen Fock ,  Eberhard Esselborn ,  Dietmar Schaefer

    IPC分类号： B01F17/00 ,  B01F17/42 ,  C08F8/14 ,  C08F20/18 ,  C08F120/18

    CPC分类号： B01F17/0028 ,  C08F8/14 ,  C08F2810/30 ,  Y10S516/06

    摘要： Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups are disclosed, which are prepared by transesterification of polyacrylate alkyl esters, the alkyl groups of which have 1 to 4 carbon atoms and which were obtained by free radical polymerization, wherein the transesterification is carried out with a mixture of selected alcohols and polyoxyalkylene monools. Compared to products obtained by copolymerization, the transesterification products are largely free of undesirable low molecular weight components, have a narrow molecular weight distribution and exhibit excellent surfactant properties. They are useful especially as W/O emulsifiers for natural and synthetic oils.

    摘要翻译： 公开了具有长链烃和聚氧化烯基团的聚丙烯酸酯，其通过聚丙烯酸酯烷基酯（其烷基具有1至4个碳原子并通过自由基聚合获得）的酯交换制备，其中酯交换反应是用 选择的醇和聚氧化烯一元醇的混合物。 与通过共聚获得的产物相比，酯交换产物大部分没有不期望的低分子量组分，具有窄的分子量分布并且表现出优异的表面活性剂性质。 它们特别适用于天然和合成油的W / O乳化剂。

    Polyethers containing perfluoroalkyl groups, methods for their synthesis and their use as surfactants and as polyol components in the preparation of polyurethanes
    4.
    发明授权
    Polyethers containing perfluoroalkyl groups, methods for their synthesis and their use as surfactants and as polyol components in the preparation of polyurethanes 失效
    含有全氟代基团的聚醚，其合成方法及其作为表面活性剂和作为多元醇组分在制备聚氨酯中的用途

    公开(公告)号：US5087687A

    公开(公告)日：1992-02-11

    申请号：US470932

    申请日：1990-01-26

    申请人： Jurgen Fock ,  Eberhard Esselborn

    发明人： Jurgen Fock ,  Eberhard Esselborn

    IPC分类号： B01F17/42 ,  C08G18/50 ,  C08G65/26 ,  C08G65/331

    CPC分类号： C08G65/2639 ,  C08G18/5015 ,  C08G65/3312

    摘要： Polyethers are disclosed which contain perfluoroalkyl groups and have the average formula ##STR1## wherein R.sup.1 is the same or different in the polymer mixture and represents hydrogen or a fluoro group,n has an average value of 4 to 12,a has an average value of 0 to 4,m has an average value of 2 to 18,x has an average value of 2 to 50 andy has an average value of 0 to 3.A method for the synthesis of the new polyols, which are usefull as surfactants and, with respect to the compounds of formula I, as polyol components in the synthesis of polyurethanes, is also disclosed.

    摘要翻译： 公开了含有全氟烷基并且具有平均分子式R 1（C n F 2n）（CH 2）a O（C m H 2 m O）x（CH 2）2和R 1（C n F 2n）（CH 2）a O（C m H 2 m O）x（CH 2 II） R1在聚合物混合物中相同或不同，表示氢或氟基，n的平均值为4〜12，a的平均值为0〜4，m的平均值为2〜18，x为 平均值为2〜50，y的平均值为0〜3。合成新的多元醇的方法，其可用作表面活性剂，对于式I化合物，作为合成中的多元醇成分 的聚氨酯。

    Fiber finishing agents and compositions containing them
    5.
    发明授权
    Fiber finishing agents and compositions containing them 失效

    公开(公告)号：US4880906A

    公开(公告)日：1989-11-14

    申请号：US219715

    申请日：1988-07-15

    申请人： Eberhard Esselborn ,  Jurgen Fock

    发明人： Eberhard Esselborn ,  Jurgen Fock

    IPC分类号： D06M15/19 ,  D06M15/263 ,  D06M15/347 ,  D06M15/53 ,  D06M15/55

    CPC分类号： D06M15/263 ,  D06M15/19 ,  D06M15/347 ,  D06M15/53 ,  D06M15/55 ,  D06M2101/06 ,  D06M2101/28 ,  D06M2101/32 ,  D06M2101/34 ,  D06M2200/00 ,  D06M2200/11 ,  D06M2200/25 ,  D06M2200/50 ,  Y10T428/2913 ,  Y10T428/2931

    摘要： A finishing agent for finishing fibers or fiber products is disclosed. The agent is a mixture of the following components:(a) 34 to 99% by weight of a polymer of the general formula ##STR1## in which R.sup.1 is a z-hybric aliphatic alcohol, z=2 to 9, m=20 to 75, n=0 to 10, p=0 to 3,(b) 0 to 55% by weight of a copolymer, obtained by copolymerization of(b.sub.1) one mole of a macromonomer of the general formula ##STR2## in which q=5 to 75, r=0 to 10, s=0 to 3, with (b.sub.2) 2 to 12 moles of a vinyl ester of the general formula CH.sub.2 .dbd.CHOCOR.sup.2, in which R.sup.2 is an alkyl group with 1 to 4 carbon atoms,(b.sub.3) 1 to 6 moles of N-vinylpyrrolidone,(b.sub.4) 0 to 6 moles of an acrylate or methacrylate ester of the general formula CH.sub.3 .dbd.CR.sup.3 --COOR.sup.4, in which R.sup.3 .dbd.H or CH.sub.3, R.sup.4 is an alkyl group with 1 to 4 carbon atoms, the quotient of the average molecular weight of the monomer (b.sub.1) and the number of moles of the monomers (b.sub.2), (b.sub.3) and (b.sub.4) being 20 to 500and(c) 1 to 35% by weight of a compound, which is reactive with respect to the oxiran group and brings about the cross linking reaction,the sum of the components (a), (b) and (c) yielding 100% by weight.Especially preferred is a finishing agent mixture of34 to 73% by weight of component (a)24 to 55% by weight of component (b) and2 to 30% by weight of component (c)the sum of components (a), (b) and (c) yielding 100% by weight.The invention also discloses a finishing composition in the form of an aqueous solution comprising 0.1 to 10% by weight of the finishing agent as active ingredient with the remainder being water. A method for fixing fibers and fiber products with the inventive composition is also disclosed.The finishing agent and composition of the invention improve the handle, the hydrophilicity and the soil release of treated textile material. At the same time, the soilability, graying and the tendency to develop electrostatic charges are reduced.

    Copolymers with epoxide groups, their synthesis and use for finishing textile fibers or fiber products
    6.
    发明授权
    Copolymers with epoxide groups, their synthesis and use for finishing textile fibers or fiber products 失效
    具有环氧基团的共聚物，它们的合成和用于整理纺织纤维或纤维产品的用途

    公开(公告)号：US4868262A

    公开(公告)日：1989-09-19

    申请号：US199001

    申请日：1988-05-26

    申请人： Eberhard Esselborn ,  Jurgen Fock

    发明人： Eberhard Esselborn ,  Jurgen Fock

    IPC分类号： C08F216/14 ,  C08F218/04 ,  C08F290/06 ,  D06M15/21 ,  D06M15/347

    CPC分类号： D06M15/21 ,  C08F216/1416 ,  C08F218/04 ,  C08F290/062 ,  D06M15/347 ,  D06M2101/06 ,  D06M2101/28 ,  D06M2101/32 ,  D06M2101/34 ,  D06M2200/12

    摘要： Copolymers having epoxide groups are disclosed which are obtained by the copolymerization of(a.sub.1) one mole of a macromonomer of the general formula ##STR1## in which m=5 to 75, n=0 to 10 and p=0 to 3; (a.sub.2) 2 to 12 moles of a vinyl ester of the general formula CH.sub.2 .dbd.CHOCOR.sup.1, wherein R.sup.1 is an alkyl group with 1 to 4 carbon atoms;(a.sub.3) 0 to 6 moles of N-vinylpyrrolidone; and(a.sub.4) 0 to 6 moles of an acrylate or methacrylate ester of the general formula CH.sub.2 .dbd.CR.sup.2 --COOR.sup.3, wherein R.sup.2 =H or CH.sub.3, R.sup.3 =alkyl with 1 to 4 carbon atoms, the quotient formed from the average molecular weight of monomer (a.sub.1) and the sum of the number of moles of the monomers (a.sub.2), (a.sub.3) and (a.sub.4) being 20 to 500.The invention moreover relates to the synthesis of these copolymers by copolymerization of appropriate comonomer mixture and to the use of the copolymers for finishing textile fibers or fiber products.

    摘要翻译： 公开了具有环氧基团的共聚物，其通过（a1）1摩尔通式为“IMAGE”的大分子单体（其中m = 5至75，n = 0至10和p = 0至3）的共聚获得; （a2）2〜12摩尔通式CH 2 = CHOCOR 1的乙烯基酯，其中R 1是具有1至4个碳原子的烷基; （a3）0〜6摩尔N-乙烯基吡咯烷酮; 和（a4）0至6摩尔通式CH 2 = CR 2 -COOR 3的丙烯酸酯或甲基丙烯酸酯，其中R 2 = H或CH 3，R 3 =具有1至4个碳原子的烷基，所述商由平均分子量 单体（a1）和单体（a2），（a3）和（a4）的摩尔数之和为20-500。本发明还涉及通过合适的共聚单体混合物与 使用共聚物来整理纺织纤维或纤维制品。

    Polyacrylate ester with long-chain alkoxylated hydrocarbonoxy groups and their use in cosmetics and personal grooming
    9.
    发明授权
    Polyacrylate ester with long-chain alkoxylated hydrocarbonoxy groups and their use in cosmetics and personal grooming 失效
    具有长链烷氧基化烃氧基的聚丙烯酸酯酯及其在化妆品和个人修饰中的应用

    公开(公告)号：US5296573A

    公开(公告)日：1994-03-22

    申请号：US648725

    申请日：1991-01-31

    申请人： Eberhard Esselborn ,  Jurgen Fock ,  Gotz Koerner ,  Dietmar Schaefer

    发明人： Eberhard Esselborn ,  Jurgen Fock ,  Gotz Koerner ,  Dietmar Schaefer

    IPC分类号： B01F17/52 ,  C08F8/14 ,  C08F20/26 ,  C08G81/02 ,  C08F220/26 ,  C08F220/28

    CPC分类号： A61Q5/02 ,  A61K8/86 ,  C08F8/14 ,  C08G81/025 ,  C08F2810/30

    摘要： Polyacrylate esters with long-chain alkoxylated hydrocarbonoxy groups are disclosed which can be obtained by the transesterification of polyacrylate esters with polyoxyalkylene monools, wherein the polyacrylate esters, up to 50% of which can be replaced by the corresponding methacrylate esters, have been obtained by free radical polymerization and wherein the polyoxyalkylene monools have the average formulaR.sup.1 O(C.sub.n H.sub.2n O--).sub.x HwhereinR.sup.1 is an alkyl, alkenyl or alkylphenyl group,n has an absolute value of 2, 3 or 4 and an average value of 2.0 to 2.5 andx is 10 to 200.The compounds, which can be used as emulsifiers, solubilizers and for thickening aqueous solutions which contain anionic surfactants, particularly in cosmetics and for personal grooming, are distinguished by a content of low molecular weight components, which is smaller compared to that of products obtained by copolymerization.

    摘要翻译： 公开了具有长链烷氧基化烃氧基的聚丙烯酸酯，其可通过聚丙烯酸酯与聚氧化烯一醇的酯交换获得，其中至多50％可被相应的甲基丙烯酸酯代替的聚丙烯酸酯已经通过游离 自由基聚合，其中聚氧化烯一元醇具有平均式R1O（CnH2nO-）xH，其中R1是烷基，烯基或烷基苯基，n的绝对值为2,3或4，平均值为2.0至2.5，x为 可用作乳化剂，增溶剂和含有阴离子表面活性剂，特别是化妆品中和用于个人修饰的阴离子表面活性剂的水溶液的化合物的特征在于低分子量组分的含量比其低 的共聚产物。

    Manufacturing polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups
    10.
    发明授权
    Manufacturing polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups 失效
    长链碳氢化合物和聚氧乙烯基团的制备聚丙烯酸酯

    公开(公告)号：US5133898A

    公开(公告)日：1992-07-28

    申请号：US471554

    申请日：1990-01-29

    申请人： Jurgen Fock ,  Eberhard Esselborn ,  Dietmar Schaefer

    发明人： Jurgen Fock ,  Eberhard Esselborn ,  Dietmar Schaefer

    IPC分类号： B01F17/00 ,  B01F17/42 ,  B01F17/52 ,  B01F17/54 ,  C08F8/14 ,  C08G81/02 ,  C10L1/192 ,  C10L1/195 ,  C10L1/198 ,  C10L10/18

    CPC分类号： B01F17/0028 ,  C08F8/14 ,  C08F2810/30 ,  Y10S516/918

    摘要： Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups are disclosed, which are prepared by transesterification of polyacrylate alkyl esters, the alkyl groups of which have 1 to 4 carbon atoms and which were obtained by free radical polymerization, wherein the transesterification is carried out with a mixture of selected alcohols and polyoxyalkylene monools. Compared to products obtained by copolymerization, the transesterification products are largely free of undesirable low molecular weight components, have a narrow molecular weight distribution and exhibit excellent surfactant properties. They are useful especially as W/O emulsifiers for natural and synthetic oils.

    摘要翻译： 公开了具有长链烃和聚氧化烯基团的聚丙烯酸酯，其通过聚丙烯酸酯烷基酯（其烷基具有1至4个碳原子并通过自由基聚合获得）的酯交换制备，其中酯交换反应是用 选择的醇和聚氧化烯一元醇的混合物。 与通过共聚获得的产物相比，酯交换产物大部分没有不期望的低分子量组分，具有窄的分子量分布并且表现出优异的表面活性剂性质。 它们特别适用于天然和合成油的W / O乳化剂。