摘要:
A lactic acid polymer composition comprising formulating 100 parts by weight of a mixture consisting of 80-95% by weight of an L-lactic acid polymer having an L-lactic acid proportion of 75% or more and 5-20% by weight of a plasticizer selected from the group consisting of a polyhydric alcohol ester and a hydroxypolycarboxylic acid ester, 0.1-5 parts by weight of an anti-blocking agent having a SiO.sub.2 content of 90% or more and an average particle size of 7-50 nm, and 0.1-2 parts by weight of a slip agent; a molded product and film obtained from the composition; and a preparation process of the same are disclosed. The molded product and film are excellent in processability, transparency, flexibility, anti-blocking property and slip, and can be degraded into harmless water and carbon dioxide under natural environment, when abandoned.
摘要:
A preparation process of heat-resistant molded articles of a lactic acid-based polymer comprising mixing the lactic acid-based polymer and poly-.epsilon.-caprolactone so as to obtain a L-lactic acid ratio of 75% by weight or more, adding to the polymer mixture a crystalline inorganic powder containing 50% by weight or more of SiO.sub.2, melt-kneading the resultant composition, filling the same into a mold which is set at 85.degree..about.125.degree. C. and forming a shape while promoting crystallization. The molded articles have excellent heat resistance and impact strength, are suitably used for food trays and beverage cups, and can be degraded, in the case of waste, into nontoxic water and carbon dioxide like natural products within a relatively short period in the natural environment.
摘要:
Foams comprising innumerable cells dispersed in thermoplastic polymer compositions substantially consisting of polylactic acid or a copolymer of lactic acid and hydroxycarboxylic acid and having degradable characteristics in the natural environment.The foams can be used for containers such as food trays and throw away cups comprising molded sheet foam of a thermoplastic and degradable polymer or heat insulating materials and cushioning materials comprising bulk foam.
摘要:
A degradable container which is excellent in transparency and impact strength and can be decomposed into nontoxic water and carbon dioxide in the natural environment within a relatively short period can be obtained by using the process for molding a container of an arbitrary shape from a thermoplastic composition having polylactic acid of lactic acids or a copolymer of lactic acids and other hydroxycarboxylic acids as a main component, preforming the composition and thereafter molding the container in a temperature range from Tg to Tg+60.degree. C. on the basis of the glass transition temperature Tg of the thermoplastic polymer composition and under the condition of a draw ratio of 6 times or less.
摘要:
A thermal resistant resin composition comprising 100 parts by weight of polyester (A) having 25-75% by weight of a lactic acid component consisting of 25-75% by weight of a lactic acid-based polymer (a1) and 25-75% by weight of other aliphatic polyester (a2) having a melting point of 100-250.degree. C., and 0.1-70 parts by weight of a crystalline inorganic filler (B) containing 10% by weight or more of SiO.sub.2. The thermal resistant resin composition of the invention performs following function:1) injection molding can be carried out at a mold temperature of Tg or less or around room temperature with a short molding-cycle,2) quick crystallization velocity and satisfactory crystallinity can be attained in the molding step, and3) the molded articles have, as a result, excellent thermal resistance and generate properties of low deterioration of a high polymer component and slow embrittlement in use.
摘要:
An aliphatic polyester formed item having transparency and crystallinity in combination by crystallizing, in the course of or after processing, an aliphatic polyester composition comprising aliphatic polyester and one or more transparent nucleating agent selected from the group consisting of aliphatic carboxylic acid amide, aliphatic carboxylic acid salt, aliphatic alcohol and aliphatic carboxylic acid ester having a melting point of 40-300° C.
摘要:
A formed product which has a thickness of 0.1˜2 mm and a haze of 5%/2 mm or less and is degraded with ease in the natural environment is obtained by holding a transparent L-lactic acid base polymer sheet having an L-lactic acid proportion of 75% or more and a thickness of 0.2˜2 mm under conditions where: (1) a holding temperature is in the range of 55˜90° C., (2) a holding time m1 (min) satisfies the formula: log10m1
摘要:
A polylactic acid-based resin composition composed of a high molecular ingredient (A) comprising polylactic acid (a1) and an aliphatic polyester (B), and a film, particularly an inflation film, prepared from the resin composition. The film comprising the polylactic acid-based resin composition of the invention is biodegradable and excellent in flexibility and resistance to blocking of film and bleeding-out of plasticizer, has no anisotropy in tear strength, and can be suitably used for an agricultural multi-film and garbage bag. When the film of the invention is used for food wrapping, the film prevents fungus growth and contamination of color or odor, and thus can be suitably used.
摘要:
A lactic acid polymer composition comprising formulating 100 parts by weight of a mixture consisting of 80-95% by weight of an L-lactic acid polymer having an L-lactic acid proportion of 75% or more and 5-20% by weight of a plasticizer selected from the group consisting of a polyhydric alcohol ester and a hydroxypolycarboxylic acid ester, 0.1-5 parts by weight of an anti-bloking agent having a SiO.sub.2 content of 90% or more and an average particle size of 7-50 nm, and 0.1-2 parts by weight of a slip agent; a molded product and film obtained from the composition; and a preparation process of the same are disclosed. The molded product and film are excellent in processability, transparency, flexibility, anti-blocking property and slip, and can be degraded into harmless water and carbon dioxide under natural environment, when abandoned.
摘要:
A thermoplastic polymer composition primarily comprising polylactic acid or a copolymer of lactic acids and the other hydroxycarboxylic acids than lactic acids, industrial fabrics which can be degraded into nontoxic water and carbon dioxide within a relatively short period under the natural environment, and flexible containers, water shielding sheets and resin coated-cloth ventilation tubes which are prepared from the industrial fabrics.