公开(公告)号：US07795360B2

公开(公告)日：2010-09-14

申请号：US10562656

申请日：2004-06-25

申请人： Toru Masatomi ,  Motoshi Sasaki ,  Hideki Kobayashi

发明人： Toru Masatomi ,  Motoshi Sasaki ,  Hideki Kobayashi

IPC分类号： C08F30/08

CPC分类号： C09D143/04

摘要： A coating agent composition of the present invention consists of: (A) an acrylic-type copolymer that has a weight-average molecular weight within the range of 3,000 to 100,000 and contains in its side molecular chains hydrolysable silyl groups of the following formula: —COO-Q-SiR2n(OR3)3-n and organosiloxysilyl groups of the following formula: —COO-Q-Si(OSiR43)3; and (B) a condensation-reaction accelerating catalyst. Prior to curing, the composition demonstrates excellent storage stability and coating properties, while after curing the composition produces a coating film of high hardness that has excellent water-repellent properties and durability.

摘要翻译： 本发明的涂料组合物由以下组成：（A）重均分子量在3,000〜100,000的丙烯酸类共聚物，并且在其分子链中含有下式的可水解甲硅烷基： COO-Q-SiR2n（OR3）3-n和下式的有机硅氧甲硅烷基：-COO-Q-Si（OSiR43）3; 和（B）缩合反应促进催化剂。 在固化之前，组合物表现出优异的储存稳定性和涂布性能，而在固化后，组合物产生具有优异的防水性能和耐久性的高硬度的涂膜。

公开(公告)号：US20070167559A1

公开(公告)日：2007-07-19

申请号：US10562656

申请日：2004-06-25

申请人： Toru Masatomi ,  Motoshi Sasaki ,  Hideki Kobayashi

发明人： Toru Masatomi ,  Motoshi Sasaki ,  Hideki Kobayashi

IPC分类号： C08L33/00

CPC分类号： C09D143/04

摘要： A coating agent composition of the present invention consists of: (A) an acrylic-type copolymer that has a weight-average molecular weight within the range of 3,000 to 100,000 and contains in its side molecular chains hydrolysable silyl groups of the following formula: —COO-Q-SiR2n(OR3)3-n and organosiloxysilyl groups of the following formula: —COO-Q-Si(OSiR43)3; and (B) a condensation-reaction accelerating catalyst. Prior to curing, the composition demonstrates excellent storage stability and coating properties, while after curing the composition produces a coating film of high hardness that has excellent water-repellent properties and durability.

摘要翻译： 本发明的涂料组合物由以下组成：（A）重均分子量在3,000〜100,000的丙烯酸类共聚物，并且在其分子链中含有下式的可水解甲硅烷基： 下式的有机甲硅烷氧基：下式的有机硅氧基甲硅烷基：（C 1 -C 4） -COO-Q-Si（OSiR 4）3 3; 和（B）缩合反应促进催化剂。 在固化之前，组合物表现出优异的储存稳定性和涂布性能，而在固化后，组合物产生具有优异的防水性能和耐久性的高硬度的涂膜。

公开(公告)号：US07368500B2

公开(公告)日：2008-05-06

申请号：US10484128

申请日：2002-07-26

申请人： Hideki Kobayashi ,  Motoshi Sasaki ,  Toru Masatomi

发明人： Hideki Kobayashi ,  Motoshi Sasaki ,  Toru Masatomi

IPC分类号： C08L83/06

CPC分类号： C09D183/10 ,  C08G77/44

摘要： A film-forming silicone resin composition, comprising a reaction product obtained by a method comprising the step of heating (A) an alkoxysilyl-functional organopolysiloxane obtained by running an equilibration reaction with components comprising (A1) a polydiorganosiloxane and (A2) an alkylpolysilicate in the presence of (A3) an equilibration polymerization catalyst; (B) colloidal silica, aluminum oxide, antimony oxide, titanium oxide, or zirconium oxide; and (C) water, and a curable film-forming silicone resin composition, comprising above film-forming silicone resin composition and (E) a condensation reaction catalyst.

摘要翻译： 一种成膜有机硅树脂组合物，其包含通过包括以下步骤的方法获得的反应产物：（A）通过与包含（A1）聚二有机硅氧烷和（A2）聚烷基硅酸盐的组分进行平衡反应获得的烷氧基甲硅烷基官能的有机聚硅氧烷 （A3）平衡聚合催化剂的存在; （B）胶体二氧化硅，氧化铝，氧化锑，氧化钛或氧化锆; 和（C）水，以及包含上述成膜硅树脂组合物和（E）缩合反应催化剂的可固化成膜硅树脂组合物。

公开(公告)号：US07074874B2

公开(公告)日：2006-07-11

申请号：US10481155

申请日：2002-06-27

申请人： Hideki Kobayashi ,  Motoshi Sasaki ,  Toru Masatomi

发明人： Hideki Kobayashi ,  Motoshi Sasaki ,  Toru Masatomi

IPC分类号： C08G77/06

CPC分类号： C08G77/38 ,  C08G77/04 ,  C08G77/10 ,  C08G77/18 ,  C08G77/44 ,  Y02P20/582

摘要： Liquid alkoxysilyl-functional silicone resins having excellent storage stability and a method of preparing these liquid alkoxysilyl-functional silicone resins comprising running an equilibration polymerization reaction with components comprising (A) a polydiorganosiloxane and (B) an alkyl polysilicate in the presence of (C) an equilibration polymerization catalyst. Curable silicone resin compositions comprising the aforesaid liquid alkoxy-functional silicone resins which have excellent curability and when cured form a water-repellent coating on a variety of substrate surfaces.

摘要翻译： 包括具有优异的储存稳定性的液体烷氧基甲硅烷基官能的有机硅树脂和制备这些液体烷氧基甲硅烷基官能的有机硅树脂的方法，包括在（C）存在下，使（A）聚二有机硅氧烷和（B）聚硅酸烷基酯的组分进行平衡聚合反应， 平衡聚合催化剂。 可固化的有机硅树脂组合物包含上述具有优异固化性的液体烷氧基官能的有机硅树脂，并且当固化时形成各种基材表面上的拒水涂料。

公开(公告)号：US09273224B2

公开(公告)日：2016-03-01

申请号：US12993575

申请日：2009-06-03

申请人： Satoshi Onodera ,  Toru Masatomi ,  Motoshi Sasaki

发明人： Satoshi Onodera ,  Toru Masatomi ,  Motoshi Sasaki

IPC分类号： C09D143/04

CPC分类号： C09D143/04

摘要： To provide a coating agent composition that cures to form a transparent film that exhibits a high water repellency, a high durability, and an excellent adhesiveness to substrate. A coating agent composition that characteristically comprises (A) an acrylic copolymer obtained by the radical copolymerization of (A1) 1 mole silane compound represented by the general formula: CH2═C(R1)—COO-Q-SiR2n(OR3)3-n, (A2) 3.70 to 6.20 moles of at least one compound that contains a vinyl polymerizable unsaturated bond, and (A3) 1.05 to 1.80 moles of a siloxysilane compound represented by general formula (2): CH2═C(R1)—COO-Q-Si(OSiR43)3 at an molar ratio (A1)/{(A1)+(A2)+(A3)}=0.11 to 0.17; and (B) a condensation reaction catalyst.

摘要翻译： 提供固化形成透明膜的涂布剂组合物，其具有高斥水性，高耐久性和对基材的优异粘附性。 一种涂料组合物，其特征在于包含（A）通过（A1）由通式：CH2 = C（R1）-COO-Q-SiR2n（OR3）3-n表示的1摩尔硅烷化合物的自由基共聚获得的丙烯酸共聚物 ，（A2）3.70〜6.20摩尔含有乙烯基聚合性不饱和键的至少一种化合物，（A3）1.05〜1.80摩尔由通式（2）表示的硅氧烷硅烷化合物：CH 2 = C（R 1）-COO- 摩尔比（A1）/ {（A1）+（A2）+（A3）}的Q-Si（OSiR43）3 = 0.11〜0.17; 和（B）缩合反应催化剂。

公开(公告)号：US20110124800A1

公开(公告)日：2011-05-26

申请号：US12993575

申请日：2009-06-03

申请人： Satoshi Onodera ,  Toru Masatomi ,  Motoshi Sasaki

发明人： Satoshi Onodera ,  Toru Masatomi ,  Motoshi Sasaki

IPC分类号： C09D133/08

CPC分类号： C09D143/04

摘要： To provide a coating agent composition that cures to form a transparent film that exhibits a high water repellency, a high durability, and an excellent adhesiveness to substrate. A coating agent composition that characteristically comprises (A) an acrylic copolymer obtained by the radical copolymerization of (A1) 1 mole silane compound represented by the general formula: CH2═C(R1)—COO-Q-SiR2n(OR3)3-n, (A2) 3.70 to 6.20 moles of at least one compound that contains a vinyl polymerizable unsaturated bond, and (A3) 1.05 to 1.80 moles of a siloxysilane compound represented by general formula (2): CH2═C(R1)—COO-Q-Si(OSiR43)3 at an molar ratio (A1)/{(A1)+(A2)+(A3)}=0.11 to 0.17; and (B) a condensation reaction catalyst.

摘要翻译： 提供固化形成透明膜的涂布剂组合物，其具有高斥水性，高耐久性和对基材的优异粘附性。 一种涂料组合物，其特征在于包含（A）通过（A1）由通式：CH2 = C（R1）-COO-Q-SiR2n（OR3）3-n表示的1摩尔硅烷化合物的自由基共聚获得的丙烯酸共聚物 ，（A2）3.70〜6.20摩尔含有乙烯基聚合性不饱和键的至少一种化合物，（A3）1.05〜1.80摩尔由通式（2）表示的硅氧烷硅烷化合物：CH 2 = C（R 1）-COO- 摩尔比（A1）/ {（A1）+（A2）+（A3）}的Q-Si（OSiR43）3 = 0.11〜0.17; 和（B）缩合反应催化剂。

公开(公告)号：US20130338265A1

公开(公告)日：2013-12-19

申请号：US13997767

申请日：2011-12-27

申请人： Toru Masatomi ,  Takeshi Yoshizawa ,  Yoshitsugu Morita ,  Motoshi Sasaki

发明人： Toru Masatomi ,  Takeshi Yoshizawa ,  Yoshitsugu Morita ,  Motoshi Sasaki

IPC分类号： C08K5/5419

CPC分类号： C08K5/5419 ,  C08G59/621 ,  C08G77/14 ,  C08G77/80 ,  H01L23/296 ,  H01L2924/0002 ,  C08L63/00 ,  C08L83/06 ,  H01L2924/00

摘要： To provide a curable epoxy resin composition that exhibits excellent fluidity during molding without having adverse effects on the physical properties of the cured material. A curable epoxy resin composition, containing (I) a curable epoxy resin, and (II) an epoxy functional group- and aromatic hydrocarbon group-containing organopolysiloxane having an epoxy equivalent weight of 3,000 or lower, a content of aromatic hydrocarbon groups of 45 to 80% by weight (mass), and a glass transition point of less than 0° C.

摘要翻译： 提供在成型时表现出优异的流动性而对固化材料的物理性能没有不利影响的可固化环氧树脂组合物。 一种可固化环氧树脂组合物，其包含（I）可固化环氧树脂，和（II）环氧当量为3,000以下的环氧官能团和芳香族烃基的有机聚硅氧烷，芳香族烃基的含量为45〜 80重量％（质量），玻璃化转变点小于0℃

公开(公告)号：US06174966B1

公开(公告)日：2001-01-16

申请号：US09301258

申请日：1999-04-28

申请人： Hideki Kobayashi ,  Toru Masatomi

发明人： Hideki Kobayashi ,  Toru Masatomi

IPC分类号： C08G1844

CPC分类号： C09D169/00 ,  C09D167/03 ,  C08L2666/44

摘要： A coating agent composition, comprising (A) 100 parts by weight of a polymer having at least two alkoxysilyl groups, wherein the polymer has a number average molecular weight of 500 to 500,000, the polymer has a principal chain comprising a polycarbonate or a polyarylate, and the alkoxysilyl groups in the polymer have the formula —SiR3−a(OR′)a, wherein R is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms, R′ is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 8 carbon atoms, and a is from 1 to 3; (B) 50 to 2,000 parts by weight of an organic solvent; (C) 1 to 90 parts by weight of an organosilane, wherein the organosilane is a compound having the formula R″eSiY4−e or a partially hydrolyzed condensate thereof, wherein R″ is a substituted or unsubstituted monovalent hydrocarbon group or a hydrogen atom, Y is a hydrolyzable group, and e is from 0 to 2; and (D) a cure catalyst in an amount sufficient to cure the composition. A method of preparing a coating agent composition and a coating agent prepared by curing the composition.

摘要翻译： 一种涂料组合物，其包含（A）100重量份具有至少两个烷氧基甲硅烷基的聚合物，其中所述聚合物的数均分子量为500至500,000，所述聚合物具有包含聚碳酸酯或多芳基化合物的主链， 聚合物中的烷氧基甲硅烷基具有式-SiR 3-a（OR'）a，其中R为取代或未取代的碳原子数为1〜10的一价烃基，R'为取代或未取代的1价〜 8个碳原子，a为1至3; （B）50〜2000重量份的有机溶剂; （C）1〜90重量份的有机硅烷，其中有机硅烷为具有式R''eSiY4-e或其部分水解缩合物的化合物，其中R“为取代或未取代的单价烃基或氢 Y为可水解基团，e为0〜2; 和（D）固化催化剂，其量足以固化组合物。 一种制备包衣剂组合物的方法和通过固化该组合物制备的包衣剂。

公开(公告)号：US06251975B1

公开(公告)日：2001-06-26

申请号：US09345333

申请日：1999-06-30

申请人： Hideki Kobayashi ,  Toru Masatomi

发明人： Hideki Kobayashi ,  Toru Masatomi

IPC分类号： C08G7724

CPC分类号： C08G77/24 ,  C08L83/08

摘要： This invention pertains to a dispersibility improver for fluororesin powders that has the ability to induce the uniform dispersion of fluororesin powders in organic resins; a modifier for application to organic resins wherein said modifier comprises fluororesin powder and the aforesaid dispersibility improver; and finally organic resin compositions that contain the aforesaid modifier and as a consequence have the ability to form uniform and transparent coatings having an excellent surface smoothness. The dispersibility improver for fluororesin powders is a polyorganosiloxane whose molecule contains (F1) at least 1 organic group selected from the group consisting of polyoxyalkylene-functional organic groups, alkyl groups having at least 12 carbon atoms, and polydialkylsiloxane chain-containing organic groups, and (F2) at least 1 perfluoroalkyl-functional organic group with the general formula —R2—X—R1—(CF2)aF wherein R1 represents C1 to C10 divalent hydrocarbon groups, R2 represents C1 to C20 divalent hydrocarbon groups, X is a group with the formula —CO— or —COO—, and a is an integer with a value of at least 3.

摘要翻译： 本发明涉及能够诱导氟树脂粉末在有机树脂中均匀分散的氟树脂粉末的分散性改进剂; 用于有机树脂的改性剂，其中所述改性剂包括氟树脂粉末和上述分散性改进剂; 最后含有上述改性剂的有机树脂组合物具有形成具有优异表面光滑度的均匀且透明的涂料的能力。氟树脂粉末的分散性改进剂是一种聚有机硅氧烷，其分子含有（F1）至少1个选自有机基团 由聚氧亚烷基官能的有机基团，具有至少12个碳原子的烷基和含聚二烷基硅氧烷链的有机基团组成的组，和（F2）具有通式-R2-X-R1的至少1个全氟烷基官能的有机基团 - （CF 2）a F其中R 1表示C 1至C 10二价烃基，R 2表示C 1至C 20二价烃基，X为式-CO-或-COO-的基团，a为至少为 3。

公开(公告)号：US5777052A

公开(公告)日：1998-07-07

申请号：US886123

申请日：1997-06-30

申请人： Hideki Kobayashi ,  Toru Masatomi

发明人： Hideki Kobayashi ,  Toru Masatomi

IPC分类号： C08F8/42 ,  C08F30/08 ,  C08F220/10 ,  C08F220/12 ,  C08F230/08 ,  C08F290/06 ,  C08L83/02 ,  C09D143/04

CPC分类号： C08F8/42 ,  C08F290/068 ,  C09D143/04 ,  C08L83/02

摘要： This invention relates to a silicone-modified vinyl polymer having a weight-average molecular weight from 1,000 to 1,000,000 containing a siloxane group having the formula (--R.sub.a SiO.sub.(3-a)/2)(F(CF.sub.2).sub.b --R.sup.4 --R.sub.c SiO.sub.3-c)/2).sub.x (R.sub.d SiO.sub.(4-d)/2).sub.y (R.sup.5 O.sub.1/2).sub.z wherein R denotes a monovalent hydrocarbon group free of unsaturated bonding, R.sup.4 denotes an alkylene group or an alkyleneoxyalkylene group, R.sup.5 denotes hydrogen or an alkyl group, a is an integer from 0 to 2, b is an integer with a value of at least 4, c is an integer from 0 to 2, d is an integer from 0 to 3, x is a number greater than 0, and y and z are each numbers with values of 0 or more. The polymers of this invention are useful in forming water repellent and oil repellent coatings.

摘要翻译： 本发明涉及具有式（-RaSiO（3-a）/ 2）（F（CF 2）b -R 4 -R c SiO 3 - ）的硅氧烷基的重均分子量为1,000〜1,000,000的硅氧烷改性乙烯基聚合物， c）/ 2）x（RdSiO（4-d）/ 2）y（R5O1 / 2）z其中R表示不饱和键的一价烃基，R4表示亚烷基或亚烷基氧亚烷基，R5表示氢或 烷基，a为0〜2的整数，b为至少为4的整数，c为0〜2的整数，d为0〜3的整数，x为大于0的数， y和z分别为0以上的数。 本发明的聚合物可用于形成防水和防油涂料。