-
1.发明授权公开(公告)号：US07060645B2
公开(公告)日：2006-06-13
申请号：US11165538
申请日：2005-06-24
IPC分类号： B01J29/40 , C07D201/04
CPC分类号： C07D201/04 , B01J29/035 , B01J37/06 , B01J2229/38 , B01J2229/40 , C01B37/02
摘要： The present invention provides a method for manufacturing a zeolite comprising following steps of: (1): calcining crystals obtained by hydrothermal synthesis reaction of a silicon compound; (2): contact treating a calcined product obtained by the step (1) with an aqueous solution including an amine and/or a quaternary ammonium compound; (3): calcining a treated product obtained by the step (2); and (4): contact treating the calcined product obtained by the step (3) with an aqueous solution including ammonia and/or an ammonium salt. According to the present invention, a method is also provided wherein ε-caprolactam is manufactured by Beckmann rearrangement reaction of cyclohexanone oxime in a gaseous phase in the presence of the zeolite manufactured by the above-described method.
摘要翻译： 本发明提供一种制造沸石的方法，包括以下步骤：（1）：煅烧通过硅化合物的水热合成反应获得的晶体; （2）：用包含胺和/或季铵化合物的水溶液接触步骤（1）得到的煅烧产物; （3）：煅烧通过工序（2）得到的处理物; 和（4）：用包含氨和/或铵盐的水溶液接触处理由步骤（3）获得的煅烧产物。 根据本发明，还提供了一种方法，其中ε-己内酰胺通过在通过上述方法制造的沸石存在下，在气相中通过环己酮肟的贝克曼重排反应制造。
-
2.发明授权Method for producing ε-caprolactam and method for reactivating catalyst for production of ε-caprolactam 失效ε-己内酰胺的制造方法以及催化剂再生催化剂生产ε-己内酰胺的方法公开(公告)号：US07026474B2
公开(公告)日：2006-04-11
申请号：US11055101
申请日：2005-02-11
IPC分类号： C07D201/04
CPC分类号： B01J38/08 , B01J29/90 , B01J38/12 , B01J38/66 , C07D201/04 , Y02P20/52 , Y02P20/584
摘要： A method for producing ε-caprolactam and a method for reactivating a zeolite catalyst for the production are provided. In the reactivation step, a zeolite catalyst is allowed to contact a gas containing a carboxylic acid, water and a compound selected from ammonia and amines. In accordance with the present invention, the catalytic activities of a zeolite catalyst used for the Beckmann rearrangement reaction of cyclohexanone oxime can be effectively restored. Consequently, ε-caprolactam may be produced with a high production yield for a long period of time by reusing the catalyst by the method described above.
摘要翻译： 提供了制备ε-己内酰胺的方法和用于再生催化剂的方法。 在再活化步骤中，使沸石催化剂与含有羧酸，水和选自氨和胺的化合物的气体接触。 根据本发明，可以有效地恢复用于环己酮肟的贝克曼重排反应的沸石催化剂的催化活性。 因此，通过上述方法重新使用催化剂，可以长期生产ε-己内酰胺。
-
3.发明申请Method for manufacturing zeolite and method for manufacturing epsilon-caprolatam 失效制造沸石的方法和制备ε-caprolatam的方法公开(公告)号：US20060004194A1
公开(公告)日：2006-01-05
申请号：US11165538
申请日：2005-06-24
IPC分类号： B01J29/40 , C07D201/04
CPC分类号： C07D201/04 , B01J29/035 , B01J37/06 , B01J2229/38 , B01J2229/40 , C01B37/02
摘要： The present invention provides a method for manufacturing a zeolite comprising following steps of: (1): calcining crystals obtained by hydrothermal synthesis reaction of a silicon compound; (2): contact treating a calcined product obtained by the step (1) with an aqueous solution including an amine and/or a quaternary ammonium compound; (3): calcining a treated product obtained by the step (2); and (4): contact treating the calcined product obtained by the step (3) with an aqueous solution including ammonia and/or an ammonium salt. According to the present invention, a method is also provided wherein ε-caprolactam is manufactured by Beckmann rearrangement reaction of cyclohexanone oxime in a gaseous phase in the presence of the zeolite manufactured by the above-described method.
摘要翻译： 本发明提供一种制造沸石的方法，包括以下步骤：（1）：煅烧通过硅化合物的水热合成反应获得的晶体; （2）：用包含胺和/或季铵化合物的水溶液接触步骤（1）得到的煅烧产物; （3）：煅烧通过工序（2）得到的处理物; 和（4）：用包含氨和/或铵盐的水溶液接触处理由步骤（3）获得的煅烧产物。 根据本发明，还提供了一种方法，其中ε-己内酰胺通过在通过上述方法制造的沸石存在下，在气相中通过环己酮肟的贝克曼重排反应制造。
-
公开(公告)号：US07189845B2
公开(公告)日：2007-03-13
申请号：US11088874
申请日：2005-03-25
IPC分类号： C07D201/04
CPC分类号： C07D201/04 , B01J29/90 , B01J38/12 , Y02P20/52 , Y02P20/584
摘要： The invention provides a method for producing ε-caprolactam comprising the steps of: a reaction process which subjects cyclohexanone oxime to a Beckmann rearrangement reaction in the presence of a solid catalyst; and a catalyst regeneration process which regenerates the solid catalyst used in the reaction process by heat treatment under an atmosphere comprising an oxygen-containing gas, wherein the solid catalyst heat-treated in the catalyst regeneration process is used in the reaction process, the carbon contents in the solid catalyst in the reaction process and the catalyst regeneration process are maintained in a range of 0.5 to 2% by weight, and the nitrogen contents in the solid catalyst in the reaction process and the catalyst regeneration process are maintained in a range of 0.01 to 0.2% by weight.According to the invention, ε-caprolactam can be produced in a high production yield for a long period of time by enhancing persistence of the catalytic activity for producing ε-caprolactam.
摘要翻译： 本发明提供了一种生产ε-己内酰胺的方法，包括以下步骤：在固体催化剂存在下将环己酮肟与贝克曼重排反应相对应的反应过程; 以及催化剂再生方法，其通过在包含含氧气体的气氛下进行热处理来再生反应过程中使用的固体催化剂，其中在反应过程中使用在催化剂再生过程中热处理的固体催化剂，碳含量 在反应过程中的固体催化剂和催化剂再生过程保持在0.5〜2重量％的范围内，并且在反应过程和催化剂再生过程中固体催化剂中的氮含量保持在0.01 至0.2重量％。 根据本发明，ε-己内酰胺可以通过增加用于生产ε-己内酰胺的催化活性的持久性，以高生产率长时间生产。
-
公开(公告)号：US20050245740A1
公开(公告)日：2005-11-03
申请号：US11088874
申请日：2005-03-25
IPC分类号： C07D223/10 , B01J29/90 , B01J38/12 , C07B61/00 , C07D201/04 , B01J20/34
CPC分类号： C07D201/04 , B01J29/90 , B01J38/12 , Y02P20/52 , Y02P20/584
摘要： The invention provides a method for producing ε-caprolactam comprising the steps of: a reaction process which subjects cyclohexanone oxime to a Beckmann rearrangement reaction in the presence of a solid catalyst; and a catalyst regeneration process which regenerates the solid catalyst used in the reaction process by heat treatment under an atmosphere comprising an oxygen-containing gas, wherein the solid catalyst heat-treated in the catalyst regeneration process is used in the reaction process, the carbon contents in the solid catalyst in the reaction process and the catalyst regeneration process are maintained in a range of 0.5 to 2% by weight, and the nitrogen contents in the solid catalyst in the reaction process and the catalyst regeneration process are maintained in a range of 0.01 to 0.2% by weight. According to the invention, ε-caprolactam can be produced in a high production yield for a long period of time by enhancing persistence of the catalytic activity for producing ε-caprolactam.
摘要翻译： 本发明提供了一种生产ε-己内酰胺的方法，包括以下步骤：在固体催化剂存在下将环己酮肟与贝克曼重排反应相对应的反应过程; 以及催化剂再生方法，其通过在包含含氧气体的气氛下进行热处理来再生反应过程中使用的固体催化剂，其中在反应过程中使用在催化剂再生过程中热处理的固体催化剂，碳含量 在反应过程中的固体催化剂和催化剂再生过程保持在0.5〜2重量％的范围内，并且在反应过程和催化剂再生过程中固体催化剂中的氮含量保持在0.01 至0.2重量％。 根据本发明，ε-己内酰胺可以通过增加用于生产ε-己内酰胺的催化活性的持久性，以高生产率长时间生产。
-
6.发明申请Method for producing epsilon-caprolactam and method for reactivating catalyst for production of epsilon-caprolactam 失效ε-己内酰胺的制造方法以及催化剂再生催化剂生产ε-己内酰胺的方法公开(公告)号：US20050182254A1
公开(公告)日：2005-08-18
申请号：US11055101
申请日：2005-02-11
IPC分类号： C07D223/10 , B01J29/035 , B01J29/90 , B01J38/06 , B01J38/08 , B01J38/12 , B01J38/18 , B01J38/62 , B01J38/66 , C07B61/00 , C07D201/04 , C07D201/14 , B01J38/04
CPC分类号： B01J38/08 , B01J29/90 , B01J38/12 , B01J38/66 , C07D201/04 , Y02P20/52 , Y02P20/584
摘要： A method for producing ε-caprolactam and a method for reactivating a zeolite catalyst for the production are provided. In the reactivation step, a zeolite catalyst is allowed to contact a gas containing a carboxylic acid, water and a compound selected from ammonia and amines. In accordance with the present invention, the catalytic activities of a zeolite catalyst used for the Beckmann rearrangement reaction of cyclohexanone oxime can be effectively restored. Consequently, ε-caprolactam may be produced with a high production yield for a long period of time by reusing the catalyst by the method described above.
摘要翻译： 提供了制备ε-己内酰胺的方法和用于再生催化剂的方法。 在再活化步骤中，使沸石催化剂与含有羧酸，水和选自氨和胺的化合物的气体接触。 根据本发明，可以有效地恢复用于环己酮肟的贝克曼重排反应的沸石催化剂的催化活性。 因此，通过上述方法重新使用催化剂，可以长期生产ε-己内酰胺。
-
7.发明授权Process for regenerating catalyst for producing e-caprolactam and process for producing e-caprolactam 失效用于生产ε-己内酰胺的催化剂再生方法和用于生产ε-己内酰胺的方法公开(公告)号：US07687621B2
公开(公告)日：2010-03-30
申请号：US11822141
申请日：2007-07-02
申请人： Keisuke Sugita , Masaru Kitamura
发明人： Keisuke Sugita , Masaru Kitamura
IPC分类号： C07D201/04
CPC分类号： B01J29/90 , B01J38/66 , B01J2229/32 , C07D201/04 , Y02P20/52 , Y02P20/584
摘要： The present invention provides a process for regenerating a catalyst for producing e-caprolactam comprising the steps of adsorbing a silicon compound on a zeolite catalyst that had been used for a Beckmann rearrangement reaction of cyclohexanone oxime and contacting the catalyst with an aqueous solution containing a compound selected from a quaternary ammonium compound, lower alkylamines and ammonia. The present invention also provides a process for producing e-caprolactam comprising subjecting cyclohexanone oxime to the Beckmann rearrangement reaction in the presence of the catalyst thus regenerated.
摘要翻译： 本发明提供了一种用于再生生产ε-己内酰胺的催化剂的方法，包括以下步骤：将硅化合物吸附在已经用于环己酮肟的贝克曼重排反应的沸石催化剂上，并使催化剂与含有化合物的水溶液接触 选自季铵化合物，低级烷基胺和氨。 本发明还提供一种生产ε-己内酰胺的方法，其包括在由此再生的催化剂存在下使环己酮肟进行贝克曼重排反应。
-
8.发明申请Process for regenerating catalyst for producing e-caprolactam and process for producing e-caprolactam 失效用于生产ε-己内酰胺的催化剂再生方法和用于生产ε-己内酰胺的方法公开(公告)号：US20080033168A1
公开(公告)日：2008-02-07
申请号：US11822141
申请日：2007-07-02
申请人： Keisuke Sugita , Masaru Kitamura
发明人： Keisuke Sugita , Masaru Kitamura
IPC分类号： C07D201/04 , B01J38/70
CPC分类号： B01J29/90 , B01J38/66 , B01J2229/32 , C07D201/04 , Y02P20/52 , Y02P20/584
摘要： The present invention provides a process for regenerating a catalyst for producing e-caprolactam comprising the steps of adsorbing a silicon compound on a zeolite catalyst that had been used for a Beckmann rearrangement reaction of cyclohexanone oxime and contacting the catalyst with an aqueous solution containing a compound selected from a quaternary ammonium compound, lower alkylamines and ammonia. The present invention also provides a process for producing e-caprolactam comprising subjecting cyclohexanone oxime to the Beckmann rearrangement reaction in the presence of the catalyst thus regenerated.
摘要翻译： 本发明提供了一种用于再生生产ε-己内酰胺的催化剂的方法，包括以下步骤：将硅化合物吸附在已经用于环己酮肟的贝克曼重排反应的沸石催化剂上，并使催化剂与含有化合物的水溶液接触 选自季铵化合物，低级烷基胺和氨。 本发明还提供一种生产ε-己内酰胺的方法，其包括在由此再生的催化剂存在下使环己酮肟进行贝克曼重排反应。
-
公开(公告)号：US06258949B1
公开(公告)日：2001-07-10
申请号：US09526885
申请日：2000-03-16
申请人： Masaru Kitamura , Yasumoto Shimazu
发明人： Masaru Kitamura , Yasumoto Shimazu
IPC分类号： C07D20104
CPC分类号： B01J8/02 , B01J8/24 , B01J2208/00106 , C07D201/04 , Y02P20/52
摘要： An apparatus for the production of &egr;-caprolactam is provided which comprises (i) a fluidized bed reactor having a solid catalyst therein for subjecting cyclohexanone oxime to a rearrangement reaction to obtain a reaction product containing unreacted cyclohexanone oxime and (ii) a fixed bed reactor packed with a solid catalyst for subjecting the unreacted cyclohexanone oxime to a rearrangement reaction to obtain &egr;-caprolactam. Using the apparatus, &egr;-caprolactam is obtained with a high yield.
摘要翻译： 提供了一种用于生产ε-己内酰胺的装置，其包括（i）其中具有固体催化剂的流化床反应器，用于使环己酮肟进行重排反应以获得含有未反应的环己酮肟的反应产物和（ⅱ）固定床反应器 填充固体催化剂，使未反应的环己酮肟进行重排反应，得到ε-己内酰胺。 使用该装置，以高产率获得ε-己内酰胺。
-
10.发明授权Process for producing epsilon-caprolactam and activating solid catalysts therefor 失效生产EPSILON-CAPROLACTAM和活化其固体催化剂的方法
公开(公告)号：US5212302A
公开(公告)日：1993-05-18
申请号：US811627
申请日：1991-12-23
IPC分类号： B01J29/035 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/90 , B01J38/12 , B01J38/66 , C07D201/04
CPC分类号： B01J29/90 , B01J29/035 , B01J29/86 , B01J29/87 , B01J29/88 , B01J38/12 , B01J38/66 , C07D201/04 , Y02P20/52 , Y02P20/584
摘要： In the production of .epsilon.-caprolactam from cyclohexanon oxime in gaseous phase in the presence of solid catalysts, the catalysts, no matter whether they may have worked, are brought into contact with either aqueous solution of ammonium salts and at least one basic material or ammonia water.
-
-
-
-
-
-
-
-
-
搜索结果
32 条记录 (耗时 0.025 秒)
