摘要:
A proton conductor is provided. The proton conductor includes a zwitterion salt such as MeImPrSO3 and a proton (H+) donor such as HTFSI. An electrochemical device having a stacked layer structure formed of a first electrode, a second electrode and a proton conducting layer held between these electrodes, wherein the proton conducting layer includes a proton conductor according to the present invention. The present invention can, therefore, provide a proton conductor and electrochemical device, which can be suitably used in a dry state or under high-temperature, non-humidified conditions, can obviate a complex accessory such as a humidifier, and can simplify the system.
摘要翻译:提供质子导体。 质子导体包括两性离子盐如MeImPr 3 SO 3和质子(H + +)供体如HTFSI。 一种电化学装置,其具有由第一电极,第二电极和保持在这些电极之间的质子传导层形成的堆叠层结构,其中质子传导层包括根据本发明的质子导体。 因此,本发明可以提供可以在干燥状态或高温非加湿条件下适当使用的质子导体和电化学装置,可以消除诸如加湿器之类的复杂附件,并且可以简化系统 。
摘要:
A mixture, cation conductor and electrochemical device using same are provided. The mixture and a cation conductor, in which cations can be moved without humidification even in a range of temperatures less than or equal to the boiling point of water, or an electrochemical device such as a fuel cell using them. A fuel electrode and an oxygen electrode, which are oppositely arranged with an electrolyte film in between, is provided. The electrolyte film contains a first compound formed of an imidazole derivative containing N having an unshared electron pair and a second compound of at least one selected from the group consisting of compounds having structures shown below.
摘要:
A mixture, cation conductor and electrochemical device using same are provided. The mixture and a cation conductor, in which cations can be moved without humidification even in a range of temperatures less than or equal to the boiling point of water, or an electrochemical device such as a fuel cell using them. A fuel electrode and an oxygen electrode, which are oppositely arranged with an electrolyte film in between, is provided. The electrolyte film contains a first compound formed of an imidazole derivative containing N having an unshared electron pair and a second compound of at least one selected from the group consisting of compounds having structures shown below.
摘要:
An ionic conductor insoluble to water and fuel, and capable of stably allowing ions such as protons to conduct therethrough, a method of manufacturing the same, and an electrochemical device. The ionic conductor having a derivative in which an ion-dissociative group is bound to a carbonaceous substance composed of at least one species selected from the group consisting of fullerene molecule, cluster mainly composed of carbon, and structure of linear or tubular carbon; and a polymer of a substance having a basic group. A method of manufacturing an ionic conductor having a step of dissolving the above-described derivative; and a polymer of the substance having the basic group; into a solvent to thereby prepare a homogeneous solution; and a step of removing the solvent. An electrochemical device having a negative electrode, a positive electrode, and an ionic conductor held therebetween, wherein the ionic conductor is composed of the ionic conductor of the present invention described in the above.
摘要:
Provided are an ion-conductive composite electrolyte that improves ionic conductivity, a membrane-electrode assembly and an electrochemical device using the same, and a method for producing an ion-conductive composite electrolyte membrane.A proton-conductive composite electrolyte contains an electrolyte having a proton-dissociative group (—SO3H) and a compound having a Lewis acid group MXn-1, wherein the Lewis acid group and the proton-dissociative group interact with each other. The compound having the Lewis acid group is a Lewis acid compound MXn or a polymer having a Lewis acid group MXn-1. The electrolyte having a proton-dissociative group is, for example, a fullerene derivative. A proton-conductive composite electrolyte membrane is formed using a solvent having a donor number of 25 or less, and a membrane-electrode assembly using the same is suitable for use in a fuel cell.
摘要:
An ion-conducting composite electrolyte membrane with strength improved without impairing ionic conductivity, and a fuel cell using the same are provided. The proton conductive composite electrolyte membrane includes an electrolyte which includes an ion-dissociating functional group and is made of a fullerene derivative or sulfonated pitch within a range of 5 wt % to 85 wt % both inclusive, and a binder which has a weight-average molecular weight of 550000 or over and a logarithmic viscosity of 2 dL/g or over, and is made of a fluorine-based polymer such as polyvinylidene fluoride and a copolymer of polyvinylidene fluoride and hexafluoropropylene within a range of 15 wt % to 95 wt % both inclusive.
摘要:
An ion-conducting composite electrolyte membrane with strength improved without impairing ionic conductivity, and a fuel cell using the same are provided. The proton conductive composite electrolyte membrane includes an electrolyte which includes an ion-dissociating functional group and is made of a fullerene derivative or sulfonated pitch within a range of 5 wt % to 85 wt % both inclusive, and a binder which has a weight-average molecular weight of 550000 or over and a logarithmic viscosity of 2 dL/g or over, and is made of a fluorine-based polymer such as polyvinylidene fluoride and a copolymer of polyvinylidene fluoride and hexafluoropropylene within a range of 15 wt % to 95 wt % both inclusive.
摘要:
There are provided an ion-conducting microparticle including an ion-dissociative group and exhibiting an affinity for a fluorine-containing resin, and a method of manufacturing the same, an ion-conducting composite including the ion-conducting microparticle, a membrane electrode assembly (MEA) including the ion-conducting composite as an electrolyte, and an electrochemical device such as a fuel cell. A reacting molecule 13, which includes, in only one end, a second reacting group 14 capable of being bonded to a first reacting group 12, and includes, in a main part and/or the other end, an atom group 5 having an affinity for a fluorine-containing resin, acts on a material microparticle 11 including an ion-dissociative group 3 and the first reacting group 12 on a surface of a base-material microparticle 2, and a reformed group 4, which is bonded at only one end to the surface of the base-material microparticle 2, and includes, in a main part and/or the other end, the atom group 5 having an affinity for a fluorine-containing resin, is introduced into the surface of the base-material microparticle 2 by a reaction between the first reacting group 12 and the second reacting group 14 to form an ion-conducting microparticle 1.
摘要:
Provided are an ion-conductive composite containing ion-conductive fine particles and a vinylidene fluoride homopolymer or copolymer and having excellent ion conductivity, a membrane electrode assembly (MEA) including the ion-conductive composite as an electrolyte, and an electrochemical device, such as a fuel cell.An ion-conductive composite is formed of ion-conductive fine particles having an ion-dissociative group and a vinylidene fluoride homopolymer or copolymer. Here, a vinylidene fluoride homopolymer or copolymer having a β-type crystal structure is used. Since polyvinylidene fluoride having the β-type crystal structure has a large dipole moment in a direction that is orthogonal to the direction of the molecular chain, permittivity in the vicinity of ion-conductive fine particles can be kept high, thus facilitating ionic conduction. As a result, the decrease in ion conductivity can be minimized when the composite is formed.
摘要:
Provided are a proton-conductive composite electrolyte, a membrane-electrode assembly, and a fuel cell in which an improvement of the proton conductivity, and suppression of crossover and insolubilization are satisfied at the same time. The proton-conductive composite electrolyte includes an electrolyte having a proton-dissociative group (—SO3H) and a compound having a Lewis acid group MXn−1, wherein the Lewis acid group and the proton-dissociative group are interacted with each other. The compound having the Lewis acid group is a Lewis acid compound MXn or a polymer having a Lewis acid group MXn−1. The electrolyte having a proton-dissociative group is a fluorine-containing electrolyte, an electrolyte composed of a hydrocarbon-based resin, an inorganic resin, a hybrid resin of an organic resin and an inorganic resin, or the like, or a fullerene compound. A membrane-electrode assembly in which catalyst electrodes are closely in contact with both surfaces of the proton-conductive composite electrolyte is preferably used in a fuel cell.