公开(公告)号：US08758596B2

公开(公告)日：2014-06-24

申请号：US13140144

申请日：2009-12-25

申请人： Kazuaki Hayasaka ,  Motoya Okazaki ,  Mayumi Yokoi

发明人： Kazuaki Hayasaka ,  Motoya Okazaki ,  Mayumi Yokoi

IPC分类号： C10G73/02

CPC分类号： C10M177/00 ,  B01J29/7261 ,  B01J29/7284 ,  B01J29/7292 ,  B01J29/7461 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/7861 ,  B01J29/7884 ,  B01J29/7892 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0201 ,  B01J2229/42 ,  C10G45/64 ,  C10G2300/1022 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2400/10 ,  C10N2270/00

摘要： A first hydroisomerization catalyst contains a support being a extruded product prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more and at least one metal supported on the support and selected from the group consisting of metals belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten, wherein the support contains (a1) a calcined zeolite prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more of an ion-exchanged zeolite obtained by ion exchange of an organic template-containing zeolite containing an organic template and having a 10-membered ring one-dimensional porous structure in a solution containing ammonium ions and/or protons, and (b1) a calcined inorganic oxide prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more of one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of two or more of these oxides, wherein the thermal treatment to which the calcined zeolite has been subjected includes calcination in which the ion-exchanged zeolite that has not been thermally treated at 350° C. or more is heated within the range of 350° C. to 450° C.

摘要翻译： 第一加氢异构化催化剂含有载体，其为通过煅烧制备的挤出产物，该热处理包括在350℃或更高温度下热处理和至少一种负载在载体上的金属，并且选自属于第8族的金属 至（10）的元素周期表中的钼和钨，其中所述载体包含（a1）通过煅烧制备的煅烧沸石，其具有热处理，所述热处理包括在350℃或更高温度下热处理通过离子交换获得的离子交换沸石 含有有机模板的沸石，含有有机模板，并且在含有铵离子和/或质子的溶液中具有10元环一维多孔结构，（b1）通过煅烧制备的煅烧无机氧化物，其具有热处理，所述热处理包括 在350℃以上的一种无机氧化物热处理，其选自氧化铝，二氧化硅，二氧化钛，氧化硼，氧化锆 ，氧化镁，二氧化铈，氧化锌，氧化磷和包含两种或更多种这些氧化物的组合的复合氧化物，其中经受煅烧沸石的热处理包括煅烧，其中没有离子交换的沸石 在350℃下进行热处理或更高温度在350℃至450℃的范围内加热。

公开(公告)号：US20090186754A1

公开(公告)日：2009-07-23

申请号：US12316978

申请日：2008-12-18

申请人： Christine Elia ,  Mohan Kalyanaraman ,  Lei Zhang ,  Madhav Acharya ,  Michael A. Daage ,  Darden Sinclair ,  Jocelyn A. Kowalski ,  Jose G. Santiesteban ,  Ajit B. Dandekar

发明人： Christine Elia ,  Mohan Kalyanaraman ,  Lei Zhang ,  Madhav Acharya ,  Michael A. Daage ,  Darden Sinclair ,  Jocelyn A. Kowalski ,  Jose G. Santiesteban ,  Ajit B. Dandekar

IPC分类号： B01J29/04 ,  B01J29/40

CPC分类号： B01J37/0009 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J29/068 ,  B01J29/7261 ,  B01J29/7292 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/7861 ,  B01J29/7892 ,  B01J35/1014 ,  B01J2229/20 ,  B01J2229/42 ,  C10G45/64 ,  C10G47/20

摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.

摘要翻译： 提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。 脱蜡催化剂包括具有低二氧化硅与氧化铝比率与低表面粘合剂组合的沸石，或者配制的催化剂具有高比例的沸石表面积与外表面积。

公开(公告)号：US20110270010A1

公开(公告)日：2011-11-03

申请号：US13140144

申请日：2009-12-25

申请人： Kazuaki Hayasaka ,  Motoya Okazaki ,  Mayumi Yokoi

发明人： Kazuaki Hayasaka ,  Motoya Okazaki ,  Mayumi Yokoi

IPC分类号： B01J29/072 ,  C07C7/148

CPC分类号： C10M177/00 ,  B01J29/7261 ,  B01J29/7284 ,  B01J29/7292 ,  B01J29/7461 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/7861 ,  B01J29/7884 ,  B01J29/7892 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/0201 ,  B01J2229/42 ,  C10G45/64 ,  C10G2300/1022 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2400/10 ,  C10N2270/00

摘要： A first hydroisomerization catalyst contains a support being a extruded product prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more and at least one metal supported on the support and selected from the group consisting of metals belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten, wherein the support contains (a1) a calcined zeolite prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more of an ion-exchanged zeolite obtained by ion exchange of an organic template-containing zeolite containing an organic template and having a 10-membered ring one-dimensional porous structure in a solution containing ammonium ions and/or protons, and (b1) a calcined inorganic oxide prepared by calcination having a thermal treatment that includes thermally treating at 350° C. or more of one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of two or more of these oxides, wherein the thermal treatment to which the calcined zeolite has been subjected includes calcination in which the ion-exchanged zeolite that has not been thermally treated at 350° C. or more is heated within the range of 350° C. to 450° C.

摘要翻译： 第一加氢异构化催化剂含有载体，其为通过煅烧制备的挤出产物，该热处理包括在350℃或更高温度下热处理和至少一种负载在载体上的金属，并且选自属于第8族的金属 至（10）的元素周期表中的钼和钨，其中所述载体包含（a1）通过煅烧制备的煅烧沸石，其具有热处理，所述热处理包括在350℃或更高温度下热处理通过离子交换获得的离子交换沸石 含有有机模板的沸石，含有有机模板，并且在含有铵离子和/或质子的溶液中具有10元环一维多孔结构，（b1）通过煅烧制备的煅烧无机氧化物，其具有热处理，所述热处理包括 在350℃以上的一种无机氧化物热处理，其选自氧化铝，二氧化硅，二氧化钛，氧化硼，氧化锆 ，氧化镁，二氧化铈，氧化锌，氧化磷和包含两种或更多种这些氧化物的组合的复合氧化物，其中经受煅烧沸石的热处理包括煅烧，其中没有离子交换的沸石 在350℃下进行热处理或更高温度在350℃至450℃的范围内加热。

公开(公告)号：US20180002615A1

公开(公告)日：2018-01-04

申请号：US15608070

申请日：2017-05-30

申请人： ExxonMobil Research and Engineering Company

发明人： Stuart S. SHIH ,  Timothy L. HILBERT ,  Anastasios I. SKOULIDAS ,  Bryan A. PATEL ,  Michael R. CHUBA ,  Sean C. SMYTH ,  Mohan KALYANARAMAN

IPC分类号： C10G65/02 ,  B01J8/18 ,  C10G45/02 ,  B01J8/00 ,  B01J8/24 ,  B01J29/72 ,  B01J23/40

CPC分类号： C10G65/02 ,  B01J8/001 ,  B01J8/008 ,  B01J8/1872 ,  B01J8/24 ,  B01J23/40 ,  B01J29/7261 ,  B01J29/7292 ,  B01J29/7461 ,  B01J29/7492 ,  C10G45/02 ,  C10G45/62 ,  C10G45/64 ,  C10G65/04 ,  C10G2300/10 ,  C10G2300/1048 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/304 ,  C10G2400/00

摘要： Systems and methods are provided for catalytically dewaxing a diesel boiling range feed. In some aspects, catalytic dewaxing can be performed at low hydrogen treat gas rates and/or low hydrogen purity conditions. In other aspects, the systems and methods can allow for distillate dewaxing while reducing or minimizing the amount of equipment required.

公开(公告)号：US08263517B2

公开(公告)日：2012-09-11

申请号：US12316978

申请日：2008-12-18

申请人： Christine N. Elia ,  Mohan Kalyanaraman ,  Lei Zhang ,  Madhav Acharya ,  Michael A. Daage ,  Darden Sinclair ,  Jocelyn A. Kowalski ,  Jose G. Santiesteban ,  Ajit B. Dandekar

发明人： Christine N. Elia ,  Mohan Kalyanaraman ,  Lei Zhang ,  Madhav Acharya ,  Michael A. Daage ,  Darden Sinclair ,  Jocelyn A. Kowalski ,  Jose G. Santiesteban ,  Ajit B. Dandekar

IPC分类号： B01J29/06

CPC分类号： B01J37/0009 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J29/068 ,  B01J29/7261 ,  B01J29/7292 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/7861 ,  B01J29/7892 ,  B01J35/1014 ,  B01J2229/20 ,  B01J2229/42 ,  C10G45/64 ,  C10G47/20

摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.

摘要翻译： 提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。 脱蜡催化剂包括具有低二氧化硅与氧化铝比率与低表面粘合剂组合的沸石，或者配制的催化剂具有高比例的沸石表面积与外表面积。

公开(公告)号：US20110087059A1

公开(公告)日：2011-04-14

申请号：US12903690

申请日：2010-10-13

申请人： Laurent SIMON ,  Antoine DAUDIN

发明人： Laurent SIMON ,  Antoine DAUDIN

IPC分类号： C10G1/00

CPC分类号： B01J29/166 ,  B01J23/883 ,  B01J29/084 ,  B01J29/72 ,  B01J29/7261 ,  B01J29/78 ,  B01J29/7861 ,  B01J37/20 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/42 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G3/54 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2400/06 ,  C10G2400/08 ,  Y02P30/20

摘要： This invention describes a process for treatment of feedstocks obtained from a renewable source implementing a catalyst that comprises at least one hydro-dehydrogenating metal that is selected from the group that is formed by the metals of group VIB and group VIII of the periodic table and a substrate that comprises at least one zeolite that has at least one series of channels whose opening is defined by a ring with 8 oxygen atoms modified by a) at least one stage for introducing at least one alkaline cation that belongs to group IA or IIA of the periodic table, b) a stage for treating said zeolite in the presence of at least one molecular compound that contains at least one silicon atom, c) at least one stage of partial exchange of said alkaline cations by NH4+ cations, and d) at least one heat treatment stage.

摘要翻译： 本发明描述了一种处理从可再生原料获得的原料的方法，该方法包括至少一种选自由元素周期表第ⅥB族和Ⅷ族金属形成的基团的至少一种氢化脱氢金属的催化剂，以及 底物，其包含至少一种沸石，其具有至少一个通道系列，其开口由具有8个氧原子的环限定，所述环具有由a）至少一个阶段修饰，用于引入至少一种碱性阳离子，所述碱性阳离子属于 周期表，b）在至少一种含有至少一个硅原子的分子化合物存在下处理所述沸石的阶段，c）至少一个阶段由NH 4 +阳离子部分交换所述碱性阳离子，和d）至少 一个热处理阶段。

公开(公告)号：US4448675A

公开(公告)日：1984-05-15

申请号：US484748

申请日：1983-04-14

申请人： Pochen Chu

发明人： Pochen Chu

IPC分类号： B01J29/70 ,  C01B37/02 ,  C01B39/48 ,  C10G11/05 ,  C10G45/12 ,  C10G45/54 ,  C10G45/64

CPC分类号： B01J29/703 ,  C01B37/02 ,  C01B39/48 ,  B01J29/7261 ,  B01J29/7861

摘要： A new porous silico-crystal, designated as ZSM-48, a method of making same and the use thereof in catalytic conversion of organic compounds. The new product has a composition, expressed in terms of moles of anhydrous oxides per 100 moles of silica as follows:(0.05 to 5) N.sub.2 O:(0.1 to 10)M.sub.2 /.sub.n O:(0 to 4) Al.sub.2 O.sub.3 :(100) SiO.sub.2wherein M is at least one cation having a valence n, N is a mixture of C.sub.2 -C.sub.12 alkylamine and more preferably of C.sub.3 -C.sub.5 tetramethyl ammonium compound, and wherein the zeolite is characterized by the distinctive x-ray powder diffraction pattern shown in Table I.

摘要翻译： 称为ZSM-48的新的多孔硅晶体，其制备方法及其在有机化合物的催化转化中的用途。 （0.05〜5）N2O：（0.1〜10）M2 / nO：（0〜4）Al2O3：（100）SiO2 其中M是至少一个n价阳离子，N是C 2 -C 12烷基胺和更优选C 3 -C 5四甲基铵化合物的混合物，其中沸石的特征在于表中所示的独特的x射线粉末衍射图 一世。