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公开(公告)号：US20110111219A1
公开(公告)日：2011-05-12
申请号：US12226045
申请日：2007-04-12
申请人： Katsumi Abe , Shinichiro Sano , Kiyofumi Fukasawa
发明人： Katsumi Abe , Shinichiro Sano , Kiyofumi Fukasawa
IPC分类号： C08K3/22 , C09J111/00 , C09J115/02 , C09J147/00 , C09J161/10 , B32B7/12
CPC分类号： C08J5/125 , B32B15/06 , C08J2321/00 , C08J2333/06 , C08K3/22 , C08L15/02 , C08L27/00 , C08L2666/04 , C09J5/02 , C09J161/06 , C09J2205/306 , C09J2461/00 , Y10T428/2804
摘要： A vulcanizable adhesive composition, which comprises 45-75% by weight of phenol resin, preferably a mixture of novolak-type and resol-type phenol resins, 5-25% by weight of halogenated polymer, and 10-30% by weight of a metal oxide, can improve an interlayer adhesiveness between the acrylic rubber and metal without surface treatment of metal, such as a chemical treatment, e.g. zinc phosphate treatment, etc., blast treatment, or primer treatment, and thus can be effectively used in the production of a metal/adhesive layer/acrylic rubber composite.
摘要翻译： 一种可硫化的粘合剂组合物，其包含45-75重量％的酚醛树脂，优选酚醛清漆型和甲阶酚醛型酚醛树脂的混合物，5-25重量％的卤化聚合物和10-30重量％的 金属氧化物，可以改善丙烯酸橡胶和金属之间的层间粘合性而不进行金属的表面处理，例如化学处理，例如， 磷酸锌处理等，喷砂处理或底漆处理，因此可以有效地用于生产金属/粘合剂层/丙烯酸橡胶复合材料。
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公开(公告)号：US20100261019A1
公开(公告)日：2010-10-14
申请号：US12083525
申请日：2006-10-02
申请人： Shinichiro Sano , Katsumi Abe , Kiyofumi Fukasawa
发明人： Shinichiro Sano , Katsumi Abe , Kiyofumi Fukasawa
CPC分类号： F16J15/0818 , B32B15/06 , B32B2255/06 , B32B2255/26 , B32B2255/28 , B32B2581/00 , C08K5/0091 , C08K5/057 , C08K5/098 , C09J125/18 , C09K3/10 , F16J15/0806 , F16J2015/0856 , H01M8/028 , Y02P70/56 , Y10T428/3154 , Y10T428/31692
摘要： A primer composition for use as a primer in the production of metal/primer/adhesive/rubber laminates, which comprises 100 parts by weight of polyparavinylphenol and 50-300 parts by weight of an organometallic compound can give distinguished water resistance and acid resistance, when used for vulcanization bonding of a plated steel sheet and unvulcanized rubber or for simple bonding of a plated steel sheet and vulcanized rubber, and metal-rubber laminates produced by using the primer composition can be effectively used as rubber-metal integrated type gaskets, particularly fuel cell gaskets, HDD cover gaskets (metallic separator-integrated type gaskets), etc.
摘要翻译： 在金属/底漆/粘合剂/橡胶层压材料的制造中用作底漆的底漆组合物，其包含100重量份的聚亚丙酰基苯酚和50-300重量份的有机金属化合物，可以提供显着的耐水性和耐酸性， 用于镀覆钢板和未硫化橡胶的硫化粘合或用于电镀钢板和硫化橡胶的简单粘合，以及通过使用底漆组合物制造的金属 - 橡胶层压材料可以有效地用作橡胶 - 金属一体型垫圈，特别是燃料 电池垫片，HDD盖垫片（金属分离器一体型垫片）等
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公开(公告)号：US08398087B2
公开(公告)日：2013-03-19
申请号：US12310383
申请日：2007-08-08
IPC分类号： F16J9/20
CPC分类号： F16J15/3284 , C08K3/22 , C08L11/00 , C08L15/02 , F16D25/12 , F16D48/02 , F16D2048/0212 , F16J15/3252 , Y10T428/28 , Y10T428/31678
摘要： A bonded piston seal, which comprises a metal ring, and a rubbery elastomer seal as vulcanization-bonded thereto expect the sliding site along which a mating seal member slides, where the rubbery elastomer seal is partially bonded to the metal ring through an adhesive layer, wherein the adhesive layers comprises (a) an underlayer adhesive layer comprising a phenol resin and an epoxy resin, and (b) an overlayer adhesive layer comprising a phenol resin, a halogenated polymer, and a metal oxide. Not only the distinguished initial adhesiveness, but also the distinguished water-resistance can be obtained by providing (a) the underlayer adhesive layer of the afore-mentioned components and (b) the overlayer adhesive layer of the afore-mentioned components.
摘要翻译： 包括金属环的粘合活塞密封件和硫化粘合的橡胶弹性体密封件期望配合密封件滑动的滑动位置，其中橡胶弹性体密封件通过粘合剂层部分地结合到金属环上， 其中所述粘合剂层包括（a）包含酚醛树脂和环氧树脂的底层粘合剂层，和（b）包含酚醛树脂，卤化聚合物和金属氧化物的覆层粘合剂层。 通过提供（a）前述组分的下层粘合剂层和（b）前述组分的覆盖层粘合剂层，不仅可以获得突出的初始粘合性，而且可以获得显着的耐水性。
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公开(公告)号：US20090311543A1
公开(公告)日：2009-12-17
申请号：US12226042
申请日：2007-04-12
申请人： Katsumi Abe , Kiyofumi Fukasawa
发明人： Katsumi Abe , Kiyofumi Fukasawa
IPC分类号： B32B15/08
CPC分类号： B32B15/06 , B32B25/14 , C08F220/00 , C08G59/621 , C08J5/128 , C08J2333/06 , C08J2461/00 , C08J2463/00 , C08L33/00 , C08L61/06 , C08L71/00 , C08L2666/16 , C08L2666/22 , C09J163/00 , Y10T428/28 , Y10T428/2804 , Y10T428/2852 , Y10T428/31678
摘要： An acrylic rubber-metal composite, which comprises a metal, (a) an undercoat adhesive layer comprising phenol resin and epoxy resin, (b) an overcoat adhesive layer comprising phenol resin, halogenated polymer, and a metal oxide, and (c) an acrylic rubber layer, the layers (a), (b) and (c) being successively laid on the surface of the metal, having not only a distinguished initial adhesiveness, but also a good water resistance, where the acrylic rubber is bonded to the metal without surface treatment of the metal such as a chemical treatment, e.g. zinc phosphate treatment, etc., a blast treatment, or a primer treatment.
摘要翻译： 一种丙烯酸橡胶 - 金属复合材料，其包含金属，（a）包含酚醛树脂和环氧树脂的底涂层粘合剂层，（b）包含酚醛树脂，卤化聚合物和金属氧化物的外涂层粘合剂层，和（c） 丙烯酸橡胶层，层（a），（b）和（c）依次铺设在金属表面上，不仅具有突出的初始粘合性，而且具有良好的耐水性，其中丙烯酸橡胶与 没有金属表面处理的金属例如化学处理，例如 磷酸锌处理等，喷丸处理或底漆处理。
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公开(公告)号：US20060041059A1
公开(公告)日：2006-02-23
申请号：US10541339
申请日：2004-01-22
申请人： Kiyofumi Fukasawa , Katsumi Abe
发明人： Kiyofumi Fukasawa , Katsumi Abe
IPC分类号： C08F16/06
CPC分类号： C09J161/04
摘要： An aqueous vulcanizable adhesive composition, which comprises a phenol resin emulsion prepared from a water-insoluble phenol resin solution in methyl ethyl ketone and an aqueous water-soluble polymeric substance solution, and a curing agent for phenol resin, uses a partially water-miscible methyl ethyl ketone in place of a completely water-miscible organic solvent, where an amount of methyl ethyl ketone is considerably reduced. PVA, preferably aceto-acetyl-modified PVA, is used as the water-soluble polymeric substance, and the aqueous vulcanizable adhesive composition is suitably used for vulcanization bonding of a metal to (hydrogenated) NBR or acrylic rubber.
摘要翻译： 一种含水可硫化粘合剂组合物，其包含由甲基乙基酮中的水不溶性酚醛树脂溶液和水溶性聚合物溶液制备的酚醛树脂乳液和酚醛树脂的固化剂，使用部分水混溶性甲基 乙基酮代替完全水混溶的有机溶剂，其中甲基乙基酮的量显着降低。 PVA，优选乙酰 - 乙酰基改性的PVA用作水溶性聚合物，并且该可水性硫化粘合剂组合物适用于金属与（氢化）NBR或丙烯酸橡胶的硫化粘合。
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公开(公告)号：US09925741B2
公开(公告)日：2018-03-27
申请号：US12663310
申请日：2008-05-13
申请人： Katsumi Abe , Kiyofumi Fukasawa
发明人： Katsumi Abe , Kiyofumi Fukasawa
CPC分类号： B32B15/06 , B32B5/147 , B32B7/12 , B32B15/18 , B32B2255/06 , B32B2255/20 , B32B2255/26 , B32B2307/306 , B32B2307/538 , B32B2307/554 , B32B2307/714 , C23C22/08 , Y10T428/24355 , Y10T428/31696
摘要： An acrylic rubber-metal composite, which comprises an iron phosphate treated iron-based metal, and an adhesive layer comprising a phenol resin and a metal oxide, and preferably further a halogenated polymer, and an acrylic rubber layer, successively provided on the iron-based metal surface, has not only distinguished initial adhesiveness and water resistance, when the acrylic rubber is bonded to the metal owing to application of the iron phosphate treatment to the metal surface, but also can reduce the abrasion of the mating materials when brought into contact with rubber-unbaked parts of the sheet, because the surface roughness Ra[according to JIS 0601(1994)] of the surface treated steel sheet is 0.6 or less.
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公开(公告)号：US08455106B2
公开(公告)日：2013-06-04
申请号：US12226042
申请日：2007-04-12
申请人： Katsumi Abe , Kiyofumi Fukasawa
发明人： Katsumi Abe , Kiyofumi Fukasawa
IPC分类号： B32B15/08
CPC分类号： B32B15/06 , B32B25/14 , C08F220/00 , C08G59/621 , C08J5/128 , C08J2333/06 , C08J2461/00 , C08J2463/00 , C08L33/00 , C08L61/06 , C08L71/00 , C08L2666/16 , C08L2666/22 , C09J163/00 , Y10T428/28 , Y10T428/2804 , Y10T428/2852 , Y10T428/31678
摘要： An acrylic rubber-metal composite, which comprises a metal, (a) an undercoat adhesive layer comprising phenol resin and epoxy resin, (b) an overcoat adhesive layer comprising phenol resin, halogenated polymer, and a metal oxide, and (c) an acrylic rubber layer, the layers (a), (b) and (c) being successively laid on the surface of the metal, having not only a distinguished initial adhesiveness, but also a good water resistance, where the acrylic rubber is bonded to the metal without surface treatment of the metal such as a chemical treatment, e.g. zinc phosphate treatment, etc., a blast treatment, or a primer treatment.
摘要翻译： 一种丙烯酸橡胶 - 金属复合材料，其包含金属，（a）包含酚醛树脂和环氧树脂的底涂层粘合剂层，（b）包含酚醛树脂，卤化聚合物和金属氧化物的外涂层粘合剂层，和（c） 丙烯酸橡胶层，层（a），（b）和（c）依次铺设在金属表面上，不仅具有突出的初始粘合性，而且具有良好的耐水性，其中丙烯酸橡胶与 没有金属表面处理的金属例如化学处理，例如 磷酸锌处理等，喷丸处理或底漆处理。
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公开(公告)号：US20090283972A1
公开(公告)日：2009-11-19
申请号：US12310383
申请日：2007-08-08
IPC分类号： F16J9/12
CPC分类号： F16J15/3284 , C08K3/22 , C08L11/00 , C08L15/02 , F16D25/12 , F16D48/02 , F16D2048/0212 , F16J15/3252 , Y10T428/28 , Y10T428/31678
摘要： A bonded piston ring, which comprises a metal ring, and a rubbery elastomer seal as vulcanization-bonded thereto except the sliding site along which a mating seal member slides, where the rubbery elastomer seal in partially bonded to the metal ring through an adhesive layer, wherein the adhesive layers comprise (a) an underlayer adhesive layer comprising a phenol resin and an epoxy resin, and (b) an overlayer adhesive layer comprising a phenol resin, a halogenated polymer, and a metal oxide. Not only the distinguished initial adhesiveness, but also the distinguished water-resistance can be obtained by providing (a) the underlayer adhesive layer of the afore-mentioned components and (b) the overlayer adhesive layer of the afore-mentioned components.
摘要翻译： 包括金属环的粘合活塞环和硫化粘合的橡胶弹性体密封件，除了配合密封件滑动的滑动位置，其中通过粘合剂层部分地粘合到金属环上的橡胶弹性体密封件， 其中所述粘合剂层包含（a）包含酚醛树脂和环氧树脂的底层粘合剂层，和（b）包含酚醛树脂，卤化聚合物和金属氧化物的覆层粘合剂层。 通过提供（a）前述组分的下层粘合剂层和（b）前述组分的覆盖层粘合剂层，不仅可以获得突出的初始粘合性，而且可以获得显着的耐水性。
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公开(公告)号：US07229708B2
公开(公告)日：2007-06-12
申请号：US10538691
申请日：2003-09-12
申请人： Katsumi Abe , Kiyofumi Fukasawa , Hironori Nishina
发明人： Katsumi Abe , Kiyofumi Fukasawa , Hironori Nishina
IPC分类号： B32B15/092
CPC分类号： C09D163/00 , C08L63/00 , C08L2666/14 , C08L2666/22 , C09J161/06 , C09J163/00 , G01D5/14 , G01P3/487 , Y10T428/31515 , Y10T428/31522 , Y10T428/31529 , Y10T428/31663 , C08L83/00 , C08L2666/16
摘要： A magnetic encoder, which comprises a stainless steel sheet; and an under coat adhesive containing epoxy resin and organopolysiloxane, a top coat adhesive containing phenol resin, or phenol resin and epoxy resin, and a rubber magnet, as successively laid one upon another on the stainless steel sheet, has distinguished water resistance and saline water resistance, and thus can be effectively used particularly as a magnetic encoder in wheel speed sensors.
摘要翻译： 磁编码器，包括不锈钢板; 和含有环氧树脂和有机聚硅氧烷的底涂层粘合剂，含有酚醛树脂或酚醛树脂和环氧树脂的面漆粘合剂和橡胶磁体，在不锈钢板上依次铺设，具有显着的耐水性和盐水 电阻，因此可以特别用作轮速传感器中的磁编码器。
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公开(公告)号：US20060275609A1
公开(公告)日：2006-12-07
申请号：US10538691
申请日：2003-09-12
申请人： Katsumi Abe , Kiyofumi Fukasawa , Hironori Nishina
发明人： Katsumi Abe , Kiyofumi Fukasawa , Hironori Nishina
CPC分类号： C09D163/00 , C08L63/00 , C08L2666/14 , C08L2666/22 , C09J161/06 , C09J163/00 , G01D5/14 , G01P3/487 , Y10T428/31515 , Y10T428/31522 , Y10T428/31529 , Y10T428/31663 , C08L83/00 , C08L2666/16
摘要： A magnetic encoder, which comprises a stainless steel sheet; and an under coat adhesive containing epoxy resin and organopolysiloxane, a top coat adhesive containing phenol resin, or phenol resin and epoxy resin, and a rubber magnet, as successively laid one upon another on the stainless steel sheet, has distinguished water resistance and saline water resistance, and thus can be effectively used particularly as a magnetic encoder in wheel speed sensors.
摘要翻译： 磁编码器，包括不锈钢板; 和含有环氧树脂和有机聚硅氧烷的底涂层粘合剂，含有酚醛树脂或酚醛树脂和环氧树脂的面漆粘合剂和橡胶磁体，在不锈钢板上依次铺设，具有显着的耐水性和盐水 电阻，因此可以特别用作轮速传感器中的磁编码器。
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