公开(公告)号：US20110270010A1

公开(公告)日：2011-11-03

申请号：US13140144

申请日：2009-12-25

申请人： Kazuaki Hayasaka ,  Motoya Okazaki ,  Mayumi Yokoi

发明人： Kazuaki Hayasaka ,  Motoya Okazaki ,  Mayumi Yokoi

IPC分类号： B01J29/072 ,  C07C7/148

CPC分类号： C10M177/00 ,  B01J29/7261 ,  B01J29/7284 ,  B01J29/7292 ,  B01J29/7461 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/7861 ,  B01J29/7884 ,  B01J29/7892 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0201 ,  B01J2229/42 ,  C10G45/64 ,  C10G2300/1022 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2400/10 ,  C10N2270/00

摘要： A first hydroisomerization catalyst contains a support being a extruded product prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more and at least one metal supported on the support and selected from the group consisting of metals belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten, wherein the support contains (a1) a calcined zeolite prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more of an ion-exchanged zeolite obtained by ion exchange of an organic template-containing zeolite containing an organic template and having a 10-membered ring one-dimensional porous structure in a solution containing ammonium ions and/or protons, and (b1) a calcined inorganic oxide prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more of one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of two or more of these oxides, wherein the thermal treatment to which the calcined zeolite has been subjected includes calcination in which the ion-exchanged zeolite that has not been thermally treated at 350° C. or more is heated within the range of 350° C. to 450° C.

摘要翻译： 第一加氢异构化催化剂含有载体，其为通过煅烧制备的挤出产物，该热处理包括在350℃或更高温度下热处理和至少一种负载在载体上的金属，并且选自属于第8族的金属 至（10）的元素周期表中的钼和钨，其中所述载体包含（a1）通过煅烧制备的煅烧沸石，其具有热处理，所述热处理包括在350℃或更高温度下热处理通过离子交换获得的离子交换沸石 含有有机模板的沸石，含有有机模板，并且在含有铵离子和/或质子的溶液中具有10元环一维多孔结构，（b1）通过煅烧制备的煅烧无机氧化物，其具有热处理，所述热处理包括 在350℃以上的一种无机氧化物热处理，其选自氧化铝，二氧化硅，二氧化钛，氧化硼，氧化锆 ，氧化镁，二氧化铈，氧化锌，氧化磷和包含两种或更多种这些氧化物的组合的复合氧化物，其中经受煅烧沸石的热处理包括煅烧，其中没有离子交换的沸石 在350℃下进行热处理或更高温度在350℃至450℃的范围内加热。

公开(公告)号：US08758596B2

公开(公告)日：2014-06-24

申请号：US13140144

申请日：2009-12-25

申请人： Kazuaki Hayasaka ,  Motoya Okazaki ,  Mayumi Yokoi

发明人： Kazuaki Hayasaka ,  Motoya Okazaki ,  Mayumi Yokoi

IPC分类号： C10G73/02

CPC分类号： C10M177/00 ,  B01J29/7261 ,  B01J29/7284 ,  B01J29/7292 ,  B01J29/7461 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/7861 ,  B01J29/7884 ,  B01J29/7892 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0201 ,  B01J2229/42 ,  C10G45/64 ,  C10G2300/1022 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2400/10 ,  C10N2270/00

摘要： A first hydroisomerization catalyst contains a support being a extruded product prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more and at least one metal supported on the support and selected from the group consisting of metals belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten, wherein the support contains (a1) a calcined zeolite prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more of an ion-exchanged zeolite obtained by ion exchange of an organic template-containing zeolite containing an organic template and having a 10-membered ring one-dimensional porous structure in a solution containing ammonium ions and/or protons, and (b1) a calcined inorganic oxide prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more of one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of two or more of these oxides, wherein the thermal treatment to which the calcined zeolite has been subjected includes calcination in which the ion-exchanged zeolite that has not been thermally treated at 350° C. or more is heated within the range of 350° C. to 450° C.

摘要翻译： 第一加氢异构化催化剂含有载体，其为通过煅烧制备的挤出产物，该热处理包括在350℃或更高温度下热处理和至少一种负载在载体上的金属，并且选自属于第8族的金属 至（10）的元素周期表中的钼和钨，其中所述载体包含（a1）通过煅烧制备的煅烧沸石，其具有热处理，所述热处理包括在350℃或更高温度下热处理通过离子交换获得的离子交换沸石 含有有机模板的沸石，含有有机模板，并且在含有铵离子和/或质子的溶液中具有10元环一维多孔结构，（b1）通过煅烧制备的煅烧无机氧化物，其具有热处理，所述热处理包括 在350℃以上的一种无机氧化物热处理，其选自氧化铝，二氧化硅，二氧化钛，氧化硼，氧化锆 ，氧化镁，二氧化铈，氧化锌，氧化磷和包含两种或更多种这些氧化物的组合的复合氧化物，其中经受煅烧沸石的热处理包括煅烧，其中没有离子交换的沸石 在350℃下进行热处理或更高温度在350℃至450℃的范围内加热。

公开(公告)号：US09458387B2

公开(公告)日：2016-10-04

申请号：US14007396

申请日：2012-03-14

申请人： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

发明人： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

IPC分类号： B01J21/00 ,  C07C27/00 ,  C10G2/00 ,  B01J21/06 ,  B01J23/00 ,  B01J23/75 ,  B01J35/00 ,  B01J37/18 ,  B01J21/08

CPC分类号： C10G2/332 ,  B01J21/066 ,  B01J21/08 ,  B01J23/005 ,  B01J23/75 ,  B01J35/002 ,  B01J37/18

摘要： A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100° C. is within a range from 0.40 to 1.0 ml/g.

摘要翻译： 费 - 托合成反应催化剂包括基于催化剂载体的质量含有0.5至14质量％的二氧化硅和氧化锆的催化剂载体，以及负载在催化剂载体上的钴金属和氧化钴 相对于催化剂的质量，相当于四氧化四铁的10〜40质量％，钴原子的还原度为75〜93％，每单位质量的氢气吸附量 在100℃下的催化剂在0.40至1.0ml / g的范围内。

公开(公告)号：US20140018454A1

公开(公告)日：2014-01-16

申请号：US14007396

申请日：2012-03-14

申请人： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

发明人： Yoshiyuki Nagayasu ,  Hideki Ono ,  Kazuaki Hayasaka ,  Mayumi Yokoi

IPC分类号： C10G2/00 ,  B01J23/75

CPC分类号： C10G2/332 ,  B01J21/066 ,  B01J21/08 ,  B01J23/005 ,  B01J23/75 ,  B01J35/002 ,  B01J37/18

摘要： A Fischer-Tropsch synthesis reaction catalyst includes a catalyst support containing a silica and zirconium oxide in an amount of 0.5 to 14% by mass based on the mass of the catalyst support, and cobalt metal and a cobalt oxide supported on the catalyst support in an amount equivalent to 10 to 40% by mass of tricobalt tetroxide based on the mass of the catalyst, wherein the degree of reduction of the cobalt atoms is within a range from 75 to 93%, and the amount of hydrogen gas adsorption per unit mass of the catalyst at 100° C. is within a range from 0.40 to 1.0 ml/g.

摘要翻译： 费 - 托合成反应催化剂包括基于催化剂载体的质量含有0.5至14质量％的二氧化硅和氧化锆的催化剂载体，以及负载在催化剂载体上的钴金属和氧化钴 相对于催化剂的质量，相当于四氧化四铁的10〜40质量％，钴原子的还原度为75〜93％，每单位质量的氢气吸附量 在100℃下的催化剂在0.40至1.0ml / g的范围内。