公开(公告)号：US20070167559A1

公开(公告)日：2007-07-19

申请号：US10562656

申请日：2004-06-25

申请人： Toru Masatomi ,  Motoshi Sasaki ,  Hideki Kobayashi

发明人： Toru Masatomi ,  Motoshi Sasaki ,  Hideki Kobayashi

IPC分类号： C08L33/00

CPC分类号： C09D143/04

摘要： A coating agent composition of the present invention consists of: (A) an acrylic-type copolymer that has a weight-average molecular weight within the range of 3,000 to 100,000 and contains in its side molecular chains hydrolysable silyl groups of the following formula: —COO-Q-SiR2n(OR3)3-n and organosiloxysilyl groups of the following formula: —COO-Q-Si(OSiR43)3; and (B) a condensation-reaction accelerating catalyst. Prior to curing, the composition demonstrates excellent storage stability and coating properties, while after curing the composition produces a coating film of high hardness that has excellent water-repellent properties and durability.

摘要翻译： 本发明的涂料组合物由以下组成：（A）重均分子量在3,000〜100,000的丙烯酸类共聚物，并且在其分子链中含有下式的可水解甲硅烷基： 下式的有机甲硅烷氧基：下式的有机硅氧基甲硅烷基：（C 1 -C 4） -COO-Q-Si（OSiR 4）3 3; 和（B）缩合反应促进催化剂。 在固化之前，组合物表现出优异的储存稳定性和涂布性能，而在固化后，组合物产生具有优异的防水性能和耐久性的高硬度的涂膜。

公开(公告)号：US07368500B2

公开(公告)日：2008-05-06

申请号：US10484128

申请日：2002-07-26

申请人： Hideki Kobayashi ,  Motoshi Sasaki ,  Toru Masatomi

发明人： Hideki Kobayashi ,  Motoshi Sasaki ,  Toru Masatomi

IPC分类号： C08L83/06

CPC分类号： C09D183/10 ,  C08G77/44

摘要： A film-forming silicone resin composition, comprising a reaction product obtained by a method comprising the step of heating (A) an alkoxysilyl-functional organopolysiloxane obtained by running an equilibration reaction with components comprising (A1) a polydiorganosiloxane and (A2) an alkylpolysilicate in the presence of (A3) an equilibration polymerization catalyst; (B) colloidal silica, aluminum oxide, antimony oxide, titanium oxide, or zirconium oxide; and (C) water, and a curable film-forming silicone resin composition, comprising above film-forming silicone resin composition and (E) a condensation reaction catalyst.

摘要翻译： 一种成膜有机硅树脂组合物，其包含通过包括以下步骤的方法获得的反应产物：（A）通过与包含（A1）聚二有机硅氧烷和（A2）聚烷基硅酸盐的组分进行平衡反应获得的烷氧基甲硅烷基官能的有机聚硅氧烷 （A3）平衡聚合催化剂的存在; （B）胶体二氧化硅，氧化铝，氧化锑，氧化钛或氧化锆; 和（C）水，以及包含上述成膜硅树脂组合物和（E）缩合反应催化剂的可固化成膜硅树脂组合物。

公开(公告)号：US07074874B2

公开(公告)日：2006-07-11

申请号：US10481155

申请日：2002-06-27

申请人： Hideki Kobayashi ,  Motoshi Sasaki ,  Toru Masatomi

发明人： Hideki Kobayashi ,  Motoshi Sasaki ,  Toru Masatomi

IPC分类号： C08G77/06

CPC分类号： C08G77/38 ,  C08G77/04 ,  C08G77/10 ,  C08G77/18 ,  C08G77/44 ,  Y02P20/582

摘要： Liquid alkoxysilyl-functional silicone resins having excellent storage stability and a method of preparing these liquid alkoxysilyl-functional silicone resins comprising running an equilibration polymerization reaction with components comprising (A) a polydiorganosiloxane and (B) an alkyl polysilicate in the presence of (C) an equilibration polymerization catalyst. Curable silicone resin compositions comprising the aforesaid liquid alkoxy-functional silicone resins which have excellent curability and when cured form a water-repellent coating on a variety of substrate surfaces.

摘要翻译： 包括具有优异的储存稳定性的液体烷氧基甲硅烷基官能的有机硅树脂和制备这些液体烷氧基甲硅烷基官能的有机硅树脂的方法，包括在（C）存在下，使（A）聚二有机硅氧烷和（B）聚硅酸烷基酯的组分进行平衡聚合反应， 平衡聚合催化剂。 可固化的有机硅树脂组合物包含上述具有优异固化性的液体烷氧基官能的有机硅树脂，并且当固化时形成各种基材表面上的拒水涂料。

公开(公告)号：US07795360B2

公开(公告)日：2010-09-14

申请号：US10562656

申请日：2004-06-25

申请人： Toru Masatomi ,  Motoshi Sasaki ,  Hideki Kobayashi

发明人： Toru Masatomi ,  Motoshi Sasaki ,  Hideki Kobayashi

IPC分类号： C08F30/08

CPC分类号： C09D143/04

摘要： A coating agent composition of the present invention consists of: (A) an acrylic-type copolymer that has a weight-average molecular weight within the range of 3,000 to 100,000 and contains in its side molecular chains hydrolysable silyl groups of the following formula: —COO-Q-SiR2n(OR3)3-n and organosiloxysilyl groups of the following formula: —COO-Q-Si(OSiR43)3; and (B) a condensation-reaction accelerating catalyst. Prior to curing, the composition demonstrates excellent storage stability and coating properties, while after curing the composition produces a coating film of high hardness that has excellent water-repellent properties and durability.

摘要翻译： 本发明的涂料组合物由以下组成：（A）重均分子量在3,000〜100,000的丙烯酸类共聚物，并且在其分子链中含有下式的可水解甲硅烷基： COO-Q-SiR2n（OR3）3-n和下式的有机硅氧甲硅烷基：-COO-Q-Si（OSiR43）3; 和（B）缩合反应促进催化剂。 在固化之前，组合物表现出优异的储存稳定性和涂布性能，而在固化后，组合物产生具有优异的防水性能和耐久性的高硬度的涂膜。

公开(公告)号：US20110124800A1

公开(公告)日：2011-05-26

申请号：US12993575

申请日：2009-06-03

申请人： Satoshi Onodera ,  Toru Masatomi ,  Motoshi Sasaki

发明人： Satoshi Onodera ,  Toru Masatomi ,  Motoshi Sasaki

IPC分类号： C09D133/08

CPC分类号： C09D143/04

摘要： To provide a coating agent composition that cures to form a transparent film that exhibits a high water repellency, a high durability, and an excellent adhesiveness to substrate. A coating agent composition that characteristically comprises (A) an acrylic copolymer obtained by the radical copolymerization of (A1) 1 mole silane compound represented by the general formula: CH2═C(R1)—COO-Q-SiR2n(OR3)3-n, (A2) 3.70 to 6.20 moles of at least one compound that contains a vinyl polymerizable unsaturated bond, and (A3) 1.05 to 1.80 moles of a siloxysilane compound represented by general formula (2): CH2═C(R1)—COO-Q-Si(OSiR43)3 at an molar ratio (A1)/{(A1)+(A2)+(A3)}=0.11 to 0.17; and (B) a condensation reaction catalyst.

摘要翻译： 提供固化形成透明膜的涂布剂组合物，其具有高斥水性，高耐久性和对基材的优异粘附性。 一种涂料组合物，其特征在于包含（A）通过（A1）由通式：CH2 = C（R1）-COO-Q-SiR2n（OR3）3-n表示的1摩尔硅烷化合物的自由基共聚获得的丙烯酸共聚物 ，（A2）3.70〜6.20摩尔含有乙烯基聚合性不饱和键的至少一种化合物，（A3）1.05〜1.80摩尔由通式（2）表示的硅氧烷硅烷化合物：CH 2 = C（R 1）-COO- 摩尔比（A1）/ {（A1）+（A2）+（A3）}的Q-Si（OSiR43）3 = 0.11〜0.17; 和（B）缩合反应催化剂。

公开(公告)号：US09273224B2

公开(公告)日：2016-03-01

申请号：US12993575

申请日：2009-06-03

申请人： Satoshi Onodera ,  Toru Masatomi ,  Motoshi Sasaki

发明人： Satoshi Onodera ,  Toru Masatomi ,  Motoshi Sasaki

IPC分类号： C09D143/04

CPC分类号： C09D143/04

摘要： To provide a coating agent composition that cures to form a transparent film that exhibits a high water repellency, a high durability, and an excellent adhesiveness to substrate. A coating agent composition that characteristically comprises (A) an acrylic copolymer obtained by the radical copolymerization of (A1) 1 mole silane compound represented by the general formula: CH2═C(R1)—COO-Q-SiR2n(OR3)3-n, (A2) 3.70 to 6.20 moles of at least one compound that contains a vinyl polymerizable unsaturated bond, and (A3) 1.05 to 1.80 moles of a siloxysilane compound represented by general formula (2): CH2═C(R1)—COO-Q-Si(OSiR43)3 at an molar ratio (A1)/{(A1)+(A2)+(A3)}=0.11 to 0.17; and (B) a condensation reaction catalyst.

摘要翻译： 提供固化形成透明膜的涂布剂组合物，其具有高斥水性，高耐久性和对基材的优异粘附性。 一种涂料组合物，其特征在于包含（A）通过（A1）由通式：CH2 = C（R1）-COO-Q-SiR2n（OR3）3-n表示的1摩尔硅烷化合物的自由基共聚获得的丙烯酸共聚物 ，（A2）3.70〜6.20摩尔含有乙烯基聚合性不饱和键的至少一种化合物，（A3）1.05〜1.80摩尔由通式（2）表示的硅氧烷硅烷化合物：CH 2 = C（R 1）-COO- 摩尔比（A1）/ {（A1）+（A2）+（A3）}的Q-Si（OSiR43）3 = 0.11〜0.17; 和（B）缩合反应催化剂。

公开(公告)号：US20130338265A1

公开(公告)日：2013-12-19

申请号：US13997767

申请日：2011-12-27

申请人： Toru Masatomi ,  Takeshi Yoshizawa ,  Yoshitsugu Morita ,  Motoshi Sasaki

发明人： Toru Masatomi ,  Takeshi Yoshizawa ,  Yoshitsugu Morita ,  Motoshi Sasaki

IPC分类号： C08K5/5419

CPC分类号： C08K5/5419 ,  C08G59/621 ,  C08G77/14 ,  C08G77/80 ,  H01L23/296 ,  H01L2924/0002 ,  C08L63/00 ,  C08L83/06 ,  H01L2924/00

摘要： To provide a curable epoxy resin composition that exhibits excellent fluidity during molding without having adverse effects on the physical properties of the cured material. A curable epoxy resin composition, containing (I) a curable epoxy resin, and (II) an epoxy functional group- and aromatic hydrocarbon group-containing organopolysiloxane having an epoxy equivalent weight of 3,000 or lower, a content of aromatic hydrocarbon groups of 45 to 80% by weight (mass), and a glass transition point of less than 0° C.

摘要翻译： 提供在成型时表现出优异的流动性而对固化材料的物理性能没有不利影响的可固化环氧树脂组合物。 一种可固化环氧树脂组合物，其包含（I）可固化环氧树脂，和（II）环氧当量为3,000以下的环氧官能团和芳香族烃基的有机聚硅氧烷，芳香族烃基的含量为45〜 80重量％（质量），玻璃化转变点小于0℃

公开(公告)号：US20060281889A1

公开(公告)日：2006-12-14

申请号：US10478158

申请日：2002-05-27

申请人： Hideki Kobayashi ,  Motoshi Sasaki

发明人： Hideki Kobayashi ,  Motoshi Sasaki

IPC分类号： C08G77/18 ,  C08G77/08

CPC分类号： C08L83/14 ,  C08G77/18 ,  C08G77/50 ,  C08L83/04 ,  C09D183/04 ,  C09D183/14

摘要： A silicone composition for a water-repellent coating comprising (A) a polydimethylsiloxane expressed by the general formula: (RO)3Si-Q-{(CH3)2SiO}n—(CH3)2Si-Q-Si(OR)3, where R is a C1 to C10 monovalent hydrocarbon group, Q is an oxygen atom or a C2 to C10 alkylene group, and n is an integer from 10 to 1000; (B) an alkoxysilane partial hydrolysate/condensate, where the alkoxysilane is described by general formula: R1xSi(OR2)4-x, where R1 is a C1 to C6 monovalent hydrocarbon group, R2 is a C1 to C6 alkyl group, and x is an integer from 0 to 3; (C) an organotitanium-based catalyst; (D) an aliphatic hydrocarbon solvent or ester-based solvent; and (E) an alcohol-based solvent.

摘要翻译： 用于防水涂料的硅氧烷组合物，其包含（A）由以下通式表示的聚二甲基硅氧烷：<？in-line-formula description =“In-Line Formulas”end =“lead”？>（RO）3 Si-Q - {（CH 3 3）2 SiO} - （CH 3 3） 2-Si-Q-Si（OR）3 <3，<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R是 C 1至C 10的一价烃基，Q为氧原子或C 2至C 10亚烷基， 亚烷基，n为10〜1000的整数， （B）烷氧基硅烷部分水解产物/缩合物，其中烷氧基硅烷由下列通式描述：R 1 Si（OR 2）_{是C 6〜C 6的烷基，x是0〜3的整数; （C）有机钛基催化剂; （D）脂族烃溶剂或酯类溶剂; 和（E）醇类溶剂。}

公开(公告)号：US06706798B2

公开(公告)日：2004-03-16

申请号：US09997749

申请日：2001-11-29

申请人： Hideki Kobayashi ,  Motoshi Sasaki

发明人： Hideki Kobayashi ,  Motoshi Sasaki

IPC分类号： C08K336

CPC分类号： C09D183/04 ,  C08L83/00 ,  C08L2666/44 ,  C08L2666/54

摘要： A water repellent silicone coating agent composition comprising (A) a diorganopolysiloxane having a viscosity of 20 to 20,000 mPa·s at 25° C. in which the terminal ends of the molecular chain are blocked by silanol groups or silicon-bonded hydrolyzable groups, (B) a cross-linking agent represented by general formula RaSiX4-a, in which R is a monovalent hydrocarbon group comprising 1 to 10 carbon atoms, X is a hydrolyzable group, and subscript a is an integer of 0 to 2, (C) a condensation reaction catalyst, (D) a hydrophobic surface treated dry process silica having a carbon content of 3.7 to 5% by weight and a bulk density of 40 to 99 g/L, or a hydrophobic surface treated dry process silica having a carbon content of 2.7 to 5% by weight and a bulk density of 100 to 300 g/L, (E) an organic functional silane coupling agent-based adhesion-imparting agent, (F) an organic solvent, and optionally (G) a non-reactive silicone fluid.

摘要翻译： 一种防水硅氧烷涂层剂组合物，其包含（A）在25℃下粘度为20〜20,000mPa.s的二有机聚硅氧烷，其中分子链的末端被硅烷醇基或硅键合的可水解基团封闭（ B）由通式RaSiX4-a表示的交联剂，其中R是含有1至10个碳原子的一价烃基，X是可水解基团，下标a是0-2的整数，（C） 缩合反应催化剂，（D）碳含量为3.7〜5重量％，堆积密度为40〜99g / L的疏水性表面处理的干法二氧化硅，或具有碳含量的疏水性表面处理的干法二氧化硅 （E）为有机官能硅烷偶联剂的粘合赋予剂，（F）有机溶剂和任选的（G）非离子表面活性剂， 反应性硅液。

公开(公告)号：US09175177B2

公开(公告)日：2015-11-03

申请号：US12523914

申请日：2008-01-18

申请人： Masaru Nagato ,  Masahiko Maeda ,  Tetsuya Masutani ,  Satoshi Onodera ,  Eiji Kitaura ,  Motoshi Sasaki ,  Peter Cheshire Hupfield

发明人： Masaru Nagato ,  Masahiko Maeda ,  Tetsuya Masutani ,  Satoshi Onodera ,  Eiji Kitaura ,  Motoshi Sasaki ,  Peter Cheshire Hupfield

IPC分类号： C09D7/12 ,  C09D167/00 ,  C08G77/24 ,  C08K5/54 ,  C08L61/20 ,  C08L83/02

CPC分类号： C09D7/1233 ,  C08G77/24 ,  C08K5/5406 ,  C08L61/20 ,  C08L83/02 ,  C09D7/63 ,  C09D167/00 ,  C08L83/00 ,  C08L2666/02

摘要： There is provided a polyester coating composition having excellent action of preventing deposition of outdoor stain and stain caused by rainfall, being capable of extending a period of time (pot life) from the mixing to the coating, and comprising (A) a polyester resin, (B) one or more of fluorine-containing organosilicon compounds having a fluorine content of 5 to 30% by mass, (C) one or more of aliphatic hydrocarbon compounds having hydroxyl group and 1 to 10 carbon atoms, in which a part of hydrogen atoms bonded to carbon atom may be substituted by fluorine atoms and/or one or more of alkoxy compounds having 2 to 10 carbon atoms, in which a part of hydrogen atoms bonded to carbon atom may be substituted by fluorine atoms, and (D) an organic solvent.

摘要翻译： 提供一种具有防止室外污渍沉积和由降雨引起的污渍的能够延长从混合到涂层的时间（适用期）的聚酯涂料组合物，并且包含（A）聚酯树脂， （B）一种或多种氟含量为5〜30质量％的含氟有机硅化合物，（C）一种或多种具有羟基和1至10个碳原子的脂族烃化合物，其中一部分氢 与碳原子键合的原子可以被氟原子和/或一个或多个具有2-10个碳原子的烷氧基化合物取代，其中一部分与碳原子键合的氢原子可以被氟原子取代，和（D） 有机溶剂。