摘要:
Disclosed is a metal vessel comprising an upper member and a lower member, each consisting of a coated cup-shaped formed metal body and a circumferential side seam being formed by lap-bonding the open ends of the upper and lower members to each other through an adhesive, wherein said coated cup-shaped formed metal body is composed of a metal blank having a coating of a vinyl chloride resin having a vinyl chloride unit content of 30 to 97% by weight and a glass transition temperature of at least 40.degree. C. and containing carboxyl groups and/or hydroxyl groups at a concentration of 10 to 500 millimoles/100 g of the resin, said adhesive is an adhesive composed mainly of a copolyester containing in the main chain at least 50 mole %, based on the total acid component, of terephthalic acid, at least 50 mole %, based on the total alcohol component, of 1,4-butane-diol and at least 1 mole % of at least one member selected from other acids and other alcohols, and the upper and lower members are bonded to each other through said vinyl chloride resin coating and said copolyester type adhesive.
摘要:
Disclosed is a metal vessel comprising an upper member and a lower member, each consisting of a coated cup-shaped formed metal body and a circumferential side seam being formed by lap-bonding the open ends of the upper and lower members to each other through an adhesive, wherein said coated cup-shaped formed metal body is composed of a metal blank having a coating of a vinyl chloride resin having a vinyl chloride unit content of 30 to 97% by weight and a glass transition temperature of at least 40.degree. C. and containing carboxyl groups and/or hydroxyl groups at a concentration of 10 to 500 millimoles/100 g of the resin, said adhesive is an adhesive composed mainly of a copolyester containing in the main chain at least 50 mole %, based on the total acid component, of terephthalic acid, at least 50 mole %, based on the total alcohol component, of 1,4-butane-diol and at least 1 mole % of at least one member selected from other acids and other alcohols, and the upper and lower members are bonded to each other through said vinyl chloride resin coating and said copolyester type adhesive.
摘要:
Disclosed is a hot-melt adhesive which comprises a copolyester of a dibasic acid component comprising 70 to 97 mole % of terephthalic acid and other dibasic acid with a polyhydric alcohol component comprising 70 to 97 mole % of 1,4-butane-diol, 3 to 30 mole % of diethylene glycol and up to 20 mole % of other polyhydric alcohol having 2 to 5 carbon atoms, said copolyester having a reduced viscosity of at least 0.6 dl/g as measured at a temperature of 30.degree. C. in a phenol/tetrachloroethane mixed solvent having a phenol/tetrachloroethane weight ratio of 60/40 at a polymer concentration of 0.25 g/100 ml, a glass transition temperature of at least 31.degree. C. and a crystallinity of 15 to 40 %.This hot-melt adhesive is excellent in the operation adaptability, and in the form of a film, the adhesive has an appropriate rigidity and a good dimension stability. Furthermore, when this hot-melt adhesive is formed into an adhesive layer between seams by hot bonding, the adhesive layer provides a high creep resistance and a good dimension stability. This hot-melt adhesive is valuably used for producing a metal vessel having a circumferential side seam by bonding cup-shaped lower and upper members along circumferential open ends of the two members.
摘要翻译:公开了一种热熔粘合剂,其包含二元酸组分的共聚酯,其包含70至97摩尔%的对苯二甲酸和其它二元酸与多元醇组分,所述多元醇组分包含70至97摩尔%的1,4-丁烷二醇,3 至30摩尔%的二甘醇和至多20摩尔%的其他具有2至5个碳原子的多元醇,所述共聚酯在苯酚中在30℃下测得的比浓粘度至少为0.6dl / g /四氯乙烷混合溶剂,聚合物浓度为0.25g / 100ml,玻璃化转变温度为31℃,结晶度为15〜40%,苯酚/四氯乙烷重量比为60/40。 该热熔粘合剂的操作适应性优异,并且以薄膜的形式,粘合剂具有适当的刚度和良好的尺寸稳定性。 此外,当通过热粘合将该热熔粘合剂形成为接缝之间的粘合剂层时,粘合剂层提供高抗蠕变性和良好的尺寸稳定性。 这种热熔粘合剂被有价值地用于制造具有圆周侧接缝的金属容器,所述金属容器通过沿两个构件的周向开口端接合杯状下部和上部构件。
摘要:
Disclosed is a process for the preparation of metallic bottles which comprises lap-bonding circumferential open end portions of upper and lower members, each consisting of a formed cup of a metal, said process being characterized by using at least one thermoplastic resin adhesive having a water absorption of less than 2%, as measured at a temperature of 23.degree. C. and a relative humidity of 80%, and an elasticity contribution ratio [R(t).sub.t=1 ] of from 1.times.10.sup.-4 to 5.times.10.sup.-1, defined by the following formula:R(t).sub.t=1 =J(t).sub.rec,t=1 /J(t).sub.t=1wherein J(t).sub.t=1 represents a creep compliance at a time constant of 1 second when the adhesive is caused to creep at a temperature higher by 30.degree. C. than the melting point of the adhesive under a shear stress of 50 to 5,000 dyne/cm.sup.2, and J(t).sub.rec,t=1 represents an equilibrium recovery creep compliance when the adhesive is caused to creep under the same conditions as described above and the adhesive is then let to recover, and containing in the main or side chain groups ##STR1## at a concentration of 10 to 1400 milliequivalents per 100 g of the adhesive.
摘要:
Disclosed is a metal bottle adhesive for lap-bonding upper and lower members, each consisting of a cup-like formed article of a metal, on the peripheral ends thereof, said adhesive comprising at least one high-molecular-weight thermoplastic resin having a post crystallinity .DELTA.Wc, defined by the following formula, of less than 20%:.DELTA.Wc=Wc.sub.II -Wc.sub.Iwherein Wc.sub.I stands for the crystallinity (%) of the adhesive which has been molten at a temperature higher by 30.degree. than the softening point thereof and then naturally cooled at room temperature, determined according to the density method, and Wc.sub.II stands for the crystallinity of the adhesive which has then been immersed in water maintained at 70.degree. C. for 10 hours and then naturally cooled and dried at room temperature, determined according to the density method,a shear creep compliance J(t).sub.t=2 hrs of less than 10.sup.-4 cm.sup.2 /hyne at 90.degree. C. and a time constant of 2 hours and a concentration of ##STR1## groups, contained in the main or side chain, of 10 to 1400 meq/100 g of the resin.
摘要:
Disclosed is a draw-ironed metal vessel having a circumferential side seam, which is formed by lap-bonding of open end portions of upper and lower members, each consisting of a seamless molded metal cap, wherein the side wall of at least one of said upper and lower members is formed by draw-ironing a tin-plated steel plate at an ironing ratio of at least 20% and a spout having a diameter smaller than that of the side wall of the vessel is formed on the top wall of the upper member.
摘要:
A metal vessel has a metal bottomed cup-shaped lower member and a metal cup-shaped upper member, the upper and lower members being bonded together by a circumferential side seam. The upper member has a pouring mouth having a small diameter in the central portion thereof. The metal vessel is formed by lap-bonding the circumferential open ends of both the upper and lower members. The side wall of the upper member is formed by subjecting a primer-coated tin-plated steel sheet to draw forming at a side wall plastic forming ratio R of from 1.1 to 1.8; the side wall plastic forming ratio R being defined by the following formula: ##EQU1## wherein W stands for the weight (g) of the blank of the upper member, t stands for the thickness (cm) of the blank of the upper member at the side wall, .rho. stands for the density (g/cm.sup.3) of the blank of the upper member, D.sub.0 stands for the inner diameter (cm) of pouring mouth of the upper member, and D.sub.1 stands for the average inner diameter (cm) of the side wall.In the circumferential bonded portion, the side wall of the lower member is bonded to the side wall of the upper member through an organic adhesive interposed between a primer coating applied to the side wall of the lower member and a primer coating applied to the side wall of the upper member. The bonding strength and resistance to leakage of the lap-bonded circumferential side seam are improved.
摘要:
Disclosed is a process for preparation of metal vessels, which comprises lap-bonding circumferential open end portions of outer and inner members, each consisting of a formed seamless metal cup, to each other through an adhesive, said process being characterized by fitting both the outer and inner members to each other through an adhesive layer interposed between the open end portions of both the members, heating the fitted portions of both the outer and inner members so as to melt the adhesive layer, and cooling the fitted portions so that the temperatures of the fitted portions of both the outer and inner members are substantially equal to each other just before solidification of the adhesive layer and the adhesive is filled between both the open end portions.
摘要:
Disclosed is a process for the preparation of metal vessels, which comprises lap-bonding both the circumferential end portions of upper and lower members, each consisting of a seamless formed metal cup, through a layer of a hot adhesive interposed therebetween, wherein a high frequency induction heating coil is arranged so that the coil covers a part, smaller than the semicircle, of the circumferential portion to be formed into a seam, which circumferential portion consists of said end portions engaged with each other through the hot adhesive layer, electricity is applied to the heating coil to induce an eddy current passing through said end portions and the circumferential portion and the heating coil are rotated relatively to each other, whereby both the end portions are heated and a seam is formed by heat bonding.
摘要:
Disclosed is a welded side-seamed can formed by welding a can blank comprising a steel plate substrate having, formed thereon, a coating layer consisting of a metallic chromium layer and a chromium oxide layer formed on the metallic chromium layer, wherein the so-formed side seam has an exposed steel plate layer consisting of a compact and dense steel oxide formed mainly of magnetite, which has a thickness of 50 to 800 A, especially 50 to 400 A, and a coating of a resin or resinous composition consisting of carbonyl, hydroxyl, ether and epoxy groups at a concentration of 10 to 2000 millimoles per 100 g of the resin is formed on at least one surface portion of said side seam through said steel oxide layer.