公开(公告)号：US20090011254A1

公开(公告)日：2009-01-08

申请号：US12167458

申请日：2008-07-03

申请人： Kenji Yamamoto ,  Tsutomu Nakajima ,  Masahiko Ogawa

发明人： Kenji Yamamoto ,  Tsutomu Nakajima ,  Masahiko Ogawa

IPC分类号： B32B7/10 ,  B05D3/02

CPC分类号： B05D5/08 ,  B05D3/08 ,  B05D7/04 ,  B05D2201/00 ,  C09J7/40 ,  C09J2400/226 ,  C09J2483/005 ,  Y10T428/31663

摘要： Provided is a release film, including a plastic film substrate, a surface modification layer formed on a single surface or both surfaces of the plastic film substrate by radiating a flame of a fuel gas including an organosilicon compound onto the single surface or both surfaces, and a silicone release layer composed of a cured product of a curable silicone composition, in which the silicone release layer is provided on top of the surface modification layer. The release film exhibits excellent adhesion between the silicone release layer and the plastic film substrate. The release film is produced at low cost and at a high level of productivity by a method including: forming the surface modification layer on a single surface or both surfaces of the plastic film substrate by radiating a flame of the fuel gas onto the single surface or both surfaces, and forming the silicone release layer on top of the surface modification layer by applying the curable silicone composition to the surface modification layer and then curing the composition.

摘要翻译： 本发明提供一种剥离膜，其包括塑料膜基材，通过将包含有机硅化合物的燃料气体的火焰喷射到单个表面或两个表面上而形成在塑料膜基材的单个表面或两个表面上的表面改性层，以及 由可固化硅氧烷组合物的固化产物组成的硅氧烷释放层，其中硅氧烷剥离层设置在表面改性层的顶部。 剥离膜在硅氧烷剥离层和塑料膜基材之间表现出优异的粘合性。 以低成本和高生产率的方式制造脱模膜，其方法包括：通过将燃料气体的火焰喷射到单个表面上，在塑料膜基材的单个表面或两个表面上形成表面改性层，或 并且通过将可固化的硅氧烷组合物施加到表面改性层上然后固化该组合物，在表面改性层的顶部上形成硅氧烷释放层。

公开(公告)号：US07459213B2

公开(公告)日：2008-12-02

申请号：US10762462

申请日：2004-01-23

申请人： Kenji Yamamoto ,  Masahiko Ogawa ,  Tsutomu Nakajima

发明人： Kenji Yamamoto ,  Masahiko Ogawa ,  Tsutomu Nakajima

IPC分类号： C08L29/05

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/16 ,  C08G77/20 ,  C08G77/24 ,  C08G77/26 ,  C08G77/70 ,  C08L29/00 ,  C08L29/04 ,  C09D129/04 ,  C09D183/04 ,  D21H17/59 ,  D21H19/32 ,  D21H21/16 ,  Y10T428/31663 ,  C08L2666/14 ,  C08L83/00

摘要： A composition comprising the following components: 100 parts by weight of an organopolysiloxane (A), 0.1 to 30 parts by weight of a crosslinking agent (B), 50 to 1,000 parts by weight of a polyvinyl alcohol homopolymer or copolymer (C), 0 to 5 parts by weight, as an active ingredient, of a catalyst (D), 100 to 100,000 parts by weight of water (E), and 0.1 to 100 parts by weight of a surfactant (F), wherein component (A) is an organopolysiloxane (A3) having at least two alkenyl groups and represented by the following formula (3): wherein each R1 may be same or different and is a group having 1 to 20 carbon atoms selected from the group consisting of alkyl groups, alicyclic groups, and aryl groups, whose hydrogen atoms bonded to the carbon atoms may partly be replaced with a halogen atom or a cyano group, R2 is an alkenyl group and X3 is the group represented by the following formula: wherein a3, b3, c3, d3 and e3 are such numbers that the organopolysiloxane (A3) has a viscosity at 25 degrees C. of from 0.05 to 500 Pa·s, and b3, c3, d3 and e3 may be zero, and α and β are integers of from 0 to 3 and component (B) is an organohydrogenpolysiloxane (B3) having at least three SiH groups per molecule.

摘要翻译： 包含以下组分的组合物：100重量份的有机聚硅氧烷（A），0.1〜30重量份的交联剂（B），50〜1000重量份的聚乙烯醇均聚物或共聚物（C），0 5重量份作为活性成分的催化剂（D），100至100,000重量份的水（E）和0.1至100重量份的表面活性剂（F），其中组分（A）为 具有至少两个烯基并由下式（3）表示的有机聚硅氧烷（A3）：其中每个R 1可以相同或不同，并且是具有1至20个碳原子的基团，其选自烷基，脂环族基团 和与碳原子键合的氢原子可以部分被卤素原子或氰基取代的芳基，R 2为烯基，X 3为下式所示的基团：其中a 3，b 3，c 3，d 3 和e3是有机聚硅氧烷（A3）在25de处具有粘度的数字 酸度C为0.05-500Pa.s，b3，c3，d3和e3可以为零，α和β为0-3的整数，组分（B）是具有至少三个的有机氢聚硅氧烷（B3） SiH基团。

公开(公告)号：US20080064814A1

公开(公告)日：2008-03-13

申请号：US11927193

申请日：2007-10-29

申请人： Kenji Yamamoto ,  Masahiko Ogawa ,  Tsutomu Nakajima

发明人： Kenji Yamamoto ,  Masahiko Ogawa ,  Tsutomu Nakajima

IPC分类号： C08L29/04

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/16 ,  C08G77/20 ,  C08G77/24 ,  C08G77/26 ,  C08G77/70 ,  C08L29/00 ,  C08L29/04 ,  C09D129/04 ,  C09D183/04 ,  D21H17/59 ,  D21H19/32 ,  D21H21/16 ,  Y10T428/31663 ,  C08L2666/14 ,  C08L83/00

摘要： Composition comprising: 100 parts by weight of an organopolysiloxane (A), 0.1 to 30 parts by weight of a crosslinking agent (B), 50 to 1,000 parts by weight of a polyvinyl alcohol homopolymer or copolymer(C), 0 to 5 parts by weight, as an active ingredient, of a catalyst (D), 100 to 100,000 parts by weight of water (E), and. 0.1 to 100 parts by weight of a surfactant (F), wherein component (A) is an organopolysiloxane (A3) having at least two alkenyl groups and represented by the following formula (3): wherein each R1 may be same or different and is a group having 1 to 20 carbon atoms selected from the group consisting of alkyl groups, alicyclic groups, and aryl groups, whose hydrogen atoms bonded to the carbon atoms may partly be replaced with a halogen atom or a cyano group, R2 is an alkenyl group and X3is the group represented by the following formula: wherein a3, b3, c3, d3 and e3 are such numbers that the organopolysiloxane (A3) has a viscosity at 25 degrees C. of from 0.05 to 500 Pa·s, and b3, c3, d3 and e3 may be zero, and α and β are integers of from 0 to 3 and component (B) is an organohydrogenpolysiloxane (B3) having at least three SiH groups per molecule.

摘要翻译： 组合物，其包含：100重量份的有机聚硅氧烷（A），0.1〜30重量份的交联剂（B），50〜1000重量份的聚乙烯醇均聚物或共聚物（C），0〜5重量份 重量，作为活性成分的催化剂（D），100至100,000重量份的水（E），和。 0.1〜100重量份表面活性剂（F），其中组分（A）是具有至少两个烯基并由下式（3）表示的有机聚硅氧烷（A3）：其中每个R 1 >可以相同或不同，并且是具有选自烷基，脂环基和芳基的碳原子数1〜20的基团，其与碳原子键合的氢原子可以部分地被卤素原子取代或 氰基，R 2为烯基，X 3为由下式表示的基团：其中a3，b3，c3，d3和e3为有机聚硅氧烷（A3）的粘度为 25℃，0.05-500Pa·s，b3，c3，d3和e3可以为零，α和β为0-3的整数，组分（B）为至少有机氢聚硅氧烷（B3） 每个分子有三个SiH基团。

公开(公告)号：US20070032596A1

公开(公告)日：2007-02-08

申请号：US11542169

申请日：2006-10-04

申请人： Kenji Yamamoto ,  Masahiko Ogawa ,  Tsutomu Nakajima

发明人： Kenji Yamamoto ,  Masahiko Ogawa ,  Tsutomu Nakajima

IPC分类号： C08L83/00 ,  C08L29/04 ,  B32B27/00

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/16 ,  C08G77/20 ,  C08G77/24 ,  C08G77/26 ,  C08G77/70 ,  C08L29/00 ,  C08L29/04 ,  C09D129/04 ,  C09D183/04 ,  D21H17/59 ,  D21H19/32 ,  D21H21/16 ,  Y10T428/31663 ,  C08L2666/14 ,  C08L83/00

摘要： Composition comprising: 100 parts by weight of an organopolysiloxane (A), 0.1 to 30 parts by weight of a crosslinking agent (B), 50 to 1,000 parts by weight of a polyvinyl alcohol homopolymer or copolymer (C), 0 to 5 parts by weight, as an active ingredient, of a catalyst (D), 100 to 100,000 parts by weight of water (E), and 0.1 to 100 parts by weight of a surfactant (F), wherein component (A) is an organopolysiloxane (A3) having at least two alkenyl groups and represented by the following formula (3): wherein each R1 may be same or different and is a group having 1 to 20 carbon atoms selected from the group consisting of alkyl groups, alicyclic groups, and aryl groups, whose hydrogen atoms bonded to the carbon atoms may partly be replaced with a halogen atom or a cyano group, R2 is an alkenyl group and X3is the group represented by the following formula: wherein a3, b3, c3, d3 and e3 are such numbers that the organopolysiloxane (A3) has a viscosity at 25 degrees C of from 0.05 to 500 Pa·s, and b3, c3,d3 and e3 may be zero, and α and β are integers of from 0 to 3 and component (B) is an organohydrogenpolysiloxane (B3) having at least three SiH groups per molecule.

摘要翻译： 组合物，其包含：100重量份的有机聚硅氧烷（A），0.1〜30重量份的交联剂（B），50〜1000重量份的聚乙烯醇均聚物或共聚物（C），0〜5重量份 重量的活性成分的催化剂（D），100至100,000重量份的水（E）和0.1至100重量份的表面活性剂（F），其中组分（A）是有机聚硅氧烷（A3 ）具有至少两个烯基并由下式（3）表示：其中每个R 1可以相同或不同，并且是具有1至20个碳原子的基团，其选自烷基 基团，脂环基和芳基，其与碳原子键合的氢原子可以部分地被卤素原子或氰基取代，R 2是烯基，X 3是由 下式：其中a3，b3，c3，d3和e3是有机聚硅氧烷（A3）在25度下具有粘度的数 C为0.05-500Pa.s，b3，c3，d3和e3可以为零，α和β为0-3的整数，组分（B）为具有至少三个SiH基团的有机氢聚硅氧烷（B3） 每分子。

公开(公告)号：US08101683B2

公开(公告)日：2012-01-24

申请号：US12790269

申请日：2010-05-28

申请人： Shinji Irifune ,  Tsutomu Nakajima ,  Kenji Yamamoto

发明人： Shinji Irifune ,  Tsutomu Nakajima ,  Kenji Yamamoto

IPC分类号： C08L83/04 ,  C08J3/03

CPC分类号： C08J3/03 ,  C08G77/12 ,  C08G77/20 ,  C08J2383/04 ,  C08L83/04 ,  C08L83/00

摘要： An addition-curable silicone emulsion that exhibits stable curability even with a small amount of platinum. The curable emulsion composition is composed of an emulsion A and an emulsion B described below which are mixed together at the time of use, wherein the ratio of [number-average particle size of dispersed particles in emulsion A]/[number-average particle size of dispersed particles in emulsion B] is within a range from 0.4 to 2.0. The emulsion A comprises a specific alkenyl group-containing organopolysiloxane, a specific organohydrogenpolysiloxane, a nonionic surfactant, a polyvinyl alcohol and water, wherein the number-average particle size of the dispersed particles is within a range from 300 to 1,000 nm. The emulsion B comprises a specific alkenyl group-containing organopolysiloxane, a platinum-based complex, a nonionic surfactant, a polyvinyl alcohol and water, wherein the number-average particle size of the dispersed particles is within a range from 300 to 1,000 nm.

摘要翻译： 即使使用少量铂也显示稳定的固化性的可加成固化的硅氧烷乳液。 可固化乳液组合物由使用时混合在一起的乳液A和下述乳液B组成，其中[乳液A中分散颗粒的数均粒径] / [数均粒径 的分散颗粒在乳液B中]在0.4至2.0的范围内。 乳液A包含特定的含烯基的有机聚硅氧烷，特定的有机氢聚硅氧烷，非离子表面活性剂，聚乙烯醇和水，其中分散粒子的数均粒径在300〜1000nm的范围内。 乳液B包含特定的含烯基的有机聚硅氧烷，铂系配合物，非离子表面活性剂，聚乙烯醇和水，其中分散粒子的数均粒径在300〜1000nm的范围内。

公开(公告)号：US20100305258A1

公开(公告)日：2010-12-02

申请号：US12790269

申请日：2010-05-28

申请人： Shinji Irifune ,  Tsutomu Nakajima ,  Kenji Yamamoto

发明人： Shinji Irifune ,  Tsutomu Nakajima ,  Kenji Yamamoto

IPC分类号： C08L83/06

CPC分类号： C08J3/03 ,  C08G77/12 ,  C08G77/20 ,  C08J2383/04 ,  C08L83/04 ,  C08L83/00

摘要： An addition-curable silicone emulsion that exhibits stable curability even with a small amount of platinum. The curable emulsion composition is composed of an emulsion A and an emulsion B described below which are mixed together at the time of use, wherein the ratio of [number-average particle size of dispersed particles in emulsion A]/[number-average particle size of dispersed particles in emulsion B] is within a range from 0.4 to 2.0. The emulsion A comprises a specific alkenyl group-containing organopolysiloxane, a specific organohydrogenpolysiloxane, a nonionic surfactant, a polyvinyl alcohol and water, wherein the number-average particle size of the dispersed particles is within a range from 300 to 1,000 nm. The emulsion B comprises a specific alkenyl group-containing organopolysiloxane, a platinum-based complex, a nonionic surfactant, a polyvinyl alcohol and water, wherein the number-average particle size of the dispersed particles is within a range from 300 to 1,000 nm.

摘要翻译： 即使使用少量铂也显示稳定的固化性的可加成固化的硅氧烷乳液。 可固化乳液组合物由使用时混合在一起的乳液A和下述乳液B组成，其中[乳液A中分散颗粒的数均粒径] / [数均粒径 的分散颗粒在乳液B中]在0.4至2.0的范围内。 乳液A包含特定的含烯基的有机聚硅氧烷，特定的有机氢聚硅氧烷，非离子表面活性剂，聚乙烯醇和水，其中分散粒子的数均粒径在300〜1000nm的范围内。 乳液B包含特定的含烯基的有机聚硅氧烷，铂系配合物，非离子表面活性剂，聚乙烯醇和水，其中分散粒子的数均粒径在300〜1000nm的范围内。

公开(公告)号：US20150119518A1

公开(公告)日：2015-04-30

申请号：US14399707

申请日：2013-05-17

申请人： Kenji Yamamoto ,  Toshiaki Ihara ,  Tsutomu Nakajima

发明人： Kenji Yamamoto ,  Toshiaki Ihara ,  Tsutomu Nakajima

IPC分类号： C08L83/04

CPC分类号： C08L83/04 ,  C08G77/14 ,  C08G77/44 ,  C08L83/10 ,  C08L2201/54 ,  C08L83/00

摘要： The present invention relates to an emulsion-based high release additive for a release sheet, the additive being characterized by being obtained by dispersing in water a condensation product (A) obtained by subjecting the following to a dehydration condensation reaction: (A-1) a polydiorganosiloxane which has an average degree of polymerization of 100-300,000 and which has one or more hydroxyl groups or hydrolyzable groups per molecule; and (A-2) a polyorganosiloxane resin, which contains (SiO4/2) units and (R3SiO1/2) units (in the formulae, the R groups each represent independently a monovalent hydrocarbon group having 1-12 carbon atoms and not having an aliphatic unsaturated bond or an alkenyl group having 2-6 carbon atoms) as primary components, in which the molar ratio of (R3SiO1/2) units relative to (SiO4/2) units is 0.6-1.2 and in which the total content of hydroxyl groups and hydrolyzable groups is not lower than 2.1 mass % and lower than 10.0 mass %. The present invention can obtain a silicone cured coating film having a high release force by adding the additive to a curable composition for a release sheet such as a release paper or release film, coating the same on a variety of base materials and curing.

摘要翻译： 本发明涉及一种用于脱模片的乳液型高释放添加剂，该添加剂的特征在于通过在水中分散通过使下列物质进行脱水缩合反应获得的缩合产物（A）获得：（A-1） 聚二有机硅氧烷，其平均聚合度为100-300,000，每分子具有一个或多个羟基或可水解基团; 和（A-2）含有（SiO 4/2）单元和（R 3 SiO 1/2）单元的聚有机硅氧烷树脂（在该式中，R基各自独立地表示具有1-12个碳原子的一价烃基， 脂族不饱和键或具有2-6个碳原子的烯基）作为主要组分，其中（R 3 SiO 1/2）单元相对于（SiO 4/2）单元的摩尔比为0.6-1.2，其中羟基的总含量 基团和可水解基团不低于2.1质量％且低于10.0质量％。 本发明通过将添加剂添加到用于剥离纸或脱模膜等剥离片的固化性组合物中，可以得到具有高剥离力的硅氧烷固化涂膜，将其涂布在各种基材上并固化。

公开(公告)号：US07515450B2

公开(公告)日：2009-04-07

申请号：US11802168

申请日：2007-05-21

申请人： Tsutomu Nakajima ,  Keiichi Yoshida

发明人： Tsutomu Nakajima ,  Keiichi Yoshida

IPC分类号： G11C5/02

CPC分类号： G11C11/412 ,  G11C11/5642 ,  G11C16/26

摘要： A flash memory 1 based on the multilevel storage technology for storing the information of two or more bits is provided with four banks 2a to 2d. For example, in the left side of the bank 2a, a data latch 6a is provided along one short side of the bank 2a, while in the right side thereof, a data latch 6b is provided along the other short side of the bank 2a. At the lower side of the data latches 6a, 6b, arithmetic circuits 7a, 7b are provided. The data latches 6a, 6b are respectively formed of SRAMs. A sense latch 5a is divided to one half in the right and left directions with reference to the center of sense latch row. The divided sense latch 5a is connected with the data latches 6a, 6b via the signal lines respectively allocated along both short sides of the bank 2a.

摘要翻译： 基于用于存储两个或更多位的信息的多级存储技术的闪速存储器1具有四个存储体2a至2d。 例如，在存储体2a的左侧，沿着存储体2a的一个短边设置有数据锁存器6a，而在右侧，沿着存储体2a的另一个短边设置数据锁存器6b。 在数据锁存器6a，6b的下侧设有运算电路7a，7b。 数据锁存器6a，6b分别由SRAM形成。 感测闩锁5a相对于感测闩锁行的中心在左右方向上分为一半。 分频检测锁存器5a经由分别沿着存储体2a的两个短边分配的信号线与数据锁存器6a，6b相连。

公开(公告)号：US20080246963A1

公开(公告)日：2008-10-09

申请号：US12062871

申请日：2008-04-04

申请人： Tsutomu Nakajima

发明人： Tsutomu Nakajima

IPC分类号： G01N15/02

CPC分类号： G01N15/0205

摘要： A particle counting method is provided whereby a liquid sample is radiated by a laser light, scattered light produced by causing the laser light to hit a particle in the liquid sample is detected by a photoelectric conversion element, and a sample value which is the output of the photoelectric conversion element is sequentially compared to a threshold preset for each particle size range, thereby counting the number of particles for each particle size range, the method comprising: a timer start-up step for starting a timer of a predetermined time when the sample value becomes smaller than a threshold of a minimum particle size for the first time and for sequentially holding the maximum value of the sample value; and a timer extension step for restarting the timer to sequentially hold the maximum value of the sample value when the sample value at the time-out of the timer start-up step is larger than the threshold of the minimum particle size.

摘要翻译： 提供一种粒子计数方法，通过激光照射液体样品，通过光电转换元件检测使得激光撞击液体样品中的颗粒而产生的散射光，并将作为输出的样品值 将光电转换元件顺序地与针对每个粒度范围预设的阈值进行比较，从而对每个粒度范围的粒子数进行计数，该方法包括：定时器启动步骤，用于在样本 值变得小于第一次的最小粒径的阈值，并且顺序地保持样本值的最大值; 以及定时器延长步骤，用于当所述定时器启动步骤超时时的所述采样值大于所述最小粒度的阈值时，重新启动所述定时器以顺序保持所述采样值的最大值。

公开(公告)号：US20080002480A1

公开(公告)日：2008-01-03

申请号：US11896912

申请日：2007-09-06

申请人： Tsutomu Nakajima ,  Satoshi Noda ,  Kenji Kozakai ,  Atsushi Tokairin

发明人： Tsutomu Nakajima ,  Satoshi Noda ,  Kenji Kozakai ,  Atsushi Tokairin

IPC分类号： G11C7/10

CPC分类号： G11C29/84 ,  G11C29/82

摘要： A nonvolatile memory apparatus which need not compare an access address with a faulty address every time for rescuing from any fault is to be provided. The apparatus has memory arrays, data registers for inputting and outputting data to and from the memory arrays, and control circuits. The control circuits, after transferring a plurality of sets of data from the memory arrays to the data registers in response to an instruction to read data, take out rescuing data out of the plurality of sets of data transferred to the data registers, and perform processing to replace with the taken-out rescuing data corresponding faulty addresses on the data register to enable the data on the data register to be supplied to the outside. When any faulty data in the read data are to be replaced with rescuing data on any data register to which data have been transferred from any memory array, read access addresses need not be checked whether or not they are faulty every time an access address is supplied from outside.

摘要翻译： 提供不需要每次对任何故障进行抢救的访问地址与故障地址进行比较的非易失性存储装置。 该装置具有存储器阵列，用于向存储器阵列输入数据和从存储器阵列输出数据的数据寄存器以及控制电路。 控制电路在响应于读取数据的指令将多组数据从存储器阵列传送到数据寄存器之后，从传送到数据寄存器的多组数据中取出拯救数据，并执行处理 取代数据寄存器上相应的故障地址的取出救援数据，使数据寄存器上的数据能够提供给外部。 当数据从任何存储器阵列传送到任何数据寄存器上时，读取数据中的任何有故障的数据将被替换为数据寄存器中的数据，每次提供访问地址时，不需要检查读取访问地址是否有故障 从外面。