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    Derivatives of quinoline fused to a five-membered heterocyclic ring
    3.
    发明授权
    Derivatives of quinoline fused to a five-membered heterocyclic ring 失效
    融合成五元杂环的喹啉衍生物

    公开(公告)号：US5167695A

    公开(公告)日：1992-12-01

    申请号：US527831

    申请日：1990-05-24

    申请人： Gunter Brill ,  Helmut Hagen ,  Karl-Otto Westphalen ,  Bruno Wuerzer

    发明人： Gunter Brill ,  Helmut Hagen ,  Karl-Otto Westphalen ,  Bruno Wuerzer

    IPC分类号： A01N43/52 ,  A01N43/76 ,  C07D471/04 ,  C07D498/04

    CPC分类号： C07D471/04

    摘要： Quinoline derivatives fused to a five-membered heterocyclic ring and of the formula ##STR1## where R.sup.1 is hydrogen, halogen, carboxyl or substituted or unsubstituted alkyl,Y is nitrogen or C--R.sup.2, whereR.sup.2 is hydrogen, halogen, hydroxyl, alkoxy, alkylthio, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted benzyl, phenethyl, phenyl or naphthyl, or a substituted or unsubstituted 5- or 6-membered heterocyclic ring with one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen,X is oxygen or N--R.sup.3, R.sup.3 being hydrogen, substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl or subsituted or unsubstituted benzyl,processes for their manufacture and their use for combating unwanted plant growth.

    摘要翻译： 与五元杂环稠合的喹啉衍生物，其中R1是氢，卤素，羧基或取代或未取代的烷基，Y是氮或C-R2，其中R2是氢，卤素，羟基，烷氧基， 烷硫基，取代或未取代的烷基，取代或未取代的环烷基，取代或未取代的苄基，苯乙基，苯基或萘基，或取代或未取代的具有一个或两个选自氧，硫的杂原子的5或6元杂环 和氮，X为氧或N-R 3，R 3为氢，取代或未取代的烷基，烯基，炔基，环烷基或取代或未取代的苄基，其制备方法及其用于防治不想要的植物生长。

    Oxime esters of substituted quinoline-8-carboxylic acids and use thereof as herbicides
    4.
    发明授权
    Oxime esters of substituted quinoline-8-carboxylic acids and use thereof as herbicides 失效
    取代喹啉-8-羧酸的肟酯及其作为除草剂的用途

    公开(公告)号：US4808212A

    公开(公告)日：1989-02-28

    申请号：US944519

    申请日：1986-12-22

    申请人： Peter Plath ,  Karl Eicken ,  Bernd Zeeh ,  Ulrich Eichenauer ,  Helmut Hagen ,  Rolf-Dieter Kohler ,  Norbert Meyer ,  Bruno Wuerzer

    发明人： Peter Plath ,  Karl Eicken ,  Bernd Zeeh ,  Ulrich Eichenauer ,  Helmut Hagen ,  Rolf-Dieter Kohler ,  Norbert Meyer ,  Bruno Wuerzer

    IPC分类号： C07D333/00 ,  A01N43/42 ,  A01N43/48 ,  A01N43/653 ,  C07D215/32 ,  C07D215/48 ,  C07D335/00 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07D521/00

    CPC分类号： C07D231/12 ,  A01N43/42 ,  A01N43/653 ,  C07D215/32 ,  C07D233/56 ,  C07D249/08 ,  C07D405/12 ,  C07D409/12

    摘要： Oxime esters of substituted quinoline-8-carboxylic acids of the formula ##STR1## where X is hydrogen, C.sub.1 -C.sub.4 -alkyl or halogen, Z is hydrogen or methyl, R.sup.1 is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxymethyl, C.sub.1 -C.sub.4 -alkoxyethyl, C.sub.1 -C.sub.4 -alkylthiomethyl, C.sub.1 -C.sub.4 -alkylthioethyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.5 -C.sub.8 -cycloalkyl, each of which is unsubstituted or bears up to 3 methyl substituents, hydrogen, cyano, acetyl, benzoyl, unsubstituted benzyl or phenyl, or benzyl or phenyl bearing up to 3 substitutents selected from the group consisting of halogen, cyano, trifluoromethyl, C.sub.1 -C.sub.4 -haloalkyloxy, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkyl, hydroxy, dimethylamino or acetamino, R.sup.2 is hydrogen if R.sup.1 is not hydrogen, R.sup.2 further denotes C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxymethyl, chloromethyl, azolylmethyl, 1,1-dimethoxymethyl, cyano, C.sub.1 -C.sub.4 -alkoxycarbony, C.sub.1 -C.sub.4 -alkoxy, phenyl if R.sup.1 is H, CH.sub.3 or acetyl, or R.sup.2 denotes, when R.sup.1 is H or methyl, furyl, tetrahydrofuryl, thienyl, tetrahydropyranyl, tetrahydrothiopyranyl, dihydro-.DELTA..sup.3 -pyranyl or dihydro-.DELTA..sup.3 -thiopyranyl; further, R.sup.1 and R.sup.2, together with the carbon atom to which they are linked, denote C.sub.1 -C.sub.12 -cycloalkylidene, C.sub.5 -C.sub.6 -cycloalkenylidene or 4-oxacyclohexadienylidene, each of which is unsubstituted or bears up to 3 methyl substituents, it being possible, where the ring is 5-membered or 6-membered, or doubly unsaturated 6-membered, for it to contain an oxygen or sulfur atom, their preparation, and their use as herbicides.

    摘要翻译： 其中X是氢，C 1 -C 4烷基或卤素，Z是氢或甲基的取代喹啉-8-羧酸的肟酯，R 1是C 1 -C 6烷基，C 1 -C 4烷氧基甲基， C 1 -C 4 - 烷氧基乙基，C 1 -C 4 - 烷硫基甲基，C 1 -C 4 - 烷硫基乙基，C 1 -C 4 - 烷氧基羰基，C 3 -C 6 - 烯基或C 5 -C 8 - 环烷基，其各自为未取代的或至多含有3个甲基取代基 ，氰基，乙酰基，苯甲酰基，未取代的苄基或苯基，或带有至多3个选自卤素，氰基，三氟甲基，C 1 -C 4卤代烷氧基，C 1 -C 6 - 烷硫基，C 1 -C 4 - 烷氧基的取代基的苄基或苯基 C1-C4烷基，羟基，二甲基氨基或乙酰氨基，如果R1不是氢，R2是氢，R2还表示C1-C6-烷基，C1-C4-烷氧基甲基，氯甲基，唑基甲基，1,1-二甲氧基甲基，氰基，C1 -C 1-4烷氧基羰基，C 1 -C 4 - 烷氧基，如果R 1为H，CH 3或乙酰基，则为苯基，或R 2表示当R 1为H或甲基时，呋喃基，四氢呋喃基，噻吩基，四氢吡喃基，四氢噻喃基，二 水合-3β-吡喃基或二氢-D-3,3-噻喃基; 此外，R 1和R 2与它们所连接的碳原子一起表示C 1 -C 12 - 亚环烷基，C 5 -C 6 - 环亚烯基或4-氧杂环己二亚苯基，其各自是未取代的或最多含有3个甲基取代基，可能是 ，其中环为5元或6元，或双不饱和6元，含有氧或硫原子，其制备及其作为除草剂的用途。

    2,3-substituted 1,8-naphthyridines, their preparation and their use as antidotes
    5.
    发明授权
    2,3-substituted 1,8-naphthyridines, their preparation and their use as antidotes 失效
    2,3-取代的1,8-萘啶，其制备及其作为抗体使用

    公开(公告)号：US5059240A

    公开(公告)日：1991-10-22

    申请号：US486867

    申请日：1990-03-01

    申请人： Helmut Hagen ,  Juergen Pfister ,  Hans Ziegler ,  Bruno Wuerzer ,  Karl-Otto Westphalen

    发明人： Helmut Hagen ,  Juergen Pfister ,  Hans Ziegler ,  Bruno Wuerzer ,  Karl-Otto Westphalen

    IPC分类号： A01N25/32 ,  A01N43/90 ,  C07D471/04 ,  C07D471/14

    CPC分类号： C07D471/04 ,  A01N25/32 ,  C07D471/14

    摘要： 2,3-substituted 1,8-naphthyridines of the general formula I ##STR1## where: R is hydrogen or C.sub.1 -C.sub.4 -alkyl (n=1 or 2)R.sup.1 is amino or substituted amino,XR.sup.5, where X is oxygen or sulfur and R.sup.5 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl-((C.sub.1 -C.sub.4)-alkyl, C.sub.5 -C.sub.8 -cycloakyl, substituted or unsubstituted phenyl, substituted or unsubstituted phenyl-(C.sub.1 -C.sub.3)-alkyl,halogen,isothiorhonium halide,C.sub.1 -C.sub.12 -alkyl,C.sub.1 -C.sub.4 -alkoxycarbonyl-C.sub.1 -C.sub.4 -alkyl,substituted or unsubstituted phenyl or phenyl-(C.sub.1 -C.sub.3)-alkyl,R.sup.2 is C.sub.1 -C.sub.4 -alkyl, cyano, carboxyl or a group ##STR2## where X is oxygen or sulfur,B is C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or alkylthio, amino, mono- or dialkylamino, where each alkyl radical is of 1 to 4 carbon atoms, morpholino, piperidyl, chlorine, bromine or substituted or unsubstituted phenyl,D is C.sub.1 -C.sub.4 alkyl or NH.sub.2 andR.sup.6 is hydrogen, C.sub.1 -C.sub.8 -alkyl or alkylcarbonyl,or R.sup.1 and R.sup.2 together are --NH--N.dbd.C(CH.sub.2)--,and their environmentally tolerated saltswith the proviso that R.sup.2 is not cyano, carboxyl or a carboxamido or carboxylic ester group when R.sup.1 is methyl, hydroxyl or amino (NH.sub.2), processes for their manufacture, and herbicidal agents containing a naphthyridine I as safener and at least one herbicidal active ingredient selected from the group consisting ofa) 2-(4-heteroaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid derivatives andb) cyclohexenone derivatives.

    摘要翻译： 具有通式I的2,3-取代的1,8-萘啶，其中：R是氢或C 1 -C 4 - 烷基（n = 1或2）R 1是氨基或取代的氨基，XR 5，其中X是氧 或（C 1 -C 4） - 烷基，C 5 -C 8 - 环烷基，取代或未取代的苯基，取代或未取代的苯基 - （C 1 -C 3） - 烷基，卤素，异卤卤化物，C 1 -C 12 - 烷基，C 1 -C 4 - 烷氧基羰基-C 1 -C 4烷基，取代或未取代的苯基或苯基 - （C 1 -C 3） - 烷基，R 2为C 1 -C 4烷基，氰基， 羧基或基团，其中X为氧或硫，B为C 1 -C 6 - 烷基，C 1 -C 6 - 烷氧基或烷硫基，氨基，单或二烷基氨基，其中每个烷基为1至4个碳原子，吗啉代 ，哌啶基，氯，溴或取代或未取代的苯基，D是C 1 -C 4烷基或NH 2，R 6是氢，C 1 -C 8 - 烷基或烷基羰基，或者R 1和R 2一起是-NH-N = C（CH 2） 其环境耐受性盐，条件是R2不是氰基，羧基或a 当R1是甲基，羟基或氨基（NH2）时，羧酰胺基或羧酸酯基，其制备方法和含有萘啶I作为安全剂的除草剂和至少一种除草活性成分，其选自a）2-（4 - 杂芳氧基） - 或2-（4-芳氧基） - 苯氧基乙酸衍生物和b）环己烯酮衍生物。

    Novel 4'(benzisothiazo-5-yloxy)-phenylurea derivatives, their preparation and their use as herbicides
    8.
    发明授权
    Novel 4'(benzisothiazo-5-yloxy)-phenylurea derivatives, their preparation and their use as herbicides 失效
    新型4'（苯并异噻唑-5-基氧基） - 苯基脲衍生物，其制备及其作为除草剂的用途

    公开(公告)号：US4589910A

    公开(公告)日：1986-05-20

    申请号：US727628

    申请日：1985-04-30

    申请人： Helmut Hagen ,  Hans Ziegler ,  Bruno Wuerzer

    发明人： Helmut Hagen ,  Hans Ziegler ,  Bruno Wuerzer

    IPC分类号： A01N47/30 ,  C07D275/04 ,  A01N47/38

    CPC分类号： C07D275/04 ,  A01N47/30

    摘要： A 4'-(Benzisothiazol-5-yloxy)-phenylureas of the formula ##STR1## where R.sup.1 and R.sup.2 are each a saturated straight-chain or branched aliphatic radical of 1 to 10 carbon atoms, an unsaturated straight-chain or branched aliphatic radical of 3 to 10 carbon atoms, or an araliphatic or aromatic radical which may be substituted by 1, 2 or 3 C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, cyano, halogen, nitro, monofluoromethyl or trifluoromethyl groups, or are each alkoxy of 1 to 6 carbon atoms, R.sup.2 may furthermore be hydrogen, or R.sup.1 and R.sup.2, together with the nitrogen atom, may be members of a 5-membered or 6-membered ring which may contain further nitrogen and/or oxygen atoms as heteroatoms, and X is hydrogen, trifluoromethyl or chlorine, processes for their preparation, and herbicides containing ureas of the formula I as active ingredients.

    摘要翻译： 式Ⅰ的4' - （苯并异噻唑-5-基氧基） - 苯基，其中R 1和R 2各自是1-10个碳原子的饱和直链或支链脂族基团，不饱和直链或支链脂族基 或可被1,2或3个C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，氰基，卤素，硝基，单氟甲基或三氟甲基取代的芳脂族或芳族基团，或各自为 具有1至6个碳原子的烷氧基，R 2还可以是氢，或者R 1和R 2与氮原子一起可以是可以含有另外的氮原子和/或氧原子作为杂原子的5元或6元环的成员 ，X为氢，三氟甲基或氯，其制备方法，以及含有式I的脲的除草剂作为活性成分。

    Herbicidal sulfonamides and their use to influence plant growth
    10.
    发明授权
    Herbicidal sulfonamides and their use to influence plant growth 失效
    除草剂磺酰胺及其用于影响植物生长的因素

    公开(公告)号：US5104441A

    公开(公告)日：1992-04-14

    申请号：US618587

    申请日：1990-11-28

    申请人： Gerhard Hamprecht ,  Helmut Hagen ,  Thomas Liese-Sauer ,  Norbert Meyer ,  Bruno Wuerzer

    发明人： Gerhard Hamprecht ,  Helmut Hagen ,  Thomas Liese-Sauer ,  Norbert Meyer ,  Bruno Wuerzer

    IPC分类号： A01N47/36 ,  C07D521/00

    CPC分类号： C07D521/00 ,  A01N47/36

    摘要： Substituted sulfonylureas of the formula I ##STR1## where R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.4 -alkenyl or alkynyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.3 -C.sub.6 -alkoxyalkyl, C.sub.4 -C.sub.6 -haloalkoxyalkyl or C.sub.5 -C.sub.6 -cycloalkyl,R.sup.2 is hydrogen, methyl or ethyl,R.sup.3 is hydrogen, halogen, methyl or methoxy,R.sup.4 is hydrogen, methyl or methoxy,X is N or C--H,and Hal is fluorine, chlorine or bromine, and alkali metal or alkaline earth metal salts thereof, with the proviso that R.sup.1 is not methyl when Hal is chlorine and X is N, a process for the manufacture of sulfonylureas of the formula I and their use as herbicides.

    摘要翻译： 取代的式I的磺酰脲其中R 1是氢，C 1 -C 4 - 烷基，C 3 -C 4 - 烯基或炔基，C 1 -C 4卤代烷基，C 3 -C 6 - 烷氧基烷基，C 4 -C 6 - 卤代烷氧基烷基或C 5 -C 6 环烷基，R 2是氢，甲基或乙基，R 3是氢，卤素，甲基或甲氧基，R 4是氢，甲基或甲氧基，X是N或CH，Hal是氟，氯或溴，以及碱金属或碱土 金属盐，条件是当Hal为氯且X为N时，R1不是甲基，制备式I磺酰脲的方法及其作为除草剂的用途。