公开(公告)号：US20110074491A1

公开(公告)日：2011-03-31

申请号：US12891897

申请日：2010-09-28

申请人： Katsuyuki YOFU ,  Kimiatsu NOMURA ,  Mitsumasa HAMANO ,  Tetsuro MITSUI

发明人： Katsuyuki YOFU ,  Kimiatsu NOMURA ,  Mitsumasa HAMANO ,  Tetsuro MITSUI

IPC分类号： H01L51/46 ,  H03K17/78 ,  C07D333/20 ,  C07D409/04 ,  C07D495/02 ,  C07D403/06

CPC分类号： H01L51/42 ,  B82Y10/00 ,  C07D333/36 ,  C07D333/56 ,  C07D333/72 ,  C07D409/04 ,  C07D409/06 ,  C07D409/12 ,  C07D495/04 ,  C07D495/14 ,  C09B3/00 ,  C09B23/105 ,  C09B57/008 ,  H01L27/307 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/4253 ,  Y02E10/549

摘要： A photoelectric conversion device comprising an electrically conductive film, an organic photoelectric conversion film, and a transparent electrically conductive film, wherein the organic photoelectric conversion film contains a compound represented by the following formula (1) and an n-type organic semiconductor: wherein each of R1 and R2 independently represents a substituted aryl group, an unsubstituted aryl group, a substituted heteroaryl group or an unsubstituted heteroaryl group, each of R3 to R11 independently represents a hydrogen atom or a substituent provided that an acidic group is excluded, m represents 0 or 1, n represents an integer of 0 or more, R1 and R2, R3 and R4, R3 and R5, R5 and R6, R6 and R8, R7 and R8, R7 and R9, or R10 and R11 may be combined each other to form a ring, and when n is an integer of 2 or more, out of a plurality of R7's and R8's, a pair of R7's, a pair of R8's, or a pair of R7 and R8 may be combined each other to form a ring.

摘要翻译： 一种光电转换元件，包括导电膜，有机光电转换膜和透明导电膜，其中有机光电转换膜包含由下式（1）表示的化合物和n型有机半导体：其中每个 R 1和R 2独立地表示取代的芳基，未取代的芳基，取代的杂芳基或未取代的杂芳基，只要不排除酸性基团，则R3至R11各自独立地表示氢原子或取代基，m表示0 或1，n表示0或更大的整数，R 1和R 2，R 3和R 4，R 3和R 5，R 5和R 6，R 6和R 8，R 7和R 8，R 7和R 9或R 10和R 11可以相互组合 形成环，当n为2以上的整数时，在多个R 7和R 8中，可以将一对R 7，一对R 8，或一对R 7和R 8相互组合形成环 。

公开(公告)号：US20110056562A1

公开(公告)日：2011-03-10

申请号：US12877264

申请日：2010-09-08

申请人： Mitsumasa HAMANO ,  Katsuyuki YOFU ,  Tetsuro MITSUI ,  Kimiatsu NOMURA

发明人： Mitsumasa HAMANO ,  Katsuyuki YOFU ,  Tetsuro MITSUI ,  Kimiatsu NOMURA

IPC分类号： H01L31/04 ,  C07C211/58 ,  C07C211/61 ,  C07D213/74 ,  C07D221/18 ,  H01L31/18

CPC分类号： C07C223/06 ,  C07C225/22 ,  C07C2102/08 ,  C07C2103/14 ,  C07C2103/18 ,  C07C2103/24 ,  C07C2103/26 ,  C07C2103/50 ,  C07C2602/08 ,  C07C2603/14 ,  C07C2603/18 ,  C07C2603/24 ,  C07C2603/26 ,  C07C2603/50 ,  C07D209/86 ,  C07D213/74 ,  C07D219/02 ,  C07D221/18 ,  C07D223/14 ,  C07D239/62 ,  C07D239/66 ,  C07D307/66 ,  C07D333/36 ,  C07D495/04 ,  C09B23/04 ,  C09B57/008 ,  H01L27/307 ,  H01L51/006 ,  H01L51/4253 ,  Y02E10/549

摘要： A compound represented by the following formula (I), and a photoelectric conversion device containing the compound: wherein Z1 is a ring containing two carbon atoms and represents a 5-membered ring, a 6-membered ring or a condensed ring containing at least either a 5-membered ring or a 6-membered ring, each of L1, L2 and L3 independently represents an unsubstituted methine group or a substituted methine group, n represents an integer of 0 or more, each of R1, R2, R3, R4, R5 and R6 independently represents a hydrogen atom or a substituent, R1 and R2, R2 and R3, R4 and R5, or R5 and R6 may be combined with each other to form a ring, and each of R21 and R22 independently represents a substituted aryl group, an unsubstituted aryl group, a substituted heteroaryl group or an unsubstituted heteroaryl group, provided that the case where both R21 and R22 are an unsubstituted phenyl group is excluded.

摘要翻译： 由下式（I）表示的化合物和含有该化合物的光电转换装置：其中Z1是含有两个碳原子并且表示5元环的环，6元环或稠环，其至少包含 5元环或6元环，L1，L2和L3各自独立地表示未取代的次甲基或取代的次甲基，n表示0以上的整数，R 1，R 2，R 3，R 4， R5和R6独立地表示氢原子或取代基，R1和R2，R2和R3，R4和R5或R5和R6可以相互结合形成环，R 21和R 22各自独立地表示取代的芳基 基团，未取代的芳基，取代的杂芳基或未取代的杂芳基，条件是R 21和R 22均为未取代的苯基的情况除外。

公开(公告)号：US20100308311A1

公开(公告)日：2010-12-09

申请号：US12793195

申请日：2010-06-03

申请人： Tetsuro MITSUI ,  Kimiatsu NOMURA ,  Katsuyuki YOFU

发明人： Tetsuro MITSUI ,  Kimiatsu NOMURA ,  Katsuyuki YOFU

IPC分类号： H01L51/46

CPC分类号： H01L51/0072 ,  B82Y10/00 ,  H01L51/0046 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/4246 ,  H01L51/4253 ,  Y02E10/549

摘要： Provided is a photoelectric conversion device comprising a transparent electrically conductive film, a photoelectric conversion film, and an electrically conductive film, wherein the photoelectric conversion film contains a compound represented by the following formula (i): wherein each of R2 to R9 independently represents a hydrogen atom or a substituent, provided that each of at least two out of R3, R4, R7 and R8 independently represents an aryl group, a heterocyclic group or —N(Ra)(Rb), each of Ra and Rb independently represents a hydrogen atom or a substituent, and at least either Ra or Rb represents an aryl group or a heterocyclic group; and R1 represents an alkyl group, an aryl group or a heterocyclic group.

摘要翻译： 提供一种包含透明导电膜，光电转换膜和导电膜的光电转换装置，其中光电转换膜含有由下式（i）表示的化合物：其中R2至R9各自独立地表示 氢原子或取代基，条件是R3，R4，R7和R8中的至少两个独立地表示芳基，杂环基或-N（Ra）（Rb），Ra和Rb各自独立地表示氢 原子或取代基，并且至少Ra或Rb表示芳基或杂环基; R 1表示烷基，芳基或杂环基。

公开(公告)号：US20100308372A1

公开(公告)日：2010-12-09

申请号：US12794220

申请日：2010-06-04

申请人： Tetsuro MITSUI ,  Kimiatsu NOMURA ,  Mitsumasa HAMANO

发明人： Tetsuro MITSUI ,  Kimiatsu NOMURA ,  Mitsumasa HAMANO

IPC分类号： H01L51/46 ,  H01L51/48

CPC分类号： H01L51/4253 ,  B82Y10/00 ,  H01L51/0012 ,  H01L51/0047 ,  H01L51/0053 ,  H01L51/0058 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/0061 ,  Y02E10/549 ,  Y02P70/521

摘要： Provided is a photoelectric conversion device comprising an electrically conductive film, a photoelectric conversion film, and a transparent electrically conductive film, wherein the photoelectric conversion film contains a fullerene or a fullerene derivative and a photoelectric conversion material having an absorption spectrum satisfying at least either the following condition (A) or (B): (A): λM1 Δ|λM2−λL2| wherein λL1, λL2, λM1 and λM2 are the wavelength at an absorption intensity of ½ of the maximum absorption intensity in the wavelength range of from 400 to 800 nm, each of λL1 and λL2 represents the wavelength in a chloroform solution spectrum when the photoelectric conversion material is dissolved in chloroform, and each of λM1 and λM2 represents the wavelength in a thin-film absorption spectrum of the photoelectric conversion material alone, provided that λL1

摘要翻译： 本发明提供一种光电转换元件，其特征在于，具有导电膜，光电转换膜和透明导电膜，其中，所述光电转换膜含有富勒烯或富勒烯衍生物，以及具有满足以下条件的吸收光谱的光电转换材料： （A）或（B）：（A）：λM1<λL1和λM2<λL2（B）：λM1<λL1和＆Dgr; |λM1-λL1|>＆Dgr | |λM2-λL2| 其中λL1，λL2，λM1和λM2是在400至800nm的波长范围内的最大吸收强度的1/2的吸收强度的波长，λL1和λL2各自表示当光电转换时氯仿溶液光谱中的波长 材料溶解在氯仿中，λL1<λL2和λM1<λM2，λM1和λM2各自表示光电转换材料的薄膜吸收光谱中的波长。

公开(公告)号：US20110063485A1

公开(公告)日：2011-03-17

申请号：US12877252

申请日：2010-09-08

申请人： Kimiatsu NOMURA ,  Eiji FUKUZAKI ,  Tetsuro MITSUI

发明人： Kimiatsu NOMURA ,  Eiji FUKUZAKI ,  Tetsuro MITSUI

IPC分类号： H04N5/335 ,  H01L51/54 ,  H01L51/56 ,  C07D403/10 ,  C07D401/10 ,  C07C211/61

CPC分类号： H01L51/0072 ,  B82Y10/00 ,  C09B23/04 ,  C09B57/008 ,  C09B57/10 ,  H01L51/0046 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/0059 ,  H01L51/0067 ,  H01L51/0069 ,  H01L51/0071 ,  H01L51/0094 ,  H01L51/4253 ,  Y02E10/549

摘要： A photoelectric conversion device comprising a transparent electrically conductive film, a photoelectric conversion film and an electrically conductive film in this order, wherein the photoelectric conversion film comprises a photoelectric conversion layer, and an electron blocking layer, wherein the electron blocking layer contains a compound represented by the specific formula.

摘要翻译： 一种光电转换装置，包括透明导电膜，光电转换膜和导电膜，其中光电转换膜包括光电转换层和电子阻挡层，其中电子阻挡层含有表示的化合物 具体公式。

公开(公告)号：US20120025179A1

公开(公告)日：2012-02-02

申请号：US13223650

申请日：2011-09-01

申请人： Tetsuro MITSUI ,  Kimiatsu NOMURA ,  Tetsu KITAMURA

发明人： Tetsuro MITSUI ,  Kimiatsu NOMURA ,  Tetsu KITAMURA

IPC分类号： H01L51/46

CPC分类号： H01L51/0051 ,  B82Y10/00 ,  H01L27/307 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/0061 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/4246 ,  H01L51/4253 ,  H01L2251/308 ,  Y10S428/917

摘要： A photoelectric conversion element includes: an electrically conductive thin layer; an organic photoelectric conversion layer containing a compound having a partial structure represented by formula (I) and a fullerene or a fullerene derivative; and a transparent electrically conductive thin layer: X represents O, S or N—R10, R10 represents a hydrogen atom or a substituent, Rx and Ry represent a hydrogen atom or a substituent, with at least one representing an electron-withdrawing group, Rx and Ry may combine to form a ring, R represents a bond (—), a hydrogen atom or a substituent, with at least one being the bond, nr represents an integer of 1 to 4, R's may be the same or different when nr is 2 or more, and R's at the 2- and 3-positions or R's at the 5- and 6-positions may combine with each other to form a ring.

摘要翻译： 光电转换元件包括：导电薄层; 含有具有式（I）表示的部分结构的化合物和富勒烯或富勒烯衍生物的有机光电转换层; 和透明导电薄层：X表示O，S或N-R10，R10表示氢原子或取代基，Rx和Ry表示氢原子或取代基，其中至少一个表示吸电子基团，Rx 和R y可以结合形成环，R表示键（ - ），氢原子或取代基，其中至少一个为键，nr表示1至4的整数，R可以相同或不同，当nr 为2以上，R 3为2-和3-位，R 6为5-和6-位可以相互结合形成环。

公开(公告)号：US20080230123A1

公开(公告)日：2008-09-25

申请号：US12046562

申请日：2008-03-12

申请人： Tetsuro MITSUI ,  Tetsu KITAMURA ,  Kimiatsu NOMURA ,  Toru HARADA

发明人： Tetsuro MITSUI ,  Tetsu KITAMURA ,  Kimiatsu NOMURA ,  Toru HARADA

IPC分类号： H01L31/04 ,  C07D207/33 ,  H01L51/42

CPC分类号： H01L51/0072 ,  C09B23/0066 ,  C09B57/007 ,  H01L27/14621 ,  H01L27/14627 ,  H01L27/14632 ,  H01L27/14645 ,  H01L27/14687 ,  H01L27/14689 ,  H01L27/307 ,  H01L51/0062 ,  H01L51/0078 ,  H01L51/4206 ,  H01L51/4213 ,  H01L51/447 ,  H01L2251/308 ,  Y02E10/549

摘要： A photoelectric conversion element comprises a first photoelectric conversion part, the first photoelectric conversion part comprising: a pair of electrodes; and a photoelectric conversion film between the pair of electrodes, wherein the photoelectric conversion film comprises an organic photoelectric conversion material having an absorption peak in an infrared region of an absorption spectrum within a combined range of a visible region and the infrared region and generating an electric charge according to light absorbed, and the first photoelectric conversion part as a whole transmits 50% or more of light in the visible region.

摘要翻译： 光电转换元件包括第一光电转换部，第一光电转换部包括：一对电极; 以及所述一对电极之间的光电转换膜，其中所述光电转换膜包括在可见光区域和所述红外区域的组合范围内的吸收光谱的红外区域中具有吸收峰的有机光电转换材料， 根据光吸收的电荷，第一光电转换部整体在可见光区域透过50％以上的光。

公开(公告)号：US20090283758A1

公开(公告)日：2009-11-19

申请号：US12465727

申请日：2009-05-14

申请人： Kimiatsu NOMURA ,  Tetsuro MITSUI ,  Hideyuki SUZUKI ,  Rui SHEN

发明人： Kimiatsu NOMURA ,  Tetsuro MITSUI ,  Hideyuki SUZUKI ,  Rui SHEN

IPC分类号： H01L51/46 ,  C07D407/06

CPC分类号： C07D407/06 ,  H01L27/307 ,  H01L51/0073 ,  H01L51/0081 ,  H01L51/424 ,  H01L2251/308

摘要： An organic semiconductor includes: a compound represented by formula (I): wherein A1 represents O, S or N—R15; each of R11, R12, R13, R14 and R15 independently represents a hydrogen atom or a substituent W as defined in the specification, R11 and R12 may be linked to form a ring; B1 represents a ring structure containing at least one nitrogen atom; and n1 represents an integer of 0 to 2.

摘要翻译： 有机半导体包括：由式（I）表示的化合物：其中A1表示O，S或N-R15; R 11，R 12，R 13，R 14和R 15各自独立地表示如说明书中定义的氢原子或取代基W，R 11和R 12可以连接形成环; B1表示含有至少一个氮原子的环结构; n1表示0〜2的整数。

公开(公告)号：US20090189058A1

公开(公告)日：2009-07-30

申请号：US12358335

申请日：2009-01-23

申请人： Tetsuro MITSUI ,  Kimiatsu NOMURA ,  Tetsu KITAMURA

发明人： Tetsuro MITSUI ,  Kimiatsu NOMURA ,  Tetsu KITAMURA

IPC分类号： H01L27/00

CPC分类号： H01L51/0051 ,  B82Y10/00 ,  H01L27/307 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/0061 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/4246 ,  H01L51/4253 ,  H01L2251/308 ,  Y10S428/917

摘要： A photoelectric conversion element is provided and includes: an electrically conductive thin layer; an organic photoelectric conversion layer containing a compound having a partial structure represented by the following formula (I) and a fullerene or a fullerene derivative; and a transparent electrically conductive thin layer. X represents O, S or N—R10, R10 represents a hydrogen atom or a substituent, Rx and Ry represent a hydrogen atom or a substituent, with at least one representing an electron-withdrawing group, Rx and Ry may combine to form a ring, R represents a bond (—), a hydrogen atom or a substituent, with at least one being the bond, nr represents an integer of 1 to 4, R's may be the same or different when nr is 2 or more, and R's at the 2- and 3-positions or R's at the 5- and 6-positions may combine with each other to form a ring.

摘要翻译： 提供了一种光电转换元件，包括：导电薄层; 含有具有下述式（I）所示的部分结构的化合物和富勒烯或富勒烯衍生物的有机光电转换层; 和透明导电薄层。 X表示O，S或N-R 10，R 10表示氢原子或取代基，Rx和Ry表示氢原子或取代基，其中至少一个表示吸电子基团，Rx和Ry可以结合形成环 ，R表示键（ - ），氢原子或取代基，至少一个为键，nr表示1〜4的整数，当nr为2以上时，R可以相同或不同，R为 5-和6-位上的2-和3-位或R可以彼此结合形成环。

公开(公告)号：US20080308149A1

公开(公告)日：2008-12-18

申请号：US12131171

申请日：2008-06-02

申请人： Kimiatsu NOMURA ,  Tetsu KITAMURA ,  Tetsuro MITSUI

发明人： Kimiatsu NOMURA ,  Tetsu KITAMURA ,  Tetsuro MITSUI

IPC分类号： H01L31/0216 ,  C07D403/02

CPC分类号： H01L51/0064 ,  C07D209/12 ,  C07D209/60 ,  H01L27/14643

摘要： A squarylium dye represented by formula (1): wherein A1 and B1 each independently represents a ring structure, and R1 and R2 each independently represents a substituent having a carbon number of 1 to 12.

摘要翻译： 由式（1）表示的方酸菁染料：其中A1和B1各自独立地表示环结构，并且R 1和R 2各自独立地表示碳数为1至12的取代基。