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1.发明授权公开(公告)号：US09496551B2
公开(公告)日：2016-11-15
申请号：US12742126
申请日：2008-11-12
CPC分类号： H01M4/505 , C01G45/1242 , C01G49/009 , C01G51/54 , C01G53/54 , C01P2002/52 , C01P2002/72 , C01P2002/85 , C01P2004/03 , C01P2004/61 , C01P2004/62 , C01P2006/12 , C01P2006/40 , H01B1/08 , H01M10/052 , Y02E60/122 , Y02P70/54
摘要： The present invention relates to lithium manganate particles having a primary particle diameter of not less than 1 μm and an average particle diameter (D50) of not less than 2 μm and not more than 10 μm as measured by a particle size distribution meter, and forming particles having substantially a single phase, which have a composition represented by the following chemical formula: Li1+xMn2−x−yY1yO4+Y2 where Y1 is at least one element selected from the group consisting of Ni, Co, Mg, Fe, Al, Cr and Ti; Y2 is at least one element constituting a sintering aid having a melting point of not higher than 800° C., x and y satisfy 0.03≦x≦0.15 and 0.05≦y≦0.20, respectively, and Y2 is present in an amount of 0.1 to 2.5 mol % based on Mn; the Y1 element being dispersed within the respective particles, and an X-ray diffraction intensity ratio of I(400)/I(111) of the particles being not less than 38% and an X-ray diffraction intensity ratio of I(440)/I(111) thereof being not less than 18%.
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2.发明申请LITHIUM MANGANATE PARTICLES FOR NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY, PROCESS FOR PRODUCING THE SAME, AND NONAQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开非水电解质二次电池用锰酸钡颗粒，其制造方法和非电解电解质二次电池公开(公告)号：US20110223483A1
公开(公告)日：2011-09-15
申请号：US13121229
申请日：2009-09-29
申请人： Kazumichi Koga , Masayuki Uegami , Hioraki Masukuni , Kazutoshi Matsumoto , Kazutoshi Ishizaki , Hideaki Sadamura
发明人： Kazumichi Koga , Masayuki Uegami , Hioraki Masukuni , Kazutoshi Matsumoto , Kazutoshi Ishizaki , Hideaki Sadamura
CPC分类号： H01M4/505 , C01G45/02 , C01G45/1242 , C01P2002/52 , C01P2002/77 , C01P2004/03 , C01P2004/61 , C01P2006/12 , C01P2006/80 , H01B1/08 , H01M4/0471 , H01M4/46 , H01M4/485 , H01M10/0525
摘要： The present invention provides lithium manganate which has a high output and is excellent in high-temperature stability. The present invention relates to lithium manganate particles which are produced by mixing a lithium compound, a manganese compound, a Y compound and an A compound with each other and then calcining the resulting mixture, and have a composition represented by the following chemical formula 1 and an average secondary particle diameter (D50) of 1 to 15 μm, Li1+xMn2−x−yYyO4+zA (Chemical Formula) in which Y is at least one element selected from the group consisting of Al and Mg; A is a sintering aid element having a melting point of not higher than 850° C.; x and y satisfy 0.03≦x≦0.15 and 0≦y≦0.20, respectively; z is in the range of 0 to 2.5 mol % based on Mn, wherein the lithium manganate particles have a sulfur content of not more than 100 ppm.
摘要翻译： 本发明提供了具有高产出并且具有优异的高温稳定性的锰酸锂。 本发明涉及通过将锂化合物，锰化合物，Y化合物和A化合物彼此混合然后煅烧所得混合物而制备的锰酸锂颗粒，并且具有由以下化学式1和 平均二次粒径（D50）为1〜15μm，其中Y为选自Al和Mg中的至少一种元素的Li1 + xMn2-x-yYyO4 + zA（化学式） A是熔点不高于850℃的烧结助剂元素; x和y分别满足0.03＆nlE; x＆nlE; 0.15和0＆nlE; y＆nlE; 0.20; z在Mn的范围内为0〜2.5摩尔％，其中，锰酸锂颗粒的硫含量不大于100ppm。
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3.发明申请公开(公告)号：US20100288969A1
公开(公告)日：2010-11-18
申请号：US12742126
申请日：2008-11-12
IPC分类号： H01M4/50
CPC分类号： H01M4/505 , C01G45/1242 , C01G49/009 , C01G51/54 , C01G53/54 , C01P2002/52 , C01P2002/72 , C01P2002/85 , C01P2004/03 , C01P2004/61 , C01P2004/62 , C01P2006/12 , C01P2006/40 , H01B1/08 , H01M10/052 , Y02E60/122 , Y02P70/54
摘要： The present invention relates to lithium manganate particles having a primary particle diameter of not less than 1 μm and an average particle diameter (D50) of not less than 2 μm and not more than 10 μm as measured by a particle size distribution meter, and forming particles having substantially a single phase, which have a composition represented by the following chemical formula: Li1+xMn2−x−yY1yO4+Y2 where Y1 is at least one element selected from the group consisting of Ni, Co, Mg, Fe, Al, Cr and Ti; Y2 is at least one element constituting a sintering aid having a melting point of not higher than 800° C., x and y satisfy 0.03≦x≦0.15 and 0.05≦y≦0.20, respectively, and Y2 is present in an amount of 0.1 to 2.5 mol % based on Mn; the Y1 element being dispersed within the respective particles, and an X-ray diffraction intensity ratio of I(400)/I(111) of the particles being not less than 38% and an X-ray diffraction intensity ratio of I(440)/I(111) thereof being not less than 18%. The lithium manganate particles of the present invention have a high output and are excellent in high-temperature stability.
摘要翻译： 本发明涉及一次粒径为1μm以上的平均粒径（D50）为2μm以上且10μm以下的由粒径分布计测定的锰酸锂颗粒，形成 具有基本上单相的颗粒，其具有由以下化学式表示的组成：Li1 + xMn2-x-yY1yO4 + Y2，其中Y1是选自Ni，Co，Mg，Fe，Al中的至少一种元素， Cr和Ti; Y2是构成熔点不高于800℃的烧结助剂的至少一种元素，x和y分别满足0.03＆nlE; x＆lt; ll; 0.15,0.05＆nlE; y＆nlE; 0.20，Y2以 相对于Mn为0.1〜2.5摩尔％ Y1元素分散在各自的粒子内，粒子的I（400）/ I（111）的X射线衍射强度比不小于38％，X射线衍射强度比I（440） / I（111）不小于18％。 本发明的锰酸锂颗粒具有高的输出，并且具有优异的高温稳定性。
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4.发明授权公开(公告)号：US08323612B2
公开(公告)日：2012-12-04
申请号：US12810367
申请日：2008-12-26
CPC分类号： C01G45/1242 , C01G45/02 , C01G49/0072 , C01G51/54 , C01G53/54 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2002/74 , C01P2004/03 , C01P2004/51 , C01P2004/61 , C01P2004/80 , C01P2004/84 , C01P2006/12 , C01P2006/40 , C04B35/016 , C04B2235/3203 , C04B2235/3206 , C04B2235/3232 , C04B2235/3241 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/34 , C04B2235/763 , H01M4/02 , H01M4/505 , H01M4/525 , H01M10/052 , H01M10/0525 , H01M2004/021 , H01M2004/028 , Y10T428/2982
摘要： The present invention relates to lithium manganate particles having a primary particle diameter of 1 to 8 μm and forming substantially single-phase particles, which have a composition represented by the following chemical formula: Li1+xMn2-x-yY1yO4+Y2 in which Y1 is at least one element selected from the group consisting of Ni, Co, Mg, Fe, Al, Cr and Ti; Y2 is P and is present in an amount of 0.01 to 0.6 mol % based on Mn; and x and y satisfy 0.03≦x≦0.15 and 0.05≦y≦0.20, respectively, and which lithium manganate particles have a specific surface area of the lithium manganate particles of 0.3 to 0.9 m2/g (as measured by BET method); and have an average particle diameter (D50) of the lithium manganate particles of 3 to 10 μm. A positive electrode active substance of a lithium ion secondary battery using the lithium manganate particles of the present invention has a high output and is excellent in high-temperature stability.
摘要翻译： 本发明涉及一次粒径为1〜8μm的锰酸锂颗粒，并形成基本上单相的颗粒，其具有由以下化学式表示的组成：Li1 + xMn2-x-yY1yO4 + Y2，其中Y1为 选自Ni，Co，Mg，Fe，Al，Cr和Ti中的至少一种元素; Y2为P，相对于Mn为0.01〜0.6摩尔％ x和y分别满足0.03＆nlE; x＆lt; ll; 0.15和0.05＆amp; nlE; y＆nlE; 0.20，锰酸锂颗粒的比表面积为0.3〜0.9m 2 / g（通过BET法测定） ; 并且具有3〜10μm的锰酸锂颗粒的平均粒径（D50）。 使用本发明的锰酸锂颗粒的锂离子二次电池的正极活性物质的输出量高，高温稳定性优异。
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5.发明申请公开(公告)号：US20100327221A1
公开(公告)日：2010-12-30
申请号：US12810367
申请日：2008-12-26
CPC分类号： C01G45/1242 , C01G45/02 , C01G49/0072 , C01G51/54 , C01G53/54 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2002/74 , C01P2004/03 , C01P2004/51 , C01P2004/61 , C01P2004/80 , C01P2004/84 , C01P2006/12 , C01P2006/40 , C04B35/016 , C04B2235/3203 , C04B2235/3206 , C04B2235/3232 , C04B2235/3241 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/34 , C04B2235/763 , H01M4/02 , H01M4/505 , H01M4/525 , H01M10/052 , H01M10/0525 , H01M2004/021 , H01M2004/028 , Y10T428/2982
摘要： The present invention relates to lithium manganate particles having a primary particle diameter of 1 to 8 μm and forming substantially single-phase particles, which have a composition represented by the following chemical formula: Li1+xMn2−x−yY1yO4+Y2 in which Y1 is at least one element selected from the group consisting of Ni, Co, Mg, Fe, Al, Cr and Ti; Y2 is P and is present in an amount of 0.01 to 0.6 mol % based on Mn; and x and y satisfy 0.03≦x≦0.15 and 0.05≦y≦0.20, respectively, and which lithium manganate particles have a specific surface area of the lithium manganate particles of 0.3 to 0.9 m2/g (as measured by BET method); and have an average particle diameter (D50) of the lithium manganate particles of 3 to 10 μm. A positive electrode active substance of a lithium ion secondary battery using the lithium manganate particles of the present invention has a high output and is excellent in high-temperature stability.
摘要翻译： 本发明涉及一次粒径为1〜8μm的锰酸锂颗粒，并形成基本单相颗粒，其具有由以下化学式表示的组成：Li1 + xMn2-x-yY1yO4 + Y2，其中Y1为 选自Ni，Co，Mg，Fe，Al，Cr和Ti中的至少一种元素; Y2为P，相对于Mn为0.01〜0.6摩尔％ x和y分别满足0.03＆nlE; x＆lt; ll; 0.15和0.05＆amp; nlE; y＆nlE; 0.20，锰酸锂颗粒的比表面积为0.3〜0.9m 2 / g（通过BET法测定） ; 并且具有3〜10μm的锰酸锂颗粒的平均粒径（D50）。 使用本发明的锰酸锂颗粒的锂离子二次电池的正极活性物质的输出量高，高温稳定性优异。
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公开(公告)号：US10161057B2
公开(公告)日：2018-12-25
申请号：US14007732
申请日：2011-12-26
申请人： Hiroyasu Watanabe , Daisuke Morita , Manabu Yamamoto , Kazumichi Koga , Akihisa Kajiyama , Hiroaki Masukuni , Hideaki Sadamura , Ryuta Masaki , Kazutoshi Matsumoto
发明人： Hiroyasu Watanabe , Daisuke Morita , Manabu Yamamoto , Kazumichi Koga , Akihisa Kajiyama , Hiroaki Masukuni , Hideaki Sadamura , Ryuta Masaki , Kazutoshi Matsumoto
IPC分类号： H01M4/48 , H01M4/52 , H01M4/525 , C30B1/10 , C01G45/12 , C01G51/00 , C01G53/00 , H01M4/505 , C30B1/02
摘要： The present invention provides a precursor of positive electrode active substance particles for non-aqueous electrolyte secondary batteries which have a high discharge voltage and a high discharge capacity, hardly suffer from side reactions with an electrolyte solution, and are excellent in cycle characteristics, positive electrode active substance particles for non-aqueous electrolyte secondary batteries, and processes for producing these particles, and a non-aqueous electrolyte secondary battery. The present invention relates to positive electrode active substance particles for non-aqueous electrolyte secondary batteries having a spinel structure with a composition represented by the following chemical formula (1), in which the positive electrode active substance particles satisfy the following characteristic (A) and/or characteristic (B) when indexed with Fd−3m in X-ray diffraction thereof: (A) when indexed with Fd−3m in X-ray diffraction of the positive electrode active substance particles, a ratio of I(311) to I(111) [I(311)/I(111)] is in the range of 35 to 43%, and/or (B) when indexed with Fd−3m in X-ray diffraction of the positive electrode active substance particles, a gradient of a straight line determined by a least square method in a graph prepared by plotting sin θ in an abscissa thereof and B cos θ in an ordinate thereof wherein B is a full-width at half maximum with respect to each peak position 2θ (10 to 90°) is in the range of 3.0×10−4 to 20.0×10−4; and Li1+xMn2−y−zNiyMzO4 Chemical Formula (1) wherein x, y, z fall within the range of −0.05≤x≤0.15, 0.4≤y≤0.6 and 0≤z≤0.20, respectively; and M is at least one element selected from the group consisting of Mg, Al, Si, Ca, Ti, Co, Zn, Sb, Ba, W and Bi.
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7.发明授权公开(公告)号：US09505631B2
公开(公告)日：2016-11-29
申请号：US13144361
申请日：2010-01-19
CPC分类号： C01G45/1242 , C01P2002/32 , C01P2002/52 , C01P2002/77 , C01P2004/03 , C01P2004/30 , C01P2004/41 , C01P2004/61 , C01P2004/62 , C01P2006/11 , C01P2006/12 , C01P2006/40 , Y02E60/122 , Y02P70/54
摘要： The present invention relates to positive electrode active substance particles for lithium ion batteries, comprising lithium manganate particles comprising Li and Mn as main components and having a cubic spinel structure (Fd-3m), wherein primary particles of the positive electrode active substance have a dodecahedral or higher-polyhedral shape in which none of crystal planes equivalent to the (111) plane are located adjacent to each other, and flat crystal planes are crossed with each other to form a clear ridge, and an average primary particle diameter of the primary particles is not less than 1 μm and not more than 20 μm. The positive electrode active substance particles according to the present invention are excellent in packing property, load characteristics and high-temperature stability.
摘要翻译： 本发明涉及用于锂离子电池的正极活性物质颗粒，其包含以Li和Mn为主要成分并具有立方尖晶石结构（Fd-3m）的锰酸锂颗粒，其中正极活性物质的一次颗粒具有十二面体 或更高多面体形状，其中不相等于（111）面的晶面彼此相邻，并且平坦的晶面彼此交叉以形成透明的脊，并且一次粒子的平均一次粒径 不小于1μm且不大于20μm。 根据本发明的正极活性物质颗粒的包装性，负载特性和高温稳定性优异。
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8.发明申请PROCESS FOR PRODUCING LITHIUM MANGANATE PARTICLES AND NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 有权生产锰酸钡颗粒和非水电解质二次电池的方法公开(公告)号：US20110210287A1
公开(公告)日：2011-09-01
申请号：US13063812
申请日：2009-09-16
CPC分类号： H01M10/052 , C01G45/02 , C01G45/1235 , C01P2004/03 , C01P2004/51 , C01P2004/61 , C01P2006/12 , C01P2006/40 , C04B35/016 , C04B35/62675 , C04B35/62802 , C04B35/62805 , C04B35/62813 , C04B35/62886 , C04B2235/3203 , C04B2235/3206 , C04B2235/3217 , C04B2235/3232 , C04B2235/3241 , C04B2235/3263 , C04B2235/3267 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3409 , C04B2235/442 , C04B2235/528 , C04B2235/5436 , C04B2235/5463 , C04B2235/5481 , C04B2235/81 , H01M4/131 , H01M4/485 , H01M4/505 , H01M4/525 , Y02E60/122 , Y02P70/54
摘要： According to the present invention, there is provided a process for producing lithium manganate particles having a high output and an excellent high-temperature stability. The present invention relates to a process for producing lithium manganate particles comprising the steps of mixing a lithium compound, a manganese compound and a boron compound with each other; and calcining the resulting mixture in a temperature range of 800 to 1050° C., wherein an average particle diameter (D50) of the boron compound is not more than 15 times an average particle diameter (D50) of the manganese compound, and wherein the lithium manganate particles have a composition represented by the following chemical formula: Li1+xMn2-x-yY1yO4+B in which Y1 is at least one element selected from the group consisting of Ni, Co, Mg, Fe, Al, Cr and Ti, and x and y satisfy the conditions of 0.03≦x≦0.15 and 0≦y≦0.20, respectively.
摘要翻译： 根据本发明，提供了一种具有高输出和优异的高温稳定性的锰酸锂颗粒的制造方法。 本发明涉及一种锰酸锂颗粒的制造方法，包括将锂化合物，锰化合物和硼化合物彼此混合的步骤; 在800〜1050℃的温度范围内煅烧所得到的混合物，其中硼化合物的平均粒径（D50）不大于锰化合物的平均粒径（D50）的15倍，其中， 锰酸锂颗粒具有由以下化学式表示的组成：Li1 + xMn2-x-yY1yO4 + B，其中Y1为选自Ni，Co，Mg，Fe，Al，Cr和Ti中的至少一种元素， x和y分别满足0.03＆nlE; x＆nlE; 0.15和0＆nlE; y＆nlE; 0.20的条件。
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9.发明授权Process for producing lithium manganate particles and non-aqueous electrolyte secondary battery 有权制造锰酸锂颗粒和非水电解质二次电池的方法公开(公告)号：US08852811B2
公开(公告)日：2014-10-07
申请号：US13063812
申请日：2009-09-16
IPC分类号： H01M4/505 , C04B35/628 , C01G45/02 , C04B35/626 , C04B35/01 , H01M4/485 , H01M10/052 , C01G45/12 , H01M4/525 , H01M4/131
CPC分类号： H01M10/052 , C01G45/02 , C01G45/1235 , C01P2004/03 , C01P2004/51 , C01P2004/61 , C01P2006/12 , C01P2006/40 , C04B35/016 , C04B35/62675 , C04B35/62802 , C04B35/62805 , C04B35/62813 , C04B35/62886 , C04B2235/3203 , C04B2235/3206 , C04B2235/3217 , C04B2235/3232 , C04B2235/3241 , C04B2235/3263 , C04B2235/3267 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3409 , C04B2235/442 , C04B2235/528 , C04B2235/5436 , C04B2235/5463 , C04B2235/5481 , C04B2235/81 , H01M4/131 , H01M4/485 , H01M4/505 , H01M4/525 , Y02E60/122 , Y02P70/54
摘要： According to the present invention, there is provided a process for producing lithium manganate particles having a high output and an excellent high-temperature stability. The present invention relates to a process for producing lithium manganate particles comprising the steps of mixing a lithium compound, a manganese compound and a boron compound with each other; and calcining the resulting mixture in a temperature range of 800 to 1050° C., wherein an average particle diameter (D50) of the boron compound is not more than 15 times an average particle diameter (D50) of the manganese compound, and wherein the lithium manganate particles have a composition represented by the following chemical formula: Li1+xMn2-x-yY1yO4+B in which Y1 is at least one element selected from the group consisting of Ni, Co, Mg, Fe, Al, Cr and Ti, and x and y satisfy the conditions of 0.03≦x≦0.15 and 0≦y≦0.20, respectively.
摘要翻译： 根据本发明，提供了一种具有高输出和优异的高温稳定性的锰酸锂颗粒的制造方法。 本发明涉及一种锰酸锂颗粒的制造方法，包括将锂化合物，锰化合物和硼化合物彼此混合的步骤; 在800〜1050℃的温度范围内煅烧所得到的混合物，其中硼化合物的平均粒径（D50）不大于锰化合物的平均粒径（D50）的15倍，其中， 锰酸锂颗粒具有由以下化学式表示的组成：Li1 + xMn2-x-yY1yO4 + B，其中Y1为选自Ni，Co，Mg，Fe，Al，Cr和Ti中的至少一种元素， x和y分别满足0.03＆nlE; x＆nlE; 0.15和0＆nlE; y＆nlE; 0.20的条件。
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10.发明申请POSITIVE ELECTRODE ACTIVE MATERIAL FOR SECONDARY BATTERIES WITH NONAQUEOUS ELECTROLYTIC SOLUTION, PROCESS FOR THE PRODUCTION OF THE ACTIVE MATERIAL, AND SECONDARY BATTERIES WITH NONAQUEOUS ELECTROLYTIC SOLUTION 有权用于具有非电解电解质的二次电池的正极电极活性材料，用于生产活性材料的方法和具有非电解电解质的二次电池公开(公告)号：US20110297876A1
公开(公告)日：2011-12-08
申请号：US13144361
申请日：2010-01-19
IPC分类号： H01M4/505
CPC分类号： C01G45/1242 , C01P2002/32 , C01P2002/52 , C01P2002/77 , C01P2004/03 , C01P2004/30 , C01P2004/41 , C01P2004/61 , C01P2004/62 , C01P2006/11 , C01P2006/12 , C01P2006/40 , Y02E60/122 , Y02P70/54
摘要： The present invention relates to positive electrode active substance particles for lithium ion batteries, comprising lithium manganate particles comprising Li and Mn as main components and having a cubic spinel structure (Fd-3m), wherein primary particles of the positive electrode active substance have a dodecahedral or higher-polyhedral shape in which none of crystal planes equivalent to the (111) plane are located adjacent to each other, and flat crystal planes are crossed with each other to form a clear ridge, and an average primary particle diameter of the primary particles is not less than 1 μm and not more than 20 μm. The positive electrode active substance particles according to the present invention are excellent in packing property, load characteristics and high-temperature stability.
摘要翻译： 本发明涉及用于锂离子电池的正极活性物质颗粒，其包含以Li和Mn为主要成分并具有立方尖晶石结构（Fd-3m）的锰酸锂颗粒，其中正极活性物质的一次颗粒具有十二面体 或更高多面体形状，其中不相等于（111）面的晶面彼此相邻，并且平坦的晶面彼此交叉以形成透明的脊，并且一次粒子的平均一次粒径 不小于1μm且不大于20μm。 根据本发明的正极活性物质颗粒的包装性，负载特性和高温稳定性优异。
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