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公开(公告)号：US4560737A
公开(公告)日：1985-12-24
申请号：US567177
申请日：1983-12-30
IPC分类号： C08L7/00 , B29C49/00 , B29C55/00 , B29C55/02 , C08J7/00 , C08L1/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L27/14 , C08L27/16 , C08L51/00 , C08L51/02 , C08L51/06 , C08L77/00 , C08L101/00 , H01B3/44 , H01L41/193 , H01L41/45
CPC分类号： H01L41/45 , C08L27/16 , H01L41/193 , H01L41/257
摘要： A piezoelectric polymeric material in the form of sheet or film, which comprises polymers of vinylidene fluoride (VDF) as principle components. The piezoelectric material is essentially a mixture of 100 parts by weight of a VDF base resin, which may be either poly(VDF) or a copolymer, and 1-100 parts by weight of a copolymer of a fluoroelastomer and either VDF monomer or a monomer mixture containing a major amount of VDF monomer. A sheet or film having a high piezoelectric modulus is obtained by stretching a sheet or film of said mixture at an adequately elevated temperature and polarizing the sheet or film after or during the stretching thereby making the stretching sheet or film an electret.
摘要翻译： 以片状或薄膜形式的压电聚合物材料，其包含偏二氟乙烯（VDF）的聚合物作为主要组分。 压电材料基本上是100重量份的可以是聚（VDF）或共聚物的VDF基础树脂和1-100重量份含氟弹性体和VDF单体或单体的共聚物的混合物 含有大量VDF单体的混合物。 通过在适当升高的温度下拉伸所述混合物的片材或薄膜，在拉伸后或拉伸过程中对片材或膜进行偏振，从而使拉伸片材或薄膜成为驻极体，获得具有高压电模量的片材或薄膜。
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公开(公告)号：US4472557A
公开(公告)日：1984-09-18
申请号：US495949
申请日：1983-05-19
IPC分类号： C08F259/08 , C08F293/00 , C08L51/00
CPC分类号： C08F293/00 , C08F259/08
摘要： A fluorohydrocarbon resin that has elasticity and retains favorable properties of known fluorohydrocarbon polymers is obtained by graft copolymerization of a fluorine-containing elastomeric polymer with a fluorine-containing crystalline polymer. One of the elastomeric and crystalline polymers is prepared by copolymerizing at least one fluorine-containing monomer with at least one unsaturated monomer that has peroxy bond. When the elastomeric polymer is employed as the basic polymer and the crystalline polymer is polyvinylidene fluoride, the graft copolymerized fluorohydrocarbon resin is high in mutual solubility with polyvinylidene fluoride, so that the addition of this resin to polyvinylidene fluoride gives a resin composition which has elasticity and good low temperature characteristics.
摘要翻译： 通过含氟弹性体聚合物与含氟结晶聚合物的接枝共聚获得具有弹性并保持已知氟代烃聚合物有利性质的氟代烃树脂。 弹性体和结晶聚合物之一通过使至少一种含氟单体与至少一种具有过氧键的不饱和单体共聚来制备。 当弹性体聚合物用作碱性聚合物并且结晶聚合物是聚偏二氟乙烯时，接枝共聚的氟代烃树脂与聚偏二氟乙烯相互溶解性高，从而将该树脂加入到聚偏二氟乙烯中得到具有弹性的树脂组合物， 良好的低温特性。
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公开(公告)号：US5696215A
公开(公告)日：1997-12-09
申请号：US608354
申请日：1996-02-28
IPC分类号： C08F2/00 , C08F259/08 , C08L51/00 , C08F259/00
CPC分类号： C08L51/00 , C08F259/08
摘要： The invention relates to an elastic fluorohydrocarbon resin. This resin is obtained by graft copolymerization of a first segment which is one of fluorine-containing elastomeric and crystalline polymers with a second segment which is the other of these polymers. The first segment is prepared by copolymerizing at least one first unsaturated monomer that has peroxy bond with at least one second fluorine-containing monomer. When the first monomer is dissolved in a first solvent prior to the copolymerization, the copolymerization can be safely conducted with higher yield. This first solvent is selected from a carboxylic ester of t-butanol, methylene chloride, 1,1,1-trichloroethane, and first, second, third and fourth compounds which are respectively represented by R.sup.1 COOR.sup.2, C.sub.2 H.sub.x Cl.sub.y F.sub.z, C.sub.3 H.sub.x Cl.sub.y F.sub.z, and C.sub.4 H.sub.x Cl.sub.y F.sub.z. When the fluorine-containing elastomeric copolymer as the first segment is purified by contact with a barium salt prior to the graft copolymerization, the elastic fluorohydrocarbon resin becomes improved in thermal stability. When the fluorine-containing elastomeric copolymer having a water content of 0.1-50 wt % as the first segment is dispersed in a liquid medium containing t-butanol and water, it becomes unnecessary to dry this elastomeric copolymer prior to the graft copolymerization. When the fluorine-containing elastomeric copolymer as the first segment is dispersed in another liquid medium containing t-butanol, water, a carboxylic ester and barium hydroxide, the elastic fluorohydrocarbon resin becomes improved in thermal stability with higher graft copolymerization rate.
摘要翻译： 本发明涉及弹性氟代烃树脂。 该树脂通过作为氟弹性体和结晶聚合物之一的第一链段与作为这些聚合物中的另一个的第二链段的接枝共聚获得。 第一段通过使至少一种具有过氧键的第一不饱和单体与至少一种第二含氟单体共聚来制备。 当在共聚之前将第一单体溶解在第一溶剂中时，可以更高的收率安全地进行共聚。 该第一溶剂选自叔丁醇，二氯甲烷，1,1,1-三氯乙烷的羧酸酯，以及分别由R1COOR2，C2HxClyFz，C3HxClyFz和C4HxClyFz表示的第一，第二，第三和第四化合物。 当作为第一段的含氟弹性体共聚物在接枝共聚之前通过与钡盐接触而纯化时，弹性氟代烃树脂的热稳定性提高。 当具有0.1-50重量％水含量的含氟弹性体共聚物作为第一链段分散在含有叔丁醇和水的液体介质中时，在接枝共聚之前不需要干燥该弹性体共聚物。 当作为第一段的含氟弹性体共聚物分散在含有叔丁醇，水，羧酸酯和氢氧化钡的另一种液体介质中时，弹性氟代烃树脂的热稳定性提高，接枝共聚速率更高。
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4.发明授权
公开(公告)号：US06025436A
公开(公告)日：2000-02-15
申请号：US861711
申请日：1997-05-23
CPC分类号： B29C43/24 , C08L27/12 , C08L51/003 , B29K2027/12 , C08L2205/02
摘要： The invention provides a thermoplastic fluorine-containing resin composition intended to be passed between at least two rollers of a calender to be thinned into a sheet or film. This composition includes: 100 parts by weight of a mixture containing 10-90 wt % of a fluorine-containing elastomeric polymer having a glass transition temperature below room temperature and 90-10 wt % of a fluorine-containing crystalline resin having a melting point not higher than 300.degree. C.; and 0.05-2.0 parts by weight of an agent for releasing the composition from the at least two rollers. The composition has a good melt characteristic and a good elasticity for calendering of the composition, and a good releasibility from a calender roller in calendering of the composition.
摘要翻译： 本发明提供一种热塑性含氟树脂组合物，其旨在通过压延机的至少两个辊之间被薄化成片或膜。 该组合物包括：将100重量份的含有10-90重量％的玻璃化转变温度低于室温的含氟弹性体聚合物和90-10重量％的不熔点的含氟结晶树脂的混合物 高于300℃。 和0.05-2.0重量份用于从至少两个辊释放组合物的试剂。 组合物具有良好的熔体特性和用于压延组合物的良好的弹性，以及在压延组合物时来自砑光辊的良好的剥离性。
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5.发明授权
公开(公告)号：US4652592A
公开(公告)日：1987-03-24
申请号：US753983
申请日：1985-07-11
IPC分类号： C08L7/00 , C08F2/46 , C08F2/54 , C08F259/00 , C08F259/08 , C08F285/00 , C08J3/24 , C08K5/34 , C08L23/00 , C08L51/00 , C08L51/02 , C08L51/06 , C08L101/00
CPC分类号： C08F259/08 , C08F285/00
摘要： The disclosure relates to enhancement of mechanical strength and heat resistance of a graft copolymer which is obtained by graft copolymerization of a fluorine-containing monomer that gives a crystalline polymer, such as vinylidene fluoride, with an elastomeric copolymer having peroxy bond, such as a ternary copolymer of vinylidene fluoride, chlorotrifluoroethylene and an unsaturated peroxy compound. A small amount of triallylisocyanurate is mixed with the graft copolymer, and the mixture is formed into a desired shape by a usual method such as calendering or compression moulding. The shaping material is exposed to ionizing radiation such as gamma-ray, which causes cross-linking of the graft copolymer.
摘要翻译： 本公开内容涉及通过使得诸如偏氟乙烯等结晶性聚合物的含氟单体与具有过氧键的弹性体共聚物（例如三元醇）的接枝共聚获得的接枝共聚物的机械强度和耐热性的提高 偏二氟乙烯，氯三氟乙烯和不饱和过氧化合物的共聚物。 将少量的三烯丙基异氰尿酸酯与接枝共聚物混合，并通过常规方法如压延或压缩成型将混合物形成所需的形状。 成型材料暴露于诸如γ射线的电离辐射，这导致接枝共聚物的交联。
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6.发明授权Elastic fluorohydrocarbon resin-based polymer blend with graft copolymers of rubbers 失效弹性氟代烃树脂基聚合物共混物与橡胶的接枝共聚物
公开(公告)号：US5898051A
公开(公告)日：1999-04-27
申请号：US594208
申请日：1996-01-31
摘要： The invention provides a fluorine-containing resin blend. This resin blend includes 100 parts by weight of a first resin and 1-50 parts by weight of a second resin. The first resin is one of an elastic fluorohydrocarbon resin and a vinylidene fluoride based resin. The second resin is a graft copolymer prepared by graft copolymerization of a rubber-like polymer with a first monomer and an optional second monomer. The first monomer is at least one of an acrylic ester and a methacrylic acid ester. The optional second monomer is at least one copolymerizable monomer other than the first monomer. When the elastic fluorohydrocarbon resin is used as the first resin, the resin blend is improved in extensibility upon molding in a melted condition and lowered in modulus of elasticity under a condition that the resin blend is strained by up to 20%, without impairing the elastic fluorohydrocarbon in its heat resistance, low-temperature characteristics and the like. When the vinylidene fluoride based resin is used as the first resin, the resin blend is improved in mechanical strength at low temperature, without impairing superior characteristics of the vinylidene fluoride based resin.
摘要翻译： 本发明提供含氟树脂共混物。 该树脂共混物包括100重量份的第一树脂和1-50重量份的第二树脂。 第一树脂是弹性氟代烃树脂和偏二氟乙烯类树脂之一。 第二树脂是通过橡胶状聚合物与第一单体和任选的第二单体的接枝共聚制备的接枝共聚物。 第一单体是丙烯酸酯和甲基丙烯酸酯中的至少一种。 任选的第二单体是除第一单体之外的至少一种可共聚单体。 当弹性氟代烃树脂用作第一树脂时，树脂共混物在熔融条件下成型时的延展性提高，并且在树脂共混物应变达20％的条件下降低弹性模量，而不损害弹性 氟代烃的耐热性，低温特性等。 当使用偏二氟乙烯基树脂作为第一树脂时，树脂共混物在低温下的机械强度提高，而不损害偏二氟乙烯类树脂的优异特性。
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7.发明授权Plastic laminate having polyamide resin surface layer and fluororesin surface layer 失效具有聚酰胺树脂表面层和氟树脂表面层的塑料层压体
公开(公告)号：US5441782A
公开(公告)日：1995-08-15
申请号：US912197
申请日：1992-07-13
CPC分类号： C08L77/00 , B32B27/08 , C08F259/08 , Y10T428/139 , Y10T428/3154 , Y10T428/31544 , Y10T428/31725 , Y10T428/31728 , Y10T428/31732 , Y10T428/31739 , Y10T428/31743 , Y10T428/31746
摘要： A plastic laminate having an apliphatic polyamide resin surface layer and a fluororesin surface layer is produced by using an intermediate layer formed of a blend of an aliphatic polyamide resin with a fluorine-containing graft copolymer, which is obtained by graft polymerization of a suitable monomer such as vinylidene fluoride, or a mixture of monomers, with an elastomeric copolymer of at least two principal monomers including at least one fluorine-containing monomer, e.g. vinyliden fluoride and chlorotrifluoroethylene, and an unsaturated peroxy compound. The fluorine-containing graft copolymer is a soft, flexible resin and is well compatible with aliphatic polyamide resins and also with various fluororesins. The fluororesin surface layer uses, for example, polyvinylidene fluoride, a vinyliden fluoride based copolymer or the fluorine-containing graft copolymer. The lamination can be accomplished by simply welding the two surface layers to the intermediate layer. The laminate can be produced in tubular form by a coextrusion method and can be used, for example, as an automotive fuel hose.
摘要翻译： 通过使用由脂肪族聚酰胺树脂与含氟接枝共聚物的共混物形成的中间层，制造具有脂肪族聚酰胺树脂表面层和氟树脂表面层的塑料层压体，其通过适当的单体的接枝聚合得到 作为偏二氟乙烯或单体的混合物与至少两种主要单体的弹性共聚物，包括至少一种含氟单体，例如 亚乙烯基氟化物和氯三氟乙烯，以及不饱和过氧化合物。 含氟接枝共聚物是柔软的柔性树脂，并且与脂族聚酰胺树脂以及各种氟树脂完全相容。 氟树脂表面层使用例如聚偏氟乙烯，亚乙烯基氟化物系共聚物或含氟接枝共聚物。 层压可以通过简单地将两个表面层焊接到中间层来实现。 层压体可以通过共挤出方法以管状形式制造，并且可以用作例如汽车燃料软管。
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8.发明授权Urethane elastomer based thermoplastic resin composition suitable for extrusion 失效聚氨酯弹性体热塑性树脂组合物适用于挤出
公开(公告)号：US5294669A
公开(公告)日：1994-03-15
申请号：US901146
申请日：1992-06-19
IPC分类号： C08F259/00 , C08F259/08 , C08L51/00 , C08L75/00 , C08L75/04 , C08L27/16
CPC分类号： C08L51/003 , C08L75/04
摘要： A thermoplastic resin composition, which is flexible and can easily be extruded, is obtained by blending (A) 100 parts by weight of a thermoplastic urethane elastomer with (B) 1-100 parts by weight of a thermoplastic graft copolymer obtained by graft polymerization of vinylidene fluoride with an elastomeric copolymer of at least two principal monomers including at least one fluorine-containing compound, e.g. vinylidene fluoride and chlorotrifluoroethylene, and an unsaturated peroxy compound. Compared with the urethane elastomer (A) itself, this resin composition is better in extrudability, lower in kinetic friction coefficient, weaker in surface tackiness of molded products and higher in resistance to heat aging.
摘要翻译： 通过将（A）100重量份的热塑性聚氨酯弹性体与（B）1-100重量份通过接枝聚合获得的热塑性接枝共聚物共混（A），得到柔软且易于挤出的热塑性树脂组合物 偏二氟乙烯与包含至少一种含氟化合物的至少两种主要单体的弹性共聚物，例如， 偏二氟乙烯和氯三氟乙烯，以及不饱和过氧化合物。 与聚氨酯弹性体（A）本身相比，该树脂组合物的挤出性更好，动摩擦系数更低，成型体的表面粘性较弱，耐热老化性更高。
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公开(公告)号：US5902859A
公开(公告)日：1999-05-11
申请号：US880545
申请日：1997-06-23
IPC分类号： C08F2/00 , C08F259/08 , C08L51/00
CPC分类号： C08L51/00 , C08F259/08
摘要： The invention relates to an elastic fluorohydrocarbon resin. This resin is obtained by graft copolymerization of a first segment which is one of fluorine-containing elastomeric and crystalline polymers with a second segment which is the other of these polymers. The first segment is prepared by copolymerizing at least one first unsaturated monomer that has peroxy bond with at least one second fluorine-containing monomer. When the first monomer is dissolved in a first solvent prior to the copolymerization, the copolymerization can be safely conducted with higher yield. This first solvent is selected from a carboxylic ester of t-butanol, methylene chloride, 1,1,1-trichloroethane, and first, second, third and fourth compounds which are respectively represented by R.sup.1 COOR.sup.2, C.sub.2 H.sub.x Cl.sub.y F.sub.z, C.sub.3 H.sub.x Cl.sub.y F.sub.z, and C.sub.4 H.sub.x Cl.sub.y F.sub.z. When the fluorine-containing elastomeric copolymer as the first segment is purified by contact with a barium salt prior to the graft copolymerization, the elastic fluorohydrocarbon resin becomes improved in thermal stability. When the fluorine-containing elastomeric copolymer having a water content of 0.1-50 wt % as the first segment is dispersed in a liquid medium containing t-butanol and water, it becomes unnecessary to dry this elastomeric copolymer prior to the graft copolymerization. When the fluorine-containing elastomeric copolymer as the first segment is dispersed in another liquid medium containing t-butanol, water, a carboxylic ester and barium hydroxide, the elastic fluorohydrocarbon resin becomes improved in thermal stability with higher graft copolymerization rate.
摘要翻译： 本发明涉及弹性氟代烃树脂。 该树脂通过作为氟弹性体和结晶聚合物之一的第一链段与作为这些聚合物中的另一个的第二链段的接枝共聚获得。 第一段通过使至少一种具有过氧键的第一不饱和单体与至少一种第二含氟单体共聚来制备。 当在共聚之前将第一单体溶解在第一溶剂中时，可以更高的收率安全地进行共聚。 该第一溶剂选自叔丁醇，二氯甲烷，1,1,1-三氯乙烷的羧酸酯，以及分别由R1COOR2，C2HxClyFz，C3HxClyFz和C4HxClyFz表示的第一，第二，第三和第四化合物。 当作为第一段的含氟弹性体共聚物在接枝共聚之前通过与钡盐接触而纯化时，弹性氟代烃树脂的热稳定性提高。 当具有0.1-50重量％水含量的含氟弹性体共聚物作为第一链段分散在含有叔丁醇和水的液体介质中时，在接枝共聚之前不需要干燥该弹性体共聚物。 当作为第一段的含氟弹性体共聚物分散在含有叔丁醇，水，羧酸酯和氢氧化钡的另一种液体介质中时，弹性氟代烃树脂的热稳定性提高，接枝共聚速率更高。
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10.发明授权
公开(公告)号：US5863657A
公开(公告)日：1999-01-26
申请号：US578919
申请日：1995-12-27
IPC分类号： B32B7/12 , C09J127/16 , C09J151/00 , B32B27/08 , C08F259/08 , C08L51/00
CPC分类号： C09J151/003 , B32B7/12 , C09J127/16 , Y10T428/2878 , Y10T428/3154 , Y10T428/31544
摘要： An adhesive for bonding together a first substrate made of vinylidene fluoride resin and a second substrate comprises an elastic fluorohydrocarbon resin, a polyisocyanate, and an organic solvent. This elastic fluorohydrocarbon resin is obtained by graft copolymerization of a fluorine-containing copolymer with a vinylidene fluoride monomer. This copolymer is prepared by copolymerizing at least one first fluorine-containing monomer with at least one unsaturated monomer that has peroxy bond. The adhesive itself is superior in durability, and bond strength between the first and second substrates is also superior.
摘要翻译： 用于将由偏氟乙烯树脂和第二基材制成的第一基材粘合在一起的粘合剂包括弹性氟代烃树脂，多异氰酸酯和有机溶剂。 该弹性氟代烃树脂通过含氟共聚物与偏二氟乙烯单体的接枝共聚获得。 该共聚物通过使至少一种第一含氟单体与至少一种具有过氧键的不饱和单体共聚来制备。 粘合剂本身的耐久性优异，第一和第二基板之间的粘结强度也优异。
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