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公开(公告)号：US09561996B2
公开(公告)日：2017-02-07
申请号：US13378959
申请日：2010-06-21
申请人： Karla S. Colle , Jorg F. Weber , Allen D. Godwin
发明人： Karla S. Colle , Jorg F. Weber , Allen D. Godwin
IPC分类号： C07C45/68 , C07C51/235 , C07C67/03 , C07C67/08 , C07C67/313 , C07C67/343 , C08K5/10 , C08K5/101 , C07C45/72 , C07C49/78 , C07C49/86 , C07C65/34 , C07C69/76 , C07C69/738 , C07C69/82 , C08L27/06
CPC分类号： C07C67/03 , C07C45/68 , C07C45/72 , C07C49/78 , C07C49/86 , C07C51/235 , C07C65/34 , C07C67/08 , C07C67/313 , C07C67/343 , C07C69/738 , C07C69/76 , C07C69/82 , C08K5/10 , C08K5/101 , C08L27/06 , Y10T428/1334 , Y10T428/139 , Y10T442/2369
摘要： Resin plasticizers are produced by esterification of keto acids derived from acylation of aromatic compounds with cyclic anhydrides, and are particularly useful in making phthalate-free articles using PVC.
摘要翻译： 树脂增塑剂是通过芳族化合物与环状酸酐的酰化衍生的酮酸的酯化制得的，特别适用于使用PVC制造不含邻苯二甲酸酯的制品。
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公开(公告)号：US20120171397A1
公开(公告)日：2012-07-05
申请号：US13378959
申请日：2010-06-21
申请人： Karla S. Colle , Jorg F. Weber , Allen D. Godwin
发明人： Karla S. Colle , Jorg F. Weber , Allen D. Godwin
IPC分类号： C07C67/08 , C07C69/78 , C08K5/101 , C08L27/06 , B32B27/22 , C08L31/04 , C08L33/00 , B32B1/02 , B32B1/08 , B32B5/02 , C07C69/738 , C08L21/00
CPC分类号： C07C67/03 , C07C45/68 , C07C45/72 , C07C49/78 , C07C49/86 , C07C51/235 , C07C65/34 , C07C67/08 , C07C67/313 , C07C67/343 , C07C69/738 , C07C69/76 , C07C69/82 , C08K5/10 , C08K5/101 , C08L27/06 , Y10T428/1334 , Y10T428/139 , Y10T442/2369
摘要： Resin plasticizers are produced by esterification of keto acids derived from acylation of aromatic compounds with cyclic anhydrides, and are particularly useful in making phthalate-free articles using PVC.
摘要翻译： 树脂增塑剂是通过芳族化合物与环状酸酐的酰化衍生的酮酸的酯化制得的，特别适用于使用PVC制造不含邻苯二甲酸酯的制品。
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公开(公告)号：US20110021680A1
公开(公告)日：2011-01-27
申请号：US12934294
申请日：2009-03-18
申请人： Karla S. Colle , Phillippe Louis Buess , Eddy Theophile Van Driessche , Allen D. Godwin , Ramzi Yanni Saleh , Jon E.R. Stanat , Raphael Frans Caers
发明人： Karla S. Colle , Phillippe Louis Buess , Eddy Theophile Van Driessche , Allen D. Godwin , Ramzi Yanni Saleh , Jon E.R. Stanat , Raphael Frans Caers
CPC分类号： C08K5/11 , C07B41/12 , C07C45/50 , C07C51/235 , C07C67/08 , C07C69/30 , C08K5/0016 , C08K5/103 , C08K5/12 , C07C69/78 , C08L27/06 , C07C47/02
摘要： Triglyceride and other polyol ester PVC plasticizers can be produced by recovery of branched C6 to C9 aldehydes from a hydroformylation product, optional hydrogenation to the alcohol, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, ethylene glycol, propylene glycol or mixtures thereof. The branched alkyl chains comprise at least 10% methyl branching. Special triglycerides are derived from branched aliphatic acids having alkyl chains with average carbon numbers from 6 to 9 and at least 10% methyl branching. These triglycerides are fast fusing plasticisers if before esterification with glycerol, an aryl acid is introduced together with the aliphatic acids.
摘要翻译： 甘油三酯和其它多元醇酯类PVC增塑剂可以通过从加氢甲酰化产物回收支链C6至C9醛，任选的氢化成醇，用氧气和/或空气氧化成酸，回收所得酸，并用甘油酯化 ，乙二醇，丙二醇或其混合物。 支链烷基链包含至少10％的甲基支链。 特别的甘油三酸酯衍生自具有平均碳数为6至9和至少10％甲基支链的烷基链的支链脂族酸。 如果在用甘油酯化之前，这些甘油三酯是快速熔化增塑剂，芳基酸与脂肪酸一起引入。
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公开(公告)号：US20100305250A1
公开(公告)日：2010-12-02
申请号：US12742505
申请日：2008-10-23
IPC分类号： C08K5/1539 , C08K5/12
CPC分类号： C08K5/0016 , C08K5/12 , C08L15/02
摘要： C7-C12 secondary alcohol esters of cyclohexanecarboxylic acids are especially useful as plasticizers for PVC and other plasticizable polymers. In embodiments, these plasticizers are useful in plastisol formulations to help improved processability of flexiblePVC material. In other embodiments these same plasticizers can be used in blends with other plasticizers to improve processability. In preferred embodiments these same plasticizers can be used to prepare flexible PVC compounds with enhanced low temperature flexibility, low toxicity, and improved resistance to outdoor aging.
摘要翻译： 环己烷羧酸的C7-C12仲醇酯特别适用于PVC和其他可塑化聚合物的增塑剂。 在实施方案中，这些增塑剂可用于增塑溶胶配方以有助于改善柔性PVC材料的可加工性。 在其它实施方案中，这些相同的增塑剂可以与其它增塑剂混合使用以改善加工性能。 在优选实施方案中，这些相同的增塑剂可用于制备具有增强的低温柔韧性，低毒性和改善的耐室外老化性能的柔性PVC化合物。
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公开(公告)号：US08669311B2
公开(公告)日：2014-03-11
申请号：US12742505
申请日：2008-10-23
CPC分类号： C08K5/0016 , C08K5/12 , C08L15/02
摘要： C7-C12 secondary alcohol esters of cyclohexanecarboxylic acids are especially useful as plasticizers for PVC and other plasticizable polymers. In embodiments, these plasticizers are useful in plastisol formulations to help improved processability of flexible PVC material. In other embodiments these same plasticizers can be used in blends with other plasticizers to improve processability. In preferred embodiments these same plasticizers can be used to prepare flexible PVC compounds with enhanced low temperature flexibility, low toxicity, and improved resistance to outdoor aging.
摘要翻译： 环己烷羧酸的C7-C12仲醇酯特别适用于PVC和其他可塑化聚合物的增塑剂。 在实施方案中，这些增塑剂可用于增塑溶胶配方以有助于改善柔性PVC材料的可加工性。 在其它实施方案中，这些相同的增塑剂可以与其它增塑剂混合使用以改善加工性能。 在优选实施方案中，这些相同的增塑剂可用于制备具有增强的低温柔韧性，低毒性和改善的耐室外老化性能的柔性PVC化合物。
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公开(公告)号：US20130210984A1
公开(公告)日：2013-08-15
申请号：US13704408
申请日：2011-06-03
申请人： Karla S. Colle , Allen D. Godwin
发明人： Karla S. Colle , Allen D. Godwin
IPC分类号： C07C67/00
CPC分类号： C07C67/00 , C07C29/095 , C07C67/04 , C08K5/11 , C08K5/12 , C07C31/125 , C07C69/003 , C07C69/14 , C07C67/08 , C07C69/82 , C07C69/44 , C07C69/80 , C07C69/76
摘要： The invention relates to secondary alcohols produced by contacting an olefin and a carboxylic acid with a zeolite, esters made therefrom, and to plasticizer compositions comprising the esters.
摘要翻译： 本发明涉及通过使烯烃和羧酸与沸石，由其制得的酯和包含酯的增塑剂组合物接触而制备的仲醇。
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公开(公告)号：US20120108726A1
公开(公告)日：2012-05-03
申请号：US13345014
申请日：2012-01-06
申请人： Allen D Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
发明人： Allen D Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
CPC分类号： C08G67/02 , C08L73/00 , C08L101/00 , C08L2666/14
摘要： The invention relates to polyketone compounds and the at least partially hydrogenated products thereof, the use of said polyketone compounds and/or the at least partially hydrogenated products thereof as plasticizers, processes of making polyketone compounds and the at least partially hydrogenated products thereof, compositions comprising the polyketone compounds and/or the at least partially hydrogenated products thereof, and to articles formed from products of the invention.
摘要翻译： 本发明涉及聚酮化合物及其至少部分氢化的产物，所述聚酮化合物和/或其至少部分氢化产物作为增塑剂的用途，制备聚酮化合物的方法及其至少部分氢化的产物，包含 聚酮化合物和/或其至少部分氢化的产物，以及由本发明的产物形成的制品。
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8.发明申请公开(公告)号：US20120289636A1
公开(公告)日：2012-11-15
申请号：US13513156
申请日：2010-11-16
申请人： Karla S. Colle , Allen D. Godwin
发明人： Karla S. Colle , Allen D. Godwin
CPC分类号： C07C67/04 , A61K8/37 , A61K8/8123 , A61K2800/30 , A61Q19/00 , C07C29/095 , C07C67/08 , C08K5/10 , C08K5/12 , C08K2201/014 , C09K8/58 , C11D3/2017 , C11D3/2048 , C07C31/125 , C07C69/14 , C07C69/003 , C07C69/80 , C08L27/06 , C07C31/02
摘要： A method for preparation of secondary alcohols with a high proportion of hydroxyl group at the C2 position is disclosed. Alkyl carboxylates, high in alpha-methylcarboxylate content, are produced via reaction of an alpha-olefin and a carboxylic acid in the presence of a cerium catalyst. The resultant alkyl carboxylate is hydrolyzed to yield a secondary alcohol with a high 2-hydroxyl content. The secondary alcohol may be used to prepare esters, especially phthalate esters or cyclohexanoate diesters, which are useful as plasticizers. These esters are more effective as plasticizers than esters derived from other secondary alcohols due to their high C2 point of attachment.
摘要翻译： 公开了一种在C2位置制备具有高比例羟基的仲醇的方法。 在铈催化剂存在下，通过α-烯烃和羧酸的反应生产α-甲基羧酸酯含量高的烷基羧酸盐。 将所得的羧酸烷基酯水解，得到具有高2-羟基含量的仲醇。 仲醇可用于制备可用作增塑剂的酯，特别是邻苯二甲酸酯或环己酸二酯。 由于其高C2连接点，这些酯作为增塑剂比来自其它仲醇的酯更有效。
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公开(公告)号：US08115034B2
公开(公告)日：2012-02-14
申请号：US12058397
申请日：2008-03-28
申请人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
发明人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
CPC分类号： C08G67/02 , C08L73/00 , C08L101/00 , C08L2666/14
摘要： The invention relates to polyketone compounds and the at least partially hydrogenated products thereof, the use of said polyketone compounds and/or the at least partially hydrogenated products thereof as plasticizers, processes of making polyketone compounds and the at least partially hydrogenated products thereof, compositions comprising the polyketone compounds and/or the at least partially hydrogenated products thereof, and to articles formed from products of the invention.
摘要翻译： 本发明涉及聚酮化合物及其至少部分氢化的产物，所述聚酮化合物和/或其至少部分氢化产物作为增塑剂的用途，制备聚酮化合物的方法及其至少部分氢化的产物，包含 聚酮化合物和/或其至少部分氢化的产物，以及由本发明的产物形成的制品。
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10.发明授权公开(公告)号：US09371267B2
公开(公告)日：2016-06-21
申请号：US13513156
申请日：2010-11-16
申请人： Karla S. Colle , Allen D. Godwin
发明人： Karla S. Colle , Allen D. Godwin
CPC分类号： C07C67/04 , A61K8/37 , A61K8/8123 , A61K2800/30 , A61Q19/00 , C07C29/095 , C07C67/08 , C08K5/10 , C08K5/12 , C08K2201/014 , C09K8/58 , C11D3/2017 , C11D3/2048 , C07C31/125 , C07C69/14 , C07C69/003 , C07C69/80 , C08L27/06 , C07C31/02
摘要： A method for preparation of secondary alcohols with a high proportion of hydroxyl group at the C2 position is disclosed. Alkyl carboxylates, high in alpha-methylcarboxylate content, are produced via reaction of an alpha-olefin and a carboxylic acid in the presence of a cerium catalyst. The resultant alkyl carboxylate is hydrolyzed to yield a secondary alcohol with a high 2-hydroxyl content. The secondary alcohol may be used to prepare esters, especially phthalate esters or cyclohexanoate diesters, which are useful as plasticizers. These esters are more effective as plasticizers than esters derived from other secondary alcohols due to their high C2 point of attachment.
摘要翻译： 公开了一种在C2位置制备具有高比例羟基的仲醇的方法。 在铈催化剂存在下，通过α-烯烃和羧酸的反应生产α-甲基羧酸酯含量高的烷基羧酸盐。 将所得的羧酸烷基酯水解，得到具有高2-羟基含量的仲醇。 仲醇可用于制备可用作增塑剂的酯，特别是邻苯二甲酸酯或环己酸二酯。 由于其高C2连接点，这些酯作为增塑剂比来自其它仲醇的酯更有效。
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