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公开(公告)号:US11530294B2
公开(公告)日:2022-12-20
申请号:US16644509
申请日:2018-06-26
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong , Shihua He
摘要: The present invention discloses a polylactic acid composite and use thereof. The polylactic acid composite includes the following components: (A) 89 to 98 parts by weight of polylactic acid; (B) 1 to 4 parts by weight of talcum powder; and (C) 1 to 7 parts by weight of a plasticizer. In the component (A), the polylactic acid has a polydispersity index P satisfying the following relationship: 1.55≤P≤2.02. In the component (B), the talcum powder has a particle size D(50) satisfying: 1 μm≤D(50)≤2.6 μm. In the component (C), the plasticizer has a relative molecular weight M satisfying: 180≤M≤670. Through research, the present invention has unexpectedly discovered that by using the polylactic acid having the polydispersity index P satisfying the relationship 1.55≤P≤2.02 as a matrix, adding a specific range of content of ultrafine talcum powder as a nucleating agent, and selecting the plasticizer of a specific molecular weight as a crystallization promotion agent, the prepared polylactic acid composite has a light transmittance T≥80%, a haze H≤40%, and a heat deflection temperature HDT≥90° C., having significantly improved heat resistance and transparency.
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公开(公告)号:US20180298188A1
公开(公告)日:2018-10-18
申请号:US15580217
申请日:2017-03-01
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Renxu Yuan , Yuke Zhong , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong
IPC分类号: C08L67/02 , C08G63/183
CPC分类号: C08L67/02 , C08G63/183 , C08G2230/00 , C08K13/02 , C08L2201/06 , C08L2201/08 , C08L2205/025 , C08L2205/03 , C08L67/04 , C08K3/013 , C08K5/1515 , C08L3/02
摘要: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of glycidyl methacrylate is 0.05 ppm-10 ppm. In the present invention, by adding a trace amount of glycidyl methacrylate into a chosen formula of the biodegradable polyester composition and controlling the weight content of glycidyl methacrylate which finally remains in the biodegradable polyester composition as 0.05 ppm-10 ppm, a compatibility between aliphatic-aromatic polyester and polylactic acid in the biodegradable polyester composition can be greatly enhanced, which enables the biodegradable polyester composition to have excellent surface property of film material, and no fisheye occurs on the film material because of a fluctuation of processing technique.
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公开(公告)号:US20180298187A1
公开(公告)日:2018-10-18
申请号:US15580173
申请日:2017-03-01
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Renxu Yuan , Yuke Zhong , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong
IPC分类号: C08L67/02 , C08G63/183
摘要: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of styrene is 0.1 ppm-30 ppm. When the weight content of styrene which is added into a chosen formula of the biodegradable polyester composition based on the total weight of the biodegradable polyester composition is controlled as 0.1 ppm-30 ppm, the present invention may guarantee the biodegradable polyester composition with excellent transmittance and haze effect, and meanwhile may guarantee the biodegradable polyester composition with suitable UV resistance function, without reducing a degradation rate of the biodegradable polyester composition.
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公开(公告)号:US10815332B2
公开(公告)日:2020-10-27
申请号:US16317648
申请日:2017-11-30
发明人: Weiwei Wang , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Renxu Yuan , Zhilong Guo , Meijun Tang
摘要: The present invention discloses a PBS resin composition and a preparation method thereof. The composition comprises: a. PBS resin; b. element titanium; c. element phosphorus, wherein a weight ratio range of titanium to phosphorus is 0.6-10:1, preferably 0.7-4:1, and more preferably 1.25-1.5:1. A weight content of the element titanium is 20-200 ppm, and a weight content of the element phosphorus is 15-70 ppm. By adding a titanium-containing compound and a phosphorus-containing compound and controlling the range of the weight ratio of the element titanium to the element phosphorus in the PBS resin composition to be 0.6-10:1, the present invention obtains a PBS resin composition. After treating in a 95° C.-distilled water bath for 12 hours and drying at 90° C. for 3 hours, a change of the melt flow index of the PBS resin composition is less than 50.0 g/10 min, and the PBS resin composition possesses an obviously improved hydrolysis property.
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公开(公告)号:US10479887B2
公开(公告)日:2019-11-19
申请号:US15580217
申请日:2017-03-01
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Renxu Yuan , Yuke Zhong , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong
IPC分类号: C08L67/02 , C08K13/02 , C08G63/183
摘要: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of glycidyl methacrylate is 0.05 ppm-10 ppm. In the present invention, by adding a trace amount of glycidyl methacrylate into a chosen formula of the biodegradable polyester composition and controlling the weight content of glycidyl methacrylate which finally remains in the biodegradable polyester composition as 0.05 ppm-10 ppm, a compatibility between aliphatic-aromatic polyester and polylactic acid in the biodegradable polyester composition can be greatly enhanced, which enables the biodegradable polyester composition to have excellent surface property of film material, and no fisheye occurs on the film material because of a fluctuation of processing technique.
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公开(公告)号:US11149112B2
公开(公告)日:2021-10-19
申请号:US16644504
申请日:2018-06-26
发明人: Weiwei Wang , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Nanbiao Ye , Zhilong Guo , Changli Lu
IPC分类号: C08G63/183
摘要: The present invention relates to a biodegradable polyester and use thereof, including components: A) acid components containing following repeating units: 50 to 58 mol % of terephthalic acid A1; 30 to 40 mol % of sebacic acid A2; and 2 to 20 mol % of an aliphatic dibasic acid A3 with a carbon chain length of 6 or less; B) butanediol. In the present invention, in the case of a high content of the terephthalic acid, the biodegradable polyester prepared by introducing an aliphatic dibasic acid unit having a carbon chain length of 6 or less can satisfy the degradation performance and rigidity and improve the tenacity of the material simultaneously.
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公开(公告)号:US10472515B2
公开(公告)日:2019-11-12
申请号:US15580173
申请日:2017-03-01
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Renxu Yuan , Yuke Zhong , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong
摘要: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of styrene is 0.1 ppm-30 ppm. When the weight content of styrene which is added into a chosen formula of the biodegradable polyester composition based on the total weight of the biodegradable polyester composition is controlled as 0.1 ppm-30 ppm, the present invention may guarantee the biodegradable polyester composition with excellent transmittance and haze effect, and meanwhile may guarantee the biodegradable polyester composition with suitable UV resistance function, without reducing a degradation rate of the biodegradable polyester composition.
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公开(公告)号:US10400100B2
公开(公告)日:2019-09-03
申请号:US15578697
申请日:2017-02-24
申请人: KINGFA SCI. & TECH. CO., LTD. , ZHUHAI WANGO CHEMICAL CO., LTD. , TIANJIN KINGFA NEW MATERIAL CO., LTD.
发明人: Changli Lu , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Renxu Yuan , Yuke Zhong , Kai Xiong , Hui Yang , Kaijin Mai , Xueteng Dong
IPC分类号: C08J5/18 , C08L67/02 , C08K3/26 , C08K3/34 , C08K5/07 , C08K5/1535 , C08K13/02 , C08L3/02 , C08L25/14 , C08L67/04
摘要: A biodegradable polyester composition based on a total weight of the biodegradable polyester composition, including a weight content of tetrahydrofuran, which is 3 ppm-200 ppm; and based on the total weight of the biodegradable polyester composition, a weight content of cyclopentanone is 0.5 ppm-85 ppm is provided. The tetrahydrofuran and cyclopentanone is added into the composition and controlling the content of tetrahydrofuran and the content of cyclopentanone in a certain range in the composition to realize printing performance. Moreover, when a velocity of film blowing is 176 Kg/h, a range of a film thickness is less than 0.2 μm and a relative deviation of the film thickness is less than 1%.
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公开(公告)号:US20190248981A1
公开(公告)日:2019-08-15
申请号:US16311262
申请日:2017-11-30
发明人: Weiwei Wang , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Renxu Yuan , Zhilong Guo , Meijun Tang
IPC分类号: C08K5/01
CPC分类号: C08K5/01 , C08J5/18 , C08J2367/02
摘要: The present invention discloses a poly(terephthalate-co-sebacate) resin composition, comprising the following components: a. poly(terephthalate-co-sebacate); and b. an alkane, which is at least one selected from the group consisting of hexadecane, heptadecane, octadecane, nonadecane and eicosane; wherein a weight content of the alkane is 5 ppm-1000 ppm based on a total weight of the poly(terephthalate-co-sebacate) resin composition. The present invention controls the content of alkane in the composition within a range of 5 ppm-1000 ppm by adding an alkane, which not only enables the poly(terephthalate-co-sebacate) resin to have obviously improved blow molding properties, a film thickness range of less than 0.3 μm, and a relative deviation of film thickness of less than 2.0%, thereby guaranteeing a bubble stability and a continuity of blow molding, but also enables the film material to prevent the ink from stripping off the film material, and to prevent excessive ink from adhering to the film material in the printing process, so that the film shows excellent printing performance.
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公开(公告)号:US11453776B2
公开(公告)日:2022-09-27
申请号:US16956556
申请日:2019-05-28
发明人: Kai Xiong , Zhimin Yuan , Tongmin Cai , Xianbo Huang , Xiangbin Zeng , Jian Jiao , Changli Lu , Hui Yang , Kaijin Mai , Xueteng Dong , Weida Ou
IPC分类号: C08L67/04 , B33Y70/00 , B29C64/314 , B33Y40/10 , B29K67/00
摘要: The present invention relates to a polylactic acid 3D printing material and a preparation method thereof, which belong to the technical field of polymer materials. The polylactic acid 3D printing material of the present invention comprises the following preparation raw materials in parts by weight: (a) 40-95 parts of crystalline or semi-crystalline polylactic acid, (b) 5-60 parts of noncrystalline polylactic acid, and (c) 0-1.0 parts of a processing aid. In the polylactic acid 3D printing material, a weight of dextral polylactic acid represents 0.5%-8% of a total weight of the polylactic acid. According to the present invention, a polylactic acid 3D printing material with a good aging resistance property can be obtained, by selecting and using two kinds of polylactic acids with different optical purities as raw materials, rationally distributing the proportional relationship between the two, and defining the content of dextral polylactic acid.
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