HIGHLY CONDUCTIVE ANION-EXCHANGE COMPOSITE MEMBRANE WITH CROSSLINKED POLYMER ELECTROLYTE FOR ALKALINE FUEL CELL AND METHOD FOR PREPARING THE SAME
    8.
    发明申请
    HIGHLY CONDUCTIVE ANION-EXCHANGE COMPOSITE MEMBRANE WITH CROSSLINKED POLYMER ELECTROLYTE FOR ALKALINE FUEL CELL AND METHOD FOR PREPARING THE SAME 审中-公开
    用于碱性燃料电池的交联聚合物电解质的高导电性阴离子交换膜复合膜及其制备方法

    公开(公告)号:US20140315119A1

    公开(公告)日:2014-10-23

    申请号:US13925073

    申请日:2013-06-24

    CPC classification number: H01M8/103 H01M8/083 H01M8/1072 H01M8/1086 Y02P70/56

    Abstract: Disclosed are a new method for preparing a highly conductive anion-exchange composite membrane with a crosslinked polymer electrolyte for an alkaline fuel cell and a composite membrane prepared by the same. The method includes (A) mixing (vinylbenzyl)trimethylammonium chloride, 1,3,5-triacryloylhexahydro-1,3,5-triazine, and a mixed solution of deionized water and dimethyl formamide at a weight ratio of 1:1 together by stirring at a weight ratio of 60˜75:5˜16:20˜25; (B) mixing 100 parts by weight of the mixed solution with 0.5 to 2 parts by weight of a photoinitiator; (C) impregnating a porous polymer support with the solution so that a monomer solution soaks into the support; (D) interposing an electrolyte-impregnated membrane between polyethylene terephthalate (PET) films and irradiating the electrolyte-impregnated membrane with ultraviolet (UV) light having an energy of 30 to 150 mJ/cm2 for crosslinking; and (E) after the crosslinking step, removing the PET films, and removing by-products on the membrane surface and washing the membrane.

    Abstract translation: 公开了一种制备具有用于碱性燃料电池的交联聚合物电解质的高导电阴离子交换复合膜和由其制备的复合膜的新方法。 该方法包括(A)通过搅拌将(乙烯基苄基)三甲基氯化铵,1,3,5-三丙烯酰基六氢-1,3,5-三嗪和去离子水与二甲基甲酰胺的混合溶液以1:1的重量比混合在一起 重量比为60〜75:5〜16:20〜25; (B)将100重量份的混合溶液与0.5〜2重量份的光引发剂混合; (C)用溶液浸渍多孔聚合物载体,使得单体溶液浸入载体中; (D)在聚对苯二甲酸乙二醇酯(PET)膜之间插入电解质浸渍的膜,并用能量为30〜150mJ / cm 2的紫外线(UV)光照射电解质浸渍膜进行交联; 和(E),除去PET膜,除去膜表面的副产物并洗涤膜。

Patent Agency Ranking