公开(公告)号：US5905008A

公开(公告)日：1999-05-18

申请号：US867523

申请日：1997-06-02

申请人： Kazuo Yoshinaga ,  Shunichiro Nishida ,  Keiko Hiraoka ,  Yayoi Nagao ,  Hideki Kobayashi ,  Toru Masatomi

发明人： Kazuo Yoshinaga ,  Shunichiro Nishida ,  Keiko Hiraoka ,  Yayoi Nagao ,  Hideki Kobayashi ,  Toru Masatomi

IPC分类号： G03G5/05 ,  G03G5/10 ,  G03G5/147 ,  G03G5/047 ,  G03G15/00

CPC分类号： G03G5/104 ,  G03G5/0578 ,  G03G5/14773

摘要： An electrophotographic photosensitive member has a photosensitive layer formed on a support. A surface layer (or the outermost layer) of the photosensitive layer contains a fluorine-modified organic silicone resin represented by the following average unit formula:{F(CF.sub.2).sub.a1 -Q.sub.1 -R.sub.1.m1 SiO.sub.(3-m1)/2 }.sub.X1 {F(CF.sub.2).sub.a2 -Q.sub.2 -R.sub.2.m2 SiO.sub.(3-m2)/2 }.sub.X2 . . . {F(CF.sub.2).sub.ap -Q.sub.p -R.sub.p.mp SiO.sub.(3-mp)/2 }.sub.Xp {R.sub.1 '.sub.n1 SiO.sub.(4-n1)/2)}.sub.y1 {R.sub.2 '.sub.n2 SiO.sub.4-n2)/2 }.sub.y2 . . . {R.sub.q '.sub.nq SiO.sub.(4-nq)/2 }.sub.yqwhere R.sub.1 -R.sub.p and R.sub.1 '-R.sub.q ' are each an alkyl or aryl group; Q.sub.1 -Q.sub.p are each an alkylene group; m1-mp are each an integer of 0 to 2; n1-nq are each an integer of 0 to 3; a1-aq are each an integer; x1-y1 are each a number larger than 0; and X2-Xp and Y2 are each respectively a number of 0 or more.

摘要翻译： 电子照相感光构件具有形成在支撑体上的感光层。 感光层的表层（或最外层）含有由以下平均单元式表示的氟改性有机硅树脂：{F（CF2）a1-Q1-R1.m1SiO（3-m1）/ 2} X1 {F（CF2）a2-Q2-R2.m2SiO（3-m2）/ 2} X2。 。 。 {F（CF 2）ap-Qp-Rp.mpSiO（3-mp）/ 2} Xp {R1'n1SiO（4-n1）/ 2）} y1 {R2'n2SiO4-n2）/ 2} y2。 。 。 {Rq'nqSiO（4-nq）/ 2} yq其中R1-Rp和R1'-Rq'各自为烷基或芳基; Q1-Qp各自为亚烷基; m1-mp分别为0〜2的整数， n1-nq各自为0〜3的整数， a1-aq均为整数; x1-y1分别大于0; X2-Xp和Y2分别为0以上的数。

公开(公告)号：US5910386A

公开(公告)日：1999-06-08

申请号：US890649

申请日：1997-07-09

申请人： Kazuo Yoshinaga ,  Shunichiro Nishida ,  Masataka Kawahara ,  Keiko Hiraoka ,  Nobuo Kushibiki ,  Hideki Kobayashi ,  Kikuko Takeuchi ,  Toru Masatomi

发明人： Kazuo Yoshinaga ,  Shunichiro Nishida ,  Masataka Kawahara ,  Keiko Hiraoka ,  Nobuo Kushibiki ,  Hideki Kobayashi ,  Kikuko Takeuchi ,  Toru Masatomi

IPC分类号： G03G5/147 ,  G03G5/14

CPC分类号： G03G5/147 ,  G03G5/14704 ,  G03G5/14773

摘要： An electrophotographic photosensitive member is disclosed which has a photosensitive layer and a protection layer. The protection layer contains a particulate colloidal silica and a siloxane resin to have a contact angle of water of not less than 90.degree.. The photosensitive member has a lowered surface energy and excellent mechanical and electrical durability.

摘要翻译： 公开了一种具有感光层和保护层的电子照相感光构件。 保护层含有胶体二氧化硅和硅氧烷树脂，其接触角不小于90°。 感光构件具有降低的表面能和优异的机械和电气耐久性。

公开(公告)号：US06376695B1

公开(公告)日：2002-04-23

申请号：US08744192

申请日：1996-11-05

申请人： Nobuo Kushibiki ,  Kikuko Takeuchi ,  Hideki Kobayashi ,  Toru Masatomi ,  Kazuo Yoshinaga ,  Yuichi Hashimoto ,  Shunichiro Nishida

发明人： Nobuo Kushibiki ,  Kikuko Takeuchi ,  Hideki Kobayashi ,  Toru Masatomi ,  Kazuo Yoshinaga ,  Yuichi Hashimoto ,  Shunichiro Nishida

IPC分类号： C07F710

CPC分类号： G03G5/078 ,  C07F7/1804 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08K9/06 ,  C08L83/04 ,  G03G5/0578 ,  G03G5/0614 ,  G03G5/0616 ,  G03G5/0629 ,  G03G5/0631 ,  G03G5/0633 ,  G03G5/0637 ,  G03G5/0642 ,  C08L2666/44

摘要： An organosilicon-modified charge transporting compound having a structure represented by the following Formula (I): wherein A represents a charge transporting group, Q represents a hydrolytic group or a hydroxyl group, R2 represents a monovalent hydrocarbon group or a halogen-substituted monovalent hydrocarbon group having 1 to 15 carbon atoms, n is 1 to 18, m is 1 to 3, and 1 is 1 to 5; and a curable composition containing the organosilicon-modified charge transporting compound and a cure type resin chiefly composed of an organosilicon high polymer.

摘要翻译： 具有由下式（I）表示的结构的有机硅改性的电荷输送化合物：其中A表示电荷输送基团，Q表示水解基团或羟基，R2表示一价烃基或卤素取代的一价烃 具有1至15个碳原子的基团，n为1至18，m为1至3，1为1至5; 以及含有有机硅改性的电荷输送性化合物和主要由有机硅高分子构成的固化型树脂的固化性组合物。

公开(公告)号：US06174966B1

公开(公告)日：2001-01-16

申请号：US09301258

申请日：1999-04-28

申请人： Hideki Kobayashi ,  Toru Masatomi

发明人： Hideki Kobayashi ,  Toru Masatomi

IPC分类号： C08G1844

CPC分类号： C09D169/00 ,  C09D167/03 ,  C08L2666/44

摘要： A coating agent composition, comprising (A) 100 parts by weight of a polymer having at least two alkoxysilyl groups, wherein the polymer has a number average molecular weight of 500 to 500,000, the polymer has a principal chain comprising a polycarbonate or a polyarylate, and the alkoxysilyl groups in the polymer have the formula —SiR3−a(OR′)a, wherein R is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms, R′ is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 8 carbon atoms, and a is from 1 to 3; (B) 50 to 2,000 parts by weight of an organic solvent; (C) 1 to 90 parts by weight of an organosilane, wherein the organosilane is a compound having the formula R″eSiY4−e or a partially hydrolyzed condensate thereof, wherein R″ is a substituted or unsubstituted monovalent hydrocarbon group or a hydrogen atom, Y is a hydrolyzable group, and e is from 0 to 2; and (D) a cure catalyst in an amount sufficient to cure the composition. A method of preparing a coating agent composition and a coating agent prepared by curing the composition.

摘要翻译： 一种涂料组合物，其包含（A）100重量份具有至少两个烷氧基甲硅烷基的聚合物，其中所述聚合物的数均分子量为500至500,000，所述聚合物具有包含聚碳酸酯或多芳基化合物的主链， 聚合物中的烷氧基甲硅烷基具有式-SiR 3-a（OR'）a，其中R为取代或未取代的碳原子数为1〜10的一价烃基，R'为取代或未取代的1价〜 8个碳原子，a为1至3; （B）50〜2000重量份的有机溶剂; （C）1〜90重量份的有机硅烷，其中有机硅烷为具有式R''eSiY4-e或其部分水解缩合物的化合物，其中R“为取代或未取代的单价烃基或氢 Y为可水解基团，e为0〜2; 和（D）固化催化剂，其量足以固化组合物。 一种制备包衣剂组合物的方法和通过固化该组合物制备的包衣剂。

公开(公告)号：US07795360B2

公开(公告)日：2010-09-14

申请号：US10562656

申请日：2004-06-25

申请人： Toru Masatomi ,  Motoshi Sasaki ,  Hideki Kobayashi

发明人： Toru Masatomi ,  Motoshi Sasaki ,  Hideki Kobayashi

IPC分类号： C08F30/08

CPC分类号： C09D143/04

摘要： A coating agent composition of the present invention consists of: (A) an acrylic-type copolymer that has a weight-average molecular weight within the range of 3,000 to 100,000 and contains in its side molecular chains hydrolysable silyl groups of the following formula: —COO-Q-SiR2n(OR3)3-n and organosiloxysilyl groups of the following formula: —COO-Q-Si(OSiR43)3; and (B) a condensation-reaction accelerating catalyst. Prior to curing, the composition demonstrates excellent storage stability and coating properties, while after curing the composition produces a coating film of high hardness that has excellent water-repellent properties and durability.

摘要翻译： 本发明的涂料组合物由以下组成：（A）重均分子量在3,000〜100,000的丙烯酸类共聚物，并且在其分子链中含有下式的可水解甲硅烷基： COO-Q-SiR2n（OR3）3-n和下式的有机硅氧甲硅烷基：-COO-Q-Si（OSiR43）3; 和（B）缩合反应促进催化剂。 在固化之前，组合物表现出优异的储存稳定性和涂布性能，而在固化后，组合物产生具有优异的防水性能和耐久性的高硬度的涂膜。

公开(公告)号：US06251975B1

公开(公告)日：2001-06-26

申请号：US09345333

申请日：1999-06-30

申请人： Hideki Kobayashi ,  Toru Masatomi

发明人： Hideki Kobayashi ,  Toru Masatomi

IPC分类号： C08G7724

CPC分类号： C08G77/24 ,  C08L83/08

摘要： This invention pertains to a dispersibility improver for fluororesin powders that has the ability to induce the uniform dispersion of fluororesin powders in organic resins; a modifier for application to organic resins wherein said modifier comprises fluororesin powder and the aforesaid dispersibility improver; and finally organic resin compositions that contain the aforesaid modifier and as a consequence have the ability to form uniform and transparent coatings having an excellent surface smoothness. The dispersibility improver for fluororesin powders is a polyorganosiloxane whose molecule contains (F1) at least 1 organic group selected from the group consisting of polyoxyalkylene-functional organic groups, alkyl groups having at least 12 carbon atoms, and polydialkylsiloxane chain-containing organic groups, and (F2) at least 1 perfluoroalkyl-functional organic group with the general formula —R2—X—R1—(CF2)aF wherein R1 represents C1 to C10 divalent hydrocarbon groups, R2 represents C1 to C20 divalent hydrocarbon groups, X is a group with the formula —CO— or —COO—, and a is an integer with a value of at least 3.

摘要翻译： 本发明涉及能够诱导氟树脂粉末在有机树脂中均匀分散的氟树脂粉末的分散性改进剂; 用于有机树脂的改性剂，其中所述改性剂包括氟树脂粉末和上述分散性改进剂; 最后含有上述改性剂的有机树脂组合物具有形成具有优异表面光滑度的均匀且透明的涂料的能力。氟树脂粉末的分散性改进剂是一种聚有机硅氧烷，其分子含有（F1）至少1个选自有机基团 由聚氧亚烷基官能的有机基团，具有至少12个碳原子的烷基和含聚二烷基硅氧烷链的有机基团组成的组，和（F2）具有通式-R2-X-R1的至少1个全氟烷基官能的有机基团 - （CF 2）a F其中R 1表示C 1至C 10二价烃基，R 2表示C 1至C 20二价烃基，X为式-CO-或-COO-的基团，a为至少为 3。

公开(公告)号：US5777052A

公开(公告)日：1998-07-07

申请号：US886123

申请日：1997-06-30

申请人： Hideki Kobayashi ,  Toru Masatomi

发明人： Hideki Kobayashi ,  Toru Masatomi

IPC分类号： C08F8/42 ,  C08F30/08 ,  C08F220/10 ,  C08F220/12 ,  C08F230/08 ,  C08F290/06 ,  C08L83/02 ,  C09D143/04

CPC分类号： C08F8/42 ,  C08F290/068 ,  C09D143/04 ,  C08L83/02

摘要： This invention relates to a silicone-modified vinyl polymer having a weight-average molecular weight from 1,000 to 1,000,000 containing a siloxane group having the formula (--R.sub.a SiO.sub.(3-a)/2)(F(CF.sub.2).sub.b --R.sup.4 --R.sub.c SiO.sub.3-c)/2).sub.x (R.sub.d SiO.sub.(4-d)/2).sub.y (R.sup.5 O.sub.1/2).sub.z wherein R denotes a monovalent hydrocarbon group free of unsaturated bonding, R.sup.4 denotes an alkylene group or an alkyleneoxyalkylene group, R.sup.5 denotes hydrogen or an alkyl group, a is an integer from 0 to 2, b is an integer with a value of at least 4, c is an integer from 0 to 2, d is an integer from 0 to 3, x is a number greater than 0, and y and z are each numbers with values of 0 or more. The polymers of this invention are useful in forming water repellent and oil repellent coatings.

摘要翻译： 本发明涉及具有式（-RaSiO（3-a）/ 2）（F（CF 2）b -R 4 -R c SiO 3 - ）的硅氧烷基的重均分子量为1,000〜1,000,000的硅氧烷改性乙烯基聚合物， c）/ 2）x（RdSiO（4-d）/ 2）y（R5O1 / 2）z其中R表示不饱和键的一价烃基，R4表示亚烷基或亚烷基氧亚烷基，R5表示氢或 烷基，a为0〜2的整数，b为至少为4的整数，c为0〜2的整数，d为0〜3的整数，x为大于0的数， y和z分别为0以上的数。 本发明的聚合物可用于形成防水和防油涂料。

公开(公告)号：US20070167559A1

公开(公告)日：2007-07-19

申请号：US10562656

申请日：2004-06-25

申请人： Toru Masatomi ,  Motoshi Sasaki ,  Hideki Kobayashi

发明人： Toru Masatomi ,  Motoshi Sasaki ,  Hideki Kobayashi

IPC分类号： C08L33/00

CPC分类号： C09D143/04

摘要： A coating agent composition of the present invention consists of: (A) an acrylic-type copolymer that has a weight-average molecular weight within the range of 3,000 to 100,000 and contains in its side molecular chains hydrolysable silyl groups of the following formula: —COO-Q-SiR2n(OR3)3-n and organosiloxysilyl groups of the following formula: —COO-Q-Si(OSiR43)3; and (B) a condensation-reaction accelerating catalyst. Prior to curing, the composition demonstrates excellent storage stability and coating properties, while after curing the composition produces a coating film of high hardness that has excellent water-repellent properties and durability.

摘要翻译： 本发明的涂料组合物由以下组成：（A）重均分子量在3,000〜100,000的丙烯酸类共聚物，并且在其分子链中含有下式的可水解甲硅烷基： 下式的有机甲硅烷氧基：下式的有机硅氧基甲硅烷基：（C 1 -C 4） -COO-Q-Si（OSiR 4）3 3; 和（B）缩合反应促进催化剂。 在固化之前，组合物表现出优异的储存稳定性和涂布性能，而在固化后，组合物产生具有优异的防水性能和耐久性的高硬度的涂膜。

公开(公告)号：US07019069B2

公开(公告)日：2006-03-28

申请号：US10467137

申请日：2001-02-12

申请人： Hideki Kobayashi ,  Mari Tateishi ,  Toru Masatomi

发明人： Hideki Kobayashi ,  Mari Tateishi ,  Toru Masatomi

IPC分类号： C08L83/04

CPC分类号： C09D183/04 ,  C08L83/00 ,  C08L2666/44 ,  C08L2666/28

摘要： Resinous composition comprising: (A) 100 weight parts of (R2SiO2/2)w(RSiO3/2)x(SiO4/2)y(O1/2R1)z wherein R is selected from the group consisting of monovalent hydrocarbon groups having 1 to 10 carbon atoms, R1 is selected from the group consisting of the hydrogen atom and saturated hydrocarbon groups having from 1 to 6 carbon atoms, w is a number from 0 to 0.2, x is a number from 0.4 to 0.9, y is a number from 0.1 to 0.6, z is a number from 0.1 to 0.5, and (w+x+y)=1; (B) 20 to 150 weight parts of an alcohol-based solvent; (C) 100 to 1000 weight parts of a solvent selected from the group consisting of hydrocarbon-based solvents and polydimethylsiloxanes described by the formula Me3SiO(Me2SiO)nSiMe3, wherein Me is the methyl group and n has a value of 0 or 1; (D) 1 to 100 weight parts of a coupling agent selected from the group consisting of alkoxysilanes and silane coupling agents; (E) 0.1 to 20 weight parts of a condensation catalyst, and (F) 0.1 to 20 weight parts of a polyoxyalkylene-modified silicone.

摘要翻译： 树脂组合物，其包含：（A）100重量份<？在线配方描述=“在线式”末端=“铅”→（R 2 SiO 2/2/2 （SiO 3/2/2）x（SiO 3/2/2）x（SiO 3/2/2） （“O”）1/2“ 其中R选自具有1-10个碳原子的一价烃基，R 1选自氢原子和饱和烃基，其具有 1〜6个碳原子，w为0〜0.2的数，x为0.4〜0.9的数，y为0.1〜0.6的数，z为0.1〜0.5的数，（w + x + y ）= 1; （B）20〜150重量份醇系溶剂; （C）100〜1000重量份选自由式Me 3 SiO（Me 2 SiO 2）表示的烃系溶剂和聚二甲基硅氧烷的溶剂， 其中Me是甲基，n的值为0或1; （D）1〜100重量份选自烷氧基硅烷和硅烷偶联剂的偶联剂; （E）0.1〜20重量份缩合催化剂，（F）0.1〜20重量份聚氧化烯改性硅酮。

公开(公告)号：US06303675B1

公开(公告)日：2001-10-16

申请号：US09507612

申请日：2000-02-21

申请人： Hideki Kobayashi ,  Hiroshi Honma ,  Toru Masatomi

发明人： Hideki Kobayashi ,  Hiroshi Honma ,  Toru Masatomi

IPC分类号： C08L8308

CPC分类号： C08G77/50 ,  C08G77/14 ,  C08G77/20 ,  C08G77/24 ,  C08G77/46 ,  C08L83/04 ,  C08L83/00

摘要： A silicone rubber composition comprising 0.01 to 50 weight percent of a perfluoroalkyl group-containing polydiorganosiloxane having on a side chain (F1) an organic group selected from the group consisting of polyoxyalkylene group-containing organic groups, C12 or higher alkyl group, and polydialkylsiloxane chain-containing organic groups, and having of a side chain or at a molecular chain terminal (F2) a perfluoroalkyl group-containing organic group described by the general formula F(CF2)a—R1—, where R1 is selected from the group consisting of an alkylene group, an alkyleneoxyalkylene group, and a group in which ═CO or —COO— is present in an alkylelne chain, and a is an integer of at least 3, and having a weight average molecular weight of at least 1000.

摘要翻译： 一种硅橡胶组合物，其包含0.01至50重量％的含侧链（F1）的含全氟烷基的聚二有机硅氧烷，选自含有聚氧化烯基的有机基团，C12或更高级烷基的基团和聚二烷基硅氧烷链 含有有机基团，并且具有侧链或分子链末端（F2），由通式R 1表示的含全氟烷基的有机基团选自亚烷基，亚烷基氧化烯基和 基团，其中= CO或-COO-存在于烷基链中，a为至少3的整数，重均分子量为至少1000。