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1.发明授权Organic nickel compounds, production and use thereof as catalysts in the polymerization of olefins 失效有机镍化合物，其在烯烃聚合中的生产和用途作为催化剂
公开(公告)号：US4620021A
公开(公告)日：1986-10-28
申请号：US654227
申请日：1984-09-25
Applicant: Karl-Heinz A. O. Starzewski , Josef Witte , Herbert Bartl
Inventor： Karl-Heinz A. O. Starzewski , Josef Witte , Herbert Bartl
Abstract: Olefins such as ethylene can be polymerized with a catalyst which comprises nickel compounds obtained by reacting a nickel-(O) compound or a nickel compound which may be converted in situ into a nickel-(O) compound with an adduct or a mixture of a quinoid compound and a tertiary phosphine and with a compound corresponding to the following general formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 independently represent C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkenyl, C.sub.6 -C.sub.12 aryl or C.sub.3 -C.sub.8 cycloalkyl optionally substituted by halogen, hydroxy, C.sub.1 -C.sub.20 alkoxy, nitro or C.sub.6 -C.sub.12 aryloxy; also C.sub.6 -C.sub.12 aryl-C.sub.1 -C.sub.20 alkyl, C.sub.6 -C.sub.12 aryl-C.sub.2 -C.sub.20 alkenyl, C.sub.1 -C.sub.20 alkyl-C.sub.6 -C.sub.12 aryl, C.sub.1 -C.sub.20 alkyl-C.sub.3 -C.sub.8 cycloalkyl and C.sub.6 -C.sub.12 aryl-C.sub.3 -C.sub.8 cycloalkyl, di-C.sub.1 -C.sub.4 alkylamino, optionally substituted phenoxy or alkoxy; R.sup.4, R.sup.5 and R.sup.6 represent hydrogen, silyl, halogen, cyano or R.sup.1 andX represents O, NR.sub.4 or ##STR2##
Abstract translation: 烯烃如乙烯可以与催化剂聚合，所述催化剂包括通过使镍 - （O）化合物或镍化合物原位转化成镍 - （O）化合物而获得的镍化合物与加合物或其混合物 喹啉化合物和叔膦，并具有对应于下列通式的化合物：其中R 1，R 2和R 3独立地表示C 1 -C 20烷基，C 2 -C 20烯基，C 6 -C 12芳基或C 3 -C 8环烷基 任选被卤素，羟基，C 1 -C 20烷氧基，硝基或C 6 -C 12芳氧基取代; 还有C 6 -C 12芳基-C 1 -C 20烷基，C 6 -C 12芳基-C 2 -C 20烯基，C 1 -C 20烷基-C 6 -C 12芳基，C 1 -C 20烷基-C 3 -C 8环烷基和C 6 -C 12芳基-C 3 -C 8环烷基 ，二-C 1 -C 4烷基氨基，任选取代的苯氧基或烷氧基; R4，R5和R6表示氢，甲硅烷基，卤素，氰基或R1，X表示O，NR4或
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Patent Agency Ranking2.发明授权
公开(公告)号：US5180872A
公开(公告)日：1993-01-19
申请号：US704751
申请日：1991-05-23
Applicant: Karl-Heinz A. O. Starzewski
Inventor： Karl-Heinz A. O. Starzewski
IPC: B01J31/22 , B01J31/18 , B01J31/24 , C07B37/02 , C07B61/00 , C07C2/04 , C07C15/44 , C07C17/26 , C07C17/275 , C07C25/24 , C07C45/69 , C07C49/784 , C07C49/796 , C07C49/813 , C08F4/26 , C08F12/00 , C08F12/08
CPC classification number: C07C49/813 , B01J31/1875 , B01J31/2247 , B01J31/2295 , B01J31/24 , B01J31/2404 , C07B37/02 , C07C15/44 , C07C17/275 , C07C2/04 , C07C25/24 , C07C45/69 , C07C49/784 , C07C49/796 , B01J2531/847 , B01J31/2291 , C07C2531/22
Abstract: The title compounds can be prepared by reaction of a styrene derivative with ethylene in the presence of a nickel catalyst which carries a phosphorus-oxygen chelate ligand, at a temperature of 20.degree.to 160.degree. C. and an ethylene pressure of 1 to 200 bar. Styrene derivatives extended with ethylene, of the formula ##STR1## in which R.sup.19 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, vinyl or chlorine and R.sup.38 denotes C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -alkenyl, C.sub.2 -C.sub.7 -acyl, flourine, chlorine or bromine andm assumes values of 4-104,with the exception of compounds wherein R.sup.19 denotes hydrogen and R.sup.38 denotes i-butyl or benzoyl, and m assumes the value 4, are new.
Abstract translation: 标题化合物可以通过苯乙烯衍生物与乙烯在携带磷 - 氧螯合配体的镍催化剂存在下，在20至160℃的温度和1至200巴的乙烯压力下反应来制备 。 苯乙烯衍生物用乙烯延伸，其结构式为：其中R 19表示氢，C 1 -C 4烷基，乙烯基或氯，R 38表示C 1 -C 4烷基，C 2 -C 4链烯基，C 2 -C 7酰基， 氯或溴，m为4-104的值，除了其中R 19表示氢，R 38表示异丁基或苯甲酰基，m为4的化合物是新的。
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公开(公告)号：US4537982A
公开(公告)日：1985-08-27
申请号：US516104
申请日：1983-07-22
Applicant: Karl-Heinz A. O. Starzewski , Josef Witte
Inventor： Karl-Heinz A. O. Starzewski , Josef Witte
Abstract: Nickel-compounds, producible by reaction of Nickel-(O)-compound or a compound convertible thereto in situ with two different compounds corresponding to the following formulae ##STR1## are useful as catalysts in the polymerization of olefins.
Abstract translation: 可通过镍 - （O） - 化合物或其可转化的化合物原位与两种不同化合物反应生成的镍化合物可用作烯烃聚合中的催化剂。
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4.再颁专利Process for the preparation of styrene derivatives extended at the double bond by ethylene and having a double bond remaining in the extension chain formed and new styrene derivatives extended with ethylene 失效通过乙烯制备在双键延伸的苯乙烯衍生物和形成的延伸链中保留双键并且用乙烯延伸的新的苯乙烯衍生物的方法
公开(公告)号：USRE34706E
公开(公告)日：1994-08-23
申请号：US84379
申请日：1993-06-29
Applicant: Karl-Heinz A. O. Starzewski
Inventor： Karl-Heinz A. O. Starzewski
IPC: B01J31/22 , B01J31/18 , B01J31/24 , C07B37/02 , C07B61/00 , C07C2/04 , C07C15/44 , C07C17/26 , C07C17/275 , C07C25/24 , C07C45/69 , C07C49/784 , C07C49/796 , C07C49/813 , C08F4/26 , C08F12/00 , C08F12/08 , C07C2/02 , C07C2/46 , C07C2/64 , C07C2/66
CPC classification number: C07C49/813 , B01J31/1875 , B01J31/2247 , B01J31/2295 , B01J31/24 , B01J31/2404 , C07B37/02 , C07C15/44 , C07C17/275 , C07C2/04 , C07C25/24 , C07C45/69 , C07C49/784 , C07C49/796 , B01J2531/847 , B01J31/2291 , C07C2531/22
Abstract: The title compounds can be prepared by reaction of a styrene derivative with ethylene in the presence of a nickel catalyst which carries a phosphorus-oxygen chelate ligand, at a temperature of 20.degree. to 160.degree. C. and an ethylene pressure of 1 to 200 bar. Styrene derivatives extended with ethylene, of the formula ##STR1## in which R.sup.19 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, vinyl or chlorine and R.sup.38 denotes C.sub.1 -C.sub.4 -alkenyl, C.sub.2 -C.sub.7 -acyl, flourine, chlorine or bromine andm assumes values of 4-104,with the exception of compounds wherein R.sup.19 denotes hydrogen and R.sup.38 denotes i-butyl or benzoyl, and m assumes the value 4, are new.
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公开(公告)号：US5326507A
公开(公告)日：1994-07-05
申请号：US38015
申请日：1993-03-29
Applicant: Karl-Heinz A. O. Starzewski
Inventor： Karl-Heinz A. O. Starzewski
IPC: B29C55/02 , B29C55/04 , B29D7/01 , B29K29/00 , B29K105/16 , B29L7/00 , C08F2/44 , C08F4/80 , C08J5/18 , G02B1/04 , G02B5/30 , B29C55/06
CPC classification number: C08J5/18 , B29C55/04 , B29D7/01 , G02B1/04 , G02B5/3033 , B29K2029/00 , B29K2995/0034 , C08J2329/04
Abstract: The process for manufacturing a polarizing film based on polyvinyl alcohol and at least one dichroic substance by casting or extrusion of a mixture of polyvinyl alcohol and a solvent, whereby the polyvinyl alcohol contains the dichroic substance, drying and stretching of the film by between 300 and 1200%, whereby, depending on the width of the unstretched film b.sub.o, a stretch gap l.sub.o is provided, satisfying the condition b.sub.o /l.sub.o
Abstract translation: 通过浇铸或挤出聚乙烯醇和溶剂的混合物制造基于聚乙烯醇和至少一种二色性物质的偏振膜的方法，由此聚乙烯醇含有二色性物质，该膜的干燥和拉伸在300和 1200％，由此，根据未拉伸膜bo的宽度，提供满足条件bo / lo <3的拉伸间隙lo，导致较高的二色性消光器。
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6.发明授权Organic nickel compounds, the production thereof and the use thereof as polymerization catalysts 失效有机镍化合物，其生产方法及其作为聚合催化剂的用途
公开(公告)号：US4691036A
公开(公告)日：1987-09-01
申请号：US830330
申请日：1986-02-18
Applicant: Karl-Heinz A. O. Starzewski , Josef Witte , Herbert Bartl
Inventor： Karl-Heinz A. O. Starzewski , Josef Witte , Herbert Bartl
Abstract: Nickel compounds which can be produced by reacting a nickel(O) compound or a nickel compound, which can be converted in situ into a nickel(O) compound, with an adduct or a mixture of maleic acid anhydride and a tertiary phosphine, optionally with a compound of the formula (I) ##STR1## wherein X represents O, NR.sup.4 or ##STR2## and n represents zero or one,and optionally with an organoaluminium compound, are suitable for the homo-and copolymerization of 1-olefins and for the polymerization of acetylene.
Abstract translation: 可以通过使镍（O）化合物或镍化合物原位转化成镍（O）化合物的镍化合物与马来酸酐和叔膦的加合物或混合物任选地与 式（I）的化合物其中X代表O，NR4或者“IMA”，n代表0或1，并且任选地与有机铝化合物一起适用于1-烯烃的均相和共聚 并用于乙炔的聚合。
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