Preparation of alkyl 2-alkyl-4-fluoromethylthiazolecarboxylates
    1.
    发明授权
    Preparation of alkyl 2-alkyl-4-fluoromethylthiazolecarboxylates 失效
    2-烷基-4-氟甲基噻唑羧酸烷基酯的制备

    公开(公告)号:US5442073A

    公开(公告)日:1995-08-15

    申请号:US182701

    申请日:1994-01-13

    CPC分类号: C07D277/56

    摘要: A process for preparing alkyl 2-alkyl-4-fluoromethylthiazolecarboxylates of the formula I ##STR1## where R.sup.1 is alkyl,R.sup.2 is difluoromethyl or trifluoromethyl andR.sup.3 is alkyl,by reacting thiocarboxamides of the formula II ##STR2## where R.sup.1 has the abovementioned meaning, with alkyl 2-chloro-4-fluoroacetoacetamides of the formula III ##STR3## where R.sup.2 and R.sup.3 have the abovementioned meanings, in an aprotic solvent at below 100.degree. C. and reacting with a dehydrating agent, in the presence of a base, at below 80.degree. C. is described.

    摘要翻译: 通过使式II的硫代甲酰胺反应,其中R 1具有式I的烷基,其中R 1是烷基,R 2是二氟甲基或三氟甲基,R 3是烷基,其中R 1是烷基, 具有式III III的2-氯-4-氟乙酰乙酸烷基酯,其中R 2和R 3具有上述含义,在低于100℃的非质子传递溶剂中,与脱水剂在脱水剂存在下反应, 描述了低于80℃的碱。

    Carbamoylcarboxamides
    4.
    发明授权
    Carbamoylcarboxamides 失效
    氨基甲酰甲酰胺

    公开(公告)号:US5847194A

    公开(公告)日:1998-12-08

    申请号:US793447

    申请日:1997-03-03

    CPC分类号: C07C271/22 F05C2225/08

    摘要: Carbamoylcarboxamides of the general formula I ##STR1## and their salts (R.sup.1 is unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl or an unsubstituted or substituted nonaromatic carbo- or heterocycle; R.sup.2 is H or unhalogenated or halogenated alkyl or cycloalkyl; R.sup.3 is unsubstituted or substituted alkyl, cycloalkyl or phenylalkyl; R.sup.4 is H or one of the radicals R.sup.3 or R.sup.3 and R.sup.4, together with the C atom to which they are bonded, are an unsubstituted or substituted carbo- or heterocycle; R.sup.5 independently of these is one of the radicals R.sup.2 ; X independently of one another is hydrogen, unsubstituted or substituted alkyl and/or alkenyl; Y independently of one another and of these is one of the radicals X; p,q independently of one another are 0, 1 or 2; R.sup.6 is halogen, cyano, nitro or unsubstituted or substituted alkyl, alkoxy, alkylthio or an unsubstituted or substituted phenyl group bonded via oxygen or sulfur; r is 0, 1, 2 or 3), and compositions containing them, processes for preparation, and the use of the compounds I and the compositions are described.

    摘要翻译: PCT No.PCT / EP95 / 03303 Sec。 371日期1997年3月3日 102(e)1997年3月3日PCT PCT 1995年8月19日PCT公布。 公开号WO96 / 07638 日期:1996年3月14日通式I(I)的氨基甲酰甲酰胺及其盐(R1是未取代或取代的烷基,烯基,炔基,环烷基,环烯基或未取代或取代的非芳族碳 - 或杂环; R2是H或 未卤化或卤代烷基或环烷基; R 3为未取代或取代的烷基,环烷基或苯基烷基; R 4为H或R 3或R 3和R 4中的一个与它们所键合的C原子一起为未取代或取代的碳 - 或杂环; R 5独立地为基团R 2; X彼此独立地为氢,未取代或取代的烷基和/或烯基; Y彼此独立地且这些基团为基团X; p,q独立地为 R 1为0,1或2; R 6为卤素,氰基,硝基或未取代或取代的烷基,烷氧基,烷硫基或未经取代或取代的通过氧或硫键合的苯基; r为0,1,2或3) 和组成 包含它们,制备方法以及化合物I和组合物的用途。

    Method of controlling pests
    5.
    发明授权
    Method of controlling pests 失效
    防治害虫的方法

    公开(公告)号:US5453432A

    公开(公告)日:1995-09-26

    申请号:US208816

    申请日:1994-03-11

    摘要: A process for controlling pests in which the pests or the plants threatened by attack with pests are treated with a 2-anilinopyridine of the formula I ##STR1## where the substituents have the following meanings: R.sup.1 is alkyl, alkenyl, alkynyl, haloalkyl, alkoxyalkyl, alkylthioalkyl, cycloalkyl, substituted cycloalkyl, alkoxy, haloalkoxy, substituted alkyl, alkenyloxy, alkynyloxy, halogen, CN, SCN, formyl, CH.dbd.NOR.sub.5, CH.dbd.NR.sub.6, CH.sub.2 NHR.sub.6R.sup.5 is hydrogen, unsubstituted or substituted alkyl, alkenyl, alkynyl, COR.sup.7 or unsubstituted or substituted phenyl,R.sup.6 is hydrogen, alkyl, unsubstituted or substituted cycloalkyl, alkenyl, alkynyl or unsubstituted or substituted phenyl,R.sup.2 is alkyl, alkenyl, alkynyl, haloalkyl or cycloalkylR.sup.3 is hydrogen CN, S(O).sub.n R.sup.8 or COR.sup.9,R.sup.8 is alkyl or substituted phenyl,R.sup.9 is hydrogen, alkyl, haloalkyl, cycloalkyl, phenyl or benzyl,R.sup.4 is hydrogen, halogen, alkyl, haloalkyl, alkoxy or haloalkoxy or cyano, and 2-anilinopyridines and also use of the compounds for the production of pesticides are described.

    摘要翻译: 用于防治害虫或植物受害虫威胁的植物的方法用下式的2-苯胺基吡啶处理如下:R 1是烷基,烯基,炔基,卤代烷基,烷氧基烷基,烷硫基烷基,环烷基,取代的环烷基,烷氧基 ,卤代烷氧基,取代烷基,烯氧基,炔氧基,卤素,CN,SCN,甲酰基,CH = NOR5,CH = NR6,CH2NHR6 R5是氢,未取代或取代的烷基,烯基,炔基,COR7或未取代或取代的苯基,R6是氢 烷基,未取代或取代的环烷基,烯基,炔基或未取代或取代的苯基,R2是烷基,烯基,炔基,卤代烷基或环烷基R3是氢CN,S(O)nR8或COR9,R8是烷基或取代的苯基,R9是 描述了氢,烷基,卤代烷基,环烷基,苯基或苄基,R4是氢,卤素,烷基,卤代烷基,烷氧基或卤代烷氧基或氰基,和2-苯胺基吡啶并且也用于制备农药的化合物。

    Fungicidal mixture
    6.
    发明授权
    Fungicidal mixture 失效
    杀菌剂混合物

    公开(公告)号:US06172083B2

    公开(公告)日:2001-01-09

    申请号:US09484530

    申请日:2000-01-18

    IPC分类号: A01N4336

    摘要: A composition comprising effective amounts of a) a compound of the formula I  or an N-oxide or salt thereof, wherein R1, R2, R3 and R4 are hydrogen, hydroxyl, nitro, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or haloalkylthio; R5, R6 and R7 are hydrogen, hydroxyl, cyano, nitro, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, hydroxyalkyl, acyl, aryl or aryloxy, wherein the aryl groups are optionally substituted, and e) a compound of the formula V  wherein R10 is fluorine or chlorine; R11 is trifluoromethyl or chlorine, or R10 and R11 together are a group —OCF2O—, exhibits a synergisitc fungicidal effect.

    摘要翻译: 包含有效量的a)式I化合物或其N-氧化物或其盐的组合物,其中R 1,R 2,R 3和R 4是氢,羟基,硝基,卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基或卤代烷硫基; R5,R6和R7是氢,羟基,氰基,硝基,卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基,羟基烷基,酰基,芳基或芳氧基,其中芳基任选地被取代,和) 式V其中R 10是氟或氯; R 11是三氟甲基或氯,或R 10和R 11一起是基团-OCF 2 O-,表现出协同作用的杀真菌作用。

    2-anilinopyridine pesticides
    8.
    发明授权
    2-anilinopyridine pesticides 失效
    2-苯胺基吡啶类杀虫剂

    公开(公告)号:US5569765A

    公开(公告)日:1996-10-29

    申请号:US422862

    申请日:1995-04-17

    摘要: A process for controlling pests in which the pests or the plants threatened by attack with pests are treated with a 2-anilinopyridine of the formula I ##STR1## where the substituents have the following meanings: R.sup.1 is alkyl, alkenyl, alkynyl, haloalkyl, alkoxyalkyl, alkylthioalkyl, cycloalkyl, substituted cycloalkyl, alkoxy, haloalkoxy, substituted alkyl, alkenyloxy, alkynyloxy, halogen, CN, SCN, formyl, CH.dbd.NOR.sub.5, CH.dbd.NR.sub.6, CH.sub.2 NHR.sub.6R.sup.5 is hydrogen, unsubstituted or substituted alkyl, alkenyl, alkynyl, COR.sup.7 or unsubstituted or substituted phenyl,R.sup.6 is hydrogen, alkyl, unsubstituted or substituted cycloalkyl, alkenyl, alkynyl or unsubstituted or substituted phenyl,R.sup.2 is alkyl, alkenyl, alkynyl, haloalkyl or cycloalkylR.sup.3 is hydrogen, CN, S(O).sub.n R.sup.8 or COR.sup.9,R.sup.8 is alkyl or substituted phenyl,R.sup.9 is hydrogen, alkyl, haloalkyl, cycloalkyl, phenyl or benzyl,R.sup.4 is hydrogen, halogen, alkyl, haloalkyl, alkoxy or haloalkoxy or cyano, and 2-anilinopyridines and also use of the compounds for the production of pesticides are described.

    摘要翻译: 用于防治害虫或植物受害虫威胁的植物的方法用下式的2-苯胺基吡啶处理如下:R 1是烷基,烯基,炔基,卤代烷基,烷氧基烷基,烷硫基烷基,环烷基,取代的环烷基,烷氧基 ,卤代烷氧基,取代烷基,烯氧基,炔氧基,卤素,CN,SCN,甲酰基,CH = NOR5,CH = NR6,CH2NHR6 R5是氢,未取代或取代的烷基,烯基,炔基,COR7或未取代或取代的苯基,R6是氢 烷基,未取代或取代的环烷基,烯基,炔基或未取代或取代的苯基,R2是烷基,烯基,炔基,卤代烷基或环烷基R3是氢,CN,S(O)nR8或COR9,R8是烷基或取代的苯基,R9 描述了氢,烷基,卤代烷基,环烷基,苯基或苄基,R4是氢,卤素,烷基,卤代烷基,烷氧基或卤代烷氧基或氰基,以及2-苯胺基吡啶并且也用于制备农药的化合物。