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公开(公告)号:US10400100B2
公开(公告)日:2019-09-03
申请号:US15578697
申请日:2017-02-24
申请人: KINGFA SCI. & TECH. CO., LTD. , ZHUHAI WANGO CHEMICAL CO., LTD. , TIANJIN KINGFA NEW MATERIAL CO., LTD.
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Renxu Yuan , Yuke Zhong , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong
IPC分类号: C08J5/18 , C08L67/02 , C08K3/26 , C08K3/34 , C08K5/07 , C08K5/1535 , C08K13/02 , C08L3/02 , C08L25/14 , C08L67/04
摘要: A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of tetrahydrofuran, which is 3 ppm-200 ppm; and based on the total weight of the biodegradable polyester composition, a weight content of cyclopentanone is 0.5 ppm-85 ppm is provided. The tetrahydrofuran and cyclopentanone is added into the composition and controlling the content of tetrahydrofuran and the content of cyclopentanone in a certain range in the composition to realize printing performance. Moreover, when a velocity of film blowing is 176 Kg/h, a range of a film thickness is less than 0.2 μm and a relative deviation of the film thickness is less than 1%.
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公开(公告)号:US10435556B2
公开(公告)日:2019-10-08
申请号:US15578689
申请日:2017-02-24
申请人: KINGFA SCI. & TECH. CO., LTD. , ZHUHAI WANGO CHEMICAL CO., LTD. , TIANJIN KINGFA NEW MATERIAL CO., LTD.
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Renxu Yuan , Yuke Zhong , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong
IPC分类号: C08L67/02 , C08K5/1535 , C08K5/156 , C08L25/14 , C08L67/04
摘要: A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of a cyclic ester compound having a structure shown as formula (I) which is 100 ppm-950 ppm; and based on the total weight of the biodegradable polyester composition, a weight content of tetrahydrofuran is 3 ppm-200 ppm is provided. The cyclic ester compound and tetrahydrofuran is added into the composition and controlling the content of the cyclic ester compound and the content of tetrahydrofuran in a certain range in the composition to realize an anti-thermal oxidative aging property of the biodegradable polyester composition. In addition, a film is prepared by blow molding or a part is prepared by injection molding after being digested with 95% ethanol at 40° C. for 240 hours.
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公开(公告)号:US11530294B2
公开(公告)日:2022-12-20
申请号:US16644509
申请日:2018-06-26
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong , Shihua He
摘要: The present invention discloses a polylactic acid composite and use thereof. The polylactic acid composite includes the following components: (A) 89 to 98 parts by weight of polylactic acid; (B) 1 to 4 parts by weight of talcum powder; and (C) 1 to 7 parts by weight of a plasticizer. In the component (A), the polylactic acid has a polydispersity index P satisfying the following relationship: 1.55≤P≤2.02. In the component (B), the talcum powder has a particle size D(50) satisfying: 1 μm≤D(50)≤2.6 μm. In the component (C), the plasticizer has a relative molecular weight M satisfying: 180≤M≤670. Through research, the present invention has unexpectedly discovered that by using the polylactic acid having the polydispersity index P satisfying the relationship 1.55≤P≤2.02 as a matrix, adding a specific range of content of ultrafine talcum powder as a nucleating agent, and selecting the plasticizer of a specific molecular weight as a crystallization promotion agent, the prepared polylactic acid composite has a light transmittance T≥80%, a haze H≤40%, and a heat deflection temperature HDT≥90° C., having significantly improved heat resistance and transparency.
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公开(公告)号:US10479887B2
公开(公告)日:2019-11-19
申请号:US15580217
申请日:2017-03-01
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Renxu Yuan , Yuke Zhong , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong
IPC分类号: C08L67/02 , C08K13/02 , C08G63/183
摘要: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of glycidyl methacrylate is 0.05 ppm-10 ppm. In the present invention, by adding a trace amount of glycidyl methacrylate into a chosen formula of the biodegradable polyester composition and controlling the weight content of glycidyl methacrylate which finally remains in the biodegradable polyester composition as 0.05 ppm-10 ppm, a compatibility between aliphatic-aromatic polyester and polylactic acid in the biodegradable polyester composition can be greatly enhanced, which enables the biodegradable polyester composition to have excellent surface property of film material, and no fisheye occurs on the film material because of a fluctuation of processing technique.
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公开(公告)号:US20180298188A1
公开(公告)日:2018-10-18
申请号:US15580217
申请日:2017-03-01
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Renxu Yuan , Yuke Zhong , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong
IPC分类号: C08L67/02 , C08G63/183
CPC分类号: C08L67/02 , C08G63/183 , C08G2230/00 , C08K13/02 , C08L2201/06 , C08L2201/08 , C08L2205/025 , C08L2205/03 , C08L67/04 , C08K3/013 , C08K5/1515 , C08L3/02
摘要: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of glycidyl methacrylate is 0.05 ppm-10 ppm. In the present invention, by adding a trace amount of glycidyl methacrylate into a chosen formula of the biodegradable polyester composition and controlling the weight content of glycidyl methacrylate which finally remains in the biodegradable polyester composition as 0.05 ppm-10 ppm, a compatibility between aliphatic-aromatic polyester and polylactic acid in the biodegradable polyester composition can be greatly enhanced, which enables the biodegradable polyester composition to have excellent surface property of film material, and no fisheye occurs on the film material because of a fluctuation of processing technique.
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公开(公告)号:US20180298187A1
公开(公告)日:2018-10-18
申请号:US15580173
申请日:2017-03-01
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Renxu Yuan , Yuke Zhong , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong
IPC分类号: C08L67/02 , C08G63/183
摘要: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of styrene is 0.1 ppm-30 ppm. When the weight content of styrene which is added into a chosen formula of the biodegradable polyester composition based on the total weight of the biodegradable polyester composition is controlled as 0.1 ppm-30 ppm, the present invention may guarantee the biodegradable polyester composition with excellent transmittance and haze effect, and meanwhile may guarantee the biodegradable polyester composition with suitable UV resistance function, without reducing a degradation rate of the biodegradable polyester composition.
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公开(公告)号:US10472515B2
公开(公告)日:2019-11-12
申请号:US15580173
申请日:2017-03-01
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Renxu Yuan , Yuke Zhong , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong
摘要: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of styrene is 0.1 ppm-30 ppm. When the weight content of styrene which is added into a chosen formula of the biodegradable polyester composition based on the total weight of the biodegradable polyester composition is controlled as 0.1 ppm-30 ppm, the present invention may guarantee the biodegradable polyester composition with excellent transmittance and haze effect, and meanwhile may guarantee the biodegradable polyester composition with suitable UV resistance function, without reducing a degradation rate of the biodegradable polyester composition.
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公开(公告)号:US11370909B2
公开(公告)日:2022-06-28
申请号:US16644459
申请日:2019-05-24
发明人: Chunping Ouyang , Jian Jiao , Kaijin Mai , Xueteng Dong , Hui Yang , Weida Qu , Kai Xiong , Changli Lu , Xiangbin Zeng , Tongmin Cai , Xianbo Huang
摘要: The present invention discloses a biodegradable polyester composition, wherein the biodegradable polyester composition comprises the following components in parts by weight: i) 58 to 80 parts by weight of an aliphatic-aromatic copolyester; ii) 20 to 32 parts by weight of starch; and iii) 0 to 10 parts by weight of a processing agent. The present invention unexpectedly found by research that by using an aliphatic-aromatic copolyester in which an amount of aromatic carboxylic acid accounts for a total amount of diacid is 44 mol % to 48 mol % as a matrix resin, where the aliphatic-aromatic copolyester has a crystallization peak width D of 5° C. to 16° C., and by using starch of which a particle size D (50) is 2 μm to 12 μm as the other phase, and meanwhile by adding a specific amount of a processing agent, the polyester composition prepared has excellent transversal and longitudinal tear strengths, and the polyester composition has a biodegradation rate of 90% or more during the 12-week degradation test, satisfying the industrial compost.
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公开(公告)号:US10815332B2
公开(公告)日:2020-10-27
申请号:US16317648
申请日:2017-11-30
发明人: Weiwei Wang , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Renxu Yuan , Zhilong Guo , Meijun Tang
摘要: The present invention discloses a PBS resin composition and a preparation method thereof. The composition comprises: a. PBS resin; b. element titanium; c. element phosphorus, wherein a weight ratio range of titanium to phosphorus is 0.6-10:1, preferably 0.7-4:1, and more preferably 1.25-1.5:1. A weight content of the element titanium is 20-200 ppm, and a weight content of the element phosphorus is 15-70 ppm. By adding a titanium-containing compound and a phosphorus-containing compound and controlling the range of the weight ratio of the element titanium to the element phosphorus in the PBS resin composition to be 0.6-10:1, the present invention obtains a PBS resin composition. After treating in a 95° C.-distilled water bath for 12 hours and drying at 90° C. for 3 hours, a change of the melt flow index of the PBS resin composition is less than 50.0 g/10 min, and the PBS resin composition possesses an obviously improved hydrolysis property.
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公开(公告)号:US11149112B2
公开(公告)日:2021-10-19
申请号:US16644504
申请日:2018-06-26
发明人: Weiwei Wang , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Nanbiao Ye , Zhilong Guo , Changli Lu
IPC分类号: C08G63/183
摘要: The present invention relates to a biodegradable polyester and use thereof, including components: A) acid components containing following repeating units: 50 to 58 mol % of terephthalic acid A1; 30 to 40 mol % of sebacic acid A2; and 2 to 20 mol % of an aliphatic dibasic acid A3 with a carbon chain length of 6 or less; B) butanediol. In the present invention, in the case of a high content of the terephthalic acid, the biodegradable polyester prepared by introducing an aliphatic dibasic acid unit having a carbon chain length of 6 or less can satisfy the degradation performance and rigidity and improve the tenacity of the material simultaneously.
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