摘要:
A mixture, cation conductor and electrochemical device using same are provided. The mixture and a cation conductor, in which cations can be moved without humidification even in a range of temperatures less than or equal to the boiling point of water, or an electrochemical device such as a fuel cell using them. A fuel electrode and an oxygen electrode, which are oppositely arranged with an electrolyte film in between, is provided. The electrolyte film contains a first compound formed of an imidazole derivative containing N having an unshared electron pair and a second compound of at least one selected from the group consisting of compounds having structures shown below.
摘要:
A mixture, cation conductor and electrochemical device using same are provided. The mixture and a cation conductor, in which cations can be moved without humidification even in a range of temperatures less than or equal to the boiling point of water, or an electrochemical device such as a fuel cell using them. A fuel electrode and an oxygen electrode, which are oppositely arranged with an electrolyte film in between, is provided. The electrolyte film contains a first compound formed of an imidazole derivative containing N having an unshared electron pair and a second compound of at least one selected from the group consisting of compounds having structures shown below.
摘要:
A proton conductor is provided. The proton conductor includes a zwitterion salt such as MeImPrSO3 and a proton (H+) donor such as HTFSI. An electrochemical device having a stacked layer structure formed of a first electrode, a second electrode and a proton conducting layer held between these electrodes, wherein the proton conducting layer includes a proton conductor according to the present invention. The present invention can, therefore, provide a proton conductor and electrochemical device, which can be suitably used in a dry state or under high-temperature, non-humidified conditions, can obviate a complex accessory such as a humidifier, and can simplify the system.
摘要翻译:提供质子导体。 质子导体包括两性离子盐如MeImPr 3 SO 3和质子(H + +)供体如HTFSI。 一种电化学装置,其具有由第一电极,第二电极和保持在这些电极之间的质子传导层形成的堆叠层结构,其中质子传导层包括根据本发明的质子导体。 因此,本发明可以提供可以在干燥状态或高温非加湿条件下适当使用的质子导体和电化学装置,可以消除诸如加湿器之类的复杂附件,并且可以简化系统 。
摘要:
Disclosed herein are an ion-dissociative functional compound, a method for production thereof, an ionic conductor, and an electrochemical device, the ion-dissociative functional compound being thermally and chemically stable under the condition required of fuel cells and being suitable for use as a material such as protonic conductor in fuel cells.The proton-dissociative functional compound shown in FIG. 1A is composed of a fullerene C60 molecule and about 10 sulfonic acid groups —SO3H as proton-dissociative groups each attached to the fullerene through a difluoromethane group —CF2—. The proton-dissociative functional compound shown in FIG. 1B is composed of fullerene molecules three-dimensionally connected to each other through a linking group —CF2SO2NHSO2CF2—. It contains, as the proton-dissociative group, sulfoneimide groups —SO2NHSO2— and sulfoneamide groups —SO2H2 in addition to sulfonic acid groups. These compounds are prepared by introduction of difluoro(fluorosulfonyl)methyl groups into fullerene molecules, and ensuing imidization and hydrolysis.
摘要:
Disclosed herein are an ion-dissociative functional compound, a method for production thereof, an ionic conductor, and an electrochemical device, the ion-dissociative functional compound being thermally and chemically stable under the condition required of fuel cells and being suitable for use as a material such as protonic conductor in fuel cells.The proton-dissociative functional compound shown in FIG. 1A is composed of a fullerene C60 molecule and about 10 sulfonic acid groups —SO3H as proton-dissociative groups each attached to the fullerene through a difluoromethane group —CF2—. The proton-dissociative functional compound shown in FIG. 1B is composed of fullerene molecules three-dimensionally connected to each other through a linking group —CF2SO2NHSO2CF2—. It contains, as the proton-dissociative group, sulfoneimide groups —SO2NHSO2— and sulfoneamide groups —SO2H2 in addition to sulfonic acid groups. These compounds are prepared by introduction of difluoro(fluorosulfonyl)methyl groups into fullerene molecules, and ensuing imidization and hydrolysis.
摘要:
The present invention relates to an ion conductive polymer which is expressed by a below-described chemical formula and has at least one or more kinds of stereospecific structures of a syndiotactic or isotactic structure. (In the above described formula, n designates an integer of 2 or more, R designates an organic residue having 1 to 20 carbon atoms or an organic residue having 1 to 20 carbon atoms and hetero atoms such as N, O, P, S, etc., X designates an anion part, and Y designates an alkali metal, an alkaline earth metal, a transition metal, a rare-earth element, an ammonium or a hydrogen.)
摘要:
A nonaqueous electrolyte battery includes a cathode that is placed opposite an anode via a separator, an open circuit voltage in the full charge state is within a range of 4.25 to 6.00 V per a pair of the cathode and the anode, the separator includes a base material layer which includes a polyolefin resin material and a surface layer which is provided at least on the surface at the side of the cathode of the base material layer and includes at least one selected from the group including polyvinylidene fluoride, polytetrafluoroethylene, and polypropylene, and at least one selected from the group including aramid, polyimide, and ceramics is present on the outermost surface of the surface layer.
摘要:
A secondary battery capable of suppressing resistance rise even after repeated charge and discharge is provided. The secondary battery includes a cathode, an anode, and an electrolytic solution. The anode contains titanium-containing lithium composite as an anode active material, and the electrolytic solution contains cyclic disulfonic acid anhydride.
摘要:
A non-aqueous electrolyte battery has a positive electrode, a negative electrode, an insulating layer present between the positive electrode and the negative electrode, and an electrolytic solution holding layer that composes the insulating layer and includes an electrolytic solution and a porous polymer compound, in which the electrolytic solution is held in the pores in the porous polymer compound and swells the porous polymer compound, the material of the porous polymer compound includes a vinylidene fluoride polymer, the vinylidene fluoride polymer is a vinylidene fluoride homopolymer or a copolymer including a vinylidene fluoride monomer unit and a hexafluoropropylene monomer unit, the mass composition ratio of the monomer units of the vinylidene fluoride polymer, or vinylidene fluoride monomer units:hexafluoropropylene monomer units, is 100:0 to 95:5, and the weight average molecular weight of the vinylidene fluoride polymer is 500,000 or more to less than 1.5 million.
摘要:
A non-aqueous electrolyte battery has a positive electrode, a negative electrode, an insulating layer present between the positive electrode and the negative electrode, and an electrolytic solution holding layer that composes the insulating layer and includes an electrolytic solution and a porous polymer compound, in which the electrolytic solution is held in the pores in the porous polymer compound and swells the porous polymer compound, the material of the porous polymer compound includes a vinylidene fluoride polymer, the vinylidene fluoride polymer is a vinylidene fluoride homopolymer or a copolymer including a vinylidene fluoride monomer unit and a hexafluoropropylene monomer unit, the mass composition ratio of the monomer units of the vinylidene fluoride polymer, or vinylidene fluoride monomer units:hexafluoropropylene monomer units, is 100:0 to 95:5, and the weight average molecular weight of the vinylidene fluoride polymer is 500,000 or more to less than 1.5 million.