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公开(公告)号：US5035849A
公开(公告)日：1991-07-30
申请号：US472801
申请日：1990-01-31
IPC分类号： B29C33/64
CPC分类号： B29C33/64
摘要： A process for producing a molded article is provided includinga) The surface of a mold is cooled with a releasing agent for powder molding which has, as an essential component, a copolymer AB derived from at least one monomer A represented by the following general formula (I) ##STR1## wherein X is a hydrogen atom or a methyl group, k is an integer of 0-5, l is an integer of 1-3, m is an integer of 1-3, n is an integer of 0-550 and Y is a methyl group or a fluorine atom-containing substituent having 1-20 carbon atoms,and at least one vinyl-polymerizable monomer B containing at least one alkyl acrylate or alkylmethacrylate wherein the alkyl group has 1 to 8 carbon atoms.b) The coated mold is heated.c) A powder of a non-rigid vinyl chloride resin containing a plasticizer is allowed to adhere to the heated mold to melt the powder.d) The mold, releasing agent and powder are cooled to form a molded article.e) The molded article is peeled from the mold. Monomer A and monomer B are combined in proportions within the copolymer AB such that the film of releasing agent has good compatibility with the vinyl chloride resin and sufficient releasability from the mold such that the film migrates to the surface of the molded article at the time of peeling.
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公开(公告)号：US4996280A
公开(公告)日：1991-02-26
申请号：US387768
申请日：1989-08-01
IPC分类号： C07F7/12 , C07F7/08 , C08G77/22 , C08G77/24 , C08G77/26 , C08G77/28 , C08G77/382 , C08G77/50
CPC分类号： C08G77/50 , C07F7/0854 , C08G77/24 , C08G77/26 , C08G77/382
摘要： A polyorganosiloxane compound which has a fluorine-containing group at its one terminal and an aminopropyl group at its other terminal.The polyorganosiloxane compound can provide various improved properties as well as new properties to synthetic resins by a chemical connection to the synthetic resins with a functional group or groups reactive with the amino group at the other terminal thereof.
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3.发明授权1,2-dichloro-1,2,2-trimethyl-1-phenyldisilane and method for producing the same 失效1,2-二氯-1,2,2-三甲基-1-苯基二硅烷及其制备方法
公开(公告)号：US4716240A
公开(公告)日：1987-12-29
申请号：US11964
申请日：1987-02-06
申请人： Yoichiro Nagai , Hamao Watanabe , Yoshinori Akutsu
发明人： Yoichiro Nagai , Hamao Watanabe , Yoshinori Akutsu
CPC分类号： C07F7/12
摘要： This invention relates to 1,2-dichloro-1,2,2-trimethyl-1-phenyldisilane expressed by the chemical formula (II),Cl(CH.sub.3).sub.2 SiSi(CH.sub.3)(C.sub.6 H.sub.5)Cl.This invention further relates to a method for producing 1,2-dichloro-1,2,2-trimethyl-1-phenyldisilane by reacting phenyl lithium with 1,1,2-trichloro-1,2,2-trimethyldisilane expressed by the chemical formula (III),Cl(CH.sub.3).sub.2 SiSi(CH.sub.3)Cl.sub.2.This invention still further relates to a method for producing 1,2-dichloro-1,2,2-trimethyl-1-phenyldisilane by reacting 1,1,2-trichloro-1,2,2-trimethyldisilane with phenylmagnesium halide expressed by the general formula (IV), C.sub.6 H.sub.5 MgX (X=halogen atom) in the presence of a cobalt catalyst.
摘要翻译： 本发明涉及由化学式（II）表示的1,2-二氯-1,2,2-三甲基-1-苯基二硅烷，Cl（CH 3）2 SiSi（CH 3）（C 6 H 5）Cl。 本发明还涉及通过使苯基锂与由化学物质表示的1,1,2-三氯-1,2,2-三甲基二硅烷反应生产1,2-二氯-1,2,2-三甲基-1-苯基二硅烷的方法 式（III），Cl（CH3）2SiSi（CH3）Cl2。 本发明还涉及通过使1,1,2-三氯-1,2,2-三甲基乙硅烷与苯基卤化镁反应生成1,2-二氯-1,2,2-三甲基-1-苯基二硅烷的方法 通式（IV），C6H5MgX（X =卤素原子）在钴催化剂存在下反应。
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4.发明授权Polysiloxane containing hydroxyl groups and a silicone-modified polyurethane using the same 失效含有羟基的聚硅氧烷和使用其的硅氧烷改性聚氨酯
公开(公告)号：US4839443A
公开(公告)日：1989-06-13
申请号：US143746
申请日：1988-01-14
申请人： Yoshinori Akutsu , Takaharu Nakano , Takahiro Saho , Nobumasa Ohtake , Hirofumi Yasuda , Tamio Kimura
发明人： Yoshinori Akutsu , Takaharu Nakano , Takahiro Saho , Nobumasa Ohtake , Hirofumi Yasuda , Tamio Kimura
CPC分类号： C08G77/16 , C07F7/1852 , C08G18/3893 , C08G18/61 , C08G77/50
摘要： A polysiloxane compound modified with two hydroxyl groups at the one end thereof and particularly suitable for improving the surface characteristics of resins prepared by polycondensation of a polyol with another polyfunctional compound, and a silicone-modified polyurethane having superior characteristics such as low frictional properties, water repellency, oil repellency, thrombosis resistance, etc. and also a process for producing the polyurethane are provided, which polysiloxane compound expressed by the formula ##STR1## wherein R represents H, Me (methyl) or Et (ethyl) and n represents an integer of 0 to 4,000, and which silicone-modified polyurethane is obtained from a compound having at least two isocyanate groups and a compound having at least two hydroxyl groups, and by using as a part of the compound having at least two hydroxyl groups, the polysiloxane compound of the above formula (I) in the urethane bond-forming reaction.
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5.发明授权1,1-dichloro-1,2,2-trimethyl-2-phenyldisilane and method for producing the same 失效1,1-二氯-1,2,2-三甲基-2-苯基二硅烷及其制备方法
公开(公告)号：US4707557A
公开(公告)日：1987-11-17
申请号：US11804
申请日：1987-02-06
申请人： Yoichiro Nagai , Hamao Watanabe , Yoshinori Akutsu
发明人： Yoichiro Nagai , Hamao Watanabe , Yoshinori Akutsu
CPC分类号： C07F7/12
摘要： This invention relates to a novel asymmetric 1,1-dichloro-1,2,2-trimethyl-2-phenyldisilane expressed by the chemical formula (I), (C.sub.6 H.sub.5) (CH.sub.3).sub.2 SiSi(CH.sub.3)Cl.sub.2.This invention further relates to a method for producing 1,1-dichloro-1,2,2-trimethyl-2-phenyl disilane by reacting 1,1,2-trichloro-1,2,2-trimethyl disilane expressed by the chemical formula (III), Cl(CH.sub.3).sub.2 SiSi(CH.sub.3)Cl.sub.2 with phenyl magnesium halide expressed by the general formula (IV), C.sub.6 H.sub.5 MgX (X=halogen atom) in the presence of a transition metal (except for cobalt) catalyst.
摘要翻译： 本发明涉及由化学式（I），（C6H5）（CH3）2SiSi（CH3）Cl2表示的新的不对称1,1-二氯-1,2,2-三甲基-2-苯基二硅烷。 本发明还涉及通过化学式表示的1,1,2-三氯-1,2,2-三甲基乙硅烷与1,1-二氯-1,2,2-三甲基-2-苯基二硅烷的制备方法 （III），Cl（CH 3）2 SiSi（CH 3）Cl 2与通式（IV）表示的苯基卤化镁，C6H5MgX（X =卤素原子）在过渡金属（钴除外）催化剂存在下反应。
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公开(公告)号：US4992521A
公开(公告)日：1991-02-12
申请号：US341225
申请日：1989-04-21
摘要： The present invention relates to an organosiloxane compound suitable for the modification of silicone rubbers and synthetic resins, an organosiloxane compound useful as its intermediate, and a process for preparing them. The organosiloxane compound of the present invention can be represented by the general formula (IV) ##STR1## wherein j is an integer of 1 to 2000, R is an alkyl group having 1 to 4 carbon atoms, and R.sup.1 is a pentafluorophenyl group or a straight-chain or a branched fluoroalkyl group represented by the formula (III)C.sub.1 H.sub.b F.sub.2a-b+1 (II)wherein a is an integer of 3 to 18, and b is an integer of 0 to 2a.The siloxane compound of the present invention has a siloxane chain each having a substituent with a fluorine atom containing group at the terminal thereof. Each of molecules constituting the polysiloxane compound of the present invention has a terminal hydrosilyl group portion and a fluorine atom-containing terminal substituent portion therein. Since the reactive group of the hydrosilyl group is chemically bonded to the synthetic resins, the deterioration in characteristics with time can be hindered. The synthetic resins can be provided with the specific function of the fluoroalkyl group without impairing characteristics which the polysiloxane has.
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公开(公告)号：US4987203A
公开(公告)日：1991-01-22
申请号：US426030
申请日：1989-10-24
IPC分类号： C07F7/12 , C08G77/14 , C08G77/22 , C08G77/24 , C08G77/385
CPC分类号： C08G77/385
摘要： A polyorganosiloxane compound contains a fluorine-containing substituent at least at its .alpha.-, .alpha.'- or .alpha."-position and a substituent having an epoxy linkage at its .omega.-position. The polyorganosiloxane compound can provide a synthetic resin with properties which cannot be provided by conventional polysiloxane compound by incorporating the polyorganosiloxane compound into the synthetic resin through a chemical linkage via the epoxy linkage thereof and a group reactive with the epoxy linkage thereof.
摘要翻译： 聚有机硅氧烷化合物至少在其α - ，α'或α'-位上含有含氟取代基和在其ω-位上具有环氧键的取代基。 聚有机硅氧烷化合物可以提供一种合成树脂，其具有通过将聚有机硅氧烷化合物通过化学键经由其环氧键和与其环氧键反应的基团引入合成树脂而不能由常规聚硅氧烷化合物提供的性质。
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公开(公告)号：US5140087A
公开(公告)日：1992-08-18
申请号：US605381
申请日：1990-10-30
摘要： The present invention relates to an organosiloxane compound suitable for the modification of silicone rubbers and synthetic resins, an organosiloxane compound useful as its intermediate, and a process for preparing them. The organosiloxane compound of the present invention can be represented by the general formula (IV) ##STR1## wherein j is an integer of 1 to 2000, R is an alkyl group having 1 to 4 carbon atoms, and R.sup.1 is a pentafluorophenyl group or a straight-chain or a branched fluoroalkyl group represented by the formula (II)C.sub.a H.sub.b F.sub.2a-b+1 (II)wherein a is an integer of 3 to 18, and b is an integer of 0 to 2a.The siloxane compounds of the present invention also include compounds having siloxane chains, at least one of the chains having a substituent with a fluorine atom containing group at the terminal thereof. Each of the molecules constituting the polysiloxane compound of the present invention has a terminal hydrosilyl group portion and a fluorine atom-containing terminal substituent portion therein. Since the reactive group of the hydrosilyl group is chemically bonded to the synthetic resins, the deterioration in characteristics with time can be hindered. The synthetic resins can be provided with the specific function of the fluoroalkyl group without impairing characteristics which the polysiloxane has.
摘要翻译： 本发明涉及适用于硅橡胶和合成树脂的有机硅氧烷化合物，可用作其中间体的有机硅氧烷化合物及其制备方法。 本发明的有机硅氧烷化合物可以由通式（IV）表示，其中j为1〜2000的整数，R为碳原子数为1〜4的烷基，R 1为五氟苯基 基团或由式（II）表示的直链或支链氟烷基，CaHbF2a-b + 1（Ⅱ）其中a为3〜18的整数，b为0〜2a的整数。 本发明的硅氧烷化合物还包括具有硅氧烷链的化合物，至少一个具有在其末端具有含氟原子的基团的取代基的链。 构成本发明的聚硅氧烷化合物的各分子在其中具有末端氢化甲硅烷基部分和含氟原子的末端取代基部分。 由于氢化硅烷基的反应性基团与合成树脂化学键合，所以可能会妨碍特性随时间的劣化。 可以提供合成树脂具有氟烷基的特定功能，而不损害聚硅氧烷具有的特性。
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公开(公告)号：US5098981A
公开(公告)日：1992-03-24
申请号：US652376
申请日：1991-02-07
摘要： A novel polyorganosiloxane is provided which has a fluorine atom-containing substituent at one terminal of its molecular chain and an unsaturated double bond-containing substituent at the other terminal thereof. The polyorgansiloxane of the present invention is represented by the general formula (I) ##STR1## wherein j is an integer of 1 to 2000, and R.sup.1 is an unsaturated double bond-containing group, each of R.sup.2 and R.sup.3 is an alkyl group having 1 to 4 carbon atoms, phenyl group, vinyl group, straight-chain or branched alkenyl group having 3 to 20 carbon atoms, or a siloxane chain which is similar to ##STR2## and R.sup.4 is a fluorine atom-containing substituent, ##STR3## wherein R.sup.10 is similar to R.sup.4 and is the fruorine atom-containing substituent, R.sup.11 is an alkyl group having 1 to 4 carbon atoms or phenyl group, and the oxygen atoms sited on the right side of the above formulae are combined with a siloxane chain having the unsaturated double bond-containing substituent at the terminal thereof which is similar to ##STR4##
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公开(公告)号：US5047491A
公开(公告)日：1991-09-10
申请号：US388076
申请日：1989-08-01
IPC分类号： C07F7/12 , C07F7/08 , C08G77/22 , C08G77/24 , C08G77/38 , C08G77/385 , C08G77/46 , C08G77/50
CPC分类号： C08G77/38 , C07F7/0852 , C08G77/24 , C08G77/385 , C08G77/50
摘要： A polyorganosiloxane compound is provided which has a fluorine-containing group at its .alpha.-position and one or more than one hydrosilyl group at its .omega.-position, has a fluorine-containing group located at least at its .alpha.- and .alpha.'-position and one or more than one hydrosilyl group at its .omega.-position or has a fluorine-containing group at least at its .alpha.-, .alpha.'- and .alpha."-position and one or more than one hydrosilyl group at its .omega.-position.
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