摘要:
Provided are a transition metal mixed hydroxide comprising an alkali metal other than Li, SO4 and a transition metal element, wherein the molar ratio of the molar content of the alkali metal to the molar content of the SO4 is not less than 0.05 and less than 2, and a lithium mixed metal oxide obtained by calcining a mixture of the transition metal mixed hydroxide and a lithium compound by maintaining the mixture at a temperature of 650 to 1000° C.
摘要:
Provided are a transition metal mixed hydroxide comprising an alkali metal other than Li, SO4 and a transition metal element, wherein the molar ratio of the molar content of the alkali metal to the molar content of the SO4 is not less than 0.05 and less than 2, and a lithium mixed metal oxide obtained by calcining a mixture of the transition metal mixed hydroxide and a lithium compound by maintaining the mixture at a temperature of 650 to 100000.
摘要:
A lithium mixed metal oxide, shown by the following formula (A): Lix(Mn1-y-z-dNiyFezMd)O2 (A) wherein M is one or more elements selected from the group consisting of Al, Mg, Ti, Ca, Cu, Zn, Co, Cr, Mo, Si, Sn, Nb and V; x is 0.9 or more and 1.3 or less; y is 0.3 or more and 0.7 or less; z is more than 0 and 0.1 or less, and d is more than 0 and 0.1 or less. A positive electrode active material, including the lithium mixed metal oxide. A positive electrode, including the positive electrode active material. A nonaqueous electrolyte secondary battery, including the positive electrode.
摘要:
The present invention provides a non-aqueous electrolyte secondary battery capable of exhibiting high discharge capacity maintenance rate at a high current rate, a lithium composite metal oxide useful therefor, and a method for producing the lithium composite metal oxide. This lithium composite metal oxide comprises Ni, Mn, Co, and Fe, and the BET specific surface area thereof is 3 m2/g to 15 m2/g. According to the present invention, a non-aqueous electrolyte secondary battery which exhibits high discharge capacity maintenance rate at a high current rate compared to a conventional lithium secondary battery can be obtained, and thus the secondary battery is very useful especially for applications where high discharge capacity maintenance rate at a high current rate is required, that is, non-aqueous electrolyte secondary batteries for automobiles or for power tools such as electric tools.
摘要:
The present invention provides a method of producing a lithium mixed metal oxide, a lithium mixed metal oxide and a nonaqueous electrolyte secondary battery. The method includes a step of calcining a mixture of one or more compounds of M wherein M is one or more elements selected from the group consisting of nickel, cobalt and manganese, and a lithium compound, in the presence of one or more inactive fluxes selected from the group consisting of a fluoride of A, a chloride of A, a carbonate of A, a sulfate of A, a nitrate of A, a phosphate of A, a hydroxide of A, a molybdate of A and a tungstate of A, wherein A is one or more elements selected from the group consisting of Na, K, Rb, Cs, Ca, Mg, Sr and Ba. The lithium mixed metal oxide contains nickel, cobalt and manganese, has a BET specific surface area of from 3 m2/g to 15 m2/g, and has an average particle diameter within a range of 0.1 μm or more to less than 1 μm, the diameter determined by a laser diffraction scattering method.
摘要:
A lithium mixed metal oxide, shown by the following formula (A): Lix(Mn1−y−z−dNiyFezMd)O2 (A) wherein M is one or more elements selected from the group consisting of Al, Mg, Ti, Ca, Cu, Zn, Co, Cr, Mo, Si, Sn, Nb and V; x is 0.9 or more and 1.3 or less; y is 0.3 or more and 0.7 or less; z is more than 0 and 0.1 or less, and d is more than 0 and 0.1 or less. A positive electrode active material, including the lithium mixed metal oxide. A positive electrode, including the positive electrode active material. A nonaqueous electrolyte secondary battery, including the positive electrode.
摘要:
The present invention provides a lithium mixed metal oxide, an electrode and a nonaqueous electrolyte secondary battery. The lithium mixed metal oxide is represented by the following formula (A): Lix(Mn1−(y+z)NiyFez)O2 (A) wherein x is not less than 0.9 and not more than 1.3, y is more than 0.5 and not more than 0.7, and z is more than 0 and not more than 0.1.
摘要:
The present invention provides a positive electrode active material. The positive electrode active material is represented by the following formula (I) and has a BET specific surface area of larger than 5 m2/g and not larger than 15 m2/g: LixM1yM31-yO2 (I) wherein M1 is at least one transition metal element selected from Group 5 elements and Group 6 elements of the Periodic Table, M3 is at least one transition metal element other than M1 and selected from among transition metal elements excluding Fe, x is not less than 0.9 and not more than 1.3, and y is more than 0 and less than 1.
摘要:
The present invention provides a method of producing a lithium mixed metal oxide, a lithium mixed metal oxide and a nonaqueous electrolyte secondary battery. The method includes a step of calcining a mixture of one or more compounds of M wherein M is one or more elements selected from the group consisting of nickel, cobalt and manganese, and a lithium compound, in the presence of one or more inactive fluxes selected from the group consisting of a fluoride of A, a chloride of A, a carbonate of A, a sulfate of A, a nitrate of A, a phosphate of A, a hydroxide of A, a molybdate of A and a tungstate of A, wherein A is one or more elements selected from the group consisting of Na, K, Rb, Cs, Ca, Mg, Sr and Ba. The lithium mixed metal oxide contains nickel, cobalt and manganese, has a BET specific surface area of from 3 m2/g to 15 m2/g, and has an average particle diameter within a range of 0.1 μm or more to less than 1 μm, the diameter determined by a laser diffraction scattering method.
摘要:
The present invention provides a positive electrode active material. The positive electrode active material is represented by the following formula (I) and has a BET specific surface area of larger than 5 m2/g and not larger than 15 m2/g: LixM1yM31-yO2 (I) wherein M1 is at least one transition metal element selected from Group 5 elements and Group 6 elements of the Periodic Table, M3 is at least one transition metal element other than M1 and selected from among transition metal elements excluding Fe, x is not less than 0.9 and not more than 1.3, and y is more than 0 and less than 1.