公开(公告)号：US06509099B1

公开(公告)日：2003-01-21

申请号：US09627877

申请日：2000-07-28

申请人： Kazuya Urata ,  Takahiro Kubota ,  Masaru Sagiyama ,  Satoru Ando ,  Tatsuya Miyoshi ,  Masaaki Yamashita

发明人： Kazuya Urata ,  Takahiro Kubota ,  Masaru Sagiyama ,  Satoru Ando ,  Tatsuya Miyoshi ,  Masaaki Yamashita

IPC分类号： B32B2700

CPC分类号： B05D7/51 ,  B05D7/14 ,  C23C22/365 ,  C23C22/368 ,  C23C22/73 ,  C23C22/83 ,  Y10T428/31551

摘要： A phosphate-treated steel plate comprises a zinc-base plated steel plate; a zinc phosphate coating layer formed on the surface of the zinc-base plated steel plate; and an organic or inorganic coating formed on the zinc phosphate coating layer. The organic coating comprises at least one organic resin selected from the group consisting of an ethylene-base resin, an epoxy-base resin, a urethane-base resin, and an acrylic-base resin. The inorganic coating comprises a phosphate coating consisting mainly of a phosphate.

摘要翻译： 磷酸盐处理钢板包括锌基电镀钢板; 形成在镀锌钢板的表面上的磷酸锌被膜层; 以及形成在磷酸锌涂层上的有机或无机涂层。 有机涂层包括至少一种选自乙烯基树脂，环氧基树脂，氨基甲酸酯基树脂和丙烯酸基树脂的有机树脂。 无机涂层包括主要由磷酸盐组成的磷酸盐涂层。

公开(公告)号：US06562474B1

公开(公告)日：2003-05-13

申请号：US09603889

申请日：2000-06-26

申请人： Naoto Yoshimi ,  Satoru Ando ,  Masaru Sagiyama ,  Akihiko Furuta ,  Masaaki Yamashita ,  Akira Matsuzaki ,  Takafumi Yamaji ,  Tatsuya Miyoshi ,  Takahiro Kubota ,  Yasuhiko Haruta ,  Hiroyasu Matsuki ,  Kenichi Tomita

发明人： Naoto Yoshimi ,  Satoru Ando ,  Masaru Sagiyama ,  Akihiko Furuta ,  Masaaki Yamashita ,  Akira Matsuzaki ,  Takafumi Yamaji ,  Tatsuya Miyoshi ,  Takahiro Kubota ,  Yasuhiko Haruta ,  Hiroyasu Matsuki ,  Kenichi Tomita

IPC分类号： B32B900

CPC分类号： C23C22/22 ,  B05D5/00 ,  B05D7/51 ,  B05D2202/10 ,  C09D5/084 ,  C09D5/10 ,  C23C22/08 ,  C23C22/18 ,  C23C22/20 ,  C23C28/00 ,  Y10T428/256 ,  Y10T428/31609

摘要： A coated steel sheet having excellent corrosion resistance comprises: a zinc or a zinc alloy plated steel sheet or an aluminum or an aluminum alloy plated steel sheet; a composite oxide coating formed on the surface of the plated steel sheet; and an organic coating formed on the composite oxide coating. The composite oxide coating contains a fine particle oxide and a phosphoric acid and/or a phosphoric acid compound. The organic coating has thickness of from 0.1 to 5 &mgr;m.

摘要翻译： 具有优异的耐腐蚀性的涂层钢板包括锌或镀锌合金钢板或铝或镀铝合金钢板; 在镀覆钢板的表面上形成的复合氧化物涂层; 和在复合氧化物涂层上形成的有机涂层。 复合氧化物涂层含有细颗粒氧化物和磷酸和/或磷酸化合物。 有机涂层的厚度为0.1〜5μm。

公开(公告)号：US06280535B1

公开(公告)日：2001-08-28

申请号：US09029574

申请日：1998-03-23

申请人： Tatsuya Miyoshi ,  Takahiro Kubota ,  Masaru Sagiyama ,  Yoshiharu Sugimoto ,  Masaaki Yamashita

发明人： Tatsuya Miyoshi ,  Takahiro Kubota ,  Masaru Sagiyama ,  Yoshiharu Sugimoto ,  Masaaki Yamashita

IPC分类号： C23C2224

摘要： A production method for a lead-containing hot-galvanized chromated steel sheet with excellent resistance to blackening and white rust formation comprises: (a) plating a steel sheet in a hot-galvanizing bath containing 0.05-0.3 wt. % lead and 0.1-0.3 wt. % aluminum; (b) coating this with a chromating solution containing chromium (VI) ions, chromium (III) ions and nitrate ions in which the Cr(III)/Cr(VI) molar ratio is 1/9-1/1 and the nitrate ion to total chromium ion molar ratio is 0.1-1.6; and (c) without washing with water, drying the sheet at 40-250 deg. C., to form a 5-50 mg/m integral 2 (in terms of chromium) chromate film.

公开(公告)号：US6015628A

公开(公告)日：2000-01-18

申请号：US809766

申请日：1997-06-18

申请人： Kazuya Urata ,  Naoto Yoshimi ,  Takahiro Kubota ,  Masaaki Yamashita ,  Yasuhiko Haruta

发明人： Kazuya Urata ,  Naoto Yoshimi ,  Takahiro Kubota ,  Masaaki Yamashita ,  Yasuhiko Haruta

IPC分类号： B05D7/14 ,  B05D7/00 ,  B32B15/08 ,  B32B15/092 ,  B21D39/00 ,  B32B27/38 ,  C03C27/02

CPC分类号： B05D7/51 ,  Y10T428/12549 ,  Y10T428/12569 ,  Y10T428/12611 ,  Y10T428/12799 ,  Y10T428/12972 ,  Y10T428/31511

摘要： This invention provides an organic composite coated steel sheet comprising, as the base, a zinc or zinc alloy coated steel sheet, which can be used in automobile bodies and electric appliances. The coated steel sheet has excellent press formability with oil, while having excellent perforation corrosion resistance and excellent corrosion resistance in a rust-contaminated environment. The coated steel sheet comprises a zinc or zinc alloy plated steel sheet having, on its surface, a chromate layer and an organic film formed in that order, in which the organic film has a thickness of from 0.1 to 3.0 .mu.m and comprises (i) an epoxy resin mixture composed of a base resin as prepared by adding at least one basic nitrogen atom and at least two primary hydroxyl groups to the ends of an epoxy resin, and a curing agent for the resin of a polyisocyanate compound, as mixed in a particular ratio by weight of the two, (ii) a composite lubricant comprising a polyolefin wax as prepared through coordination-anionic polymerization using a Ziegler catalyst, and fine powder of a fluorine resin, as combined in a particular ratio by weight of the two, and (iii) a rust preventive additive, as combined in a particular ratio of (i), (ii) and (iii).

摘要翻译： PCT No.PCT / JP96 / 02156 Sec。 371日期：1997年6月18日 102（e）1997年6月18日PCT PCT 1996年7月31日PCT公布。 出版物WO97 / 04957 日期1997年2月13日本发明提供一种有机复合涂层钢板，其包含可用于汽车车身和电器的锌或锌合金涂层钢板作为基底。 涂布钢板与油的冲压成形性优异，同时在防锈污染的环境中具有优异的耐穿孔性和优异的耐腐蚀性。 涂覆钢板包括锌或锌合金电镀钢板，其表面上具有铬酸盐层和依次形成的有机膜，其中有机膜的厚度为0.1-3.0μm，并且包含（i ）由通过向环氧树脂的末端添加至少一个碱性氮原子和至少两个伯羟基而制备的基础树脂的环氧树脂混合物，以及多异氰酸酯化合物的树脂固化剂 （ii）通过使用齐格勒催化剂的配位 - 阴离子聚合制备的包含聚烯烃蜡的复合润滑剂和氟树脂的细粉末，以特定的二重量比例组合， ，和（iii）以特定比例（i），（ii）和（iii）组合的防锈添加剂。

公开(公告)号：US20120321908A1

公开(公告)日：2012-12-20

申请号：US13511229

申请日：2010-11-19

申请人： Katsuya Hoshino ,  Takahiro Kubota ,  Tatsuya Miyoshi ,  Masahiko Tada

发明人： Katsuya Hoshino ,  Takahiro Kubota ,  Tatsuya Miyoshi ,  Masahiko Tada

IPC分类号： B32B15/08 ,  B32B15/082 ,  B32B15/09 ,  B32B15/095 ,  B32B15/18 ,  B32B15/092

CPC分类号： C22C38/00 ,  B32B15/013 ,  B32B2605/00 ,  C23C2/26 ,  C23C28/00 ,  C23C30/00 ,  Y10T428/12569

摘要： A galvanized steel sheet has an organic inorganic complex coating on the surface thereof which contains an organic resin and a crystalline layered substance and has an average film thickness of 0.10 to 2.0 μm. The organic inorganic complex coating contains the crystalline layered substance in a solid content of not less than 0.5 parts by weight with respect to 100 parts by weight of the solid content of the organic resin.

摘要翻译： 镀锌钢板在其表面上具有含有有机树脂和结晶层状物质的平均膜厚为0.10〜2.0μm的有机无机复合涂层。 有机无机复合涂层相对于有机树脂的固体成分100重量份含有固体成分为0.5重量份以上的结晶性层状物质。

公开(公告)号：US07527876B2

公开(公告)日：2009-05-05

申请号：US11899570

申请日：2007-09-06

申请人： Nobue Fujibayashi ,  Akira Matsuzaki ,  Satoru Ando ,  Syuji Nomura ,  Takahiro Kubota ,  Yoshikazu Morohoshi ,  Takashi Nakano ,  Takashi Okubo ,  Jun Akui

发明人： Nobue Fujibayashi ,  Akira Matsuzaki ,  Satoru Ando ,  Syuji Nomura ,  Takahiro Kubota ,  Yoshikazu Morohoshi ,  Takashi Nakano ,  Takashi Okubo ,  Jun Akui

IPC分类号： B32B15/00 ,  B21B39/00

CPC分类号： B32B15/013 ,  C23C2/26 ,  C23C28/00 ,  Y10T428/12493 ,  Y10T428/12535 ,  Y10T428/12611 ,  Y10T428/12618 ,  Y10T428/12757 ,  Y10T428/12799 ,  Y10T428/12806 ,  Y10T428/12951 ,  Y10T428/12972 ,  Y10T428/27

摘要： A surface-treated steel sheet is disclosed, including a zinc based plated steel sheet having thereon a surface-treated film containing titanium, nickel, aluminum and fluorine and having a film thickness of from 0.05 to 1.0 μm, the surface-treated film having a titanium deposition amount of from 0.01 to 0.5 g/m2 and containing from 0.01 to 5 parts by mass of nickel, from 0.1 to 25 parts by mass of aluminum and from 1 to 500 parts by mass of fluorine relative to 100 parts by mass of titanium. This surface-treated steel sheet does not contain hexavalent chromium in the film thereof at all and has excellent heat discoloration resistance, corrosion resistance and resistance to blackening.

摘要翻译： 公开了一种经表面处理的钢板，其包括其上具有含有钛，镍，铝和氟的表面处理膜并且膜厚度为0.05至1.0μm的锌基电镀钢板，表面处理膜具有 钛沉积量为0.01〜0.5g / m 2，含有0.01〜5质量份的镍，0.1〜25质量份的铝和1〜500质量份的氟，相对于100质量份的钛 。 该表面处理钢板根本不含有六价铬，耐热变色性，耐腐蚀性和耐黑变性优异。

公开(公告)号：US5110689A

公开(公告)日：1992-05-05

申请号：US657281

申请日：1991-02-19

申请人： Tsutomu Watanabe ,  Masaaki Yamashita ,  Takahiro Kubota ,  Yoshiaki Miyosawa ,  Tadashi Nishimoto

发明人： Tsutomu Watanabe ,  Masaaki Yamashita ,  Takahiro Kubota ,  Yoshiaki Miyosawa ,  Tadashi Nishimoto

IPC分类号： B32B15/08 ,  B05D7/16 ,  B32B15/092 ,  C08K3/36 ,  C23C22/00 ,  C23C22/24 ,  C23C28/00 ,  C25D11/38

CPC分类号： B05D7/16 ,  C08K3/36 ,  C23C28/00 ,  C25D11/38 ,  Y10T428/12549 ,  Y10T428/12569 ,  Y10T428/12611 ,  Y10T428/12799 ,  Y10T428/12972

摘要： A first characteristic of the invention is present in forming a chromate film on the surface of a zinc or a zinc alloy plated steel sheet, and a resin composition film at a coating amount of 0.3 to 5.0 g/m.sup.2 on said chromate fim, said resin composition film comprising an organic solvent soluble epoxy resin and hydrophobic silica in a ratio of 80:20 to 50:50 by weight of epoxy resin:hydrophobic resin, said epoxy resin having a glass transition temperature of 293.degree. to 342.degree. K.A second characteristic of the invention is present in forming a chromate film on the surface of a zinc or zinc alloy plated steel sheet, and a resin composition film at a coating amount of 0.3 to 5.0 g/m.sup.2 on said chromate film, and resin composition film comprising an organic solvent soluble epoxy resin having glass transition temperature of 293.degree. to 342.degree. K. and hydrophobic silica and sparingly water soluble Cr compound in a ratio of 80:20 to 50:50 by weight of epoxy resin:(hydrophobic silica+sparingly water soluble Cr compound), and in a ratio 37:3 to 20:20 by weight of hydrophobic silica:sparingly water soluble Cr compound.

公开(公告)号：US4775600A

公开(公告)日：1988-10-04

申请号：US932771

申请日：1986-11-18

申请人： Takeshi Adaniya ,  Masaaki Yamashita ,  Akira Enatsu ,  Takahiro Kubota ,  Norio Nikaido ,  Yoshiaki Miyosawa ,  Tadashi Nishimoto ,  Kazuhiko Ozawa

发明人： Takeshi Adaniya ,  Masaaki Yamashita ,  Akira Enatsu ,  Takahiro Kubota ,  Norio Nikaido ,  Yoshiaki Miyosawa ,  Tadashi Nishimoto ,  Kazuhiko Ozawa

IPC分类号： B05D7/00 ,  C08G18/58 ,  C23C22/83 ,  C23C28/00 ,  C25D11/38 ,  B32B15/04

CPC分类号： B05D7/51 ,  C08G18/58 ,  C23C22/83 ,  C23C28/00 ,  C25D11/38 ,  B05D2350/20 ,  B05D2504/00 ,  C23C2222/20 ,  Y10T428/12549 ,  Y10T428/12569 ,  Y10T428/12611 ,  Y10T428/12799 ,  Y10T428/12972

摘要： The present invention relates to a highly corrosion-resistant surface-treated steel plate. The steel plate of the present invention comprises a zinc deposition or zinc alloy deposition film as the undercoat deposition layer, a chromate film formed on the undercoat deposition layer and a film of a resin composition formed on the chromate film. This resin composition comprises a base resin formed by adding at least one basic nitrogen atom and at least two primary hydroxyl groups to terminals of an epoxy resin. The resin composition may comprise a polyisocyanate compound as the curing agent. Furthermore, the resin composition may comprise silica or a hardly soluble chromium compound as the additive for improving the corrosion resistance. Moreover, the resin composition may comprise a silane compound as the crosslinking agent for the base resin and silica.

摘要翻译： 本发明涉及一种高耐腐蚀表面处理钢板。 本发明的钢板包括作为底涂层沉积层的锌沉积或锌合金沉积膜，在底涂层沉积层上形成的铬酸盐膜和形成在铬酸盐膜上的树脂组合物的膜。 该树脂组合物包含通过向环氧树脂的末端添加至少一个碱性氮原子和至少两个伯羟基而形成的基础树脂。 树脂组合物可以包含作为固化剂的多异氰酸酯化合物。 此外，树脂组合物可以包含二氧化硅或难溶溶性铬化合物作为用于提高耐腐蚀性的添加剂。 此外，树脂组合物可以包含作为基础树脂和二氧化硅的交联剂的硅烷化合物。

公开(公告)号：US07291402B2

公开(公告)日：2007-11-06

申请号：US10515303

申请日：2003-02-14

申请人： Okai Kazuhisa ,  Akira Matsuzaki ,  Naoto Yoshimi ,  Takahiro Kubota ,  Masaaki Yamashita ,  Hisato Noro ,  Haruo Nakamichi ,  Kaoru Sato ,  Hiroyasu Matsuki ,  Reijiro Nishida ,  Masahiro Murata ,  Shoichi Tanaka ,  Yoshikazu Morohoshi ,  Shingo Amaki

发明人： Okai Kazuhisa ,  Akira Matsuzaki ,  Naoto Yoshimi ,  Takahiro Kubota ,  Masaaki Yamashita ,  Hisato Noro ,  Haruo Nakamichi ,  Kaoru Sato ,  Hiroyasu Matsuki ,  Reijiro Nishida ,  Masahiro Murata ,  Shoichi Tanaka ,  Yoshikazu Morohoshi ,  Shingo Amaki

IPC分类号： B32B15/08 ,  B32B15/092 ,  B32B15/18 ,  B32B15/20 ,  B05D3/02

CPC分类号： C23C22/08 ,  B05D7/56 ,  B05D2202/10 ,  B05D2350/65 ,  C08G59/4035 ,  C09D5/08 ,  C09D163/00 ,  C23C22/12 ,  C23C22/18 ,  C23C22/20 ,  C23C22/22 ,  C23C22/34 ,  C23C22/42 ,  C23C2222/20 ,  Y10T428/12569 ,  Y10T428/12611 ,  Y10T428/12757 ,  Y10T428/12799 ,  Y10T428/12951 ,  Y10T428/24967 ,  Y10T428/265 ,  Y10T428/31529 ,  Y10T428/31663 ,  Y10T428/31678 ,  C08L2666/28 ,  C08L2666/20 ,  C08L2666/54

摘要： The invention is to provide a surface-treated steel sheet of good white rust resistance with no chromium in its surface treatment film, and it has realized a surface-treated steel sheet of higher-level corrosion resistance by forming a reaction layer of plating metal with a barrier layer effective for anticorrosion not in a two-layered film but in a single-layered film. The surface-treated steel sheet is fabricated by applying a surface-treating composition that contains: (a) a water-dispersible resin and/or a water-soluble resin obtained through reaction of an epoxy group-containing resin (A) with an active hydrogen-containing compound (B) a part or all of which is an active hydrogen-containing hydrazine derivative and preferably with a hydrophilic organic component (C), (b) a silane coupling agent, (c) a phosphoric acid and/or a hexafluoro-metal acid, and (d) preferably an aqueous dispersion of an urethane resin, to a zinc-plated or aluminium-plated steel sheet followed by drying it to form thereon a surface treatment film having a thickness of from 0.02 to 5 μm. Regarding its film structure, the surface treatment film comprises an amorphous compound layer containing P, Zn and/or Al, and O, and an overlying organic resin matrix layer where the matrix is a hydrazine derivative-modified epoxy group-containing resin or the epoxy group-containing resin and an urethane resin.

摘要翻译： 本发明提供一种在其表面处理膜中不产生铬的耐白锈锈的表面处理钢板，通过形成电镀金属的反应层，实现了具有较高耐腐蚀性的表面处理钢板 不是在双层膜中而是在单层膜中有效地防腐蚀的阻挡层。 表面处理钢板通过涂布表面处理组合物制造，所述表面处理组合物包含：（a）通过含环氧基的树脂（A）与活性物质的反应获得的水分散性树脂和/或水溶性树脂 含氢化合物（B）的一部分或全部为含活性氢的肼衍生物，优选具有亲水性有机成分（C），（b）硅烷偶联剂，（c）磷酸和/或 六氟金属酸，（d）优选为聚氨酯树脂的水分散体，涂布到镀锌或镀铝钢板上，然后干燥，形成厚度为0.02〜5μm的表面处理膜。 关于其膜结构，表面处理膜包括含有P，Zn和/或Al和O的无定形化合物层，以及基质是含有肼衍生物改性的含环氧基的树脂或环氧树脂的上覆有机树脂基质层 含有基团的树脂和聚氨酯树脂。

公开(公告)号：US20050147832A1

公开(公告)日：2005-07-07

申请号：US10515303

申请日：2003-02-14

申请人： Kazuhisa Okai ,  Akira Matsuzaki ,  Naoto Yoshimi ,  Takahiro Kubota ,  Masaaki Yamashita ,  Hisato Noro ,  Haruo Nakamichi ,  Kaoru Sato ,  Hiroyasu Matsuki ,  Reijiro Nishida ,  Masahiro Murata ,  Shoichi Tanaka ,  Yoshikazu Morohoshi ,  Shingo Amaki

发明人： Kazuhisa Okai ,  Akira Matsuzaki ,  Naoto Yoshimi ,  Takahiro Kubota ,  Masaaki Yamashita ,  Hisato Noro ,  Haruo Nakamichi ,  Kaoru Sato ,  Hiroyasu Matsuki ,  Reijiro Nishida ,  Masahiro Murata ,  Shoichi Tanaka ,  Yoshikazu Morohoshi ,  Shingo Amaki

IPC分类号： B05D7/00 ,  C08G59/40 ,  C09D5/08 ,  C09D163/00 ,  C23C22/07 ,  C23C22/08 ,  C23C22/12 ,  C23C22/18 ,  C23C22/20 ,  C23C22/22 ,  C23C22/34 ,  C23C22/42 ,  B32B15/08 ,  B32B15/18

CPC分类号： C23C22/08 ,  B05D7/56 ,  B05D2202/10 ,  B05D2350/65 ,  C08G59/4035 ,  C09D5/08 ,  C09D163/00 ,  C23C22/12 ,  C23C22/18 ,  C23C22/20 ,  C23C22/22 ,  C23C22/34 ,  C23C22/42 ,  C23C2222/20 ,  Y10T428/12569 ,  Y10T428/12611 ,  Y10T428/12757 ,  Y10T428/12799 ,  Y10T428/12951 ,  Y10T428/24967 ,  Y10T428/265 ,  Y10T428/31529 ,  Y10T428/31663 ,  Y10T428/31678 ,  C08L2666/28 ,  C08L2666/20 ,  C08L2666/54

摘要： The invention is to provide a surface-treated steel sheet of good white rust resistance with no chromium in its surface treatment film, and it has realized a surface-treated steel sheet of higher-level corrosion resistance by forming a reaction layer of plating metal with a barrier layer effective for anticorrosion not in a two-layered film but in a single-layered film. The surface-treated steel sheet is fabricated by applying a surface-treating composition that contains: (a) a water-dispersible resin and/or a water-soluble resin obtained through reaction of an epoxy group-containing resin (A) with an active hydrogen-containing compound (B) a part or all of which is an active hydrogen-containing hydrazine derivative and preferably with a hydrophilic organic component (C), (b) a silane coupling agent, (c) a phosphoric acid and/or a hexafluoro-metal acid, and (d) preferably an aqueous dispersion of an urethane resin, to a zinc-plated or aluminium-plated steel sheet followed by drying it to form thereon a surface treatment film having a thickness of from 0.02 to 5 μm. Regarding its film structure, the surface treatment film comprises an amorphous compound layer containing P, Zn and/or Al, and O, and an overlying organic resin matrix layer where the matrix is a hydrazine derivative-modified epoxy group-containing resin or the epoxy group-containing resin and an urethane resin.

摘要翻译： 本发明提供一种在其表面处理膜中不产生铬的耐白锈锈的表面处理钢板，通过形成电镀金属的反应层，实现了具有较高耐腐蚀性的表面处理钢板 不是在双层膜中而是在单层膜中有效地防腐蚀的阻挡层。 表面处理钢板通过涂布表面处理组合物制造，所述表面处理组合物包含：（a）通过含环氧基的树脂（A）与活性物质的反应获得的水分散性树脂和/或水溶性树脂 含氢化合物（B）的一部分或全部为含活性氢的肼衍生物，优选具有亲水性有机成分（C），（b）硅烷偶联剂，（c）磷酸和/或 六氟金属酸，（d）优选为聚氨酯树脂的水分散体，涂布到镀锌或镀铝钢板上，然后干燥，形成厚度为0.02〜5μm的表面处理膜。 关于其膜结构，表面处理膜包括含有P，Zn和/或Al和O的无定形化合物层，以及上层有机树脂基质层，其中基质是含肼衍生物改性的含环氧基的树脂或环氧 含有基团的树脂和聚氨酯树脂。